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公开(公告)号：US4964870A
公开(公告)日：1990-10-23
申请号：US366192
申请日：1989-06-08
申请人： Ronald A. Fong , Stephen B. Kong
发明人： Ronald A. Fong , Stephen B. Kong
IPC分类号： C07C409/24 , C07C409/26 , C11D3/39
CPC分类号： C11D3/3907
摘要： The invention provides novel peracid precursors representative of which is the structure: ##STR1## wherein R.sup.1 is alkyl of 1 to 20 carbon atoms; R.sup.2 is OH, --O--R.sup.3, or ##STR2## and X.sup.1, X.sup.2, Y and Z are individually selected from H, SO.sub.3.sup.--, CO.sub.2.sup.--, NO.sub.2, NR.sub.4.sup.5+, halogen, R.sup.6 and mixtures thereof;wherein R.sup.3 of --O--R.sup.3 is alkyl of 1 to 20 carbon atoms; R.sup.4 of ##STR3## is alkyl of 1 to 20 carbon atoms; R.sup.5 of NR.sub.4.sup.5+ is selected from H, alkyl of 1 to 24 carbon atoms and mixtures thereof; and R.sup.6 is alkyl of 1 to 20 carbon atoms.In one embodiment of the invention, the novel peracid precursors are combined with a source of hydrogen peroxide and sufficient quantities of buffer to impact an alkaline pH when the composition is placed in aqueous solution. Preferred embodiments of the invention include wherein R.sup.2 is hydroxy, and R.sup.1 is alkyl of 1 to 20 carbon atoms (monoester); and wherein R.sup.2 is ##STR4## and R.sup.1 and R.sup.4 are alkyls of 1 to 20 carbon atoms (diester) and may be either symmetrical (i.e., R.sup.1 =R.sup.4) or mixed (i.e., R.sup.1 .noteq.R.sup.4). The mixed diester embodiment appears to provide benefits of mixed hydrophobic/hydrophilic peracid generation to oxidize both hydrophobic and hydrophilic soils. Various detergent adjuncts known to those skilled in the art may be added, such as surfactants, builders, fragrances, antimicrobial compounds and the like.
摘要翻译： 本发明提供新的过酸前体，其代表的结构是：其中R 1是1至20个碳原子的烷基; R 2是OH，-O-R 3或者X 3，X 1，X 2，Y和Z分别选自H，SO 3 - ，CO 2 - ，NO 2，NR 45 +，卤素，R 6及其混合物; 其中-O-R 3的R 3为1至20个碳原子的烷基;
的R4是1〜20个碳原子的烷基; NR45 +的R5选自H，1至24个碳原子的烷基及其混合物; R6为1〜20个碳原子的烷基。 在本发明的一个实施方案中，当将组合物置于水溶液中时，新型过酸前体与过氧化氢源和足够量的缓冲液组合以冲击碱性pH。 本发明的优选实施方案包括其中R 2为羟基，R 1为1至20个碳原子的烷基（单酯）; 并且其中R 2是R 1和R 4是具有1至20个碳原子的烷基（二酯），并且可以是对称的（即R1 = R4）或混合的（即，R 1等式R 4）。 混合二酯实施方案似乎提供混合的疏水/亲水过酸产生的优点，以氧化疏水性和亲水性的土壤。 可以加入本领域技术人员已知的各种洗涤助剂，例如表面活性剂，助洗剂，香料，抗微生物化合物等。 -
2.发明授权Antimicrobial hard surface cleaner comprising an ethoxylated quaternary ammonium surfactant 有权包含乙氧基化季铵表面活性剂的抗微生物硬表面清洁剂公开(公告)号：US06605584B2
公开(公告)日：2003-08-12
申请号：US09849660
申请日：2001-05-04
申请人： Ronald A. Fong , Stephen B. Kong , David Peterson
发明人： Ronald A. Fong , Stephen B. Kong , David Peterson
IPC分类号： C11D1835
摘要： The invention provides a, non- or minimized streaking/filming antimicrobial formulation, the cleaner containing: a. an akoxylated quaternary ammonium surfactant, present in a cleaning-effective amount; b. an alkoxylated short chain nonionic surfactant, also present in a cleaning-effective amount; c. alkanolamine as an alkalinity source, present in an amount effective to enhance soil removal in said cleaner; d. a quaternary ammonium compound in an amount present for antimicrobial efficacy; e. at least one water-soluble or dispersible organic solvent having a vapor pressure of at least 0.001 mm Hg at 25° C., said at least one organic solvent present in a solubilizing—or dispersion—effective amount; and f. the remainder, water.
摘要翻译： 本发明提供一种非或最小条纹/成膜抗微生物制剂，该清洁剂包含：a。 以清洁有效量存在的烷氧基化季铵表面活性剂; b。 也是存在于清洁有效量的烷氧基化短链非离子表面活性剂; c。 链烷醇胺作为碱度来源，以有效增强所述清洁剂中去除污垢的量存在; d。 以抗菌功效存在的季铵化合物; e。 至少一种在25℃下蒸气压至少为0.001mm Hg的水溶性或分散性有机溶剂，所述至少一种有机溶剂以增溶或分散有效量存在; 和。 剩下的，水。
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3.发明授权Composition and method for fabric encrustation prevention comprising a lignin derivative 失效包含木质素衍生物的织物结垢预防的组合物和方法
公开(公告)号：US5104584A
公开(公告)日：1992-04-14
申请号：US542240
申请日：1990-06-22
申请人： Stephen B. Kong
发明人： Stephen B. Kong
CPC分类号： C11D3/0036 , C11D1/30 , C11D3/10
摘要： Cleaning composition and method comprising in a first embodiment an alkali metal carbonate builder and a fabric encrustation prevention system comprising a substoichiometric level of lignosulfonic acid or its salts and esters which acts to inhibit and prevent the deposition of insoluble precipitates containing water hardness ions on fabrics; in a second embodiment the cleaning composition includes a detersive surfactant for laundry applications; in either embodiment the following adjuncts may be included: co-builders, alkali metal silicates, bleaching species, enzymes, fragrances, dyes, brighteners and others.
摘要翻译： 在第一实施方案中，包括碱金属碳酸盐助洗剂和织物结垢防止体系的清洁组合物和方法包括亚化学计量级木质素磺酸或其盐和酯，其用于抑制和防止在织物上含有水硬度离子的不溶性沉淀物的沉积; 在第二实施方案中，清洁组合物包括用于洗衣应用的去污表面活性剂; 在任一实施方案中，可以包括以下助剂：助洗剂，碱金属硅酸盐，漂白物质，酶，香料，染料，增白剂等。
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公开(公告)号：US5639722A
公开(公告)日：1997-06-17
申请号：US379010
申请日：1995-01-27
申请人： Stephen B. Kong , Robert L. Blum
发明人： Stephen B. Kong , Robert L. Blum
IPC分类号： C02F5/08 , C11D1/24 , C11D1/62 , C11D1/65 , C11D3/20 , C11D3/34 , C11D7/08 , C11D17/00 , C11D3/02 , B08B3/00 , C11D3/39
CPC分类号： C11D17/003 , C02F5/08 , C11D1/62 , C11D1/65 , C11D3/2079 , C11D3/2082 , C11D3/2086 , C11D3/3418 , C11D7/08 , C11D1/24
摘要： A thickened, buffered aqueous acidic cleaning composition suitable for removing mineral deposits is provided. In one embodiment, the composition comprises a weak acid and its conjugate base wherein the weak acid has a pK.sub.a of approximately 2 to 3.5 and where the composition has a pH of approximately 2 to 3.5. Organic acids, such as citric acid, are particularly suited. The addition of a thickening system comprising cetyl trimethyl ammonium chloride and sodium xylene sulfonate or alkyl diphenylether sulfonate produces a viscoelastic composition in which the viscosity can be controlled by the level and/or ratio of the surfactant/counterion. Suitable stable adjuncts including fragrances, dyes, organic solvents, disinfectants, and bleaches can be added to the composition.
摘要翻译： 提供了适用于去除矿物沉积物的增稠缓冲的含水酸性清洁组合物。 在一个实施方案中，组合物包含弱酸及其共轭碱，其中弱酸的pKa为约2至3.5，并且组合物的pH为约2至3.5。 有机酸，如柠檬酸，特别适合。 加入包含十六烷基三甲基氯化铵和二甲苯磺酸钠或烷基二苯基醚磺酸盐的增稠体系产生粘弹性组合物，其中粘度可以通过表面活性剂/抗衡离子的水平和/或比例来控制。 可以将合适的稳定助剂，包括香料，染料，有机溶剂，消毒剂和漂白剂加入到组合物中。
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5.发明授权
公开(公告)号：US5505740A
公开(公告)日：1996-04-09
申请号：US119506
申请日：1993-09-09
IPC分类号： C11D7/54 , C11D3/39 , D06L3/02 , D06M13/02 , D06M13/165 , D06M13/224 , D06M13/244 , D06M13/248 , D06M13/262 , D06M13/322 , D06M13/46 , C01B3/00 , C01B15/04
CPC分类号： C11D17/0039 , C11D3/0047 , C11D3/2075 , C11D3/3907 , D06L3/021
摘要： A bleaching product and a method of removing soils from fabrics by contacting the fabrics in an aqueous wash solution with a product comprising a peracid precursor, a source of hydrogen peroxide and a source for delayed release of an acid into the wash solution to initially permit effective in situ formation of peracid, the acid thereafter reducing the pH of the wash solution for enhancing bleach performance of the peracid. The source of the acid may be included in the bleaching product, for example, as an acid of delayed solubility, an acid coated with a low solubility agent or an acid generating species, or independent of the bleaching product. The acid source is selected to be compatible with the peracid or precursor and adjuncts. The method for removing soils thus comprises contacting the fabrics in an aqeuous solution with a peracid precursor and a source of hydrogen peroxide, initially raising the pH of the solution for effective in situ formation of peracid and then reducing the pH for enhancing bleach performance of the peracid.
摘要翻译： 一种漂白产品和一种通过使水洗涤溶液中的织物与包含过酸前体，过氧化氢源和用于将酸延迟释放到洗涤溶液中的来源的产品接触织物的方法，以最初允许有效 原位形成过酸，此后酸降低洗涤溶液的pH，以增强过酸的漂白性能。 酸的来源可以包括在漂白产品中，例如作为延迟溶解的酸，涂覆有低溶解剂或产酸物质的酸，或独立于漂白产物。 酸源被选择为与过酸或前体和辅助剂相容。 因此，用于去除污垢的方法包括使织物在过饱和溶液中与过酸前体和过氧化氢源接触，最初提高溶液的pH以有效地原位形成过酸，然后降低pH以提高漂白剂的漂白性能 过酸
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公开(公告)号：US5412958A
公开(公告)日：1995-05-09
申请号：US162563
申请日：1993-12-06
CPC分类号： D06F43/007 , B08B7/0021 , D06F43/02 , D06F43/08
摘要： A dry cleaning system particularly suited for employing supercritical CO.sub.2 as the cleaning fluid consisting of a sealable cleaning vessel containing a rotatable drum adapted for holding soiled substrate, a cleaning fluid storage vessel, and a gas vaporizer vessel for recycling used cleaning fluid is provided. The drum is magnetically coupled to a motor so that it can be rotated during the cleaning process. The system is adapted for automation which permits increased energy efficiency as the heating and cooling effect associated with CO.sub.2 gas condensation and expansion can be channeled to heat and cool various parts of the system.
摘要翻译： 提供了一种特别适用于采用超临界CO2作为清洗液的干洗系统，该清洗流体由可密封的清洁容器组成，该清洁容器包含适于容纳污染的基底的可旋转滚筒，清洁液储存容器和用于再循环使用的清洁流体的气体蒸发器容器。 滚筒磁耦合到电机，使其可以在清洁过程中旋转。 该系统适用于自动化，其允许提高能量效率，因为可以将与CO 2气体冷凝和膨胀相关联的加热和冷却效果引导以加热和冷却系统的各个部件。
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公开(公告)号：US5370742A
公开(公告)日：1994-12-06
申请号：US912933
申请日：1992-07-13
CPC分类号： C11D11/0064 , B08B7/0021 , D06F43/007
摘要： The invention provides a cleaning method in which a solvent such as densified carbon dioxide can be used for rapid and efficient cleaning, but with decreased damage to solid components such as buttons. The method comprises contacting a substrate to be cleaned with a first fluid, removing the first fluid from contact with the substrate while replacing with a second fluid, and recovering the substrate substantially free of the first and second fluids and from the contaminant. The first fluid is a densified gas while the second fluid is a compressed gas. A preferred embodiment of the method includes the use of a pretreatment designed for compatibility with the densified first fluid.
摘要翻译： 本发明提供了一种清洁方法，其中诸如致密二氧化碳的溶剂可以用于快速和有效的清洁，但是对固体组分如按钮的损害减少。 该方法包括使要清洗的基底与第一流体接触，在用第二流体替换的同时，将第一流体与基底相接触，并且基本上不含第一流体和第二流体以及从污染物回收基底。 第一流体是致密气体，而第二流体是压缩气体。 该方法的优选实施方案包括使用设计用于与致密化的第一流体相容的预处理。
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公开(公告)号：US4655781A
公开(公告)日：1987-04-07
申请号：US626825
申请日：1984-07-02
CPC分类号： C11D3/3937 , C11D3/3945 , C11D3/3947
摘要： This invention provides stable peroxyacid bleaching compositions comprising:(a) a surface active peroxyacid, and(b) at least one surfactant which forms a mixed micelle in aqueous solution with said peroxyacid;wherein said aqueous solution contains a detergent concentration of about 0.1 to 3.0 grams/liter.Buffers and other typical cleaning adjuncts known to those skilled in the art may be included.The invention also provides a method of stabilizing the decomposition rate of surface active peroxyacids.
摘要翻译： 本发明提供了稳定的过氧酸漂白组合物，其包含：（a）表面活性过氧酸，和（b）至少一种与所述过氧酸在水溶液中形成混合胶束的表面活性剂; 其中所述水溶液含有约0.1-3.0克/升的洗涤剂浓度。 可以包括本领域技术人员已知的缓冲液和其它典型的清洁助剂。 本发明还提供了稳定表面活性过氧酸的分解速率的方法。
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