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公开(公告)号：US06987152B1
公开(公告)日：2006-01-17
申请号：US11143906
申请日：2005-06-02
IPC分类号： C07C7/00
CPC分类号： C08F210/16 , C08F2/34 , C08F210/14 , C08F2500/12 , C08F2500/07
摘要： A method for olefin polymerization is provided. A feed stream comprising more than 0.1 ppm by volume of oxygen and 0.3 ppm by volume of water is passed through a first packed bed to selectively remove at least a portion of the oxygen. The feed stream is then passed through a second packed bed to selectively remove at least a portion of the water, providing a purified feed stream comprising less than 0.1 ppm by volume of oxygen and 0.3 ppm by volume of water. Both the first and second packed beds operate at a temperature of from about 0° C. to about 50° C. The purified feed stream is then passed to a polymerization reactor.
摘要翻译： 提供了一种烯烃聚合方法。 包含大于0.1ppm体积的氧气和0.3ppm体积的水的进料流通过第一填充床以选择性地除去至少一部分氧气。 然后将进料流通过第二填充床以选择性地除去至少一部分水，提供包含少于0.1ppm体积的氧和0.3ppm体积的水的纯化进料流。 第一和第二填充床都在约0℃至约50℃的温度下操作。然后将纯化的进料流送入聚合反应器。
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公开(公告)号：US06540165B1
公开(公告)日：2003-04-01
申请号：US09404746
申请日：1999-09-24
IPC分类号： B02C100
摘要： A process comprising the steps of: (1) pressurizing a particulate material in bead or pellet form in a vessel to an elevated pressure with a first gas, (2) reducing the particulate material under the elevated pressure to a fine consistency, (3) conveying the fine consistency particulate material into a receiving vessel.
摘要翻译： 一种方法，包括以下步骤：（1）用容器中的珠粒或颗粒形式的颗粒材料用第一气体加压至高压，（2）在升高的压力下将颗粒材料还原成细的稠度，（3） 将细密度颗粒材料输送到接收容器中。
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3.发明授权Processes for the polymerization of olefins with extracted metal carboxylate salts 有权用提取的金属羧酸盐进行烯烃聚合的方法公开(公告)号：US08742041B2
公开(公告)日：2014-06-03
申请号：US13988956
申请日：2011-11-10
申请人： R. Eric Pequeno , Fathi David Hussein , Kevin Joseph Cann , Chi-I Kuo , Bruce Jon Savatsky , Eric J. Markel , Daniel Paul Zilker, Jr. , Agapios Kyriacos Agapiou , David M. Glowczwski
发明人： R. Eric Pequeno , Fathi David Hussein , Kevin Joseph Cann , Chi-I Kuo , Bruce Jon Savatsky , Eric J. Markel , Daniel Paul Zilker, Jr. , Agapios Kyriacos Agapiou , David M. Glowczwski
CPC分类号： C08F4/642 , C08F4/602 , C08F4/6428 , C08F4/646 , C08F4/65904 , C08F4/65916 , C08F4/6592 , C08F4/65925 , C08F4/65927 , C08F10/00 , C08F210/16 , C08F2410/01 , C08F2410/02 , Y10S526/943 , C08F4/652 , C08F4/65912 , C08F4/655 , C08F2/002 , C08F210/14 , C08F2500/12 , C08F2500/08 , C08F2500/18
摘要： Processes for the polymerization of olefins with extracted metal carboxylate salts are provided. The polymerization processes have increased productivity and/or increased resin bulk density.
摘要翻译： 提供了用提取的金属羧酸盐进行烯烃聚合的方法。 聚合方法具有提高的生产率和/或增加的树脂堆积密度。
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4.发明申请公开(公告)号：US20130253153A1
公开(公告)日：2013-09-26
申请号：US13988956
申请日：2011-11-10
申请人： R. Eric Pequeno , Fathi David Hussein , Kevin Joseph Cann , Chi-I Kuo , Bruce Jon Savatsky , Eric J. Markel , Daniel Paul Zilker, Jr. , Agapios Kyriacos Agapiou , David M. Glowczwski
发明人： R. Eric Pequeno , Fathi David Hussein , Kevin Joseph Cann , Chi-I Kuo , Bruce Jon Savatsky , Eric J. Markel , Daniel Paul Zilker, Jr. , Agapios Kyriacos Agapiou , David M. Glowczwski
IPC分类号： C08F4/6592
CPC分类号： C08F4/642 , C08F4/602 , C08F4/6428 , C08F4/646 , C08F4/65904 , C08F4/65916 , C08F4/6592 , C08F4/65925 , C08F4/65927 , C08F10/00 , C08F210/16 , C08F2410/01 , C08F2410/02 , Y10S526/943 , C08F4/652 , C08F4/65912 , C08F4/655 , C08F2/002 , C08F210/14 , C08F2500/12 , C08F2500/08 , C08F2500/18
摘要： Processes for the polymerization of olefins with extracted metal carboxylate salts are provided. The polymerization processes have increased productivity and/or increased resin bulk density.
摘要翻译： 提供了用提取的金属羧酸盐进行烯烃聚合的方法。 聚合方法具有提高的生产率和/或增加的树脂堆积密度。
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公开(公告)号：US08420754B2
公开(公告)日：2013-04-16
申请号：US12944498
申请日：2010-11-11
申请人： Kevin J Cann , Minghui Zhang , Jose Fernando Cevallos-Candau , John Moorhouse , Mark Gregory Goode , Daniel Paul Zilker, Jr. , Maria Apecetche
发明人： Kevin J Cann , Minghui Zhang , Jose Fernando Cevallos-Candau , John Moorhouse , Mark Gregory Goode , Daniel Paul Zilker, Jr. , Maria Apecetche
CPC分类号： C08F10/00 , B01J21/08 , B01J31/0212 , B01J31/122 , B01J31/128 , B01J31/143 , B01J31/34 , B01J35/1019 , B01J35/1023 , B01J35/1047 , C08F110/02 , C08F210/16 , Y02P20/52 , Y10S526/901 , C08F4/69 , C08F2500/12 , C08F2500/18 , C08F2500/04 , C08F2500/10 , C08F210/14 , C08F4/025
摘要： The present invention is directed to the use of aluminum alkyl activators and co-catalysts to improve the performance of chromium-based catalysts. The aluminum alkyls allow for the variable control of polymer molecular weight, control of side branching while possessing desirable productivities, and may be applied to the catalyst directly or separately to the reactor. Adding the alkyl aluminum compound directly to the reactor (in-situ) eliminates induction times.
摘要翻译： 本发明涉及使用烷基铝活化剂和助催化剂来改进铬基催化剂的性能。 烷基铝允许聚合物分子量的可变控制，侧分枝的控制，同时具有所需的生产率，并且可以直接或分别地施加到催化剂到反应器。 将烷基铝化合物直接加入反应器（原位）消除了诱导时间。
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公开(公告)号：US07504463B2
公开(公告)日：2009-03-17
申请号：US11202309
申请日：2005-08-11
申请人： Kevin J Cann , Minghui Zhang , Jose Fernando Cevallos-Candau , John Moorhouse , Mark Gregory Goode , Daniel Paul Zilker, Jr. , Maria Apecetche
发明人： Kevin J Cann , Minghui Zhang , Jose Fernando Cevallos-Candau , John Moorhouse , Mark Gregory Goode , Daniel Paul Zilker, Jr. , Maria Apecetche
CPC分类号： C08F10/00 , B01J21/08 , B01J31/0212 , B01J31/122 , B01J31/128 , B01J31/143 , B01J31/34 , B01J35/1019 , B01J35/1023 , B01J35/1047 , C08F110/02 , C08F210/16 , Y02P20/52 , Y10S526/901 , C08F4/69 , C08F2500/12 , C08F2500/18 , C08F2500/04 , C08F2500/10 , C08F210/14 , C08F4/025
摘要： The present invention is directed to the use of aluminum alkyl activators and co-catalysts to improve the performance of chromium-based catalysts. The aluminum alkyls allow for the variable control of polymer molecular weight, control of side branching while possessing desirable productivities, and may be applied to the catalyst directly or separately to the reactor. Adding the alkyl aluminum compound directly to the reactor (in-situ) eliminates induction times.
摘要翻译： 本发明涉及使用烷基铝活化剂和助催化剂来改进铬基催化剂的性能。 烷基铝允许聚合物分子量的可变控制，侧分枝的控制，同时具有所需的生产率，并且可以直接或分别地施加到催化剂到反应器。 将烷基铝化合物直接加入反应器（原位）消除了诱导时间。
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7.发明授权Supported chromium oxide catalyst for the production of broad molecular weight polyethylene 有权用于生产宽分子量聚乙烯的负载型氧化铬催化剂公开(公告)号：US06989344B2
公开(公告)日：2006-01-24
申请号：US10716291
申请日：2003-11-18
申请人： Kevin J. Cann , Minghui Zhang , Jose Fernando Cevallos-Candau , John Moorhouse , Mark Gregory Goode , Daniel Paul Zilker, Jr. , Maria Apecetche
发明人： Kevin J. Cann , Minghui Zhang , Jose Fernando Cevallos-Candau , John Moorhouse , Mark Gregory Goode , Daniel Paul Zilker, Jr. , Maria Apecetche
IPC分类号： B01J31/00
CPC分类号： C08F10/00 , B01J21/08 , B01J31/0212 , B01J31/122 , B01J31/128 , B01J31/143 , B01J31/34 , B01J35/1019 , B01J35/1023 , B01J35/1047 , C08F110/02 , C08F210/16 , Y02P20/52 , Y10S526/901 , C08F4/69 , C08F2500/12 , C08F2500/18 , C08F2500/04 , C08F2500/10 , C08F210/14 , C08F4/025
摘要： The present invention is directed to the use of aluminum alkyl activators and co-catalysts to improve the performance of chromium-based catalysts. The aluminum alkyls allow for the variable control of polymer molecular weight, control of side branching while possessing desirable productivities, and may be applied to the catalyst directly or separately to the reactor. Adding the alkyl aluminum compound directly to the reactor (in-situ) eliminates induction times.
摘要翻译： 本发明涉及使用烷基铝活化剂和助催化剂来改进铬基催化剂的性能。 烷基铝允许聚合物分子量的可变控制，侧分枝的控制，同时具有所需的生产率，并且可以直接或分别地施加到催化剂到反应器。 将烷基铝化合物直接加入反应器（原位）消除了诱导时间。
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公开(公告)号：US07634937B2
公开(公告)日：2009-12-22
申请号：US11296597
申请日：2005-12-06
CPC分类号： F27D19/00 , B01J8/1809 , B01J2208/00274 , B01J2219/002 , B01J2219/00247 , B01J2219/00254 , C08F10/00 , C08F2400/02 , F27B15/20 , F27D21/00 , G01N2291/0427 , C08F2/00 , C08F2/34
摘要： Particle and multi-phase system monitoring methods, systems and apparatus are disclosed. Preferred embodiments comprise one or more mechanical resonator sensing elements. In preferred embodiments a sensor or a sensor subassembly is ported to a fluidized bed vessel such as a fluidized bed polymerization reactor.
摘要翻译： 公开了粒子和多相系统监测方法，系统和装置。 优选实施例包括一个或多个机械谐振器感测元件。 在优选实施例中，传感器或传感器子组件移入流化床容器，例如流化床聚合反应器。
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公开(公告)号：US07563851B2
公开(公告)日：2009-07-21
申请号：US11202311
申请日：2005-08-11
申请人： Kevin J Cann , Minghui Zhang , Jose Fernando Cevallos-Candau , John Moorhouse , Mark Gregory Goode , Daniel Paul Zilker, Jr. , Maria Apecetche
发明人： Kevin J Cann , Minghui Zhang , Jose Fernando Cevallos-Candau , John Moorhouse , Mark Gregory Goode , Daniel Paul Zilker, Jr. , Maria Apecetche
CPC分类号： C08F10/00 , B01J21/08 , B01J31/0212 , B01J31/122 , B01J31/128 , B01J31/143 , B01J31/34 , B01J35/1019 , B01J35/1023 , B01J35/1047 , C08F110/02 , C08F210/16 , Y02P20/52 , Y10S526/901 , C08F4/69 , C08F2500/12 , C08F2500/18 , C08F2500/04 , C08F2500/10 , C08F210/14 , C08F4/025
摘要： The present invention is directed to the use of aluminum alkyl activators and co-catalysts to improve the performance of chromium-based catalysts. The aluminum alkyls allow for the variable control of polymer molecular weight, control of side branching while possessing desirable productivities, and may be applied to the catalyst directly or separately to the reactor. Adding the alkyl aluminum compound directly to the reactor (in-situ) eliminates induction times.
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10.发明授权公开(公告)号：US06592827B1
公开(公告)日：2003-07-15
申请号：US09694852
申请日：2000-10-24
IPC分类号： G05D1600
CPC分类号： B01J8/1809 , B01J2208/00964 , B01J2208/00973 , B01J2208/00982 , B01J2219/00191 , B01J2219/002 , C08F10/00 , C08F2400/02 , G01N1/2247 , G01N2001/105 , G01N2001/2014 , G01N2001/2071 , G01N2001/2238 , C08F2/34 , C08F2/00
摘要： There is provided an automated sampling system for taking polymer samples from a fluidized bed, gas phase reaction system which utilizes at least one volatile, hazardous monomer. The sampling system provides minimal sample-to-sample variability, improved reactor control and polymerization operability which minimizing potential exposure or release of the volatile, hazardous monomers.
摘要翻译： 提供了一种用于从流化床获取聚合物样品的自动采样系统，其利用至少一种挥发性有害单体的气相反应系统。 采样系统提供最小的样品与样品的变异性，改进的反应器控制和聚合操作性，从而最大限度地减少挥发性有害单体的潜在暴露或释放。
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