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    Catalyst compositions comprising small silica support materials and methods of use in polymerization reactions
    1.
    发明申请
    Catalyst compositions comprising small silica support materials and methods of use in polymerization reactions 有权
    包含小二氧化硅载体材料的催化剂组合物和在聚合反应中使用的方法

    公开(公告)号：US20060281880A1

    公开(公告)日：2006-12-14

    申请号：US11441505

    申请日：2006-05-26

    申请人： Maria Apecetche ,  Phuong Cao ,  Michael Awe ,  Ann Schoeb-Wolters ,  Ryan Impelman

    发明人： Maria Apecetche ,  Phuong Cao ,  Michael Awe ,  Ann Schoeb-Wolters ,  Ryan Impelman

    IPC分类号： C08F4/44 ,  B01J31/00

    CPC分类号： C08F210/16 ,  C08F10/00 ,  C08F2/34 ,  C08F4/025 ,  C08F4/6543 ,  C08F4/651 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/18

    摘要： Improved catalyst compositions, and polymerization processes using such improved catalyst compositions, are provided. An example of an improved catalyst composition is a supported catalyst system that includes at least one titanium compound, at least one magnesium compound, at least one electron donor compound, at least one activator compound, and at least one silica support material, the at least one silica support material having a median particle size in the range of from 20 to 50 microns with no more than 10% of the particles having a size less than 10 microns and no more than 10% of the particles having a size greater than 50 microns and average pore diameter of at least

    摘要翻译： 提供改进的催化剂组合物和使用这种改进的催化剂组合物的聚合方法。 改进的催化剂组合物的实例是载体催化剂体系，其包括至少一种钛化合物，至少一种镁化合物，至少一种电子给体化合物，至少一种活化剂化合物和至少一种二氧化硅载体材料，至少 一种二氧化硅载体材料，其中值粒度在20至50微米的范围内，不超过10％的具有小于10微米尺寸的颗粒和不超过10％的尺寸大于50微米的颗粒 平均孔径至少<220埃。

    Blow molding polyethylene resins
    6.
    发明申请
    Blow molding polyethylene resins 审中-公开
    吹塑聚乙烯树脂

    公开(公告)号：US20070027276A1

    公开(公告)日：2007-02-01

    申请号：US11190481

    申请日：2005-07-27

    申请人： Kevin Cann ,  Ronald Eisinger ,  Mark Goode ,  John Moorehouse ,  Cliff Mure ,  Stephen Jaker ,  Maria Apecetche

    发明人： Kevin Cann ,  Ronald Eisinger ,  Mark Goode ,  John Moorehouse ,  Cliff Mure ,  Stephen Jaker ,  Maria Apecetche

    IPC分类号： C08F4/06

    CPC分类号： C08F210/16 ,  C08F2/34 ,  C08F4/24 ,  C08F210/08 ,  C08F2500/14 ,  C08F2500/13 ,  C08F2500/12 ,  C08F2500/04 ,  C08F210/14

    摘要： Disclosed herein are various processes, including continuous fluidized-bed gas-phase polymerization processes for making a high strength, high density polyethylene copolymer, comprising (including): contacting monomers that include ethylene and optionally at least one non-ethylene monomer with fluidized catalyst particles in a gas phase in the presence of hydrogen gas at an ethylene partial pressure of 100 psi or more and a polymerization temperature of 105° C. or less to produce a polyethylene copolymer having a density of 0.945 g/cc or more and an ESCR Index of 1.0 or more wherein the catalyst particles are prepared at an activation temperature of 700° C. or less, and include silica, chromium, and titanium.

    摘要翻译： 本文公开了各种方法，包括用于制备高强度，高密度聚乙烯共聚物的连续流化床气相聚合方法，包括（包括）：使包含乙烯和任选的至少一种非乙烯单体的单体与流化催化剂颗粒接触 在气相存在下，在乙烯分压为100psi以上且聚合温度为105℃以下的氢气存在下，生成密度为0.945g / cc以上的聚乙烯共聚物和ESCR指数 为1.0以上，其中催化剂颗粒在700℃或更低的活化温度下制备，并且包括二氧化硅，铬和钛。

    Hindered polyalicyclic alkyl catalysts and their use in a gas-phase polymerization reactor
    9.
    发明申请
    Hindered polyalicyclic alkyl catalysts and their use in a gas-phase polymerization reactor 有权
    受阻的多环脂族烷基催化剂及其在气相聚合反应器中的应用

    公开(公告)号：US20060128908A1

    公开(公告)日：2006-06-15

    申请号：US11249193

    申请日：2005-10-13

    申请人： Maria Apecetche ,  John Moorhouse ,  Mark Goode ,  Ronald Eisinger ,  Kevin Cann

    发明人： Maria Apecetche ,  John Moorhouse ,  Mark Goode ,  Ronald Eisinger ,  Kevin Cann

    IPC分类号： C08F2/00

    CPC分类号： C08F10/00 ,  C08F10/02 ,  C08F110/02 ,  C08F210/16 ,  C08F4/69 ,  C08F4/22 ,  C08F2500/12 ,  C08F2500/18 ,  C08F210/14 ,  C08F4/025

    摘要： Embodiments of the present invention include a method of polymerizing olefins comprising contacting olefins with a catalyst composition made by the process of combining a hindered polyalicyclic alkyl catalyst precursor with a particulate inorganic oxide for a deposition time greater than 2 hours to form a catalyst composition. Embodiments of the present invention also include catalyst compositions comprising a hindered polyalicyclic alkyl catalyst precursor made by the process of combining the hindered polyalicyclic alkyl catalyst precursor with a particulate inorganic oxide for a deposition time greater than 2 hours to form the catalyst composition. In one embodiment, the hindered polyalicyclic alkyl catalyst precursor is formed by first combining an acid, a compound having the formula RX, and a metal oxide selected from the group consisting of Group 3 to Group 10 oxide compounds to produce a catalyst precursor; characterized in that R is selected from the group consisting of hindered polyalicyclic alkyls, and substituted derivatives thereof, and X is selected from the group consisting of any suitable leaving group.

    摘要翻译： 本发明的实施方案包括使烯烃聚合的方法，其包括使烯烃与通过将受阻多环脂族烷基催化剂前体与颗粒无机氧化物结合沉积时间大于2小时的方法制备的催化剂组合物形成催化剂组合物。 本发明的实施方案还包括催化剂组合物，其包含通过将受阻多环脂族烷基催化剂前体与颗粒无机氧化物结合沉积时间大于2小时的方法制备的受阻多环脂族烷基催化剂前体，以形成催化剂组合物。 在一个实施方案中，受阻多环脂族烷基催化剂前体通过首先组合酸，具有式RX的化合物和选自第3族至第10族氧化物化合物的金属氧化物以形成催化剂前体而形成; 其特征在于R选自受阻多环脂族烷基及其取代衍生物，X选自任何合适的离去基团。