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    Process for the production of high molecular weight polychloroprene and its use as a starting material for adhesives
    1.
    发明授权
    Process for the production of high molecular weight polychloroprene and its use as a starting material for adhesives 失效
    用于生产高分子量聚氯丁二烯的方法及其用作粘合剂的起始材料

    公开(公告)号：US4405742A

    公开(公告)日：1983-09-20

    申请号：US280018

    申请日：1981-06-30

    申请人： Rudiger Musch ,  Rudiger Schubart ,  Wilhelm Gobel ,  Heinrich Alberts ,  Gerhard Hohmann

    发明人： Rudiger Musch ,  Rudiger Schubart ,  Wilhelm Gobel ,  Heinrich Alberts ,  Gerhard Hohmann

    IPC分类号： C08F36/18 ,  C09J3/12 ,  C08F2/24 ,  C08F2/38

    CPC分类号： C08F36/18

    摘要： By adding substances corresponding to the following general formula I ##STR1## in which X=O, S or N--R.sub.5 ; R.sub.1 =hydrogen, C.sub.1 -C.sub.19 -alkyl, C.sub.2 -C.sub.19 -alkenyl, phenyl, C.sub.1 -C.sub.4 -alkylene phenyl, C.sub.5 -C.sub.12 -cycloalkyl or C.sub.5 -C.sub.12 -cycloalkenyl; R.sub.2 =hydrogen, C.sub.1 -C.sub.19 -alkyl, C.sub.2 -C.sub.12 -alkenyl, phenyl or C.sub.1 -C.sub.4 -alkylene phenyl; R.sub.3 =hydrogen, C.sub.1 -C.sub.19 -alkyl, C.sub.2 -C.sub.19 -alkenyl, phenyl, C.sub.1 -C.sub.4 -alkylene phenyl, acryl formyl or acetyl; R.sub.4 and R.sub.5 =same or different, C.sub.1 -C.sub.19 -alkyl, C.sub.2 -C.sub.19 -alkenyl, phenyl, C.sub.1 -C.sub.4 -alkylene phenyl, acryl, C.sub.5 -C.sub.12 -cycloalkyl or C.sub.5 -C.sub.12 -cycloalkenyl; R.sub.4 and R.sub.5 may also form a C.sub.4 -C.sub.7 -ring which may optionally contain an oxygen atom in ether form and the radicals R.sub.1 and R.sub.2 may form a C.sub.5 -C.sub.12 -alkylene bridge or a C.sub.5 -C.sub.12 -alkenylene bridge, the radicals R.sub.1 and R.sub.4 may form a C.sub.2 -C.sub.9 -alkylene bridge and the radicals R.sub.1 and R.sub.3 may form a C.sub.3 -C.sub.10 -alkylene bridge; where R.sub.1 and R.sub.2 are attached, the ring formed may be bridged by a C.sub.1 -C.sub.4 -alkylene bridge and the ring systems formed may be substituted by the radical R.sub.6 which represents hydrogen, C.sub.1 -C.sub.5 -alkyl or C.sub.2 -C.sub.5 -alkenyl, in quantities of from 0.05 to 3% by weight, based on 100 parts by weight of monomer, to the aqueous emulsion polymerization of chloroprene at the beginning of the reaction, during or after polymerization, but at the latest before the residual monomers are removed, high-viscosity polychloroprenes characterized by excellent processing behaviour and product properties are obtained.

    摘要翻译： 通过添加对应于下列通式I（I）的物质，其中X = O，S或N-R 5; R1 =氢，C1-C19 - 烷基，C2-C19 - 烯基，苯基，C1-C4-亚烷基苯基，C5-C12-环烷基或C5-C12-环烯基; R2 =氢，C1-C19 - 烷基，C2-C12-烯基，苯基或C1-C4-亚烷基苯基; R3 =氢，C1-C19 - 烷基，C2-C19 - 烯基，苯基，C1-C4-亚烷基苯基，丙烯酰甲酰基或乙酰基; R 4和R 5相同或不同，C 1 -C 19 - 烷基，C 2 -C 19 - 烯基，苯基，C 1 -C 4亚烷基苯基，丙烯酰基，C 5 -C 12 - 环烷基或C 5 -C 12 - 环烯基; R4和R5还可以形成可以任选地含有醚形式的氧原子的C 4 -C 7环，并且基团R 1和R 2可以形成C 5 -C 12亚烷基桥或C 5 -C 12 - 亚烯基桥，基团R 1和 R4可以形成C 2 -C 9 - 亚烷基桥，基团R 1和R 3可以形成C 3 -C 10亚烷基桥; 其中R 1和R 2连接，所形成的环可以被C 1 -C 4 - 亚烷基桥桥连，所形成的环体系可以被代表氢，C 1 -C 5 - 烷基或C 2 -C 5 - 烯基的基团R 6代替， 在反应开始时，在聚合过程中或之后的氯丁二烯的水乳液聚合中，基于100重量份的单体，以0.05重量％的量计，残留单体除去之前的量高 获得以优异的加工性能和产品性能为特征的粘性聚氯乙烯。

    Process for polymerization of chloroprene
    3.
    发明授权
    Process for polymerization of chloroprene 失效
    氯丁二烯聚合方法

    公开(公告)号：US4975501A

    公开(公告)日：1990-12-04

    申请号：US399333

    申请日：1989-08-28

    申请人： Rudiger Musch ,  Eberhard Muller ,  Wolfgang Konter ,  Gerhard Hohmann ,  Ludwig Mott

    发明人： Rudiger Musch ,  Eberhard Muller ,  Wolfgang Konter ,  Gerhard Hohmann ,  Ludwig Mott

    IPC分类号： C08F2/28 ,  C08F2/24 ,  C08F2/26 ,  C08F36/18

    CPC分类号： C08F36/18

    摘要： The polymerization of chloroprene leads to non-colored products when a mixture of 2.0 to 5.0% by weight of a salt of disproportionated abietic acid and 0.1 to 1.0% by weight, in each case relative to the total amount of monomer, of a compound of the formula ##STR1## in which R.sub.1 and R.sub.2, independently of one another, denote hydrogen or CH.sub.3,m denotes a number from 0 to 14,n denotes a number from 0 to 13,p denotes a number from 0 to 2, andy denotes hydrogen, Na or K, andthe total number of aliphatic carbon atoms is 11 to 15,is used as emulsifier, the emulsifiers having the advantage of being biologically degradable.

    摘要翻译： 氯丁二烯的聚合导致当2.0％至5.0％重量比例的歧化松香酸和0.1至1.0％重量（在每种情况下相对于单体的总量）的混合物的混合物中的无色产物为 式中，R 1和R 2彼此独立地表示氢或CH 3，m表示0〜14的数，n表示0〜13的数，p表示0〜2的数，y表示 表示氢，Na或K，脂族碳原子的总数为11〜15，用作乳化剂，乳化剂具有生物可降解的优点。

    Polymerization of chloroprene
    4.
    发明授权
    Polymerization of chloroprene 失效
    氯丁二烯的聚合

    公开(公告)号：US4786698A

    公开(公告)日：1988-11-22

    申请号：US132975

    申请日：1987-12-15

    申请人： Rudiger Musch ,  Eberhard Muller ,  Peter Wendling ,  Wolfgang Konter ,  Gerhard Hohmann

    发明人： Rudiger Musch ,  Eberhard Muller ,  Peter Wendling ,  Wolfgang Konter ,  Gerhard Hohmann

    IPC分类号： C08F2/22 ,  C08F2/24 ,  C08F2/26 ,  C08F2/38 ,  C08F4/30 ,  C08F4/40 ,  C08F36/18

    CPC分类号： C08F36/18

    摘要： Gel-free polychloroprene is obtained, at high monomer conversions, using a polymerization initiator comprising sodium dithionite or a mixture of sodium dithionite with formamidinesulphinic acid or with potassium peroxydisulphate or with formamidinesulphinic acid and potassium peroxodisulphate or with potassium peroxodisulphate and sodium anthraquinon-.beta.-sulphonate or with formamidinesulphinic acid and potassium peroxodisulphate and sodium anthraquinone-.beta.-sulphonate, and in the presence of oxygen and a chain transfer agent when 30 to 90% of the initiator is present at the commencement of polymerization and the remainder is added in portions during the polymerization, only further sodium dithionite being added at a conversion >60% in the case of an initiator combination, and when 20 to 80% by weight of the total amount of chain transfer agents is present before or at the commencement of polymerization and the remaining amount is added in one or more parts at monomer conversions of greater than 20%.

    摘要翻译： 使用包含连二亚硫酸钠或连二亚硫酸钠与甲酰胺亚磺酸钠或与过氧二硫酸钾或与甲脒亚磺酸和过氧二硫酸钾或与过氧二硫酸钾和蒽醌-β-磺酸钠的混合物的聚合引发剂，以高单体转化率获得无凝胶的聚氯丁二烯 或与甲酰胺亚磺酸和过二硫酸钾和蒽醌-β-磺酸钠反应，并且在氧和链转移剂存在下，当聚合开始时存在30至90％的引发剂，其余部分在 在引发剂组合的情况下，只有进一步的连二亚硫酸钠以60％的转化率加入，并且当在聚合开始之前或在聚合开始时存在20至80重量％的链转移剂的总量 在单体转化时，一个或多个部分加入量 大于20％。

    Polymerization of chloroprene
    6.
    发明授权
    Polymerization of chloroprene 失效
    氯丁二烯的聚合

    公开(公告)号：US4839447A

    公开(公告)日：1989-06-13

    申请号：US223092

    申请日：1988-07-22

    申请人： Rudolf Casper ,  Peter Wendling ,  Wolfgang Konter ,  Gerhard Hohmann

    发明人： Rudolf Casper ,  Peter Wendling ,  Wolfgang Konter ,  Gerhard Hohmann

    IPC分类号： C08F2/22 ,  C08F2/24 ,  C08F2/26 ,  C08F2/38 ,  C08F4/30 ,  C08F4/40 ,  C08F36/18

    CPC分类号： C08F36/18

    摘要： Storage-stable polychloroprene is obtained, using a polymerization initiator comprising a mixture of(1) a redox system comprising(a) a reducing agent selected from the group consisting of(i) sodium dithionite,(ii) formamidine sulphinic acid, and(iii) a mixture from (i) and (ii),(b) potassium peroxodisulphate as an oxidizing agent and, optionally,(2) sodium anthraquinone-.beta.-sulphonate as a co-activatorin the presence of oxygen, wherein from 10 to 90 by weight of the initiator are present at the commencement of polymerization and the remainder is added during the polymerization, and after a certain degree of conversion the reducing agent is the only component of redox system (1) which remains to be added.

    摘要翻译： 使用包含（1）氧化还原体系的混合物的聚合引发剂获得存储稳定的聚氯丁二烯，所述氧化还原体系包含（a）选自（i）连二亚硫酸钠，（ii）甲脒亚磺酸和（iii） ）来自（i）和（ii）的混合物，（b）过氧二硫酸钾作为氧化剂，和任选地（2）在氧气存在下作为共活化剂的蒽醌-β-磺酸钠，其中10至90 重量的引发剂在聚合开始时存在，并且在聚合过程中加入剩余物，并且在一定程度的转化后，还原剂是剩余添加的氧化还原体系（1）的唯一组分。