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公开(公告)号：US06469115B1
公开(公告)日：2002-10-22
申请号：US09572135
申请日：2000-05-16
IPC分类号： C08F400
CPC分类号： C08F210/10 , C08F4/00 , C08F2/38
摘要： A method for preparing a moisture-curable, virtually telechelic, silyl-functional polyisobutylene is disclosed, said method comprising reacting, in the presence of a Lewis acid, (A) isobutylene; (B) an initiator of the formula (C) a styryl comonomer of the formula wherein R is selected from H or methyl group, R′ is a divalent non-aromatic hydrocarbon group having 1 to 6 carbon atoms, R″ is independently selected from alkyl groups having 1 to 10 carbon atoms or aryl groups having 6 to 10 carbon atoms, R′″ is a divalent non-aromatic hydrocarbon group having 2 to 6 carbon atoms, X is independently a halogen group, Y is halogen and n is independently 1, 2 or 3.
摘要翻译： 公开了一种制备湿气固化的，实际上是遥爪的甲硅烷基官能的聚异丁烯的方法，所述方法包括在路易斯酸存在下使（A）异丁烯反应;（B）式（C）的引发剂，苯乙烯基 式中R的共聚单体选自H或甲基，R'是具有1至6个碳原子的二价非芳族烃基，R“独立地选自具有1至10个碳原子的烷基或具有6个 至10个碳原子，R“是具有2至6个碳原子的二价非芳族烃基，X独立地为卤素基团，Y为卤素且n独立地为1,2或3。
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2.发明授权Living cationic polymers prepared from silyl-functional aromatic initiators 失效由甲硅烷基官能的芳族引发剂制备的活性阳离子聚合物公开(公告)号：US06194597B1
公开(公告)日：2001-02-27
申请号：US09292333
申请日：1999-04-15
IPC分类号： C07P712
CPC分类号： C08F297/00 , C08F2/38 , C08F4/42 , C08F8/00 , C08F10/10 , C08F12/00 , C08F10/00 , C08F4/16 , C08F4/00
摘要： There is disclosed a method for preparing a silyl-functional living cationic polymer which can be subsequently coupled to form a moisture-curable telechelic system, said method comprising reacting, in the presence of a Lewis acid, (A) at least one cationically polymerizable monomer with (B) an initiator of the formula wherein R is selected from H or methyl group, R′ is a divalent non-aromatic hydrocarbon group having, 1 to 6 carbon atoms, R″ is selected from alkyl groups having 1 to 10 carbon atoms or aryl groups having, 6 to 10 carbon atoms, X is halogen, Y is halogen and n is 1, 2 or 3.
摘要翻译： 公开了一种制备甲硅烷基官能的活性阳离子聚合物的方法，其可以随后偶联以形成湿气固化遥爪系统，所述方法包括在路易斯酸存在下使（A）至少一种阳离子可聚合单体 （B）式中R的引发剂选自H或甲基，R'是具有1至6个碳原子的二价非芳族烃基，R“选自具有1-10个碳原子的烷基 或具有6〜10个碳原子的芳基，X为卤素，Y为卤素，n为1,2或3。
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公开(公告)号：US5981785A
公开(公告)日：1999-11-09
申请号：US204900
申请日：1998-12-03
IPC分类号： C07F7/12
CPC分类号： C07F7/12
摘要： A novel initiator which may be used to prepare a silyl-functional living cationic polymer is disclosed, said initiator having the formula ##STR1## wherein R is independently selected from the group consisting of alkyl groups having 1 to 10 carbon atoms and aryl groups having 6 to 10 carbon atoms, R' is a divalent aliphatic hydrocarbon group having at least 3 carbon atoms, X is halogen, Y is selected from the group consisting of halogen, alkoxy, acyloxy and hydroxyl groups and a is 1, 2 or 3.
摘要翻译： 公开了可用于制备甲硅烷基官能的活性阳离子聚合物的新型引发剂，所述引发剂具有下式：其中R独立地选自具有1-10个碳原子的烷基和具有6-10个碳原子的芳基 原子，R'是具有至少3个碳原子的二价脂族烃基，X是卤素，Y选自卤素，烷氧基，酰氧基和羟基，a是1,2或3。
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公开(公告)号：US06268451B1
公开(公告)日：2001-07-31
申请号：US09677744
申请日：2000-10-03
IPC分类号： C08F23008
CPC分类号： C08F230/08 , C08F210/10
摘要： A method for preparing a moisture-curable, pseudo-telechelic, silyl-functional polyisobutylene terpolymer is disclosed, said method comprising reacting, in the presence of a Lewis acid and a solvent, (A) an isobutylene monomer; (B) a isopropenylphenyl comonomer having the formula (C) a vinylphenyl comonomer of the formula wherein R′ is a divalent non-aromatic hydrocarbon group having 2 to 6 carbon atoms, R″ is independently selected from alkyl groups having 1 to 10 carbon atoms or aryl groups having 6 to 10 carbon atoms, R is a divalent non-aromatic hydrocarbon group having 2 to 6 carbon atoms, X is independently a hydrolyzable group and n is independently 1, 2 or 3, with the proviso that rAC is greater than 1 and rAB is less than 1, wherein rAB is the reactivity ratio of said isobutylene in the presence of said comonomer (B) and said solvent and rAC is the reactivity ratio of said isobutylene in the presence of said comonomer (C) and said solvent.
摘要翻译： 公开了一种制备湿气固化的假手爪，甲硅烷基官能的聚异丁烯三元共聚物的方法，所述方法包括在路易斯酸和溶剂的存在下使（A）异丁烯单体反应;（B）异丙烯基苯基共聚单体 具有式（C）的式（C）式R 2的乙烯基苯基共聚单体是具有2至6个碳原子的二价非芳族烃基，R“独立地选自具有1至10个碳原子的烷基或具有6至 10个碳原子，R是具有2至6个碳原子的二价非芳族烃基，X独立地是可水解基团，n独立地是1,2或3，条件是rAC大于1且rAB小于 1，其中rAB是所述异丁烯在所述共聚单体（B）和所述溶剂存在下的反应活性比，rAC是所述异丁烯在所述共聚单体（C）和所述溶剂存在下的反应活性比。
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公开(公告)号：US6051657A
公开(公告)日：2000-04-18
申请号：US204899
申请日：1998-12-03
IPC分类号： C08F4/52 , C08C19/44 , C08F2/38 , C08F4/16 , C08F8/00 , C08F8/42 , C08F10/00 , C08F12/00 , C08F36/00 , C08F255/08 , C08F257/02 , C08F279/02 , C08F269/000
CPC分类号： C08F8/42 , C08C19/44 , C08F255/08 , C08F257/02 , C08F279/02
摘要： There is disclosed a method for preparing a silyl-functional living cationic polymer which can be subsequently coupled to form a moisture-curable telechelic system, said method comprising reacting, in the presence of a Lewis acid,(A) at least one cationically polymerizable monomer with(B) an initiator of the formula ##STR1## wherein R is selected from alkyl groups having 1 to 10 carbon atoms or aryl groups having 6 to 10 carbon atoms, R' is a divalent aliphatic hydrocarbon group having at least 3 carbon atoms, X is halogen, Y is selected from the group consisting of halogen, alkoxy. acyloxy and hydroxyl groups and a is 1, 2 or 3.
摘要翻译： 公开了一种制备甲硅烷基官能的活性阳离子聚合物的方法，其可以随后偶联以形成湿气固化遥爪系统，所述方法包括在路易斯酸存在下使（A）至少一种阳离子可聚合单体 （B）具有下式的引发剂其中R选自具有1至10个碳原子的烷基或具有6至10个碳原子的芳基，R'是具有至少3个碳原子的二价脂族烃基，X是卤素 Y选自卤素，烷氧基。 酰氧基和羟基，a是1,2或3。
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公开(公告)号：US6046281A
公开(公告)日：2000-04-04
申请号：US965443
申请日：1997-11-06
IPC分类号： C07D307/00 , C07D307/40 , C08F8/00 , C08F10/10 , C08G81/02 , C08F299/00
CPC分类号： C08F10/10 , C07D307/40 , Y10S525/918
摘要： A method for coupling a living cationic polymer is disclosed, said method comprising reacting the living cationic polymer with an organic compound having at least 2 furan rings in its molecule, said reaction taking place in the presence of a Lewis acid. Preferably, the living cationic polymer is first prepared by polymerizing at least one monomer selected from isobutylene, isoprene or a styrenic monomer using a specific initiator, this reaction also being carried out in the presence of a Lewis acid.
摘要翻译： 公开了一种偶联活性阳离子聚合物的方法，所述方法包括使活性阳离子聚合物与其分子中具有至少2个呋喃环的有机化合物反应，所述反应在路易斯酸存在下进行。 优选地，活性阳离子聚合物首先通过使用特定引发剂聚合至少一种选自异丁烯，异戊二烯或苯乙烯单体的单体来制备，该反应也在路易斯酸的存在下进行。
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公开(公告)号：US07414188B2
公开(公告)日：2008-08-19
申请号：US10350919
申请日：2003-01-24
IPC分类号： H01L31/00
CPC分类号： H01G9/2063 , H01G9/2031 , H01L51/006 , H01L51/0086 , H01L51/0097 , Y02E10/542
摘要： Co-sensitizers that co-adsorb with a sensitizing dye to the surface of an interconnected semiconductor oxide nanoparticle material increase the efficiency of photovoltaic cells by improving their charge transfer efficiency and reducing the back transfer of electrons from the interconnected semiconductor oxide nanoparticle material to the sensitizing dye.
摘要翻译： 与感光染料共同吸附到相互连接的半导体氧化物纳米颗粒材料的表面的共同敏化剂通过改善光电池的电荷转移效率并减少电子从互连的半导体氧化物纳米颗粒材料向敏感的反向转移来提高光伏电池的效率 染料。
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