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    Continuous hydroformylation of olefinically unsaturated compounds
    1.
    发明授权
    Continuous hydroformylation of olefinically unsaturated compounds 失效
    烯属不饱和化合物的连续加氢甲酰化

    公开(公告)号：US4533757A

    公开(公告)日：1985-08-06

    申请号：US570988

    申请日：1984-01-16

    申请人： Rudolf Kummer ,  Wolfgang Richter ,  Kurt Schwirten ,  Peter Stops

    发明人： Rudolf Kummer ,  Wolfgang Richter ,  Kurt Schwirten ,  Peter Stops

    IPC分类号： B01J31/00 ,  B01J31/22 ,  B01J31/24 ,  C07B61/00 ,  C07C45/00 ,  C07C45/50 ,  C07C67/00

    CPC分类号： C07C45/50

    摘要： Olefinically unsaturated compounds are continuously hydroformylated under from 2 to 30 bar and at from 80.degree. to 130.degree. C. using, as a catalyst, a rhodium complex which contains, as ligands, sparingly volatile compounds of the general formula I ##STR1## where A is phosphorus, arsenic, antimony or bismuth and R.sup.1, R.sup.2 and R.sup.3 are each organic radicals, by a method in which the hydroformylation mixture consisting of liquid and gaseous components is removed from the reactor and is subjected to relatively high temperatures and/or relatively low pressures for a short time in a devolatilization column, the mixture at the same time being separated into a gas phase and a liquid phase, the gas phase is separated into the product and the recycle gas in a separator, and the recycle gas and the liquid phase from the devolatilization column are recycled to the reactor.

    摘要翻译： 使用作为催化剂的2至30巴和80至130℃下的烯属不饱和化合物连续加氢甲酰化，所述铑配合物含有作为配体的通式Ⅰ的微量挥发性化合物，其中 A是磷，砷，锑或铋，R1，R2和R3各自为有机基团，其中将由液体和气体组分组成的加氢甲酰化混合物从反应器中除去并经受较高温度和/或相对 在脱挥发分塔中短时间内的低压，同时将该混合物分离成气相和液相，气相在分离器中分离成产物和再循环气体，再循环气体和 来自脱挥发分塔的液相再循环到反应器中。

    Preparation of aldehydes
    2.
    发明授权
    Preparation of aldehydes 失效
    醛的制备

    公开(公告)号：US4262141A

    公开(公告)日：1981-04-14

    申请号：US69919

    申请日：1979-08-27

    申请人： Wolfgang Richter ,  Rudolf Kummer ,  Kurt Schwirten

    发明人： Wolfgang Richter ,  Rudolf Kummer ,  Kurt Schwirten

    IPC分类号： B01J31/00 ,  B01J31/28 ,  C07B61/00 ,  C07C45/00 ,  C07C45/50 ,  C07C67/00

    CPC分类号： C07C45/50

    摘要： Aldehydes are prepared by hydroformylating the corresponding olefinically unsaturated compounds with the aid of rhodium-carbonyl complexes which contain tertiary phosphines as ligands, by carrying out the reaction in the presence of compounds of copper, silver or zinc which are soluble in the reaction mixture and do not contain any component which deactivates the rhodium-carbonyl complexes.

    摘要翻译： 通过在可溶于反应混合物的铜，银或锌化合物的存在下进行反应，借助于含有叔膦作为配体的铑 - 羰基络合物，通过对相应的烯属不饱和化合物进行加氢甲酰化来制备醛 不含任何使铑 - 羰基络合物失活的组分。

    Working up of hydroformylation or carbonylation reaction mixtures
    3.
    发明授权
    Working up of hydroformylation or carbonylation reaction mixtures 失效
    加工甲酰化或羰基化反应混合物

    公开(公告)号：US4568653A

    公开(公告)日：1986-02-04

    申请号：US222893

    申请日：1981-01-06

    申请人： Kurt Schwirten ,  Rudolf Kummer ,  Wolfgang Richter

    发明人： Kurt Schwirten ,  Rudolf Kummer ,  Wolfgang Richter

    IPC分类号： C07C45/49 ,  C07C29/16 ,  C07C29/76 ,  C07C29/86 ,  C07C45/00 ,  C07C45/50 ,  C07C45/78 ,  C07C67/00 ,  C07C67/38 ,  C07C67/58 ,  B01J31/40 ,  C07C51/14

    CPC分类号： C07C29/16 ,  C07C29/76 ,  C07C29/86 ,  C07C45/50 ,  C07C45/78

    摘要： Reaction mixtures which are obtained on hydroformylation or carbonylation of olefinically unsaturated compounds and which contain dissolved non-volatile complex compounds of metals of group VIII of the periodic table are worked up by a method wherein the products, after distillative removal of low-boiling constituents alone, or of these constituents plus a part of the high-boiling residue, or a part of the high-boiling residue after distillative removal of the desired products, are or is extracted with carbon dioxide, a C.sub.2 -C.sub.4 -paraffin, a C.sub.2 -C.sub.4 -olefin or a normally gaseous halohydrocarbon at above the critical temperature and above the critical pressure of these (extractant) compounds.

    摘要翻译： 在烯属不饱和化合物的加氢甲酰化或羰基化获得并且含有周期表第VIII族金属的溶解的非挥发性络合物的反应混合物通过一种方法来处理，其中产物在蒸馏除去低沸点组分之后 ，或这些成分加上一部分高沸点残余物，或蒸馏除去所需产物后的一部分高沸点残余物，用二氧化碳，C2-C4-链烷烃，C2- 在高于临界温度并高于这些（萃取剂）化合物的临界压力的C4-烯烃或正常气态的卤代烃。

    Hydroformylation of olefinically unsaturated compounds
    4.
    发明授权
    Hydroformylation of olefinically unsaturated compounds 失效
    烯属不饱和化合物的加氢甲酰化

    公开(公告)号：US4400549A

    公开(公告)日：1983-08-23

    申请号：US324277

    申请日：1981-11-23

    申请人： Wolfgang Richter ,  Rudolf Kummer ,  Kurt Schwirten

    发明人： Wolfgang Richter ,  Rudolf Kummer ,  Kurt Schwirten

    IPC分类号： C07C27/22 ,  B01J31/00 ,  B01J31/24 ,  C07B61/00 ,  C07C27/00 ,  C07C29/158 ,  C07C45/49 ,  C07C45/50 ,  C07C67/00

    CPC分类号： C07C45/50

    摘要： A process for hydroformylating olefinically unsaturated compounds by means of rhodium/triphenylphosphine/carbonyl complexes formed in situ from rhodium acetate, triphenylphosphine and carbon monoxide, wherein the hydroformylation reaction is preceded by a starting phase in which the mixture of the hydroformylation medium, the triphenylphosphine and rhodium acetate is heated at from 90.degree. to 120.degree. C. under a CO/H.sub.2 pressure of from 5 to 20 bar and the acetic acid liberated is discharged from the reactor in gaseous form in a stream of CO and H.sub.2, until virtually no more acetic acid can be detected in this gaseous discharge.

    摘要翻译： 一种通过铑/三苯基膦/羰基络合物将乙酸铑，三苯基膦和一氧化碳原位形成的铑/三苯基膦/羰基络合物加氢甲酰化的方法，其中加氢甲酰化反应之前是起始阶段，其中加氢甲酰化介质，三苯基膦和 乙酸铑在50至20巴的CO / H 2压力下加热至90℃至120℃，释放的乙酸以CO和H 2的气流形式从反应器中排出，直到几乎不再 可以在该气体放电中检测乙酸。

    Manufacture of methacrylic acid and butyrolactone
    8.
    发明授权
    Manufacture of methacrylic acid and butyrolactone 失效
    甲基丙烯酸和丁内酯的制造

    公开(公告)号：US3980670A

    公开(公告)日：1976-09-14

    申请号：US552734

    申请日：1975-02-25

    申请人： Rudolf Kummer ,  Rolf Platz ,  Kurt Schwirten

    发明人： Rudolf Kummer ,  Rolf Platz ,  Kurt Schwirten

    IPC分类号： C07C69/02 ,  B01J21/00 ,  C07B61/00 ,  C07C51/00 ,  C07C51/14 ,  C07C51/377 ,  C07C57/065 ,  C07C67/00 ,  C07D307/33 ,  C07D315/00 ,  C07D307/32

    CPC分类号： C07D315/00 ,  C07C51/14 ,  C07C51/377

    摘要： Methacrylic acid and butyrolactone are manufactured by hydroformylation of allyl esters of lower carboxylic acids in the presence of rhodium catalysts and inert organic solvents, followed by oxidation of the resulting formyl compounds with molecular oxygen (e.g. with air) in the presence of lower fatty acids, without prior removal of the rhodium catalysts, and elimination of the carboxylic acid from the acyloxybutyric acids formed, at from 150.degree. to 500.degree.C, using catalysts such as aluminum oxide, silicates or active charcoal.

    摘要翻译： 甲基丙烯酸和丁内酯是通过在铑催化剂和惰性有机溶剂的存在下将低级羧酸的烯丙酯加氢甲酰化，然后在低级脂肪酸存在下用分子氧（例如与空气）氧化得到的甲酰基化合物来制备的， 没有事先去除铑催化剂，并且使用催化剂如氧化铝，硅酸盐或活性炭，在150℃至500℃下从形成的酰氧基丁酸中除去羧酸。

    Manufacture of pent-3-enoic acid and its alkyl esters
    10.
    发明授权
    Manufacture of pent-3-enoic acid and its alkyl esters 失效
    戊-3-烯酸及其烷基酯的制备

    公开(公告)号：US4550195A

    公开(公告)日：1985-10-29

    申请号：US295088

    申请日：1981-08-21

    申请人： Rolf Platz ,  Rudolf Kummer ,  Heinz-Walter Schneider ,  Kurt Schwirten

    发明人： Rolf Platz ,  Rudolf Kummer ,  Heinz-Walter Schneider ,  Kurt Schwirten

    IPC分类号： C07C69/533 ,  B01J31/00 ,  C07B61/00 ,  C07C51/00 ,  C07C51/14 ,  C07C57/03 ,  C07C67/00 ,  C07C67/38

    CPC分类号： C07C51/14

    摘要： A process for the manufacture of pent-3-enoic acid and its alkyl esters, of the general formulaCH.sub.3 --CH.dbd.CH--CH.sub.2 --CO--ORwhere R is hydrogen or alkyl of 1 to 4 carbon atoms, comprising carbonylating butadiene with carbon monoxide and a compound ROH at from 300 to 1,000 bars CO pressure and from 100.degree. to 160.degree. C. in the presence of cobalt catalysts and nitrogen bases, wherein C.sub.4 cuts are used as starting materials and a tertiary amine having a pK.sub.A of from 3 to 11 is used as the nitrogen base. The pent-3-enoic acid or alkyl esters produced may be used for the manufacture of adipic acid or its alkyl esters, which compounds are starting materials for the manufacture of nylons.

    摘要翻译： 制备通式为CH 3 -CH = CH-CH 2 -CO-OR的戊-3-烯酸及其烷基酯的方法，其中R是氢或1至4个碳原子的烷基，其包括将碳酸丁二烯与碳 在钴催化剂和氮碱的存在下，在300至1,000巴CO压力和100至160℃下进行一氧化碳和化合物ROH，其中使用C4馏分作为起始原料，并使用pKA为3的叔胺 至11为氮基。 所制备的戊-3-烯酸或烷基酯可用于制造己二酸或其烷基酯，该化合物是用于制造尼龙的起始原料。