摘要:
A method of continuous polymerization using differential radial stirring is provided. Particularly suited for this method is a stirred tube reactor with a plurality of collinear stirring shafts that may rotate independently.
摘要:
Disclosed are block copolymers and end-functionalized polymers containing in their backbones at least one fluoro alkyl (meth)acrylate mer unit comprising —C6F13, —C4F9, or —C3F7.
摘要:
A composition comprising a fluorinated block copolymer and at least one of an intercalated layered silicate or exfoliated silicate platelets, and methods of making the same.
摘要:
A mixture of layered silicate, block copolymer having at least one block that is compatible with the first layered silicate, and a solvent is sheared while the solvent is removed.
摘要:
Disclosed is a method for modifying a polymer by carrying out a thermally-induced reaction in a mixing apparatus having a high shear environment and devolatilization capabilities. Also disclosed are the resulting materials.
摘要:
The device of the present invention delivers reactants to a reaction zone in a plug flow reactor. The feedblock encircles the reaction zone. Reactants enter the feedblock through an inlet port leading to a manifold for the delivery of reactants into a plurality of feed ports that are in connection with the reaction zone of a plug flow reactor. The invention additionally encompasses plug flow reactors including one or more feedblocks and the method of utilizing the feedblock for the reduction of radial variation in concentration upon entry of a reactant into the reaction zone.
摘要:
Compositions comprising a plurality of carbon nanotubes, a host polymer, and A block copolymer comprising a first block and a second block, wherein no block is compatible with the host polymer. In one aspect, the block copolymer is amphiphilic. In another aspect, the block copolymer may comprise a first block and a second block, wherein at least one of the first and second blocks comprises repeating units derived from a monomer having the general formula: (R)2C═C(R)(Rf) wherein Rf is selected from fluorine, a C1 to C10 fluorinated or perfluorinated alkyl group, and a C1 to C10 fluorinated or perfluorinated alkoxy group; each R is independently selected from F, H, Cl, Rf, a C1 to C10 alkyl group, and R2A, wherein R2 is a C1 to C10 alkylene group and A is selected from CO2M and SO3M, wherein M is selected from H, an ammonium and organo onium group.
摘要:
Compositions comprising a plurality of carbon nanotubes, a host polymer, and A block copolymer comprising a first block and a second block, wherein no block is compatible with the host polymer. In one aspect, the block copolymer is amphiphilic. In another aspect, the block copolymer may comprise a first block and a second block, wherein at least one of the first and second blocks comprises repeating units derived from a monomer having the general formula: (R)2C═C(R)(Rf) wherein Rf is selected from fluorine, a C1 to C10 fluorinated or perfluorinated alkyl group, and a C1 to C10 fluorinated or perfluorinated alkoxy group; each R is independently selected from F, H, Cl, Rf, a C1 to C10 alkyl group, and R2A, wherein R2 is a C1 to C10 alkylene group and A is selected from CO2M and SO3M, wherein M is selected from H, an ammonium and organo onium group.