公开(公告)号：US08410035B2

公开(公告)日：2013-04-02

申请号：US11886960

申请日：2006-03-24

申请人： Ryousuke Kaneshige ,  Akihiro Matsuda ,  Satoshi Ikeda ,  Keiji Okada ,  Masaaki Kawasaki

发明人： Ryousuke Kaneshige ,  Akihiro Matsuda ,  Satoshi Ikeda ,  Keiji Okada ,  Masaaki Kawasaki

IPC分类号： C10M119/02 ,  C08F10/06

CPC分类号： C10M169/041 ,  C10M107/02 ,  C10M143/00 ,  C10M2203/1006 ,  C10M2205/02 ,  C10M2205/022 ,  C10M2205/024 ,  C10M2209/084 ,  C10N2220/02 ,  C10N2220/021 ,  C10N2220/022 ,  C10N2220/032 ,  C10N2230/02 ,  C10N2230/68 ,  C10N2240/04 ,  C10N2240/042

摘要： A lubricating oil composition for a power transmission system, which is excellent in both of low-temperature viscosity property and shear stability, is provided. The viscosity modifier of a lubricating oil for a power transmission system according to the present invention comprises an ethylene/α-olefin copolymer (B) having the properties: (B1) an ethylene content in the range of 70 to 85% by mol, (B2) an intrinsic viscosity [η] in the range of 0.2 to 1.0 dl/g, (B3) Mw/Mn not more than 2.4, and (B4) a melting point, as measured by DSC, not higher than 60° C., or no melting point observed.

摘要翻译： 提供了低温粘度特性和剪切稳定性优异的动力传递系统用润滑油组合物。 根据本发明的用于动力传动系统的润滑油的粘度调节剂包括具有以下性质的乙烯/α-烯烃共聚物（B）：（B1）乙烯含量在70至85摩尔％的范围内（ B2）在0.2〜1.0dl / g范围内的特性粘度[（e）]，（B3）Mw / Mn不大于2.4，（B4）通过DSC测定的熔点不高于60℃ ，或没有观察到熔点。

公开(公告)号：US20090023619A1

公开(公告)日：2009-01-22

申请号：US11886960

申请日：2006-03-24

申请人： Ryousuke Kaneshige ,  Akihiro Matsuda ,  Satoshi Ikeda ,  Keiji Okada ,  Masaaki Kawasaki

发明人： Ryousuke Kaneshige ,  Akihiro Matsuda ,  Satoshi Ikeda ,  Keiji Okada ,  Masaaki Kawasaki

IPC分类号： C10M145/14 ,  C08F210/02 ,  C10M143/02

CPC分类号： C10M169/041 ,  C10M107/02 ,  C10M143/00 ,  C10M2203/1006 ,  C10M2205/02 ,  C10M2205/022 ,  C10M2205/024 ,  C10M2209/084 ,  C10N2220/02 ,  C10N2220/021 ,  C10N2220/022 ,  C10N2220/032 ,  C10N2230/02 ,  C10N2230/68 ,  C10N2240/04 ,  C10N2240/042

摘要： A lubricating oil composition for a power transmission system, which is excellent in both of low-temperature viscosity property and shear stability, is provided. The viscosity modifier of a lubricating oil for a power transmission system according to the present invention comprises an ethylene/α-olefin copolymer (B) having the properties: (B1) an ethylene content in the range of 70 to 85% by mol, (B2) an intrinsic viscosity [η] in the range of 0.2 to 1.0 dl/g, (B3) Mw/Mn not more than 2.4, and (B4) a melting point, as measured by DSC, not higher than 60° C., or no melting point observed.

摘要翻译： 提供了低温粘度特性和剪切稳定性优异的动力传递系统用润滑油组合物。 根据本发明的用于动力传动系统的润滑油的粘度调节剂包括具有以下性质的乙烯/α-烯烃共聚物（B）：（B1）乙烯含量在70至85摩尔％范围内（ B2）特性粘度η在0.2〜1.0dl / g的范围内，（B3）Mw / Mn不大于2.4，（B4）通过DSC测定的熔点不高于60℃。 ，或没有观察到熔点。

公开(公告)号：US20060122079A1

公开(公告)日：2006-06-08

申请号：US10534580

申请日：2003-11-11

申请人： Ryousuke Kaneshige ,  Keiji Okada ,  Masaaki Kawasaki ,  Satoshi Ikeda

发明人： Ryousuke Kaneshige ,  Keiji Okada ,  Masaaki Kawasaki ,  Satoshi Ikeda

IPC分类号： C10M143/04 ,  C10M107/06

CPC分类号： C10M107/06 ,  C10M2205/022 ,  C10N2220/02 ,  C10N2220/021 ,  C10N2220/022 ,  C10N2230/02 ,  C10N2230/06 ,  C10N2230/08 ,  C10N2240/04 ,  C10N2240/08 ,  C10N2240/10 ,  C10M2205/024

摘要： The present invention provides a lubricating oil composition having excellent low temperature viscosity properties suitable for engine oils for automobiles and industries, gear oils, shock absorber oils, hydraulic fluids and it also provides a lubricating oil for internal-combustion engines formed from the composition. The lubricating oil composition comprises; a lubricating oil base (A) having a kinematic viscosity at 100° C. of 1 to 50 mm2/s and a viscosity index of not less than 80, an ethylene•propylene copolymer (B) having the following properties (B1) to (B4) such that (B1) the ethylene content is from 30 to 75% by weight, (B2) the intrinsic viscosity [η] is from 1.3 to 2.0 dl/g, (B3) the Mw/Mn is not more than 2.4 and (B4) the melting point as measured with DSC is not higher than 30° C., and optionally a pour point depressant (C).

摘要翻译： 本发明提供一种具有优异的低温粘度性能的润滑油组合物，其适用于汽车和工业用发动机油，齿轮油，减震器油，液压油，并且还提供由该组合物形成的内燃机的润滑油。 润滑油组合物包含： 在100℃下的运动粘度为1〜50mm 2 / s，粘度指数为80以上的润滑油基材（A），乙烯 - 丙烯共聚物（B）具有 （B1）至（B4）的特性粘度η为1.3〜2.0dl / g，（B1）乙烯含量为（B）为30〜75重量％，（B 2） / Mn不大于2.4，（B4）用DSC测得的熔点不高于30℃，任选地是倾点下降剂（C）。

公开(公告)号：US07622433B2

公开(公告)日：2009-11-24

申请号：US10534580

申请日：2003-11-11

申请人： Ryousuke Kaneshige ,  Keiji Okada ,  Masaaki Kawasaki ,  Satoshi Ikeda

发明人： Ryousuke Kaneshige ,  Keiji Okada ,  Masaaki Kawasaki ,  Satoshi Ikeda

IPC分类号： C10L1/16

CPC分类号： C10M107/06 ,  C10M2205/022 ,  C10N2220/02 ,  C10N2220/021 ,  C10N2220/022 ,  C10N2230/02 ,  C10N2230/06 ,  C10N2230/08 ,  C10N2240/04 ,  C10N2240/08 ,  C10N2240/10 ,  C10M2205/024

摘要： The present invention provides a lubricating oil composition having excellent low temperature viscosity properties suitable for engine oils for automobiles and industries, gear oils, shock absorber oils, hydraulic fluids and it also provides a lubricating oil for internal-combustion engines formed from the composition.The lubricating oil composition comprises; a lubricating oil base (A) having a kinematic viscosity at 100° C. of 1 to 50 mm2/s and a viscosity index of not less than 80, an ethylene•propylene copolymer (B) having the following properties (B1) to (B4) such that (B1) the ethylene content is from 30 to 75% by weight, (B2) the intrinsic viscosity [η] is from 1.3 to 2.0 dl/g, (B3) the Mw/Mn is not more than 2.4 and (B4) the melting point as measured with DSC is not higher than 30° C., and optionally a pour point depressant (C).

摘要翻译： 本发明提供一种具有优异的低温粘度性能的润滑油组合物，其适用于汽车和工业用发动机油，齿轮油，减震器油，液压油，并且还提供由该组合物形成的内燃机的润滑油。 润滑油组合物包含： 在100℃下的运动粘度为1〜50mm 2 / s，粘度指数为80以上的润滑油基材（A）具有以下特性的乙烯 - 丙烯共聚物（B）（B1）〜（ B4），使得（B1）乙烯含量为30〜75重量％，（B2）特性粘度η为1.3〜2.0dl / g，（B3）Mw / Mn为2.4以下， （B4）用DSC测定的熔点不高于30℃，任选地是倾点降低剂（C）。

公开(公告)号：US20070219320A1

公开(公告)日：2007-09-20

申请号：US11587756

申请日：2005-04-28

申请人： Kotaro Ichino ,  Masao Kunizane ,  Yuji Ishii ,  Kunihide Hiraoka ,  Masaaki Kawasaki ,  Hidetatsu Murakami ,  Keiji Okada

发明人： Kotaro Ichino ,  Masao Kunizane ,  Yuji Ishii ,  Kunihide Hiraoka ,  Masaaki Kawasaki ,  Hidetatsu Murakami ,  Keiji Okada

IPC分类号： C08F8/00

CPC分类号： C08L21/00 ,  B60C1/0016 ,  C08K5/0016 ,  C08L9/00 ,  C08L23/16 ,  C08L2666/06 ,  C08L2666/08

摘要： A process for producing a rubber composition containing a nonconjugated polyene copolymer (A), a softener (B) and a diene rubber (C), comprising: a step of mixing a copolymer composition (I), said copolymer composition (I) comprising 100 parts by weight of a nonconjugated polyene copolymer (A), said nonconjugated polyene copolymer (A) being a random copolymer containing 96 to 70 mol % of the structural units derived from α-olefin (A1) and 4 to 30 mol % of the structural units derived from nonconjugated polyene (A2) and having a glass transition temperature (Tg) of −25 to 20° C., and 1 to 100 parts by weight of the softener (B); the diene rubber (C); and optionally further the softener (B). A tire tread using the rubber composition and a tire having the tire tread.

摘要翻译： 一种制备含有非共轭多烯共聚物（A），软化剂（B）和二烯橡胶（C）的橡胶组合物的方法，包括：将共聚物组合物（I），所述共聚物组合物（I） 重量份的非共轭多烯共聚物（A），所述非共轭多烯共聚物（A）是含有96-70％（摩尔）衍生自α-烯烃（A1）的结构单元和4-30％（摩尔）结构 衍生自非共轭多烯（A2）并且玻璃化转变温度（Tg）为-25至20℃的单元和1至100重量份的软化剂（B）; 二烯橡胶（C）; 和任选地进一步的软化剂（B）。 使用橡胶组合物的轮胎胎面和具有轮胎胎面的轮胎。

公开(公告)号：US06303727B1

公开(公告)日：2001-10-16

申请号：US09320838

申请日：1999-05-26

申请人： Ken Maeda ,  Masaaki Yasuda ,  Terunori Fujita ,  Keiji Okada ,  Makoto Kamimura ,  Kazuyuki Takimoto ,  Hidetatsu Murakami ,  Masaaki Kawasaki ,  Keiji Watanabe

发明人： Ken Maeda ,  Masaaki Yasuda ,  Terunori Fujita ,  Keiji Okada ,  Makoto Kamimura ,  Kazuyuki Takimoto ,  Hidetatsu Murakami ,  Masaaki Kawasaki ,  Keiji Watanabe

IPC分类号： C08F13600

CPC分类号： C08F236/22 ,  C07C2/04 ,  C07C11/21 ,  C07C2527/24 ,  C07C2531/14

摘要： A novel and useful linear triene compound represented by the following formula (1) is co-polymerized with an &agr;-olefin to obtain an ethylenically unsaturated copolymer which is superior in weather-ability, heat resitance and fastness to ozone, together with superior scorch stability and vulcanizability at high velocity in which R1, R2, R3, R4, R5 and R6 stand each, independently of each other, for hydrogen atom or an alkyl having 1-3 carbon atoms, R7 represents an alkyl having 1-3 carbon atoms and n is an integer of 0-5, with the proviso that each of R4s or of R5s may be identical with or different from each other, respectively, when n is 2 or greater.

摘要翻译： 由下式（1）表示的新型有用的线性三烯化合物与α-烯烃共聚，得到耐候性，耐热性和耐臭氧性优异的烯属不饱和共聚物，以及优异的焦烧稳定性 和R 1，R 2，R 3，R 4，R 5和R 6各自独立地表示氢原子或具有1-3个碳原子的烷基的高速度下的硫化性，R7表示具有1-3个碳原子的烷基，n表示 是0-5的整数，条件是当n为2或更大时，R 4或R 5中的每一个可以分别彼此相同或不同。

公开(公告)号：US5354828A

公开(公告)日：1994-10-11

申请号：US79845

申请日：1993-06-22

申请人： Masaaki Kawasaki ,  Syuji Minami ,  Tetsuo Tojo ,  Keiji Okada

发明人： Masaaki Kawasaki ,  Syuji Minami ,  Tetsuo Tojo ,  Keiji Okada

IPC分类号： C08F4/658 ,  C08F210/14 ,  C08L23/16 ,  C08F236/20 ,  C08L19/00

CPC分类号： C08L23/16 ,  C08F210/14 ,  C08L23/10 ,  C08L23/20 ,  C08L2312/00

摘要： The higher .alpha.-olefin copolymers obtained in accordance with the present invention are copolymers derived from higher .alpha.-olefin and non-conjugated diene represented by the following general formula [I], and (a) the non-conjugated diene content thereof is from 0.01 to 30 mol %, and (b) the intrinsic viscosity [.eta.], as measured in decahydronaphthalene at 135.degree. C., of said copolymer is from 1.0 to 10.0 dl/g. ##STR1## The invention also provides a process for preparing such higher .alpha.-olefin copolymers as illustrated above, and vulcanization products obtained from said copolymers.Furthermore, the invention provides vulcanizable compositions containing rubber comprising of the above-mentioned higher .alpha.-olefin copolymers and a specific diene rubber or a specific ethylene/.alpha.-olefin copolymer rubber.

摘要翻译： PCT No.PCT / JP90 / 00527 Sec。 371 1990年12月13日第 102（e）1990年12月13日的PCT PCT 1990年4月24日提交PCT公布。 WO90 / 12818 PCT公开号 1990年1月11日。根据本发明获得的高级α-烯烃共聚物是由以下通式[I]表示的高级α-烯烃和非共轭二烯衍生的共聚物，（a） 共轭二烯含量为0.01〜30摩尔％，（b）在135℃的十氢化萘中测定的特性粘度η为1.0〜10.0dl / g。 本发明还提供了制备如上所述的这种高级α-烯烃共聚物的方法和由所述共聚物获得的硫化产物。 此外，本发明提供含有上述高级α-烯烃共聚物和特定二烯橡胶或特定乙烯/α-烯烃共聚物橡胶的橡胶的可硫化组合物。

公开(公告)号：US20080188621A1

公开(公告)日：2008-08-07

申请号：US11587904

申请日：2005-04-28

申请人： Kotaro Ichino ,  Masao Kunizane ,  Yuji Ishit ,  Kunihide Hiraoka ,  Masaaki Kawasaki ,  Hidetatsu Murakami ,  Keiji Okada

发明人： Kotaro Ichino ,  Masao Kunizane ,  Yuji Ishit ,  Kunihide Hiraoka ,  Masaaki Kawasaki ,  Hidetatsu Murakami ,  Keiji Okada

IPC分类号： C08L9/02

CPC分类号： C08L21/00 ,  B60C1/0016 ,  C08L9/00 ,  C08L9/02 ,  C08L23/16 ,  C08L53/00 ,  C08L2666/02 ,  C08L2666/08

摘要： Provided is a rubber composition which can give a tire excellent in braking performance and fuel consumption and which is excellent in mechanical strength and fatigue resistance, and a use thereof.The rubber composition of the present invention contains a (A) 60 to 0.1 parts by weight of a nonconjugated polyene copolymer, which is a random copolymer containing 96 to 70 mol % of the structural units derived from α-olefin (A1) and 4 to 30 mol % of the structural units derived from a nonconjugated polyene (A2), and has a glass transition temperature (Tg) of −25 to 20° C., (B) 40 to 99.9 parts by weight of a diene rubber and (C) at least one selected from the group consisting of specific polymers.

摘要翻译： 提供一种橡胶组合物，其能够赋予制动性能和燃料消耗优异并且机械强度和耐疲劳性优异的轮胎及其用途。 本发明的橡胶组合物含有（A）60〜0.1重量份的非共轭多烯共聚物，其是含有96〜70摩尔％的来自α-烯烃（A1）的结构单元和4〜 衍生自非共轭多烯（A2）的结构单元的30摩尔％，玻璃化转变温度（Tg）为-25〜20℃，（B）为40〜99.9重量份的二烯系橡胶，（C ）选自由特定聚合物组成的组中的至少一种。

公开(公告)号：US06787623B1

公开(公告)日：2004-09-07

申请号：US09787890

申请日：2001-03-26

申请人： Hidetatsu Murakami ,  Keiji Okada ,  Masaaki Kawasaki ,  Kotaro Ichino

发明人： Hidetatsu Murakami ,  Keiji Okada ,  Masaaki Kawasaki ,  Kotaro Ichino

IPC分类号： C08F23620

CPC分类号： C08L21/00 ,  B60C1/0016 ,  C08F210/02 ,  C08F210/18 ,  C08L23/08 ,  C08L23/0823 ,  Y10T152/10495 ,  C08L2666/06 ,  C08L2666/04 ,  C08F236/20 ,  C08F2500/25 ,  C08F2500/17 ,  C08F210/06

摘要： A tire provided with a tire tread made from a rubber composition comprising (A) a random copolymer based on non-conjugated cyclic polyene comprising structural units originated from one or more &agr;-olefins (A1) and originated from one or more non-conjugated cyclic polyene (A2), the said random copolymer having a content of the structural unit(s) originated from one or more &agr;-olefins (A1) in the range of 93 to 70 mole %; a content of the structural unit originated from one or more non-conjugated cyclic polyene (A2) in the range of 7 to 30 mole %; an intrinsic viscosity [&eegr;], determined in decalin at 135° C., in the range of 0.01 to 20 dl/g; a glass transition temperature (Tg) of not higher than 40° C.; and an iodine value in the range of 50 to 150, and (B) a rubber based on diene, in a weight proportion of {the random copolymer based on non-conjugated cyclic polyene (A)} versus {the rubber based on diene (B)} in the range from 60/40 to 0.1/99.9 exhibits a superior braking performance and, compatible therewith, a superior driving fuel cost aspect.

摘要翻译： 本发明提供一种轮胎胎面，其由橡胶组合物制成，该轮胎胎面由（A）基于非共轭环状多烯的无规共聚物构成，所述非共轭环多烯包含源自一种或多种α-烯烃（A1）的结构单元，并且源于一种或多种非共轭环 多烯（A2），所述无规共聚物具有来源于一种或多种α-烯烃（A1）的结构单元的含量在93-70摩尔％范围内; 来自一种或多种7-30摩尔％的非共轭环状多烯（A2）的结构单元的含量; 在135℃的萘烷中测定的特性粘度η在0.01至20dl / g的范围内; 玻璃化转变温度（Tg）不高于40℃; 碘值在50〜150范围内，（B）基于二烯的橡胶，以{非共轭环状多烯（A）}为基准的无规共聚物）与{基于二烯的橡胶 B）}在60/40至0.1 / 99.9的范围内表现出优异的制动性能，并且与其兼容，具有优异的驱动燃料成本方面。

公开(公告)号：US5807948A

公开(公告)日：1998-09-15

申请号：US783238

申请日：1997-01-14

申请人： Toshihiro Sagane ,  Toshiyuki Tsutsui ,  Masaaki Kawasaki ,  Keiji Okada ,  Hidenari Nakahama ,  Tetsuo Tojo

发明人： Toshihiro Sagane ,  Toshiyuki Tsutsui ,  Masaaki Kawasaki ,  Keiji Okada ,  Hidenari Nakahama ,  Tetsuo Tojo

IPC分类号： C08F4/64 ,  C08F4/659 ,  C08F4/6592 ,  C08F210/18 ,  C08L23/16 ,  C08F236/20

CPC分类号： C08F210/18 ,  C08L23/16 ,  C08F4/65912 ,  C08F4/65927 ,  C08L2312/00 ,  Y10S526/943

摘要： Disclosed is a process for preparing an ethylene-.alpha.-olefin-nonconjugated polyene random copolymer comprising random copolymerizing (a) ethylene, (b) an .alpha.-olefin of 3 or more carbon atoms and (c) a nonconjugated polyene in the presence of a metallocene catalyst containing a specific metallocene compound. The ethylene-.alpha.-olefin-nonconjugated polyene random copolymer prepared by the process has such properties that (i) the copolymer contains units derived from ethylene (a) and units derived from the .alpha.-olefin of 3 or more carbon atoms (b) in a molar ratio of 40/60 to 95/5 �(a)/(b)!, (ii) the iodine value is 1 to 50, (iii) the intrinsic viscosity (.eta.) is more than 0.1 dl/g and less than 8.0 10 dl/g, (iv) the intensity ratio D of T.alpha..beta. to T.alpha..alpha. in the .sup.13 C-NMR spectrum, T.alpha..beta./T.alpha..alpha., is not more than 0.5, (v) the B value is 1.00 to 1.50, (vi) the glass transition temperature Tg is not higher than -50.degree. C., and (vii) the ratio g.eta.* of the intrinsic viscosity (.eta.) of this copolymer defined above to the intrinsic viscosity (.eta.).sub.blank of a straight-chain ethylene-propylene copolymer having the same weight-average molecular weight as this random copolymer and having an ethylene content of 70% by mol, (.eta.)/(.eta.).sub.blank, is more than 0.9. Also disclosed is a vulcanizable rubber composition containing the random copolymer. The ethylene-.alpha.-olefin-nonconjugated polyene random copolymer and the rubber composition are excellent in mechanical strength, weathering resistance, ozone resistance, processability, low-temperature flexibility and heat resistance.

摘要翻译： 公开了一种制备乙烯-α-烯烃 - 非共轭多烯无规共聚物的方法，包括（a）乙烯，（b）3个或更多个碳原子的α-烯烃和（c）非共轭多烯在 含有特定茂金属化合物的茂金属催化剂。 通过该方法制备的乙烯-α-烯烃 - 非共轭多烯无规共聚物具有以下特性：（i）共聚物含有衍生自乙烯（a）的单元和衍生自3个或更多个碳原子的（b）的α-烯烃的单元 摩尔比为40/60〜95/5 [（a）/（b）]，（ii）碘值为1〜50，（iii）特性粘度（η）大于0.1dl / g以下 （iv）13 C-NMR光谱中的Tαβ与Tαα的强度比D（Tαβ/Tαα）不大于0.5，（v）B值为 1.00至1.50，（vi）玻璃化转变温度Tg不高于-50℃，（vii）上述定义的共聚物的特性粘度（η）与特性粘度（η）的比值g eta * 空白的具有与该无规共聚物相同的重均分子量且乙烯含量为70摩尔％（eta）/（η）空白的直链乙烯 - 丙烯共聚物大于0.9。 还公开了含有无规共聚物的可硫化橡胶组合物。 乙烯-α-烯烃 - 非共轭多烯无规共聚物和橡胶组合物的机械强度，耐候性，耐臭氧性，加工性，低温柔韧性和耐热性都优异。