公开(公告)号：US20130190470A1

公开(公告)日：2013-07-25

申请号：US13636658

申请日：2011-03-22

申请人： Sébastien Marrot ,  John White ,  Michel Feder ,  Fédéric Magd

发明人： Sébastien Marrot ,  John White ,  Michel Feder ,  Fédéric Magd

IPC分类号： C09D183/04

CPC分类号： C09D183/04 ,  C08G77/38 ,  C08L83/00

摘要： The invention relates to cross-linkable or cross-linked silicone compositions that can be used, in particular, to form a non-stick water-repellent coating for flexible substrates, for example paper or similar, in the form of natural or synthetic polymer films.

摘要翻译： 本发明涉及可交联或交联的有机硅组合物，其可以特别用于形成天然或合成聚合物膜形式的柔性基材例如纸或类似物的不粘拒水涂料 。

公开(公告)号：US08901269B2

公开(公告)日：2014-12-02

申请号：US13636658

申请日：2011-03-22

申请人： Sébastien Marrot ,  John White ,  Michel Feder ,  Fédéric Magd

发明人： Sébastien Marrot ,  John White ,  Michel Feder ,  Fédéric Magd

IPC分类号： C08G77/14 ,  C09D183/04 ,  C08G77/38

CPC分类号： C09D183/04 ,  C08G77/38 ,  C08L83/00

摘要： The invention relates to cross-linkable or cross-linked silicone compositions that can be used, in particular, to form a non-stick water-repellent coating for flexible substrates, for example paper or similar, in the form of natural or synthetic polymer films.

摘要翻译： 本发明涉及可交联或交联的有机硅组合物，其可以特别用于形成天然或合成聚合物膜形式的柔性基材例如纸或类似物的不粘拒水涂料 。

公开(公告)号：US08859635B2

公开(公告)日：2014-10-14

申请号：US13169215

申请日：2011-06-27

申请人： John White ,  Michel Feder ,  Alain Pouchelon ,  Yassine Maadadi ,  Lucile Gambut-Garel

发明人： John White ,  Michel Feder ,  Alain Pouchelon ,  Yassine Maadadi ,  Lucile Gambut-Garel

IPC分类号： C08L83/04 ,  C09D183/04 ,  C08G77/20 ,  C08G77/00 ,  C08G77/18 ,  C08G77/14

CPC分类号： C08L83/04 ,  C08G77/12 ,  C08G77/14 ,  C08G77/18 ,  C08G77/20 ,  C08G77/70 ,  C08G77/80 ,  C09D183/04 ,  Y10T428/31511 ,  C08L83/00

摘要： Silicone composites subject to reticulation or reticulated, particularly for creating a coating or water-repellent and anti-adhesive film for flexible substrates such as paper or similar in the form of natural or synthetic polymer films. These compounds contain reticulating polyorganosiloxanes that have SiH units and unsaturated polyorganosiloxanes, preferably vinylated, suitable for reacting with the reticulating agent in an addition reaction and in the presence of platinum to form the reticulated anti-adhesive coating on the flexible substrate, plus at least one additive (D) to promote adhesion to it. A new liquid silicone compound can be applied without using a solvent, which is beneficial, that can be reticulated instantly to produce an anti-adhesive and/or water-repellent coating for the flexible substrate, giving very high quality reticulated silicone coatings, particularly in terms of sticking/adhering to the substrate, being harder to rub off and the anti-adhesion profile (sufficiently increase detaching force at high speed.

摘要翻译： 经过网状或网状的硅氧烷复合材料，特别是为天然或合成聚合物膜形式的柔性基材如纸或类似物形成涂层或防水防粘膜。 这些化合物含有网状聚有机硅氧烷，其具有SiH单元和不饱和聚有机硅氧烷，优选为乙烯基化，适于在加成反应中和在铂存在下与网状化合物反应，以在柔性基材上形成网状抗粘剂涂层，加上至少一种 添加剂（D）以促进其粘附。 可以在不使用溶剂的情况下施加新的液体硅氧烷化合物，这是有利的，其可以立即网状地制备用于柔性基材的抗粘合剂和/或防水涂料，提供非常高质量的网状硅氧烷涂料，特别是在 粘附/粘附在基材上的问题，难以擦去和防粘附特性（足以高速地提高分离力）。

公开(公告)号：US20110257288A1

公开(公告)日：2011-10-20

申请号：US13169215

申请日：2011-06-27

申请人： John White ,  Michel Feder ,  Alain Pouchelon ,  Yassine Maadadi ,  Lucile Gambut-Garel

发明人： John White ,  Michel Feder ,  Alain Pouchelon ,  Yassine Maadadi ,  Lucile Gambut-Garel

IPC分类号： C09D183/04 ,  B05D3/10 ,  C07F7/08

CPC分类号： C08L83/04 ,  C08G77/12 ,  C08G77/14 ,  C08G77/18 ,  C08G77/20 ,  C08G77/70 ,  C08G77/80 ,  C09D183/04 ,  Y10T428/31511 ,  C08L83/00

摘要： Silicone composites subject to reticulation or reticulated, particularly for creating a coating or water-repellent and anti-adhesive film for flexible substrates such as paper or similar in the form of natural or synthetic polymer films. These compounds contain reticulating polyorganosiloxanes that have SiH units and unsaturated polyorganosiloxanes, preferably vinylated, suitable for reacting with the reticulating agent in an addition reaction and in the presence of platinum to form the reticulated anti-adhesive coating on the flexible substrate, plus at least one additive (D) to promote adhesion to it. A new liquid silicone compound can be applied without using a solvent, which is beneficial, that can be reticulated instantly to produce an anti-adhesive and/or water-repellent coating for the flexible substrate, giving very high quality reticulated silicone coatings, particularly in terms of sticking/adhering to the substrate, being harder to rub off and the anti-adhesion profile (sufficiently increase detaching force at high speed.

摘要翻译： 经过网状或网状的硅氧烷复合材料，特别是为天然或合成聚合物膜形式的柔性基材如纸或类似物形成涂层或防水防粘膜。 这些化合物含有网状聚有机硅氧烷，其具有SiH单元和不饱和聚有机硅氧烷，优选为乙烯基化，适于在加成反应中和在铂存在下与网状化合物反应，以在柔性基材上形成网状抗粘剂涂层，加上至少一种 添加剂（D）以促进其粘附。 可以在不使用溶剂的情况下施加新的液体硅氧烷化合物，这是有利的，其可以立即网状地制备用于柔性基材的抗粘合剂和/或防水涂料，提供非常高质量的网状硅氧烷涂料，特别是在 粘附/粘附在基材上的问题，难以擦去和防粘附特性（足以高速地提高分离力）。

公开(公告)号：US20100266856A1

公开(公告)日：2010-10-21

申请号：US12302039

申请日：2007-05-31

申请人： John White ,  Sean Duffy ,  Michel Feder ,  Alain Pouchelon

发明人： John White ,  Sean Duffy ,  Michel Feder ,  Alain Pouchelon

IPC分类号： C09D183/04 ,  B05D3/02 ,  B32B27/08

CPC分类号： C08J7/047 ,  C08G77/12 ,  C08G77/20 ,  C08G77/70 ,  C08G77/80 ,  C08J2483/00 ,  C08L83/04 ,  C09D183/04 ,  Y10T428/31663 ,  C08L83/00

摘要： Silicon compositions with the silicon compound ingredient A alkenylated PolyOrganoSiloxane (POS) containing an F1 fraction and an F2 fraction that are different from each other; F2, an adherence enhancer comprising a linear monoalkenylated silicon oil (A2.1) at one of its ends and/or a long linear α,ω,-alkenylated silicon oil (A2.2) and/or a “weakly alkenylated linear oil. Applications: non-stick silicon coatings obtained from crosslinking/polyaddition for PET.

摘要翻译： 具有硅化合物成分A的含硅组合物，含有彼此不同的F1级分和F2级分的烯基化聚硅氧烷（POS）; F2，其一端具有直链单烯基化硅油（A2.1）和/或长线型α，ω-烯基化硅油（A2.2）和/或“弱烯基化线型油”的粘附增强剂。 应用范围：从PET的交联/加聚获得的不粘硅涂层。

公开(公告)号：US08093339B2

公开(公告)日：2012-01-10

申请号：US12304554

申请日：2007-06-27

申请人： John White ,  Michel Feder ,  Alain Pouchelon ,  Yassine Maadadi ,  Lucile Gambut-Garel

发明人： John White ,  Michel Feder ,  Alain Pouchelon ,  Yassine Maadadi ,  Lucile Gambut-Garel

IPC分类号： C08L83/04

CPC分类号： C08L83/04 ,  C08G77/12 ,  C08G77/14 ,  C08G77/18 ,  C08G77/20 ,  C08G77/70 ,  C08G77/80 ,  C09D183/04 ,  Y10T428/31511 ,  C08L83/00

摘要： Silicone composites subject to reticulation or reticulated, particularly for creating a coating or water-repellent and anti-adhesive film for flexible substrates such as paper or similar in the form of natural or synthetic polymer films. These compounds contain reticulating polyorganosiloxanes that have SiH units and unsaturated polyorganosiloxanes, preferably vinylated, suitable for reacting with the reticulating agent in an addition reaction and in the presence of platinum to form the reticulated anti-adhesive coating on the flexible substrate, plus at least one additive (D) to promote adhesion to it. A new liquid silicone compound can be applied without using a solvent, which is beneficial, that can be reticulated instantly to produce an anti-adhesive and/or water-repellent coating for the flexible substrate, giving very high quality reticulated silicone coatings, particularly in terms of sticking/adhering to the substrate, being harder to rub off and the anti-adhesion profile (sufficiently increase detaching force at high speed.

摘要翻译： 经过网状或网状的硅氧烷复合材料，特别是为天然或合成聚合物膜形式的柔性基材如纸或类似物形成涂层或防水防粘膜。 这些化合物含有网状聚有机硅氧烷，其具有SiH单元和不饱和聚有机硅氧烷，优选为乙烯基化，适于在加成反应中和在铂存在下与网状化合物反应，以在柔性基材上形成网状抗粘剂涂层，加上至少一种 添加剂（D）以促进其粘附。 可以在不使用溶剂的情况下施加新的液体硅氧烷化合物，这是有利的，其可以立即网状地制备用于柔性基材的抗粘合剂和/或防水涂料，提供非常高质量的网状硅氧烷涂料，特别是在 粘附/粘附在基材上的问题，难以擦去和防粘附特性（足以高速地提高分离力）。

公开(公告)号：US20100028685A1

公开(公告)日：2010-02-04

申请号：US12304554

申请日：2007-06-27

申请人： John White ,  Michel Feder ,  Alain Pouchelon ,  Yassine Maadadi ,  Lucile Gambut-Garel

发明人： John White ,  Michel Feder ,  Alain Pouchelon ,  Yassine Maadadi ,  Lucile Gambut-Garel

IPC分类号： B32B27/08 ,  C09D183/06 ,  C07F7/00 ,  B05D3/02

CPC分类号： C08L83/04 ,  C08G77/12 ,  C08G77/14 ,  C08G77/18 ,  C08G77/20 ,  C08G77/70 ,  C08G77/80 ,  C09D183/04 ,  Y10T428/31511 ,  C08L83/00

摘要： Silicone composites subject to reticulation or reticulated, particularly for creating a coating or water-repellent and anti-adhesive film for flexible substrates such as paper or similar in the form of natural or synthetic polymer films. These compounds contain reticulating polyorganosiloxanes that have SiH units and unsaturated polyorganosiloxanes, preferably vinylated, suitable for reacting with the reticulating agent in an addition reaction and in the presence of platinum to form the reticulated anti-adhesive coating on the flexible substrate, plus at least one additive (D) to promote adhesion to it. A new liquid silicone compound can be applied without using a solvent, which is beneficial, that can be reticulated instantly to produce an anti-adhesive and/or water-repellent coating for the flexible substrate, giving very high quality reticulated silicone coatings, particularly in terms of sticking/adhering to the substrate, being harder to rub off and the anti-adhesion profile (sufficiently increase detaching force at high speed.

摘要翻译： 经过网状或网状的硅氧烷复合材料，特别是为天然或合成聚合物膜形式的柔性基材如纸或类似物形成涂层或防水防粘膜。 这些化合物含有网状聚有机硅氧烷，其具有SiH单元和不饱和聚有机硅氧烷，优选为乙烯基化，适于在加成反应中和在铂存在下与网状化合物反应，以在柔性基材上形成网状抗粘剂涂层，加上至少一种 添加剂（D）以促进其粘附。 可以在不使用溶剂的情况下施加新的液体硅氧烷化合物，这是有利的，其可以立即网状地制备用于柔性基材的抗粘合剂和/或防水涂料，提供非常高质量的网状硅氧烷涂料，特别是在 粘附/粘附在基材上的问题，难以擦去和防粘附特性（足以高速地提高分离力）。

公开(公告)号：US20110183566A1

公开(公告)日：2011-07-28

申请号：US13056173

申请日：2009-07-29

申请人： Michel Feder ,  Yassine Maadadi

发明人： Michel Feder ,  Yassine Maadadi

IPC分类号： D03D25/00 ,  C09K3/18 ,  B32B9/04 ,  D04H13/00

CPC分类号： D06M11/79 ,  C08G77/16 ,  C08L83/04 ,  C09D183/04 ,  D06M15/643 ,  Y10T428/31663 ,  Y10T442/2861 ,  Y10T442/3976 ,  Y10T442/696 ,  C08L83/00

摘要： Crosslinkable or crosslinked silicone compositions, forming water-repellent and release coating for a flexible heat sensitive support of paper or polymer, and comprising crosslinking polyorganosiloxanes (POSs) bearing ≡Si—H units and unsaturated, preferably ≡Si-Vi, vinyl-containing POSs, capable of reacting with the crosslinker by polyaddition, in the presence of platinum in order to form the crosslinked release coating on the flexible support. The object is enabling the coating composition to crosslink instantaneously to produce, on various flexible supports (paper, e.g. glassine, or polymer, e.g. polyester such as polyethylene terephthalate PET), a crosslinked silicone coating leaving the coating machine, with excellent attachment (adhesion) and mechanical strength or cohesion—“Rub-off”—properties. The invention uses, per 100 parts by weight of silicone base, of 1 to 40 parts by weight of an additive comprising from 1 or 5 to 80% by weight of particulate filler, preferably nanoscale filler, in a silicone oil reacting with the crosslinker.

摘要翻译： 可交联或交联的硅氧烷组合物，形成用于纸或聚合物的柔性热敏载体的防水和脱模涂层，并且包括交联含有≡Si-H单元的聚有机硅氧烷（POS）和不饱和的，优选≡Si-Vi，含乙烯基的POS 能够在铂的存在下通过加聚与交联剂反应，以便在柔性载体上形成交联的剥离涂层。 目的是使涂料组合物瞬间交联，在各种柔性载体（纸，例如玻璃纤维或聚合物，如聚酯如聚对苯二甲酸乙二酯PET）上生产出离开涂布机的交联硅氧烷涂层，具有优异的附着力（粘合性） 机械强度或凝聚力 - “脱落” - 性能。 本发明每100重量份的硅氧烷基使用1至40重量份的添加剂，该添加剂包含1至5重量％至80重量％的颗粒填料，优选纳米级填料，在与交联剂反应的硅油中。

公开(公告)号：US20060122323A1

公开(公告)日：2006-06-08

申请号：US10518401

申请日：2003-06-17

申请人： Laurent Dumont ,  Michel Feder ,  Francis Layfaysse ,  Sylvie Robelin

发明人： Laurent Dumont ,  Michel Feder ,  Francis Layfaysse ,  Sylvie Robelin

IPC分类号： C08L83/04 ,  B01F3/08 ,  B32B27/04

CPC分类号： D06N3/128 ,  C03C25/40 ,  C08G77/12 ,  C08G77/14 ,  C08G77/16 ,  C08G77/20 ,  C08G77/26 ,  C08G77/70 ,  C08L83/04 ,  D06M15/643 ,  Y10T428/31663 ,  C08L83/00

摘要： An aqueous polyorganosiloxane (POS) emulsion which can easily be deposited on/applied to a fibrous substrate at high speed and at limited deposition rates, for example less than 40 g/m2. The emulsion contains (A) a POS with ≡Si-vinyl units, (B) a POS with ≡SiH units, (C) an adhesion promoter, (D) a catalyst, (E) at least one surfactant, (F) optionally a POS resin with ≡Si-vinyl units, (G) optionally a crosslinking inhibitor, (H) optionally a pH fixing agent, (I) optionally a formulating additive, (J) optionally a filler, and (K) water. Adhesion promoter (C) is selected from protective hydrocolloids, hydroxylated silanes and/or POS carrying at least one hydroxyl group and at least one salified amino group per molecule, and mixtures thereof, and is present in the range from 0.005 to 10% by weight, based on the silicone phase. Also disclosed is the corresponding coating process and the coated substrate.

摘要翻译： 一种水溶性聚有机硅氧烷（POS）乳液，其可以容易地以高速和有限的沉积速率沉积在/施加到纤维基材上，例如小于40g / m 2。 乳液含有（A）具有≡Si-乙烯基单元的POS，（B）具有≡SiH单元的POS，（C）粘合促进剂，（D）催化剂，（E）至少一种表面活性剂，（F） 具有≡Si-乙烯基单元的POS树脂，（G）任选的交联抑制剂，（H）任选的pH固定剂，（I）任选的配制添加剂，（J）任选的填料和（K）水。 粘合促进剂（C）选自保护性水胶体，羟基化硅烷和/或POS，每个分子具有至少一个羟基和至少一个成盐氨基，以及它们的混合物，并且其含量范围为0.005-10重量％ ，基于有机硅相。 还公开了相应的涂覆工艺和涂覆的基材。

公开(公告)号：US08927627B2

公开(公告)日：2015-01-06

申请号：US13056173

申请日：2009-07-29

申请人： Michel Feder ,  Yassine Maadadi

发明人： Michel Feder ,  Yassine Maadadi

IPC分类号： C08K9/00 ,  C08K9/06 ,  B32B27/02 ,  B32B9/04 ,  D06M11/79 ,  C08L83/04 ,  C09D183/04 ,  D06M15/643 ,  C08G77/16

CPC分类号： D06M11/79 ,  C08G77/16 ,  C08L83/04 ,  C09D183/04 ,  D06M15/643 ,  Y10T428/31663 ,  Y10T442/2861 ,  Y10T442/3976 ,  Y10T442/696 ,  C08L83/00

摘要： Crosslinkable or crosslinked silicone compositions, forming water-repellent and release coating for a flexible heat sensitive support of paper or polymer, and comprising crosslinking polyorganosiloxanes (POSs) bearing ≡Si—H units and unsaturated, preferably ≡Si-Vi, vinyl-containing POSs, capable of reacting with the crosslinker by polyaddition, in the presence of platinum in order to form the crosslinked release coating on the flexible support. The object is enabling the coating composition to crosslink instantaneously to produce, on various flexible supports (paper, e.g. glassine, or polymer, e.g. polyester such as polyethylene terephthalate PET), a crosslinked silicone coating leaving the coating machine, with excellent attachment (adhesion) and mechanical strength or cohesion—“Rub-off”—properties. The invention uses, per 100 parts by weight of silicone base, of 1 to 40 parts by weight of an additive comprising from 1 or 5 to 80% by weight of particulate filler, preferably nanoscale filler, in a silicone oil reacting with the crosslinker.

摘要翻译： 可交联或交联的硅氧烷组合物，形成用于纸或聚合物的柔性热敏载体的防水和脱模涂层，并且包括交联含有≡Si-H单元的聚有机硅氧烷（POS）和不饱和的，优选≡Si-Vi，含乙烯基的POS 能够在铂的存在下通过加聚与交联剂反应，以便在柔性载体上形成交联的剥离涂层。 目的是使涂料组合物瞬间交联，在各种柔性载体（纸，例如玻璃纤维或聚合物，如聚酯如聚对苯二甲酸乙二酯PET）上生产出离开涂布机的交联硅氧烷涂层，具有优异的附着力（粘合性） 机械强度或凝聚力 - “脱落” - 性能。 本发明每100重量份的硅氧烷基使用1至40重量份的添加剂，该添加剂包含1至5重量％至80重量％的颗粒填料，优选纳米级填料，在与交联剂反应的硅油中。