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公开(公告)号：US4425455A
公开(公告)日：1984-01-10
申请号：US416945
申请日：1982-09-13
CPC分类号： C08L25/18 , C09K8/36 , Y10S507/91
摘要： The present invention relates to powdered sulfonated thermoplastic polymers which function as viscosification agents when added to oil-based drilling muds which are the fluids used to maintain pressure, cool drill bits and lift cuttings from the holes in the drilling operation for oil and gas wells. The powdered sulfonated thermoplastic polymer has about 5 to about 100 meq. of sulfonate groups per 100 grams of the sulfonated thermoplastic polymer, wherein the sulfonated groups are neutralized with a metallic cation or an amine or ammonium counterion. The powdered sulfonated thermoplastic polymers have a particle size range of 0.25 .mu.m to 2.5 .mu.m and are prepared by spray drying an emulsion of the sulfonated thermoplastic polymer which has been prepared by a free radical copolymerization process. A polar cosolvent can optionally be added to the mixture of oil drilling mud and sulfonated polymer, wherein the polar cosolvent increases the solubility of the sulfonated polymer in the oil drilling mud by decreasing the strong ionic interactions between the sulfonate groups of the sulfonated polymer.
摘要翻译： 本发明涉及粉末状磺化热塑性聚合物，当添加到油基钻井泥浆中时，其作为增粘剂，其是用于在油气井的钻井操作中从孔中保持压力的液体，冷钻头和提升切屑。 粉状磺化热塑性聚合物具有约5至约100meq。 的磺酸盐基团/ 100克磺化热塑性聚合物，其中磺化基团被金属阳离子或胺或铵抗衡离子中和。 粉状磺化热塑性聚合物的粒度范围为0.25μm至2.5μm，并通过喷雾干燥已经通过自由基共聚方法制备的磺化热塑性聚合物的乳液制备。 可以任选地将极性助溶剂加入到石油钻井泥浆和磺化聚合物的混合物中，其中极性助溶剂通过降低磺化聚合物的磺酸盐基团之间的强离子相互作用而增加磺化聚合物在石油钻井泥浆中的溶解度。
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2.发明授权Drilling fluids based on sulfonated thermoplastic polymers having improved low temperature rheological properties 失效基于具有改进的低温流变性能的磺化热塑性聚合物的钻井液
公开(公告)号：US4525522A
公开(公告)日：1985-06-25
申请号：US416935
申请日：1982-09-13
CPC分类号： C09K8/36
摘要： The present invention relates to latices of sulfonated thermoplastic polymers which function as viscosification agents when added to oil-based drilling muds which are the fluids used to maintain pressure, cool drill bits and lift cuttings from the holes in the drilling operation for oil and gas wells. The sulfonated thermoplastic polymer of the latex has about 5 to about 100 meq. of sulfonate groups per 100 grams of the sulfonated thermoplastic polymer, wherein the sulfonated groups are neutralized with a metallic cation or an amine or ammonium counterion. A polar cosolvent can optionally be added to the mixture of oil drilling mud and sulfonated polymer, wherein the polar cosolvent increases the solubility of the sulfonated polymer in the oil drilling mud by decreasing the strong ionic interactions between the sulfonate groups of the sulfonated polymer.
摘要翻译： 本发明涉及当添加到油基钻井泥浆中时作为增粘剂的磺化热塑性聚合物的胶乳，油基钻井泥浆是用于在油气井钻井操作中从孔中保持压力的液体，冷钻头和提升切屑 。 乳液的磺化热塑性聚合物具有约5至约100meq。 的磺酸盐基团/ 100克磺化热塑性聚合物，其中磺化基团被金属阳离子或胺或铵抗衡离子中和。 可以任选地将极性助溶剂加入到石油钻井泥浆和磺化聚合物的混合物中，其中极性助溶剂通过降低磺化聚合物的磺酸盐基团之间的强离子相互作用而增加磺化聚合物在石油钻井泥浆中的溶解度。
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3.发明授权Drilling fluids based on a mixture of a sulfonated thermoplastic polymer and a sulfonated elastomeric polymer 失效基于磺化热塑性聚合物和磺化弹性体聚合物的混合物的钻井液体
公开(公告)号：US4425461A
公开(公告)日：1984-01-10
申请号：US416936
申请日：1982-09-13
CPC分类号： C09K8/36
摘要： The present invention relates to mixtures of sulfonated thermoplastic polymers and sulfonated elastomeric polymers which function as viscosification agents when added to oil-based drilling muds which are the fluids used to maintain pressure, cool drill bits, and lift cuttings from the holes in the drilling operation for oil and gas wells. The sulfonated thermoplastic and elastomeric polymers both have about 5 to about 200 meq. of sulfonate groups per 100 grams of the sulfonated thermoplastic or elastomeric polymers, wherein the sulfonated groups are neutralized with a metallic cation or an amine or ammonium counterion. A polar cosolvent can optionally be added to the mixture of oil drilling mud and sulfonated thermoplastic and elastomeric polymers, wherein the polar cosolvent increases the solubility of the sulfonated thermoplastic and elastomeric polymer in the oil drilling mud by decreasing the strong ionic interactions between the sulfonate groups of the sulfonated polymers.
摘要翻译： 本发明涉及磺化热塑性聚合物和磺化弹性体聚合物的混合物，其在添加到油基钻井泥浆中时起粘稠剂的作用，油基钻井泥浆是用于在钻井操作中从孔中保持压力的液体，冷钻头和提升切屑 用于油气井。 磺化的热塑性和弹性体聚合物都具有约5至约200meq。 每100克磺化热塑性或弹性聚合物的磺酸盐基团，其中磺化基团被金属阳离子或胺或铵的抗衡离子中和。 可以任选地将极性助溶剂加入到油钻泥浆和磺化热塑性弹性体聚合物的混合物中，其中极性助溶剂通过降低磺酸盐基团之间的强离子相互作用而增加磺化热塑性弹性体聚合物在石油钻井泥浆中的溶解度 的磺化聚合物。
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4.发明授权Intramolecular polymer complexes - viscosifiers for high ionic strength drilling fluids 失效分子内聚合物复合物 - 用于高离子强度钻井液的增粘剂
公开(公告)号：US4540496A
公开(公告)日：1985-09-10
申请号：US478683
申请日：1983-03-25
IPC分类号： C09K8/04 , C08F20/52 , C08F220/56 , C08F220/60 , C09K8/12 , C09K8/24 , C09K7/02
CPC分类号： C09K8/12 , C08F220/56 , C09K8/24
摘要： A new family of terpolymers based on acrylamide/sodium styrene sulfonate/methacrylamidopropyltrimethylammonium chloride has been found to be an improved viscosity control additive for water-based drilling muds. The resultant muds display good viscosity characteristics, thermal stability and gel strength when formulated from the terpolymer intramolecular complex having the appropriate polymer concentration and salt level.
摘要翻译： 已经发现，一种新的基于丙烯酰胺/苯乙烯磺酸钠/甲基丙烯酰胺基丙基三甲基氯化铵的三元共聚物是用于水基钻井泥浆的改进的粘度控制添加剂。 当由具有适当聚合物浓度和盐水平的三元共聚物分子内复合物配制时，所得泥浆显示出良好的粘度特性，热稳定性和凝胶强度。
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5.发明授权Drilling fluids based on a mixture of sulfonated thermoplastic polymer and an amine-treated clay 失效基于磺化热塑性聚合物和胺处理粘土的混合物的钻井液
公开(公告)号：US4425463A
公开(公告)日：1984-01-10
申请号：US416934
申请日：1982-09-13
申请人： Thad O. Walker , S. Richard Turner , Robert D. Lundberg , Warren A. Thaler , Dennis G. Pfeiffer
发明人： Thad O. Walker , S. Richard Turner , Robert D. Lundberg , Warren A. Thaler , Dennis G. Pfeiffer
CPC分类号： C09K8/36 , Y10S507/901 , Y10S507/91
摘要： The present invention relates to mixtures of sulfonated thermoplastic polymers and amine-treated clays which function as viscosification agents when added to oil-based drilling muds which are the fluids used to maintain pressure, cool drill bits and lift cuttings from the holes in the drilling operation for oil and gas wells. The sulfonated thermoplastic polymers have about 5 to about 100 meq. of sulfonate groups per 100 grams of the sulfonated thermoplastic polymer, wherein the sulfonated groups are neutralized with a metallic cation or an amine or ammonium counterion. A polar cosolvent can optionally be added to the mixture of oil drilling mud and sulfonated thermoplastic polymer, wherein the polar cosolvent increases the solubility of the sulfonated thermoplastic polymer in the oil drilling mud by decreasing the strong ionic interactions between the sulfonate groups of the sulfonated polymer.
摘要翻译： 本发明涉及磺化热塑性聚合物和胺处理粘土的混合物，当加入油基钻井泥浆中时，其作为增粘剂起作用，油基钻井泥浆是用于在钻井操作中从孔中保持压力的液体，冷钻头和提升切屑 用于油气井。 磺化热塑性聚合物具有约5至约100meq。 的磺酸盐基团/ 100克磺化热塑性聚合物，其中磺化基团被金属阳离子或胺或铵抗衡离子中和。 可以任选地将极性助溶剂加入到油钻泥浆和磺化热塑性聚合物的混合物中，其中极性助溶剂通过降低磺化聚合物的磺酸盐基团之间的强离子相互作用而增加磺化热塑性聚合物在石油钻井泥浆中的溶解度 。
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公开(公告)号：US4425462A
公开(公告)日：1984-01-10
申请号：US416937
申请日：1982-09-13
IPC分类号： C08F236/10 , C09K8/36 , C08K3/24 , C08L25/08 , C09K7/02
CPC分类号： C08F236/10 , C09K8/36 , Y10S507/91
摘要： The present invention relates to sulfonated elastomeric polymers which are copolymers of isoprene and sodium styrene sulfonate or teropolymers of isoprene, styrene and sodium styrene sulfonate wherein these sulfonated polymers function as viscosification agents when added to oil-based drilling muds which are the fluids used to maintain pressure, cool drill bits and lift cuttings from the holes in the drilling operation for oil and gas wells. The sulfonated and elastomeric polymers have about 5 to about 100 meq. of sulfonate groups per 100 grams of the sulfonated elastomeric polymer, wherein the sulfonated groups are neutralized with a metallic cation or an amine or ammonium counterion. A polar cosolvent can optionally be added to the mixture of oil drilling mud and sulfonated elastomeric polymer, wherein the polar cosolvent increases the solubility of the sulfonated elastomeric polymer in the oil drilling mud by decreasing the strong ionic interactions between the sulfonate groups of the sulfonated polymer.
摘要翻译： 本发明涉及作为异戊二烯和苯乙烯磺酸钠的共聚物或异戊二烯，苯乙烯和苯乙烯磺酸钠的三元共聚物的磺化弹性体聚合物，其中这些磺化聚合物当加入到用作维持的流体的油基钻井泥浆中时用作粘稠剂 石油和天然气井的钻井操作中的孔中的压力，冷钻头和提升切屑。 磺化和弹性聚合物具有约5至约100meq。 每100克磺化弹性体聚合物的磺酸盐基团，其中磺化基团被金属阳离子或胺或铵抗衡离子中和。 可以任选地将极性助溶剂加入到油钻泥浆和磺化弹性体聚合物的混合物中，其中极性助溶剂通过降低磺化聚合物的磺酸盐基团之间的强离子相互作用而增加磺化弹性体聚合物在石油钻井泥浆中的溶解度 。
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7.发明授权Intramolecular polymeric complexes-viscosifiers for acid, base and salt (aqueous) solutions 失效分子内聚合复合物 - 用于酸，碱和盐（水溶液）的增粘剂
公开(公告)号：US4461884A
公开(公告)日：1984-07-24
申请号：US478657
申请日：1983-03-25
IPC分类号： C08F12/00 , C08F20/00 , C08F20/52 , C08F212/00 , C08F212/14 , C08F220/00 , C08F220/56 , C08F220/60 , C09K3/00 , C09K8/24 , C08F30/04 , C08F130/04 , C08F230/04
CPC分类号： C08F220/56 , C09K8/24
摘要： The present invention relates to improved viscosification agents for a variety of aqueous solutions which comprise a family of intramolecular polymeric complexes (i.e., polyampholytes) which are terpolymers of acrylamide/metal styrene sulfonate/methacrylamidopropyltrimethylammonium chloride (MAPTAC).The metal styrene sulfonate is an anionic monomer, while MAPTAC is cationically charged. These acrylamide-based polyampholytes have approximately 1 to about 50 mol % of the anionic monomer and approximately 1 to about 50 mole % of the cationic moiety present within the macromolecular structure. These groups are not necessarily present in an equimolar charge ratio. The excess undissociated charge allows for facile dispensability or solubility of the polyampholytes into fresh water.
摘要翻译： 本发明涉及用于各种水溶液的改性增稠剂，其包含作为丙烯酰胺/金属苯乙烯磺酸盐/甲基丙烯酰胺基丙基三甲基氯化铵（MAPTAC）的三元共聚物的分子内聚合物复合物（即聚阴离子）家族。 金属苯乙烯磺酸盐是阴离子单体，而MAPTAC是阳离子充电的。 这些基于丙烯酰胺的聚阴离子聚合物具有约1至约50mol％的阴离子单体和约1至约50mol％的存在于大分子结构内的阳离子部分。 这些基团不一定以等摩尔电荷比存在。 过量的未解离的电荷使得聚氨基甲酸酯易于分配或溶解在淡水中。
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公开(公告)号：US4460758A
公开(公告)日：1984-07-17
申请号：US547910
申请日：1983-11-02
IPC分类号： C08F220/56 , C08F20/00
CPC分类号： C08F220/56 , Y10S507/925 , Y10T137/0391
摘要： The present invention relates to improved drag reduction agents for aqueous solutions which comprises a polymeric complex which is a terpolymer of acrylamide/metal styrene sulfonate/methacrylamidopropyltrimethyl ammonium chloride.The metal styrene sulfonate is an anionic monomer, while MAPTAC is cationically charged. These acrylamide-based polyampholytes have approximately 1 to about 50 mole % of the anionic monomer and approximately 1 to about 50 mole % of the cationic moiety present within the macromolecular structure. These groups are not necessarily present in an equimolar charge ratio. The excess undissociated charge allows for facile dispensability or solubility of the polyampholytes into fresh water.
摘要翻译： 本发明涉及用于水溶液的改进的减阻剂，其包含聚合物络合物，其是丙烯酰胺/金属苯乙烯磺酸盐/甲基丙烯酰胺丙基三甲基氯化铵的三元共聚物。 金属苯乙烯磺酸盐是阴离子单体，而MAPTAC是阳离子充电的。 这些基于丙烯酰胺的聚阴离子聚合物具有约1至约50摩尔％的阴离子单体和约1至约50摩尔％的存在于大分子结构内的阳离子部分。 这些基团不一定以等摩尔电荷比存在。 过量的未解离的电荷使得聚氨基甲酸酯易于分配或溶解在淡水中。
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9.发明授权Sodium styrene sulfonate-co-sodium-n-(4-sulfophenyl)-maleimide- an improved viscosity control additive 失效苯乙烯磺酸钠 - 共 - 正 - （4-磺基苯基） - 马来酰亚胺 - 改进的粘度控制添加剂
公开(公告)号：US4478727A
公开(公告)日：1984-10-23
申请号：US416939
申请日：1982-09-13
CPC分类号： C09K8/24
摘要： A new copolymer of sodium styrene sulfonate-co-sodium-N-(4-sulfophenyl)-maleimidehas been found to be an improved viscosity control additive for water-based drilling muds.
摘要翻译： 已经发现苯乙烯磺酸钠 - 共 - 钠-N-（4-磺基苯基）马来酰亚胺的新共聚物是用于水基钻井泥浆的改进的粘度控制添加剂。
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公开(公告)号：US4552939A
公开(公告)日：1985-11-12
申请号：US563062
申请日：1983-12-19
IPC分类号： C08F212/06 , C08F228/02 , C08K5/17
CPC分类号： C08F212/06 , Y10T428/2982
摘要： This invention relates to the preparation of sulfonated copolymers having a particle size in the range of 10 to 5,000 .mu.m by a suspension copolymerization process, wherein an unsulfonated monomer is copolymerized with a sulfonated monomer such as the trioctylammonium salt of vinyl sulfonate monomer or the trioctylammonium salt of acrylamedomethylpropane sulfonate.
摘要翻译： 本发明涉及通过悬浮共聚方法制备粒度在10〜5000μm范围内的磺化共聚物，其中未磺化的单体与磺化单体如乙烯基磺酸酯单体的三辛基铵盐或三辛基铵 丙烯甲基丙烷磺酸盐。
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