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公开(公告)号：US11198746B2
公开(公告)日：2021-12-14
申请号：US16766018
申请日：2018-11-19
发明人： Peter Neuteboom , Diego Mauricio Castaneda Zuniga , Jan Nicolaas Eddy Duchateau , Franciscus Petrus Hermanus Schreurs , Jerome Vachon , Carolina De Los Angeles Toloza Porras
IPC分类号： C08F210/02 , C08F210/16 , C08F210/14
摘要： The present invention relates to an ethylene copolymer obtained by radical polymerisation through a high-pressure process comprising (i) ≥78.0 and ≤99.99 mole % of recurring units derived from ethylene; (it) ≥0.01 and ≤22.0 mole % of recurring units derived from comonomer A according to Formula (I), wherein R1 is composed of a saturated aliphatic moiety comprising 5-40 carbon atoms or R1 is composed of a saturated aliphatic moiety and consists of hydrogen atoms and 5-40 carbon atoms; R2 is selected from —H or —CH3; R3 is selected from —O—, —(CO)—(NH)— or —(CO)—O—; n=0 or 1 The ethylene copolymers have a reduced peak melting temperature and reduced enthalpy of fusion, indicating that these ethylene copolymers have a reduced degree of crystallinity and improved clarity, combined with a desired melt mass-flow rate.
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公开(公告)号：US20200347210A1
公开(公告)日：2020-11-05
申请号：US16930961
申请日：2020-07-16
发明人： Peter Neuteboom , Maria Soliman
IPC分类号： C08L23/06 , C09D123/06 , C08L23/16 , C08L51/06
摘要： The present invention relates to a polymer composition for use in thermal spray coating application comprising an α-olefin homopolymer or copolymer, a functionalized a-olefin homopolymer or copolymer, a polyolefinic elastomer and an anti-corrosion additive. Such polymer compositions have a good long-term corrosion resistance, good coating to substrate adhesion, good long-term adhesion and good long-term weather resistance.
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公开(公告)号：US20190002646A1
公开(公告)日：2019-01-03
申请号：US15743865
申请日：2016-06-30
摘要： The present invention relates to a process for producing polyolefin particles from a polyolefin composition, comprising the steps of: a) providing a melted composition of a polyolefin and b) providing particles from the melted composition by: b1) mixing a first flow of a supercritical fluid in the melted composition in a pressure vessel to obtain a solution saturated with the supercritical fluid and b2) passing the solution from the pressure vessel through a throttling device to a spraying tower to expand the solution to obtain the polyolefin particles in the spraying tower, wherein a second flow of a supercritical fluid is injected in the throttling device, wherein the supercritical fluid is a supercritical fluid of a substance selected from the group consisting of CO2, NH3, H2O, N2O, CH4, ethane, propane, propylene, n-butane, i-butane, n-pentane, benzene, methanol, ethanol, isopropanol, isobutanol, chlorotrifluoromethane, monofluoromethane, 1,1,1,2-Tetrafluoroethane, toluene, pyridine, cyclohexane, cyclohexanol, o-xylene, dimethyl ether and SF6 and combinations thereof.
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公开(公告)号：US20180223018A1
公开(公告)日：2018-08-09
申请号：US15738968
申请日：2016-06-06
发明人： Peter Neuteboom , Franciscus Petrus Hermanus Schreurs , Carolina de los Angeles Toloza Porras , Diego Mauricio Castaneda Zuniga , Jan Nicolaas Eddy Duchateau
IPC分类号： C08F210/02
CPC分类号： C08F210/02 , C08F4/34 , C08F232/04 , C08F2500/17 , C08F2500/04 , C08F2500/25 , C08F2500/26 , C08F2500/07
摘要： The present invention relates to an ethylene polymer comprising moieties according to formula (I): wherein R is a moiety comprising ≥1 and ≤10 carbon atoms; wherein the ethylene polymer has a molecular weight distribution of ≥3.0 and ≤13.0; the ethylene polymer has a melting temperature of ≥115° C.; the ethylene polymer has a density ≥935 and ≤960 kg/m3; the ethylene polymer is essentially free from chromium, hafnium, zirconium and tetrahydrofuran; for the fraction of the ethylene polymer having a molecular weight ≥100 kg/mol, the intrinsic viscosity of the ethylene polymer is related to the molecular weight according to the inequality: log I. V.
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公开(公告)号：US20210130568A1
公开(公告)日：2021-05-06
申请号：US16474849
申请日：2017-12-12
发明人： Diego Mauricio Castaneda Zuniga , Jerome Vachon , Jan Nicolaas Eddy Duchateau , Peter Neuteboom , Zeljko Knez
摘要： The present invention relates to a process for recycling polyolefin, comprising the steps of: 1) feeding a solid post-consumer polyolefin composition comprising polyolefin and contaminants and a flow of an extraction fluid to an extractor having a pressure of 100-1000 bar and a temperature of 20-80° C. to obtain a solid extracted composition, 2) melting the solid extracted composition to obtain a melted composition, 3) providing particles from the melted composition by: 3a) mixing a flow of a supercritical fluid in the melted composition in a pressure vessel to obtain a solution saturated with the supercritical fluid and 3b) passing the solution from the pressure vessel through a throttling device to a spraying tower to expand the solution to obtain polyolefin particles in the spraying tower.
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公开(公告)号：US10858462B2
公开(公告)日：2020-12-08
申请号：US16062184
申请日：2016-12-07
发明人： Diego Mauricio Castaneda Zuniga , Carolina de los Angeles Toloza Porras , Peter Neuteboom , Jan Nicolaas Eddy Duchateau , Jerome Vachon , Franciscus Petrus Hermanus Schreurs
IPC分类号： C08F220/20 , C08F210/02 , C08F210/14 , C08J5/18 , C08F2/01 , C08F216/14 , C08F220/26 , C08K5/14 , C08K5/23 , C08F220/28
摘要： The present invention relates to an ethylene copolymer comprising: (iv) ≥78.0 and ≤99.9 mol % of recurring units derived from ethylene; (v) ≥0.10 and ≤20.0 mol % of a recurring units derived from a comonomer A according to formula (I) wherein R1 is a moiety comprising 1-30 carbon atoms; R2 is selected from —H or —CH3; R3 is selected from —O—, —(CO)—(NH)— or —(CO)—O—; n=0 or 1; and m≥1 and ≤10; and (vi) ≥0.01 and ≤2.00 mol % of a recurring units derived from a comonomer B according to formula (II) wherein R1 is a moiety comprising 1-30 carbon atoms; each R2 may individually be selected from —H or —CH3; each of R3 is individually selected from —O—, —(CO)—(NH)— or —(CO)—O—; n=0 or 1; p=0 or 1; and m≥1 and ≤10; the mol % of each of (i), (ii) and (iii) being related to the sum of the mol % of (i), (ii) and (iii), the sum of the mol % of (i), (ii) and (iii) adding up to 100 mol %. Such ethylene copolymers have a reduced peak melting temperature and reduced enthalpy of fusion, indicating that these ethylene copolymers have a reduced degree of crystallinity and improved clarity and contact angle, combined with a desired melt mass-flow rate.
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公开(公告)号：US20170002188A1
公开(公告)日：2017-01-05
申请号：US15106432
申请日：2014-12-10
发明人： Peter Neuteboom , Pieter Valkier
CPC分类号： C08L23/14 , B29C45/0001 , B29K2023/10 , B29L2031/3055 , C08K3/34 , C08L23/0815 , C08L23/12 , C08L23/16 , C08L2205/025 , C08L2207/02 , C08L2308/00 , C08L2314/02
摘要： The present invention relates to a polyolefin composition comprising a first heterophasic propylene copolymer and a second heterophasic propylene copolymer, wherein the first heterophasic propylene copolymer comprises: from 70-90 wt % of a first polypropylene having a melt flow index of from 55-85 g/10 min as measured according to ISO 1133 (2.16 kg and 230° C.), from 10-30 wt % of a first ethylene α-olefin copolymer having a melt flow index of from 2.5-5.0 g/10 min in accordance with ISO 1133 (2.16 kg and 230° C.), the respective amounts of first polypropylene and first ethylene α-olefin copolymer being based on the weight of the first heterophasic propylene copolymer and wherein the second heterophasic propylene copolymer comprises: from 60-85 wt % of a second polypropylene having a melt flow index of from 50-100 g/10 min as measured according to ISO 1133 (2.16 kg, 230° C.), from 15-40 wt % of a second ethylene α-olefin copolymer having a melt flow index of from 0.050-0.30 g/10 min in accordance with ISO 1133 (2.16 kg and 230° C.), the respective amounts of second polypropylene and second ethylene α-olefin copolymer being based on the weight of the second heterophasic propylene copolymer, and wherein a weight ratio of said first and second heterophasic propylene copolymer is from 1 to 10. The invention further relates to automotive parts comprising said composition and having good tiger stripe performance.
摘要翻译： 本发明涉及包含第一多相丙烯共聚物和第二多相丙烯共聚物的聚烯烃组合物，其中第一多相丙烯共聚物包含：70-90重量％的熔体流动指数为55-85g的第一聚丙烯 / 10分钟，根据ISO 1133（2.16kg和230℃）测量，10-30wt％的熔体流动指数为2.5-5.0g / 10min的第一乙烯α-烯烃共聚物根据 ISO 1133（2.16kg和230℃），第一聚丙烯和第一乙烯α-烯烃共聚物的相应量基于第一多相丙烯共聚物的重量，其中第二多相丙烯共聚物包含：60-85wt ％的根据ISO 1133（2.16kg，230℃）测量的熔体流动指数为50-100g / 10min的第二聚丙烯，15-40wt％的第二乙烯α-烯烃共聚物，其具有 熔体流动指数为0.050-0.30g / 10 min，根据ISO 1133（2.16kg和230℃），第二聚丙烯和第二乙烯α-烯烃共聚物的相应量基于第二异相丙烯共聚物的重量，并且其中所述第一和第二乙烯α-烯烃共聚物的重量比 第二异相丙烯共聚物为1〜10。本发明还涉及包含所述组合物并具有良好的虎条纹性能的汽车部件。
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公开(公告)号：US10696763B2
公开(公告)日：2020-06-30
申请号：US15755123
申请日：2016-07-14
发明人： Diego Mauricio Castaneda Zuniga , Peter Neuteboom , Jan Nicolaas Eddy Duchateau , Carolina de los Angeles Toloza Porras , Franciscus Petrus Hermanus Schreurs , Jerome Vachon
IPC分类号： C08F210/02 , C08F2/02
摘要： The present invention relates to a process for the production of ethylene polymers in a tubular reactor comprising reacting in said tubular reactor a feed composition comprising ethylene and one or more composition comprising one or more cyclic olefin wherein the cyclic olefin is a compound having the structure of Formula (I): wherein R may be a moiety comprising ≥1 and ≤10 carbon atoms; wherein R1 and R2 may each individually be hydrogen or a moiety comprising ≥1 and ≤5 carbon atoms, R1 and R2 may be the same or different; wherein ⋅ the tubular reactor may be operated at a pressure of ≥200 and ≤280 MPa; ⋅ the average reaction peak temperature may be ≥220° C. and ≤300° C.; ⋅ the composition comprising one or more cyclic olefin may be fed to the reactor in one or more feed inlet of said tubular reactor; and ⋅ said cyclic olefin may be fed to the tubular reactor in quantities of ≤1.0 mol %, with regards to the total feed composition. Such process allows for the production of ethylene polymers having a high density and a high purity.
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公开(公告)号：US10150826B2
公开(公告)日：2018-12-11
申请号：US15327526
申请日：2015-07-23
发明人： Jan Nicolaas Eddy Duchateau , Peter Neuteboom , Diego Mauricio Castaneda Zuniga , Markus Busch , Sebastian Bruno Fries
IPC分类号： C08F210/02 , C08J5/18 , C08F2/38 , C08F238/00 , C08F4/34
摘要： A process for preparing an ethylene copolymer in the presence of free-radical polymerization initiator at pressures from 150 MPa to 350 MPa and temperatures from 100° C. to 350° C., by copolymerizing ethylene and a comonomer having a C≡C bond and optionally further comonomers, wherein the comonomer having the C≡C bond is represented by formula wherein R1 is hydrogen or methyl; X1 is —CO—O— or —CO—NH—; R2 is —CH2—O—, —O—CO—, —Si(CH3)2—, —Si(CH3)2—O— or —CR5R6— wherein R5 and R6 are independently selected from hydrogen, methyl, ethyl and hydroxyl; n is an integer from 1 to 32 and R2 is same or different from each other when n is 2 to 32; and R3 is —C≡C— and R4 is hydrogen, C1-C10 linear or branched alkyl, C1-C10 linear or branched hydroxyalkyl or phenyl, or the unit R3-R4 stands for wherein X2 is F, Cl, Br or I.
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公开(公告)号：US10047218B2
公开(公告)日：2018-08-14
申请号：US15106432
申请日：2014-12-10
发明人： Peter Neuteboom , Pieter Valkier
CPC分类号： C08L23/14 , B29C45/0001 , B29K2023/10 , B29L2031/3055 , C08K3/34 , C08L23/0815 , C08L23/12 , C08L23/16 , C08L2205/025 , C08L2207/02 , C08L2308/00 , C08L2314/02
摘要： The present invention relates to a polyolefin composition comprising a first heterophasic propylene copolymer and a second heterophasic propylene copolymer, wherein the first heterophasic propylene copolymer comprises: from 70-90 wt % of a first polypropylene having a melt flow index of from 55-85 g/10 min as measured according to ISO 1133 (2.16 kg and 230° C.), from 10-30 wt % of a first ethylene α-olefin copolymer having a melt flow index of from 2.5-5.0 g/10 min in accordance with ISO 1133 (2.16 kg and 230° C.), the respective amounts of first polypropylene and first ethylene α-olefin copolymer being based on the weight of the first heterophasic propylene copolymer and wherein the second heterophasic propylene copolymer comprises: from 60-85 wt % of a second polypropylene having a melt flow index of from 50-100 g/10 min as measured according to ISO 1133 (2.16 kg, 230° C.), from 15-40 wt % of a second ethylene α-olefin copolymer having a melt flow index of from 0.050-0.30 g/10 min in accordance with ISO 1133 (2.16 kg and 230° C.), the respective amounts of second polypropylene and second ethylene α-olefin copolymer being based on the weight of the second heterophasic propylene copolymer, and wherein a weight ratio of said first and second heterophasic propylene copolymer is from 1 to 10. The invention further relates to automotive parts comprising said composition and having good tiger stripe performance.
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