POLYPROPYLENE COMPOSITIONS
    1.
    发明申请

    公开(公告)号:US20180334558A1

    公开(公告)日:2018-11-22

    申请号:US15528146

    申请日:2015-11-10

    Abstract: The invention relates to a composition comprising (a) polypropylene having a melt mass flow rate as measured in accordance with ISO 1133 using a 2.16 kg weight and at a temperature of 230° C. in the range from 10 to 40 g/10 min and (b) a polymer preferably chosen from the group consisting of polyoxymethylene, polyamide and mixture thereof, wherein the amount of component (b) is from 0.005 to 5 wt % based on the total weight of the components (a) and (b) and wherein the polypropylene has a melt temperature TmPP and a crystallization temperature TcPP, the polymer has a melt temperature TmP and a crystallization temperature TcP, wherein the TcP is 5-40° C. higher than TcPP, wherein the Tm and Tc are determined using Differential Scanning Calorimetry according to ASTM D 3418-08 using a scan rate of 10° C./min on a sample of 10 mg and using the second heating cycle.

    Polypropylene compositions
    2.
    发明授权

    公开(公告)号:US10597522B2

    公开(公告)日:2020-03-24

    申请号:US15528146

    申请日:2015-11-10

    Abstract: The invention relates to a composition comprising (a) polypropylene having a melt mass flow rate as measured in accordance with ISO 1133 using a 2.16 kg weight and at a temperature of 230° C. in the range from 10 to 40 g/10 min and (b) a polymer preferably chosen from the group consisting of polyoxymethylene, polyamide and mixture thereof, wherein the amount of component (b) is from 0.005 to 5 wt % based on the total weight of the components (a) and (b) and wherein the polypropylene has a melt temperature TmPP and a crystallization temperature TcPP, the polymer has a melt temperature TmP and a crystallization temperature TcP, wherein the TcP is 5-40° C. higher than TcPP, wherein the Tm and Tc are determined using Differential Scanning Calorimetry according to ASTM D 3418-08 using a scan rate of 10° C./min on a sample of 10 mg and using the second heating cycle.

    Process for transitioning between incompatible catalysts

    公开(公告)号:US10822433B2

    公开(公告)日:2020-11-03

    申请号:US16063935

    申请日:2016-11-29

    Abstract: The invention relates to a process for transitioning from a first continuous polymerization in a gas phase reactor conducted in the presence of a metallocene catalyst to a second polymerization conducted in the presence of a Ziegler-Natta catalyst in the gas phase reactor wherein the metallocene catalyst and the Ziegler-Natta catalysts are incompatible, the process comprising: (a) discontinuing the introduction of the metallocene catalyst into the gas phase reactor; (b) introducing an effective amount of cyclohexylamine into the reactor to at least partially deactivate the metallocene catalyst; (c) introducing an organometallic compound into the reactor and reacting the organometallic compound with cyclohexylamine; (d) degas the gas composition of the reactor and build up a new composition inside the reactor for the second polymerization with the Ziegler-Natta catalyst (e) introducing the Ziegler-Natta catalyst into the reactor.

    PROCESS FOR TRANSITIONING BETWEEN INCOMPATIBLE CATALYSTS

    公开(公告)号:US20200270373A1

    公开(公告)日:2020-08-27

    申请号:US16063935

    申请日:2016-11-29

    Abstract: The invention relates to a process for transitioning from a first continuous polymerization in a gas phase reactor conducted in the presence of a metallocene catalyst to a second polymerization conducted in the presence of a Ziegler-Natta catalyst in the gas phase reactor wherein the metallocene catalyst and the Ziegler-Natta catalysts are incompatible, the process comprising: (a) discontinuing the introduction of the metallocene catalyst into the gas phase reactor; (b) introducing an effective amount of cyclohexylamine into the reactor to at least partially deactivate the metallocene catalyst; (c) introducing an organometallic compound into the reactor and reacting the organometallic compound with cyclohexylamine; (d) degas the gas composition of the reactor and build up a new composition inside the reactor for the second polymerization with the Ziegler-Natta catalyst (e) introducing the Ziegler-Natta catalyst into the reactor.

    PROCESS FOR TRANSITIONING BETWEEN INCOMPATIBLE CATALYSTS

    公开(公告)号:US20170342174A1

    公开(公告)日:2017-11-30

    申请号:US15537997

    申请日:2015-12-22

    Abstract: The invention relates to a process for transitioning from a first continuous polymerization reaction in a gas phase reactor conducted in the presence of a first catalyst to a second polymerization reaction conducted in the presence of a second catalyst in the gas phase reactor wherein the first and second catalysts are incompatible, the process comprising: (a) discontinuing the introduction of the first catalyst into the gas phase reactor; (b) introducing an effective amount of cyclohexylamine into the reactor to at least partially deactivate the first catalyst; (c) introducing an organometallic compound into the reactor and reacting the organometallic compound with cyclohexylamine; (d) introducing a gas composition into the reactor for the second polymerization reaction and (e) introducing the second catalyst into the reactor.

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