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公开(公告)号:US20180334558A1
公开(公告)日:2018-11-22
申请号:US15528146
申请日:2015-11-10
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor: Said Fellahi , Azzedine Kioul
CPC classification number: C08L23/12 , B29C45/0001 , B29K2023/12 , B29K2105/0094 , C08K7/14 , C08L23/10 , C08L59/02 , C08L77/02 , C08L2201/10 , C08L77/00
Abstract: The invention relates to a composition comprising (a) polypropylene having a melt mass flow rate as measured in accordance with ISO 1133 using a 2.16 kg weight and at a temperature of 230° C. in the range from 10 to 40 g/10 min and (b) a polymer preferably chosen from the group consisting of polyoxymethylene, polyamide and mixture thereof, wherein the amount of component (b) is from 0.005 to 5 wt % based on the total weight of the components (a) and (b) and wherein the polypropylene has a melt temperature TmPP and a crystallization temperature TcPP, the polymer has a melt temperature TmP and a crystallization temperature TcP, wherein the TcP is 5-40° C. higher than TcPP, wherein the Tm and Tc are determined using Differential Scanning Calorimetry according to ASTM D 3418-08 using a scan rate of 10° C./min on a sample of 10 mg and using the second heating cycle.
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公开(公告)号:US10597522B2
公开(公告)日:2020-03-24
申请号:US15528146
申请日:2015-11-10
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor: Said Fellahi , Azzedine Kioul
Abstract: The invention relates to a composition comprising (a) polypropylene having a melt mass flow rate as measured in accordance with ISO 1133 using a 2.16 kg weight and at a temperature of 230° C. in the range from 10 to 40 g/10 min and (b) a polymer preferably chosen from the group consisting of polyoxymethylene, polyamide and mixture thereof, wherein the amount of component (b) is from 0.005 to 5 wt % based on the total weight of the components (a) and (b) and wherein the polypropylene has a melt temperature TmPP and a crystallization temperature TcPP, the polymer has a melt temperature TmP and a crystallization temperature TcP, wherein the TcP is 5-40° C. higher than TcPP, wherein the Tm and Tc are determined using Differential Scanning Calorimetry according to ASTM D 3418-08 using a scan rate of 10° C./min on a sample of 10 mg and using the second heating cycle.
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公开(公告)号:US10822433B2
公开(公告)日:2020-11-03
申请号:US16063935
申请日:2016-11-29
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor: Yahya Banat , Abdulaziz Hamad Al-Humydi , Said Fellahi
IPC: C08F2/01 , C08F2/34 , B01J8/26 , C08F2/00 , C08F4/6592
Abstract: The invention relates to a process for transitioning from a first continuous polymerization in a gas phase reactor conducted in the presence of a metallocene catalyst to a second polymerization conducted in the presence of a Ziegler-Natta catalyst in the gas phase reactor wherein the metallocene catalyst and the Ziegler-Natta catalysts are incompatible, the process comprising: (a) discontinuing the introduction of the metallocene catalyst into the gas phase reactor; (b) introducing an effective amount of cyclohexylamine into the reactor to at least partially deactivate the metallocene catalyst; (c) introducing an organometallic compound into the reactor and reacting the organometallic compound with cyclohexylamine; (d) degas the gas composition of the reactor and build up a new composition inside the reactor for the second polymerization with the Ziegler-Natta catalyst (e) introducing the Ziegler-Natta catalyst into the reactor.
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公开(公告)号:US20180186906A1
公开(公告)日:2018-07-05
申请号:US15538013
申请日:2015-12-22
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor: Yahya BANAT , Abdulaziz Hamad Al-Humydi , Said Fellahi
IPC: C08F10/02
CPC classification number: C08F10/02 , C08F2/34 , C08F2/42 , C08F10/00 , C08F210/16 , C08F210/14 , C08F2500/12 , C08F2500/24
Abstract: The invention relates to a process for transitioning from a first continuous polymerization reaction in a gas phase reactor conducted in the presence of a first catalyst to a second polymerization reaction conducted in the presence of a second catalyst in the gas phase reactor wherein the first and second catalysts are incompatible, the process comprising: (a) discontinuing the introduction of the first catalyst from a first catalyst feeding system into a reactor; (b) introducing a catalyst killer to at least partially deactivate the first catalyst in the reactor (c) introducing into the reactor a second catalyst from a second catalyst feeding system separate from the first catalyst feeding system.
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公开(公告)号:US20170349734A1
公开(公告)日:2017-12-07
申请号:US15535273
申请日:2015-12-02
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor: Salaheldin M A. Habibi , Said Fellahi , Akhlaq A. Moman , Yahya Banat , Abdulaziz Hamad Al-Humydi
CPC classification number: C08L23/06 , C08J5/18 , C08J2323/06 , C08J2423/06 , C08L23/0815 , C08L2203/16 , C08L2205/025 , C08L2207/066 , C08L2314/02 , C08L2314/06 , C08F210/16 , C08F210/14 , C08F2500/12 , C08F2500/17 , C08F2500/26 , C08F2500/19 , C08F4/6546 , C08F4/6565 , C08F4/025
Abstract: The invention is directed to a polyethylene composition comprising 20-90 wt % of a LLDPE A and 80-10 wt % of a LLDPE B, wherein i) LLDPE A is obtainable by a process for producing a copolymer of ethylene and another α-olefin in the presence of an Advanced Ziegler-Natta catalyst, ii) LLDPE B is obtainable by a process for producing a copolymer of ethylene and another α-olefin in the presence of a metallocene catalyst.
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公开(公告)号:US20200270373A1
公开(公告)日:2020-08-27
申请号:US16063935
申请日:2016-11-29
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor: Yahya Banat , Abdulaziz Hamad Al-Humydi , Said Fellahi
IPC: C08F2/00 , C08F2/01 , C08F2/34 , C08F4/6592
Abstract: The invention relates to a process for transitioning from a first continuous polymerization in a gas phase reactor conducted in the presence of a metallocene catalyst to a second polymerization conducted in the presence of a Ziegler-Natta catalyst in the gas phase reactor wherein the metallocene catalyst and the Ziegler-Natta catalysts are incompatible, the process comprising: (a) discontinuing the introduction of the metallocene catalyst into the gas phase reactor; (b) introducing an effective amount of cyclohexylamine into the reactor to at least partially deactivate the metallocene catalyst; (c) introducing an organometallic compound into the reactor and reacting the organometallic compound with cyclohexylamine; (d) degas the gas composition of the reactor and build up a new composition inside the reactor for the second polymerization with the Ziegler-Natta catalyst (e) introducing the Ziegler-Natta catalyst into the reactor.
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公开(公告)号:US20180171125A1
公开(公告)日:2018-06-21
申请号:US15738591
申请日:2016-06-23
Applicant: SABIC Global Technologies B.V.
Inventor: Said Fellahi , Yahya Banat , Maria Johanna Willems , Bart van den Esschert , Abdulaziz Hamad Al-Humydi
CPC classification number: C08L23/06 , B65D81/18 , C08F2500/26 , C08J5/18 , C08J2323/08 , C08K5/0083 , C08K5/092 , C08K5/098 , C08L2203/16 , C08L2205/24 , C08L2207/066 , C08L2314/06
Abstract: The present invention relates to a polymer composition comprising a linear low-density polyethylene produced in the presence of a single-site catalyst system and 0.01-2.00% by weight of a nucleating agent, the linear low-density polyethylene having a density as determined according to ISO 1183-1 (2012), method A of >900 kg/m3and ≤940 kg/m3, wherein films produced using the polymer composition have a total defected area of ≤50 ppm of surface, the total defected area being the fraction of surface area of the film accounted for by gels having an equivalent diameter of >50 μm. Such polymer compositions are suitable for the production of films having a low oxygen transmission rate and a low water vapour transmission rate.
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公开(公告)号:US09944727B2
公开(公告)日:2018-04-17
申请号:US15537997
申请日:2015-12-22
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor: Yahya Banat , Abdulaziz Hamad Al-Humydi , Said Fellahi
CPC classification number: C08F10/02 , B01J8/0015 , B01J8/24 , B01J2208/00752 , C08F2/34 , C08F2/42 , C08F10/00
Abstract: The invention relates to a process for transitioning from a first continuous polymerization reaction in a gas phase reactor conducted in the presence of a first catalyst to a second polymerization reaction conducted in the presence of a second catalyst in the gas phase reactor wherein the first and second catalysts are incompatible, the process comprising: (a) discontinuing the introduction of the first catalyst into the gas phase reactor; (b) introducing an effective amount of cyclohexylamine into the reactor to at least partially deactivate the first catalyst; (c) introducing an organometallic compound into the reactor and reacting the organometallic compound with cyclohexylamine; (d) introducing a gas composition into the reactor for the second polymerization reaction and (e) introducing the second catalyst into the reactor.
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公开(公告)号:US20170342174A1
公开(公告)日:2017-11-30
申请号:US15537997
申请日:2015-12-22
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor: Yahya BANAT , Abdulaziz Hamad Al-Humydi , Said Fellahi
CPC classification number: C08F10/02 , B01J8/0015 , B01J8/24 , B01J2208/00752 , C08F2/34 , C08F2/42 , C08F10/00
Abstract: The invention relates to a process for transitioning from a first continuous polymerization reaction in a gas phase reactor conducted in the presence of a first catalyst to a second polymerization reaction conducted in the presence of a second catalyst in the gas phase reactor wherein the first and second catalysts are incompatible, the process comprising: (a) discontinuing the introduction of the first catalyst into the gas phase reactor; (b) introducing an effective amount of cyclohexylamine into the reactor to at least partially deactivate the first catalyst; (c) introducing an organometallic compound into the reactor and reacting the organometallic compound with cyclohexylamine; (d) introducing a gas composition into the reactor for the second polymerization reaction and (e) introducing the second catalyst into the reactor.
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