公开(公告)号：US20210403704A1

公开(公告)日：2021-12-30

申请号：US16490334

申请日：2018-08-16

Applicant: SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： Xing Liu ,  Wei Shan ,  Yaming Niu ,  Ying Na ,  Hongmei Zhou ,  Rahul Patil ,  Yusuf Sulub ,  Pooja Bajaj ,  Wei Zhao ,  Peter Vollenberg

IPC: C08L69/00 ,  C08G64/10 ,  C08G64/18 ,  C08L83/04 ,  C08F120/14 ,  C08L53/00 ,  C08L23/16 ,  C08L25/12 ,  C08L27/18 ,  B29C48/00

Abstract: A polycarbonate composition includes: a continuous polycarbonate phase; discontinuous first domains distributed in the continuous phase, and comprising a core-shell silicone-(meth)acrylate impact modifier comprising a silicone elastomer core and a (meth)acrylate copolymer shell, wherein the first domains have an aspect ratio of at least 1.7, preferably at least 1.8; and discontinuous second domains distributed in the continuous phase, and comprising an alkenyl aromatic-olefin block copolymer impact modifier, wherein the second domains have an aspect ratio of at least 3, preferably at least 4, and a domain size of 6400 square nanometers or less, more preferably 5700 square nanometers or less. Optionally, the polycarbonate composition includes: a polycarbonate; a brominated polycarbonate different from the polycarbonate; a poly(carbonate-siloxane) comprising 30 to 70 weight percent of siloxane blocks; a core-shell silicone-(meth)acrylate impact modifier comprising a silicone elastomer core and an (meth)acrylate copolymer shell; and an alkenyl aromatic-olefin block copolymer impact modifier.

公开(公告)号：US20210222002A1

公开(公告)日：2021-07-22

申请号：US17081734

申请日：2020-10-27

Applicant: SABIC Global Technologies B.V.

Inventor： Xing Liu ,  Wei Shan ,  Jian Wang

IPC: C08L69/00 ,  H01R13/527

Abstract: A thermoplastic polycarbonate composition comprising: 10 to 30 wt % of a brominated polycarbonate; 10 to 80 wt % of a homopolycarbonate; optionally, 1 to 60 wt % of an aromatic poly(ester-carbonate) comprising carbonate units derived from bisphenol A, resorcinol, or a combination thereof, and ester units derived from a bisphenol, preferably bisphenol A, or resorcinol, and terephthalic acid, isoterephthalic acid, or a combination thereof, wherein a molar ratio of carbonate units to ester units ranges from 1:99 to 99:1; 5 to 15 wt % of a core-shell impact modifier; 1 to 10 wt % of an α,β-unsaturated glycidyl ester copolymer impact modifier; 0.01 to 1 wt % of a hydrostabilizer, preferably an epoxy hydrostabilizer; optionally, 0.1 to 10 wt % of an additive composition; wherein the wt % of each component is based on the total weight of the composition, which totals 100 wt %.

公开(公告)号：US11332613B2

公开(公告)日：2022-05-17

申请号：US16490334

申请日：2018-08-16

Applicant: SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： Xing Liu ,  Wei Shan ,  Yaming Niu ,  Ying Na ,  Hongmei Zhou ,  Rahul Patil ,  Yusuf Sulub ,  Pooja Bajaj ,  Wei Zhao ,  Peter Vollenberg

IPC: C08L69/00 ,  C08L53/00 ,  C08L83/04 ,  B29C48/00 ,  C08F120/14 ,  C08G64/10 ,  C08G64/18 ,  C08L23/16 ,  C08L25/12 ,  C08L27/18

Abstract: A polycarbonate composition includes: a continuous polycarbonate phase; discontinuous first domains distributed in the continuous phase, and comprising a core-shell silicone-(meth)acrylate impact modifier comprising a silicone elastomer core and a (meth)acrylate copolymer shell, wherein the first domains have an aspect ratio of at least 1.7, preferably at least 1.8; and discontinuous second domains distributed in the continuous phase, and comprising an alkenyl aromatic-olefin block copolymer impact modifier, wherein the second domains have an aspect ratio of at least 3, preferably at least 4, and a domain size of 6400 square nanometers or less, more preferably 5700 square nanometers or less. Optionally, the polycarbonate composition includes: a polycarbonate; a brominated polycarbonate different from the polycarbonate; a poly(carbonate-siloxane) comprising 30 to 70 weight percent of siloxane blocks; a core-shell silicone-(meth)acrylate impact modifier comprising a silicone elastomer core and an (meth)acrylate copolymer shell; and an alkenyl aromatic-olefin block copolymer impact modifier.