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公开(公告)号：US20210403704A1
公开(公告)日：2021-12-30
申请号：US16490334
申请日：2018-08-16
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor： Xing Liu , Wei Shan , Yaming Niu , Ying Na , Hongmei Zhou , Rahul Patil , Yusuf Sulub , Pooja Bajaj , Wei Zhao , Peter Vollenberg
IPC: C08L69/00 , C08G64/10 , C08G64/18 , C08L83/04 , C08F120/14 , C08L53/00 , C08L23/16 , C08L25/12 , C08L27/18 , B29C48/00
Abstract: A polycarbonate composition includes: a continuous polycarbonate phase; discontinuous first domains distributed in the continuous phase, and comprising a core-shell silicone-(meth)acrylate impact modifier comprising a silicone elastomer core and a (meth)acrylate copolymer shell, wherein the first domains have an aspect ratio of at least 1.7, preferably at least 1.8; and discontinuous second domains distributed in the continuous phase, and comprising an alkenyl aromatic-olefin block copolymer impact modifier, wherein the second domains have an aspect ratio of at least 3, preferably at least 4, and a domain size of 6400 square nanometers or less, more preferably 5700 square nanometers or less. Optionally, the polycarbonate composition includes: a polycarbonate; a brominated polycarbonate different from the polycarbonate; a poly(carbonate-siloxane) comprising 30 to 70 weight percent of siloxane blocks; a core-shell silicone-(meth)acrylate impact modifier comprising a silicone elastomer core and an (meth)acrylate copolymer shell; and an alkenyl aromatic-olefin block copolymer impact modifier.
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公开(公告)号：US20190352497A1
公开(公告)日：2019-11-21
申请号：US16413866
申请日：2019-05-16
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor： Yagang Chen , Wei Shan , Shijie Song , Yaming Niu
Abstract: A polycarbonate composition contains, based on the total weight of the polycarbonate composition: one or more polycarbonate homopolymers; a poly(carbonate-siloxane) copolymer comprising siloxane units with an average block length of 5 to 120, preferably 10 to 100, the poly(carbonate-siloxane) copolymer being present in an amount effective to provide 2.5 to 10 wt % of siloxane units based on the total weight of the polycarbonate composition; 1 to 8 wt % of an elastomer-modified graft copolymer; 0.01 to 5 wt % of a silicone oil; and 0.1 to 8 wt % of an additive; and wherein the composition has a melt mass flow rate higher than 16 g/10 min, determined in accordance with ASTM D1238 under a load of 1.2 kg at 300° C. with a dwelling time of 300 seconds; and an Izod notched impact energy of at least 700 J/m measured at 23° C. on a sample of 3.2 mm thickness according to ASTM D256-10.
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公开(公告)号：US10005903B2
公开(公告)日：2018-06-26
申请号：US15023146
申请日：2015-03-09
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor： Jean-Francois Morizur , Yaming Niu , Robert Dirk van de Grampel , Miao Shen , Jian Yang
CPC classification number: C08L69/005 , C08K5/42 , C08L69/00 , C08L83/04
Abstract: A thermoplastic composition comprises: 35 to 45 weight percent of a branched, end capped polycarbonate, 55 to 70 weight percent of a poly(aliphatic ester-carbonate) having a weight average molecular weight of 15,000 to 25,000, a non-flourinated sulfonate salt flame retardant and a polysiloxane. Weight percent is based on the combined weight of the branched, end capped polycarbonate and poly(aliphatic ester-carbonate).
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Patent Agency Ranking
公开(公告)号：US20170362432A1
公开(公告)日：2017-12-21
申请号：US15023146
申请日：2015-03-09
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor： Jean-Francois Morizur , Yaming Niu , Robert Dirk van de Grampel , Miao Shen , Jian Yang
CPC classification number: C08L69/005 , C08K5/42 , C08L69/00 , C08L83/04
Abstract: A thermoplastic composition comprisese: 35 to 45 weight percent of a branched, end capped polycarbonate, 55 to 70 weight percent of a poly(aliphatic ester-carbonate) having a weight average molecular weight of 15,000 to 25,000, a non-flourinated sulfonate salt flame retardant and a polysiloxane. Weight percent is based on the combined weight of the branched, end capped polycarbonate and poly(aliphatic ester-carbonate).
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5.发明申请公开(公告)号：US20160130437A1
公开(公告)日：2016-05-12
申请号：US14988024
申请日：2016-01-05
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor： Jean-Francois Morizur , Yaming Niu , Thomas Evans
IPC: C08L69/00
CPC classification number: C08L69/00 , C08K5/005 , C08K5/0066 , C08K5/134 , C08K5/524 , C08K5/527 , C08K5/5435 , C08L2205/02
Abstract: Provided herein are branched polycarbonate resin compositions. The compositions include a first heat stabilizer, a second heat stabilizer, a branched polycarbonate, a cyclic siloxane, and a flame retardant salt. The compositions withstand discoloration and increased melt viscosity when exposed to elevated temperatures. These compositions are useful in the manufacture of various shaped, formed and/or molded articles.
Abstract translation: 本文提供支链聚碳酸酯树脂组合物。 组合物包括第一热稳定剂，第二热稳定剂，支链聚碳酸酯，环状硅氧烷和阻燃盐。 当暴露于升高的温度时，组合物耐受变色和增加的熔体粘度。 这些组合物可用于制造各种成型，成型和/或模塑制品。
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公开(公告)号：US11332613B2
公开(公告)日：2022-05-17
申请号：US16490334
申请日：2018-08-16
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor： Xing Liu , Wei Shan , Yaming Niu , Ying Na , Hongmei Zhou , Rahul Patil , Yusuf Sulub , Pooja Bajaj , Wei Zhao , Peter Vollenberg
IPC: C08L69/00 , C08L53/00 , C08L83/04 , B29C48/00 , C08F120/14 , C08G64/10 , C08G64/18 , C08L23/16 , C08L25/12 , C08L27/18
Abstract: A polycarbonate composition includes: a continuous polycarbonate phase; discontinuous first domains distributed in the continuous phase, and comprising a core-shell silicone-(meth)acrylate impact modifier comprising a silicone elastomer core and a (meth)acrylate copolymer shell, wherein the first domains have an aspect ratio of at least 1.7, preferably at least 1.8; and discontinuous second domains distributed in the continuous phase, and comprising an alkenyl aromatic-olefin block copolymer impact modifier, wherein the second domains have an aspect ratio of at least 3, preferably at least 4, and a domain size of 6400 square nanometers or less, more preferably 5700 square nanometers or less. Optionally, the polycarbonate composition includes: a polycarbonate; a brominated polycarbonate different from the polycarbonate; a poly(carbonate-siloxane) comprising 30 to 70 weight percent of siloxane blocks; a core-shell silicone-(meth)acrylate impact modifier comprising a silicone elastomer core and an (meth)acrylate copolymer shell; and an alkenyl aromatic-olefin block copolymer impact modifier.
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公开(公告)号：US11104796B2
公开(公告)日：2021-08-31
申请号：US16413866
申请日：2019-05-16
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor： Yagang Chen , Wei Shan , Shijie Song , Yaming Niu
Abstract: A polycarbonate composition contains, based on the total weight of the polycarbonate composition: one or more polycarbonate homopolymers; a poly(carbonate-siloxane) copolymer comprising siloxane units with an average block length of 5 to 120, preferably 10 to 100, the poly(carbonate-siloxane) copolymer being present in an amount effective to provide 2.5 to 10 wt % of siloxane units based on the total weight of the polycarbonate composition; 1 to 8 wt % of an elastomer-modified graft copolymer; 0.01 to 5 wt % of a silicone oil; and 0.1 to 8 wt % of an additive; and wherein the composition has a melt mass flow rate higher than 16 g/10 min, determined in accordance with ASTM D1238 under a load of 1.2 kg at 300° C. with a dwelling time of 300 seconds; and an Izod notched impact energy of at least 700 J/m measured at 23° C. on a sample of 3.2 mm thickness according to ASTM D256-10.
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公开(公告)号：US20200070204A1
公开(公告)日：2020-03-05
申请号：US16552509
申请日：2019-08-27
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor： Fen Zhang , Hengjie Lai , Yaming Niu , Yapeng Fang
Abstract: A polycarbonate article comprises: a substrate comprising a poly(carbonate-bisphenol arylate ester) composition that comprises, based on the total weight of the poly(carbonate-bisphenol arylate ester) composition, 90 to 99.9 wt. %, preferably 95 to 99.9 wt. % of a poly(carbonate-bisphenol arylate ester), and 0.1 to 10 wt. %, preferably 0.1 to 5 wt. % of an additive comprising at least one of a processing aid, a heat stabilizer, an antioxidant, and an ultra violet light absorber; and a siloxane urethane acrylate coating disposed on at least a portion of a surface of the substrate, the siloxane urethane acrylate coating having a thickness of greater than or equal to 8 micrometers; wherein the article has a pencil hardness of 2H or harder when measured according to ASTM D3363-00 at 1,000 g force on the siloxane urethane acrylate coating.
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