公开(公告)号：US20150070933A1

公开(公告)日：2015-03-12

申请号：US14289253

申请日：2014-05-28

Applicant: SABIC Innovative Plastics IP B.V.

Inventor： Joshua Arie van den Bogerd ,  Johannes de Brouwer

IPC: F21V3/04 ,  F21V8/00 ,  F21S8/10 ,  F21V5/04

CPC classification number: F21V3/0436 ,  C08K5/1515 ,  C08K5/529 ,  F21S41/285 ,  F21V3/062 ,  F21V5/04 ,  F21V5/045 ,  G02B6/0005 ,  G02B6/0065 ,  Y10T29/49826 ,  C08L69/00

Abstract: Illuminating devices are disclosed having plastic light-transmitting article(s) formed from a thermoplastic composition including a polycarbonate having repeating structural carbonate units according to the formula: in which at least 60 percent of the total number of R1 groups contain aromatic moieties and the balance thereof are aliphatic, alicyclic, or aromatic. The composition also includes an epoxy additive having at least two epoxy groups per molecule and a phenolic diphosphite derived from pentaerythritol. The thermoplastic composition exhibits a dE (2000 hrs.) value of less than 1.5 after 2000 hours of heat aging at 130° C., measured according ISO 11664-4:2008(E)/CIE S 014-4/E:2007 using CIE illuminant D65 and a 2.5 mm thick molded plaque of the thermoplastic composition.

Abstract translation: 公开了一种照明装置，其具有由热塑性组合物形成的塑料透光制品，所述热塑性组合物包含具有根据下式的重复结构碳酸酯单元的聚碳酸酯：其中R1基团总数的至少60％含有芳族部分，余量 是脂族的，脂环族的或芳族的。 该组合物还包括每分子具有至少两个环氧基的环氧添加剂和衍生自季戊四醇的酚二磷酸酯。 根据ISO 11664-4：2008（E）/ CIE S 014-4 / E：2007使用热塑性组合物在130℃下热老化2000小时后，dE（2000小时）值小于1.5。 CIE发光体D65和2.5mm厚的热塑性组合物的模板。

公开(公告)号：US09772086B2

公开(公告)日：2017-09-26

申请号：US14289253

申请日：2014-05-28

Applicant: SABIC Innovative Plastics IP B.V.

Inventor： Joshua Arie van den Bogerd ,  Johannes de Brouwer

IPC: F21V3/00 ,  F21V5/00 ,  F21V7/04 ,  B21D39/03 ,  F21V3/04 ,  C08K5/1515 ,  C08K5/529 ,  F21S8/10 ,  F21V5/04 ,  F21V8/00

CPC classification number: F21V3/0436 ,  C08K5/1515 ,  C08K5/529 ,  F21S41/285 ,  F21V3/062 ,  F21V5/04 ,  F21V5/045 ,  G02B6/0005 ,  G02B6/0065 ,  Y10T29/49826 ,  C08L69/00

Abstract: Illuminating devices are disclosed having plastic light-transmitting article(s) formed from a thermoplastic composition including a polycarbonate having repeating structural carbonate units according to the formula: in which at least 60 percent of the total number of R1 groups contain aromatic moieties and the balance thereof are aliphatic, alicyclic, or aromatic. The composition also includes an epoxy additive having at least two epoxy groups per molecule and a phenolic diphosphite derived from pentaerythritol. The thermoplastic composition exhibits a dE (2000 hrs.) value of less than 1.5 after 2000 hours of heat aging at 130° C., measured according ISO 11664-4:2008(E)/CIE S 014-4/E:2007 using CIE illuminant D65 and a 2.5 mm thick molded plaque of the thermoplastic composition.

公开(公告)号：US20140357765A1

公开(公告)日：2014-12-04

申请号：US14289228

申请日：2014-05-28

Applicant: SABIC INNOVATIVE PLASTICS IP B.V.

Inventor： Joshua Arie van den Bogerd ,  Johannes de Brouwer

IPC: G02B1/04

CPC classification number: G02B1/04 ,  C08K5/1515 ,  C08K5/527 ,  C08K5/529 ,  C08L69/00

Abstract: A plastic article formed from a thermoplastic composition including a polycarbonate having repeating structural carbonate units according to the formula: in which at least 60 percent of the total number of R1 groups contain aromatic moieties and the balance thereof are aliphatic, alicyclic, or aromatic. The composition also includes an epoxy additive having at least two epoxy groups per molecule and a phenolic diphosphite derived from pentaerythritol. The thermoplastic composition exhibits a dE (2000hrs.) value of less than 1.5 after 2000 hours of heat aging at 130° C., measured according ISO 11664-4:2008(E)/CIE S 014-4/E:2007 using CIE illuminant D65 and a 2.5 mm thick molded plaque of the thermoplastic composition.

Abstract translation: 一种由热塑性组合物形成的塑料制品，所述塑料制品包括具有根据下式的重复结构碳酸酯单元的聚碳酸酯：其中R 1基团总数的至少60％含有芳族部分，余量为脂族，脂环族或芳族。 该组合物还包括每分子具有至少两个环氧基的环氧添加剂和衍生自季戊四醇的酚二磷酸酯。 根据ISO 11664-4：2008（E）/ CIE S 014-4 / E：2007使用CIE测量，热塑性组合物在130℃下热老化2000小时后显示小于1.5的dE（2000hrs。）值 发光体D65和2.5mm厚的热塑性组合物的模塑板。

公开(公告)号：US09821523B2

公开(公告)日：2017-11-21

申请号：US14063042

申请日：2013-10-25

Applicant: SABIC Innovative Plastics IP B.V.

Inventor： Hendrikus Petrus Cornelis van Heerbeek ,  Frank Huijs ,  Johannes de Brouwer ,  Christopher Luke Hein

IPC: C08L69/00 ,  C08K5/357 ,  B29D11/00 ,  H01L33/56 ,  H01L33/50

CPC classification number: B29D11/0074 ,  C08K5/357 ,  H01L33/501 ,  H01L33/56 ,  C08L69/00

Abstract: A light emitting diode lighting device contains a light emitting diode and a lighting device component, wherein the device component comprises a polycarbonate composition comprising a bisphenol A polycarbonate; and 2,2′-(1,4-phenylene)bis(4H-3,1-benzoxazin-4-one) in an amount effective to provide a composition wherein a molded sample of the composition has a UL94 rating of V-2 or better at a thickness of 0.9 mm; an absorbance of less than 2 a.u. in the region of 370 to 380 nanometers; and an increase in yellowness index (ΔYI) of 12 or less at 2.5 mm thickness after heat aging at 130° C. for 5,000 hours.

公开(公告)号：US09006378B2

公开(公告)日：2015-04-14

申请号：US14289228

申请日：2014-05-28

Applicant: SABIC Innovative Plastics IP B.V.

Inventor： Joshua Arie van den Bogerd ,  Johannes de Brouwer

IPC: C08G64/00 ,  G02B1/04 ,  C08K5/1515 ,  C08K5/529 ,  C08G63/02

CPC classification number: G02B1/04 ,  C08K5/1515 ,  C08K5/527 ,  C08K5/529 ,  C08L69/00

Abstract: A plastic article formed from a thermoplastic composition including a polycarbonate having repeating structural carbonate units according to the formula: in which at least 60 percent of the total number of R1 groups contain aromatic moieties and the balance thereof are aliphatic, alicyclic, or aromatic. The composition also includes an epoxy additive having at least two epoxy groups per molecule and a phenolic diphosphite derived from pentaerythritol. The thermoplastic composition exhibits a dE (2000 hrs.) value of less than 1.5 after 2000 hours of heat aging at 130° C., measured according ISO 11664-4:2008(E)/CIE S 014-4/E:2007 using CIE illuminant D65 and a 2.5 mm thick molded plaque of the thermoplastic composition.

Abstract translation: 一种由热塑性组合物形成的塑料制品，所述塑料制品包括具有根据下式的重复结构碳酸酯单元的聚碳酸酯：其中R 1基团总数的至少60％含有芳族部分，余量为脂族，脂环族或芳族。 该组合物还包括每分子具有至少两个环氧基的环氧添加剂和衍生自季戊四醇的酚二磷酸酯。 根据ISO 11664-4：2008（E）/ CIE S 014-4 / E：2007使用热塑性组合物在130℃下热老化2000小时后，dE（2000小时）值小于1.5。 CIE发光体D65和2.5mm厚的热塑性组合物的模板。

公开(公告)号：US20140117393A1

公开(公告)日：2014-05-01

申请号：US14063042

申请日：2013-10-25

Applicant: SABIC Innovative Plastics IP B.V.

Inventor： Hendrikus Petrus Cornelis van Heerbeek ,  Frank Huijs ,  Johannes de Brouwer ,  Christopher Luke Hein

IPC: H01L33/52 ,  B29D11/00

CPC classification number: B29D11/0074 ,  C08K5/357 ,  H01L33/501 ,  H01L33/56 ,  C08L69/00

Abstract: A light emitting diode lighting device contains a light emitting diode and a lighting device component, wherein the device component comprises a polycarbonate composition comprising a bisphenol A polycarbonate; and 2,2′-(1,4-phenylene)bis(4H-3,1-benzoxazin-4-one) in an amount effective to provide a composition wherein a molded sample of the composition has a UL94 rating of V-2 or better at a thickness of 0.9 mm; an absorbance of less than 2 a.u. in the region of 370 to 380 nanometers; and an increase in yellowness index (ΔYI) of 12 or less at 2.5 mm thickness after heat aging at 130° C. for 5,000 hours.

Abstract translation: 发光二极管照明装置包含发光二极管和照明装置部件，其中装置部件包括包含双酚A聚碳酸酯的聚碳酸酯组合物; 和2,2' - （1,4-亚苯基）双（4H-3,1-苯并恶嗪-4-酮），其量可以有效地提供组合物，其中组合物的模塑样品的UL94等级为V-2 或更好的厚度为0.9mm; 吸光度小于2 a.u. 在370〜380纳米的区域; 并且在130℃下热老化5000小时后，2.5mm厚度的黄度指数（＆Dgr; YI）增加12或更小。