摘要:
Synthetic polymer compositions stabilized against photo- and thermal-deteriorations wherein there is incorporated, in a sufficient amount to prevent such deteriorations, at least one of the secondary amine derivatives having the formula
WHEREIN R1 and R2 may be the same or different and each represents a group capable of being derived from carboxylic acid and m and n individually are an integer of 4 or 5 and the metal salts thereof, said secondary amine derivatives being known per se.
摘要:
SYNTHETIC POLYMERS SUCH AS HOMOPOLYMERS OF OLEFINS, COPOLYMERS OF OLEFINES WITH OTHER ETHYLENICALLY UNSATURATED MONOMERS, POLYURETHANES, POLYAMIDES, POLYACETALS, POLYESTERS, POLYMERIZED VINYL MONOMERS AND THE LIKE ARE STABILIZED AGAINST PHOTO- AND THERMAL-DETERIORATIONS THEREOF BY HAVING INCORPORATED THEREIN AN EFFECTIVE AMOUNT OF ONE OF THE 2,5-TRI- OR TETRASUBSTITUTED-4-OXO (OR THRIOXO)-IMIDAZOLIDINES. AMONG THESE IMIDAZOLIDINES, SOME OF THE 2,5TRI- OR TETRAUBSTITUTED-4-OXO-IMIDAZOLIDINES ARE NOVEL SUBSTANCES AND OTHER IMIDAZOLIDINES AS SUCH ARE DISCLOSED IN THE PRIOR ART. THESE NOVEL AND OLD 2,5-TRI- OR TETRASUBSTITUTED-4-OXO-IMIDZOLIDINES ARE PREPARED BY A NOVEL PROCESS WHICH COMPRISES (1) REACTING THE CORRESPONDING A-AMINONITRILE WITH AN APPROPRIATE KETONE OR ALDEHYDE IN THE PRESENCE OF A BASIC CATALYST OR (2) REACTING THE CORRESPONDING A-AMINONITRILE WITH AN APPROPRIATE KETONE OR ALDEHYDE AND THEN SUBJECTING THE INTERMEDIATE. SCHIFF BASE TO THE ACTION OF A BASIC CATALYST.
摘要:
A novel piperidine derivative having a stabilizing effect on a synthetic polymeric material and a composition comprising said piperidine derivative and a synthetic polymeric material.