摘要:
WHEREIN ARYL IS FROM THE GROUP Z is bromine or chlorine, m and m'' are integers having a value of 1-7, y is an integer having a value of 1-5, i and i'' are integers having a value of 0-2, and A is cyano, nitro, lower alkoxy, lower alkyl, fluorine, dialkylamino, phenyl, halo-phenyl, benzyl or halo- benzyl and alkylene is a straight or branched chain alkylene group having from 1 to 6 carbon atoms.
Plastic compositions containing poly(phenylene oxide) and bisaryloxy compounds having the formula
摘要:
Synthetic polymer compositions stabilized against photo- and thermal-deteriorations wherein there is incorporated, in a sufficient amount to prevent such deteriorations, at least one of the secondary amine derivatives having the formula
WHEREIN R1 and R2 may be the same or different and each represents a group capable of being derived from carboxylic acid and m and n individually are an integer of 4 or 5 and the metal salts thereof, said secondary amine derivatives being known per se.
摘要:
New 2,4 bis-(3,5-di-tert.butyl-4-hydroxy-phenoxy)-s-triazines are stabilizers for organic materials. They are prepared by reacting the bis-(imino-carbonic acid-(3,5-di-tert.butyl-4hydroxyphenyl)ester)-imide with a corresponding carboxylic acid chloride.
摘要:
Hydroxypenyl acylamide compounds having the formula
ARE PREPARED BY REACTING AN ALKYL AMINOPHENOL WITH AN ACYL CHLORIDE. These compounds are useful as stabilizers of organic materials which are subject to oxidative deterioration.
WHEREIN R1 AND R2 ARE THE SAME OR DIFFERENT AND EACH IS A STRAIGHTOR BRANCHED ALKYL RESIDUE HAVING FROM 1 TO 12 CARBON ATOMS OR R1 AND R2, TOGETHER WITH THE CARBON ATOM TO WHICY THEY ARE BOUND FORM A CYCLOALKYL RESIDUE HAVING FROM 5 TO 12 CARBON ATOMS, R3 IS HYDROGEN, A STRAIGHT-OR BRACHED ALKYL RESIDUE HAVING FROM 1 TO 4 CARBON ATOMS, AN ARALKYL RESIDUE HAVING FROM 7 TO 9 CARBON ATOMS, OR A CYCLOALKYL RESIDUE HAVING 5 TO 6 CARBON ATOMS R4 IS HYDROGEN, A HYDROCARBYL RESIDUE HAVING FROM 1 TO 20 CARBON ATOMS, EITHER UNSUBSTITUTED OR SUBSTITUTED BY HALOGEN, OR INTERRUPTED BY ONE OR MORE OXYGEN OR SULPHUR ATOMS, OR R4 HAS THE STRUCTURE:
1-Y,2-R1,2-R2,6,6-DI(H3C-)-PIPERIDIN-4-YL-
WHEREIN Y IS HYDROGEN OR A STRAIGHT-OR BRANCHED ALKYL RESIDUE HAVING FROM 1 TO 12 CARBON ATOMS, AN ALKENYL RESIDUE HAVING FROM 3 TO 12 CARBON ATOMS OR AN ARALKYL RESIDUE HAVING FROM 7 TO 12 CARBON ATOMS AND R1 AND R2 HAVE THEIR PREVIOUS SIGNIFICANCE; X IS -O-, -S- OR >NR5 WHEREIN R5 HAS THE SAME SIGNIFICANCE AS R3; OR R4 AND R5, TOGETHER WITH THE NITROGEN ATOM TO WHICH THEY ARE BOUND FORM A HETEROCYCLIC RESIDUE HAVING FROM 4 TO 10 CARBON ATOMS.
摘要:
SYNTHETIC POLYMER COMPOSITIONS, PARTICULARYL POLYURETHANE COMPOSITIONS, STABILIZED AGAINST THEIR DETERIORATIONS WHICH CONTAIN AT LEAST ONE OF 6-SUBSTITUTED OR UNSUBSTITURED-5,5,7,7-TETRAMETHLPIPERIDINO-(5,4 = C)->3-TIAZOLINE2-SPIRO-4''-(1''-SUBSTITUTED OR UNSUBSTITUTED-2'',2'',6'',6''-TETRAMETHYLPIPERIDINE) COMPOUNDS. SUCH PIPERIDINO-TRIAZOLINE COMPOUNDS ARE PREPARED BY REACTING THE CORRESPONDING 2,2,6,6-TETRAMETHYL-PIPERIDINO-(5.4-C) ->3- THIAZOLINE-2-SPIROFUR UNDER THE STREAM OF GASEOUS NH3 OR BY REACTING 5,57,7-TETRAMETHYLPIPERIDINO-(5.4-C) ->3-THIAZOLINE-2-SPIRO4''-(2'',2'',6'',6''-TETRAMETHYLPIPERIDINE) WITH THE CORRESPONDING HALIDE.
摘要:
ACYL DERIVATIVES OF P-NITROSOPHENOLS, P-NITROSOANILINES AND P-NITROSOPHENYLHYDROXYLAMINES ARE ANTIOXIDANTS FOR RUBBER WHICH ARE RESISTANT TO EXTTRACTION BY SOLVENTS. THE ACYL DERIVATIVES ARE PREFERABLY PREPARED BY ACYLATION AT 10-40*C. IN A WATER-MISCIBLE SOLVENT, BEST IN ADMIXTURE, IN PRESENCE OF A WEAKLY BASIC ACID BINDING AGENT.
摘要:
Organic materials, especially synthetic polymers such as polyolefins, or various lubricating and mineral oils, are stabilized against oxidative and/or thermal degradation by incorporating therein 2,4,6-tris-(alkylthioalkylthio)-1,3,5triazine compounds.
摘要:
Heat stabilized thermoplastic polyurethane rubber compositions comprise: (1) a thermoplastic polyurethane rubber together with small amounts each of (2) certain organic di-isocyanate dimers and (3) at least one inhibitor for the cross-linking of said polyurethane rubber.
摘要:
OXIDATIVE DEGRADATION IN POLYMERIC HYDROCARBON MATERIALS SUCH AS POLYETHYLENE AND POLYPROPYLENE IS RETARDED BY INCORPORATION THEREIN OF PHENYLHYDRAZONES.