Abstract:
A nonaqueous electrolyte solution for a secondary battery, including an electrolyte, a solvent and an additive, and a nonaqueous electrolyte secondary battery including the nonaqueous electrolyte solution. The additive contains a compound represented by the following formula (I): wherein n represents an integer of 1 to 4, in the case of n=1, R1 represents a halogen atom or the like, in the case of n=2, R1 represents an alkaline earth metal atom or the like, in the case of n=3, R1 represents a trivalent transition metal atom or the like, in the case of n=4, R1 represents a tetravalent transition metal atom or the like, and R2 represents an alkylene group of 1 to 6 carbon atoms or an alkenylene group of 2 to 6 carbon atoms.
Abstract:
Provided is an oligosilane production method with which a target oligosilane can be selectively produced. A reaction-produced mixture fluid which contains an oligosilane obtained by the dehydrogenative coupling of a hydrosilane is supplied to a membrane separator under specific conditions and/or brought into contact with an adsorbent under specific conditions.
Abstract:
A method for producing an oligosilane which includes a reaction step of producing an oligosilane by dehydrogenative coupling of hydrosilane. The reaction step is carried out in the presence of a catalyst containing at least one transition element selected from the group consisting of Periodic Table group 3 transition elements, group 4 transition elements, group 5 transition elements, group 6 transition elements, and group 7 transition elements. Also disclosed is a method for producing a catalyst for dehydrogenative coupling that produces an oligosilane by dehydrogenative coupling of hydrosilane.
Abstract:
A method for producing an oligosilane including a reaction step of introducing a fluid containing a hydrosilane into a continuous reactor provided with a catalyst layer inside to produce an oligosilane from the hydrosilane and discharging a fluid containing the oligosilane from the reactor. The reaction step satisfies all of the following conditions (i) to (iii): (i) a temperature of the hydrosilane-containing fluid at an inlet of the catalyst layer is higher than a temperature of the oligosilane-containing fluid at an outlet of the catalyst layer; (ii) the temperature of the hydrosilane-containing fluid at the inlet of the catalyst layer is from 200 to 400° C.; and (iii) the temperature of the oligosilane-containing fluid at the outlet of the catalyst layer is from 50 to 300° C.
Abstract:
An object of the present invention is to provide an oligosilane production method with which a target oligosilane can be selectively produced. Oligosilanes can be efficiently produced at an improved selectivity for a target oligosilane by using, as a raw material, not only monosilane but also an oligosilane with a smaller number of silicon atoms than the target oligosilane or conversely an oligosilane with a larger number of silicon atoms than the target oligosilane.