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公开(公告)号:US20180346755A1
公开(公告)日:2018-12-06
申请号:US15994132
申请日:2018-05-31
发明人: Hyunjoon OH , Kyungtae KIM , Boa KIM , Sanghoon KIM , Sangil PARK , Heonjung SHIN , Hyejin OH , Jeoungsub LEE , Minhoon CHOI , Taekyung YANG , Heewoo RHEE , Sungmin CHO
IPC分类号: C09D175/04
摘要: Provided are a nanocomposite body, a method of manufacturing the nanocomposite body, and a nanocomposite film including the nanocomposite body. The nanocomposite body includes: inorganic particles; a polymer matrix; and grafting polymer chains each of which includes a polyol structure, wherein the inorganic particles and the polymer matrix are linked by the grafting polymer chains.
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公开(公告)号:US20180198147A1
公开(公告)日:2018-07-12
申请号:US15742010
申请日:2016-03-15
发明人: Heewoo RHEE , Sangwoo KIM , Taeyung YOUN
IPC分类号: H01M8/1004 , H01M8/1041 , C08L83/08
CPC分类号: H01M8/1004 , B82Y30/00 , B82Y40/00 , C08G77/24 , C08G77/26 , C08G77/28 , C08G77/30 , C08G77/385 , C08G77/392 , C08J5/2237 , C08J2327/12 , C08J2327/18 , C08J2483/06 , C08L83/06 , C08L83/08 , C08L2203/20 , H01M8/1011 , H01M8/1041 , H01M2300/0082 , H01M2300/0088 , Y02P70/56 , C08L83/00 , C08L27/18
摘要: The present invention relates to a proton conductive nanocomposite membrane and a method for manufacturing same, the proton conductive nanocomposite membrane having polyhedral oligomeric silsesquioxane (POSS) having a proton donor and POSS having a proton acceptor introduced into an aromatic hydrocarbon polymer membrane having a sulfonyl group. The nanocomposite membrane of the present invention has both the POSS having a proton donor and the POSS having a proton acceptor added thereto, and thus protons (cations) that are generated are easily hopped in an ion channel by means of hydrogen bonding, and thus ionic conductivity is increased. In addition, the POSS used in the present invention has a very small size, and thus hardly obstructs proton migration in the ion channel in the polymer membrane, and thus excellent proton conductivity may be enabled. In addition, the proton conductive nanocomposite membrane by the present invention exhibits excellent mechanical strength even though the degree of sulfonation of the polymer membrane is increased.
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公开(公告)号:US20180208768A1
公开(公告)日:2018-07-26
申请号:US15742030
申请日:2016-03-15
发明人: Heewoo RHEE , Sangwoo KIM , Taeyung YOUN
CPC分类号: C08L83/06 , B82Y30/00 , B82Y40/00 , C08G65/4056 , C08G77/24 , C08G77/26 , C08G77/28 , C08G77/30 , C08G77/46 , C08G81/00 , C08J5/2256 , C08J2371/00 , C08J2381/06 , C08J2483/06 , C08K5/42 , C08L71/00 , C08L83/08 , H01M8/1004 , H01M8/1011 , H01M8/102 , H01M8/1032 , C08L83/00
摘要: The present invention relates to a proton conductive nanocomposite membrane and a method for manufacturing same, the proton conductive nanocomposite membrane having polyhedral oligomeric silsesquioxane (POSS) having a proton donor and POSS having a proton acceptor introduced into an aromatic hydrocarbon polymer membrane having a sulfonyl group. The nano-composite membrane of the present invention has both the POSS having a proton donor and the POSS having a proton acceptor added thereto, and thus protons (cations) that are generated are easily hopped in an ion channel by means of hydrogen bonding, and thus ionic conductivity is increased. In addition, the POSS used in the present invention has a very small size, and thus hardly obstructs proton migration in the ion channel in the polymer membrane, and thus excellent proton conductivity may be enabled. In addition, the proton conductive nanocomposite membrane by the present invention exhibits excellent mechanical strength even though the degree of sulfonation of the polymer membrane is increased.
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公开(公告)号:US20170200962A1
公开(公告)日:2017-07-13
申请号:US15324726
申请日:2015-07-02
发明人: Heewoo RHEE , Sangwoo KIM , Taeyung YOUN
IPC分类号: H01M8/1051 , H01B1/12 , H01M8/1025 , B01J39/19 , C08J5/22
CPC分类号: H01M8/1051 , B01J39/19 , C08J5/2256 , C08J5/2275 , C08J2371/10 , C08J2381/06 , H01B1/12 , H01M8/1025 , H01M8/1048 , H01M8/1069 , H01M2008/1095 , H01M2300/0068 , H01M2300/0082 , H01M2300/0091 , Y02P70/56
摘要: The present invention relates to a sulfonated polyetheretherketone (sPEEK) nanocomposite film containing silsesquioxane and exhibiting excellent proton conductivity and mechanical strength, and a method for manufacturing the same. The nanocomposite film of the present invention has excellent conductivity since multiple sulfonic acid groups as a proton source exist in POSS used as a filler. In addition, the POSS used in the present invention is very small, having a size of 1-2 nm, and thus hardly obstructs the migration of protons in the ion channel in the polymer membrane, thereby realizing excellent proton conductivity. In addition, the proton conductive nanocomposite film by the present invention shows excellent mechanical strength even though the degree of sulfonation of sulfonated polyetheretherketone is increased.
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