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1.
公开(公告)号:US10807916B2
公开(公告)日:2020-10-20
申请号:US16069163
申请日:2016-11-29
申请人: SOOCHOW UNIVERSITY
发明人: Guozheng Liang , Longhui Zheng , Aijuan Gu , Bihuan Peng , Li Yuan
IPC分类号: C04B41/45 , C08G59/68 , C04B35/468 , C08G59/40 , C04B41/52 , C04B41/90 , C04B35/636 , C04B35/634 , C08G59/50 , C04B38/06 , C04B41/00 , C04B41/48 , C04B41/83 , C08J5/24
摘要: In a method of preparing a modified barium titanate foam ceramic/thermosetting resin composite material, an organic additive is used as an auxiliary; deionized water is used as a solvent; nanometer barium titanate is used as a ceramic raw material; and these components are mixed and grounded to form a slurry. A pre-treated polymer sponge is impregnated in the slurry for slurry coating treatment and a barium titanate foam ceramic is obtained after drying and sintering. Then, through dopamine modification, micrometer/nanometer silver is deposited in situ on a skeleton surface. A resin, which is in the molten state and is thermosettable, is immersed into pores of the modified barium titanate foam ceramic, and the modified barium titanate foam ceramic/thermosetting resin composite material is obtained after a thermosetting treatment.
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公开(公告)号:US10053544B2
公开(公告)日:2018-08-21
申请号:US15534500
申请日:2015-05-28
申请人: SOOCHOW UNIVERSITY
发明人: Guozheng Liang , Yicheng Jiao , Aijuan Gu , Li Yuan
IPC分类号: C08J3/00 , C08K7/24 , C08L63/00 , C08L79/04 , C08L79/08 , B29B7/00 , B29B7/18 , B29B7/82 , C08J3/20 , C08L35/00 , H01B3/30 , H01B3/40 , H01B3/44 , C08J3/205 , B29K63/00 , B29K79/00 , B29K307/04
CPC分类号: C08J3/005 , B29B7/005 , B29B7/183 , B29B7/82 , B29K2063/00 , B29K2079/085 , B29K2307/04 , B29K2995/0006 , C08J3/201 , C08J3/203 , C08J3/2056 , C08J2300/24 , C08J2335/00 , C08J2363/02 , C08J2379/04 , C08J2479/04 , C08J2479/08 , C08K7/24 , C08L35/00 , C08L63/00 , C08L79/04 , C08L79/08 , C08L2205/02 , C08L2205/03 , H01B3/303 , H01B3/306 , H01B3/40 , H01B3/448 , C08K3/041
摘要: The invention discloses a carbon nanotube/polyetherimide/thermosetting resin dielectric composite and a preparation method therefor. 100 parts by weight of polyetherimide and 1-7 parts by weight of carbon nanotube are mixed uniformly in an Haake torque melt cavity to obtain a carbon nanotubes/polyetherimide composite; 20 parts of the carbon nanotube/polyetherimide composite are dissolved in 100-150 parts of dichloromethane, then the mixed solution is added in 100 parts of molten thermocurable thermosetting resin, mixing, and heat preserving, stirring are performed until a mixture is formed in a uniform state, and curing and post-treating are performed to obtain a carbon nanotube/thermosetting resin dielectric composite, wherein the substrate thereof has a typical reverse phase structure, while the carbon nanotubes are dispersed in a polyetherimide phase. The composite has a relatively low percolation threshold, a high dielectric constant and a low dielectric loss. The preparation method of the present invention has a simple process and is suitable for large-scale production.
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公开(公告)号:US11942272B2
公开(公告)日:2024-03-26
申请号:US16759329
申请日:2018-07-04
申请人: SOOCHOW UNIVERSITY
发明人: Aijuan Gu , Hao Fang , Guozheng Liang , Li Yuan
CPC分类号: H01G11/86 , C08J5/046 , C08J5/06 , C08L29/04 , H01G11/26 , H01G11/36 , C08J2329/04 , C08J2477/06 , C08L2205/035 , C08L2205/16
摘要: A method for preparing an aramid fiber electrochemical capacitor includes (1) immersing aramid fiber bundles in an aqueous solution; (2) adding polyvinylpyrrolidone into a silver ammonia solution to obtain a solution C, adding an aqueous glucose solution to the solution C to obtain aramid fiber bundles coated with silver nanoparticles; (3) adding the aramid fiber bundles into an aqueous solution containing γ-(2,3-glycidoxy) propyltrimethoxysilane; (4) adding the aramid fiber bundles coated by silver nanoparticles with epoxy groups into an ethanol containing carbon nanotubes with carboxyl groups; (5) adding the aramid fiber bundles with two-layered coatings into an aqueous solution containing pyrrole; (6) heating a mixture of a polyvinyl alcohol, an acid, and water to obtain a polyvinyl alcohol gel, immersing two strands of the aramid fiber bundles, carbon nanotubes and silver nanoparticle in the polyvinyl alcohol gel, and twisting the two strands together to obtain the aramid fiber electrochemical capacitor.
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公开(公告)号:US11387053B2
公开(公告)日:2022-07-12
申请号:US16759330
申请日:2018-07-04
申请人: SOOCHOW UNIVERSITY
发明人: Aijuan Gu , Hao Fang , Guozheng Liang , Li Yuan
IPC分类号: H01G11/36 , D06M11/83 , H01G11/24 , H01G11/40 , H01G11/86 , D06M11/74 , D06M13/11 , D06M15/61 , D06M13/513 , D06M15/37 , D06M23/08
摘要: The invention discloses an aramid fiber electrode and a preparation method thereof. Silver nanoparticles, carbon nanotubes and polypyrrole were sequentially coated on the surface of the aramid fiber by chemical bonding, to prepare an aramid fiber electrode, two aramid fiber electrodes were wound with an electrolyte to obtain an aramid fiber electrochemical capacitor. Compared with the polymer fiber electrochemical capacitor prepared in the prior art, the aramid fiber electrochemical capacitor provided by the present invention has both high specific capacitance, high energy density, high mechanical performance, high stability, good flexibility and wearability. And other characteristics; the preparation method is controllable and suitable for large-scale applications.
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公开(公告)号:US11008423B2
公开(公告)日:2021-05-18
申请号:US16466111
申请日:2016-12-03
申请人: SOOCHOW UNIVERSITY
发明人: Aijuan Gu , Jiatao Miao , Guozheng Liang , Li Yuan
摘要: The present invention discloses a modified bismaleimide resin and preparation method thereof; under conditions of N,N-dimethylformamide serving as a catalyst, biomass-based 2,5-furandicarboxylic acid and thionyl chloride are acylated to obtain 2,5-furan diformyl chloride, which is then dissolved in dichloromethane with a biomass-based eugenol; under tertiary amine conditions an esterification reaction takes place, and a fully biomass-based bis(4-allyl-2-methoxyphenyl)furan-2,5-dicarboxylic acid ester is thus obtained; same is used for preparing a modified bismaleimide resin. The bismaleimide resin prepared by the present invention has excellent thermal properties and rigidity; the preparation method uses 2,5-furandicarboxylic acid from biomass as well as eugenol; the raw materials are green and environmentally friendly and renewable; the invention also has the feature of a simple production process, and has broad prospects for application in such fields as aeronautics and astronautics, electronic information, electrical insulation.
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6.
公开(公告)号:US10882797B2
公开(公告)日:2021-01-05
申请号:US16069160
申请日:2016-11-29
申请人: SOOCHOW UNIVERSITY
发明人: Guozheng Liang , Longhui Zheng , Aijuan Gu , Tiekuang Ding , Li Yuan
IPC分类号: C04B35/468 , C04B41/88 , C04B38/10 , C04B35/634 , C04B38/06 , C04B41/00 , C04B41/51 , C04B35/636 , C04B38/00 , C08L75/04 , C04B111/20 , C08L25/06 , C08L27/06
摘要: Disclosed are a micrometer/nanometer silver-loaded barium titanate foam ceramic and a preparation method therefor. An organic additive is used as an auxiliary; deionized water is used as a solvent; nanometer barium titanate is used as a ceramic raw material; and same are mixed and ground so as to form a slurry. A pre-treated polymer sponge is impregnated in the slurry for slurry coating treatment and a barium titanate foam ceramic blank is obtained after drying; and then a barium titanate foam ceramic is obtained through sintering. Through dopamine modification, micrometer/nanometer silver is in-situ deposited on a skeleton surface so as to obtain a modified micrometer/nanometer silver-loaded barium titanate foam ceramic. The modified micrometer/nanometer silver-loaded barium titanate foam ceramic is then put into a newly prepared Tollens' reagent for further reduction so as to obtain a micrometer/nanometer silver-loaded barium titanate foam ceramic with a three-dimensional network skeleton structure.
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7.
公开(公告)号:US11479671B2
公开(公告)日:2022-10-25
申请号:US16759328
申请日:2018-07-04
申请人: SOOCHOW UNIVERSITY
发明人: Guozheng Liang , Youhao Zhang , Aijuan Gu , Li Yuan
摘要: This invention provides a scrollable and foldable transparent polysiloxane film and its preparation and self-healing method. 2-Hydroxyethyl disulfide, diisocyanate and alkane chloride were mixed and reacted to get disulfide-containing diisocyanate. α,ω-Aminopropyl terminated polydimethylsiloxane, diisocyanate and alkane chloride were mixed and reacted get linear chain-extended polydimethylsiloxane. Linear chain-extended polydimethylsiloxane, multi-amino terminated hyperbranched polysiloxane, disulfide-containing diisocyanate and alkane chloride were mixed and poured into a mould. After drying, the scrollable and foldable transparent polysiloxane film was obtained. The polysiloxane film described in this invention are constructed by dynamic physical crosslinking induced by hydrogen bond and permanent chemical crosslinking generated by hyperbranched polysiloxane. Hence, the polysiloxane film achieves both high stiffness and toughness. The good self-healing behavior of the polysiloxane films is originated from the temperature controlled dissociation of hydrogen bonds and exchange reaction rate of disulfide bonds.
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公开(公告)号:US11046808B2
公开(公告)日:2021-06-29
申请号:US16564802
申请日:2019-09-09
申请人: SOOCHOW UNIVERSITY
发明人: Aijuan Gu , Zhenjie Ding , Guozheng Liang , Li Yuan
摘要: A preparation method of thermadapt shape memory polymers includes: (1) synthesis of pendant hydroxyl groups functionalized epoxy oligomer using epoxy resin and alcohol amine; (2) synthesis of alkoxyl groups terminated silane crosslinking agent by isocyanate silane coupling agent and diamine; (3) crosslinked shape memory polymers were prepared by condensation reaction of pendant hydroxyl groups functionalized epoxy oligomer and alkoxyl groups terminated silane crosslinking agent. The thermadapt shape memory polymers show high glass transition temperatures and high tensile strength. The original shape of thermadapt shape memory polymers can be reconfigured to a new permanent shape as needed, and thus effectively solving the bottleneck problems of reprocessing or reshape in the traditional crosslinked polymers once after molding. The thermadapt shape memory polymers are suitable for smart materials based on shape memory polymers with complex three-dimensional permanent shapes, and showing unfolding or folding behaviors along with convert to three-dimensional structures under heat stimulation.
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公开(公告)号:US10745515B2
公开(公告)日:2020-08-18
申请号:US16466075
申请日:2016-12-03
申请人: SOOCHOW UNIVERSITY
发明人: Aijuan Gu , Jiatao Miao , Guozheng Liang , Li Yuan
IPC分类号: C08G59/24 , C08G59/68 , C08G59/26 , C07D307/68 , C07D407/14 , C07D301/14 , C07D303/02
摘要: The present invention discloses a biomass-based epoxy resin and preparation method thereof; under conditions of N,N-dimethylformamide as a catalyst, 2,5-furandicarboxylic acid and thionyl chloride are acylated to obtain 2,5-furan diformyl chloride; then it is dissolved with dichloromethane; under tertiary amine conditions an esterification reaction takes place, and bis(4-allyl-2-methoxyphenyl)furan-2,5-dicarboxylic acid ester is thus obtained; by means of meta-chloroperoxybenzoic acid, its unsaturated double bond is epoxidized to obtain a biomass-based epoxy resin. The process of the present invention is simple; the raw materials come from biomass 2,5-furandicarboxylic acid and eugenol; in comparison with bisphenol-A epoxy resin based on petroleum and coal resources, the raw materials are green and renewable, and are advantageous to reducing the consumption of renewable resources with regard to polymeric material. The obtained cured epoxy resin has excellent thermal properties and modulus, and has broad prospects for application.
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10.
公开(公告)号:US09951188B2
公开(公告)日:2018-04-24
申请号:US15328008
申请日:2015-05-28
申请人: SOOCHOW UNIVERSITY
发明人: Aijuan Gu , Yuanzhen Wang , Guozheng Liang , Li Yuan
IPC分类号: C08G79/12 , C08G77/398 , C08G77/26 , C08G77/18
CPC分类号: C08G79/12 , C08G77/18 , C08G77/26 , C08G77/398
摘要: A method of preparing an organotin containing hyperbranched polysiloxane structure includes the following steps: (1) by weight, 0.5-1.5 portions of hyperbranched polysiloxane with reactive functional groups is dissolved in 50-100 portions of an alcohol solvent, to obtain a solution A; (2) by weight, 0.5-0.9 portions of a tin-based initiator and 50-100 portions of the alcohol solvent are mixed to obtain a solution B, wherein said tin-based initiator is selected from dihydroxy butyl tin chloride, butyl tin trichloride, and dibutyl tin dichloride; and (3) dropping the solution B into the solution A at the temperature of 0° C.-60° C., reacting for 3-6 h, filtering and drying to obtain the organotin containing hyperbranched polysiloxane structure.
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