Mineral lubricating oil containing high molecular weight alkyl substituted phenolic sulfonamide
    1.
    发明授权
    Mineral lubricating oil containing high molecular weight alkyl substituted phenolic sulfonamide 失效
    含高分子量烷基取代苯酚磺胺的矿物润滑油

    公开(公告)号:US3674691A

    公开(公告)日:1972-07-04

    申请号:US3674691D

    申请日:1970-04-01

    CPC classification number: C10M1/08 C10M2219/044 C10M2223/045 C10N2210/02

    Abstract: Polymethylene polyamine sulfonamides of alkyl-substituted phenolic sulfonic acids wherein the alkyl-substituent has a molecular weight within the range of 400 to 3000 are novel compounds soluble in mineral hydrocarbon oils of the lubricating oil range and as solutes therein are ashless addition agents imparting to the solution a combination of anti-oxidant and detergency-dispersancy properties useful in the lubrication of internal combustion engines. Illustrative of such sulfonamides are mono- and disulfonamides of hexamethylene diamine, tetraethylene pentamine, 2,6-di(aminoethyl) pyridine and N,N''di(aminopropyl) piperazine with 4-alkylphenolic sulfonic acids such as 4-alkyl-1-hydroxyphenyl, 4,4''-dialkyl-1,1''-dihydroxy2,2''-biphenyl, 4-alkyl-1-alkoxyphenyl or 2-tri- and tetra-(4''alkyl-1-hydroxybenzyl)-substituted 4-alkyl-1-hydroxyphenyl sulfonic acid chlorides.

    Polymeric-alkylphenolsulfonamides
    3.
    发明授权
    Polymeric-alkylphenolsulfonamides 失效
    聚合烷基苯磺酰胺

    公开(公告)号:US3928355A

    公开(公告)日:1975-12-23

    申请号:US30112172

    申请日:1972-10-26

    Inventor: LEE RICHARD J

    CPC classification number: C07D295/13 C08F8/32 C08F10/00 C08F240/00

    Abstract: Novel sulfonamides soluble in C6 and higher alkanes and lubricating oils, which are antioxidants therefor preventing oxidative thickening of the oil, are obtained from nuclear carbon-to-carbon dimers to heptemers of 85 to 3,000 MW alkylsubstituted phenol converted to sulfonylchloride by known means and reacted with an amine, preferably an amine having at least two primary amino radicals. Sulfonamides of the monomeric alkylphenols while imparting detergency and dispersancy to lubricating oils prevent oxidative thickening of the oil.

    Abstract translation: 可溶于C6和高级烷烃和润滑油的新型磺酰胺,其是用于防止油的氧化增稠的抗氧化剂,其由核碳对二聚体获得,通过已知方法从85至3,000MW烷基取代的苯酚转化为磺酰氯 并与胺,优选具有至少两个伯氨基的胺反应。 单体烷基酚的磺酰胺同时赋予润滑油的去污力和分散性,防止油的氧化增稠。

    Alkane hydroxy amines and the method of preparing the same
    7.
    发明授权
    Alkane hydroxy amines and the method of preparing the same 失效
    ALKANE羟基胺及其制备方法

    公开(公告)号:US3681463A

    公开(公告)日:1972-08-01

    申请号:US3681463D

    申请日:1969-09-08

    Inventor: LEE RICHARD J

    CPC classification number: C10L1/2383 C07C205/40

    Abstract: Oil-soluble alkane hydroxy amine derivatives of alkenes containing at least ten carbon atoms, particularly low molecular weight unsaturated polymers of propene and butene, are useful as chemical intermediates and as additives in petroleum products. The amine derivatives are produced by nitrating the alkene with nitrogen tetraoxide under non-oxidizing conditions to form the corresponding nitro-nitrito alkane and reducing the nitro-nitrito alkane with hydrogen in the presence of a metallic hydrogenation catalyst.

    Abstract translation: 含有至少十个碳原子的烯烃的油溶性烷烃羟基胺衍生物,特别是丙烯和丁烯的低分子量不饱和聚合物,可用作石油产品中的化学中间体和添加剂。 胺衍生物通过在非氧化条件下用四氧化氮对烯烃进行硝化来形成相应的硝基 - 硝基烷烃,并在金属氢化催化剂存在下用氢还原硝基 - 硝基烷烃。

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