Abstract:
Polymethylene polyamine sulfonamides of alkyl-substituted phenolic sulfonic acids wherein the alkyl-substituent has a molecular weight within the range of 400 to 3000 are novel compounds soluble in mineral hydrocarbon oils of the lubricating oil range and as solutes therein are ashless addition agents imparting to the solution a combination of anti-oxidant and detergency-dispersancy properties useful in the lubrication of internal combustion engines. Illustrative of such sulfonamides are mono- and disulfonamides of hexamethylene diamine, tetraethylene pentamine, 2,6-di(aminoethyl) pyridine and N,N''di(aminopropyl) piperazine with 4-alkylphenolic sulfonic acids such as 4-alkyl-1-hydroxyphenyl, 4,4''-dialkyl-1,1''-dihydroxy2,2''-biphenyl, 4-alkyl-1-alkoxyphenyl or 2-tri- and tetra-(4''alkyl-1-hydroxybenzyl)-substituted 4-alkyl-1-hydroxyphenyl sulfonic acid chlorides.
Abstract:
Novel sulfonamides soluble in C6 and higher alkanes and lubricating oils, which are antioxidants therefor preventing oxidative thickening of the oil, are obtained from nuclear carbon-to-carbon dimers to heptemers of 85 to 3,000 MW alkylsubstituted phenol converted to sulfonylchloride by known means and reacted with an amine, preferably an amine having at least two primary amino radicals. Sulfonamides of the monomeric alkylphenols while imparting detergency and dispersancy to lubricating oils prevent oxidative thickening of the oil.
Abstract:
DISCLOSED IS A COMPOSITION PREPARED BY (A) REACTING AN OIL-SOLUBLE, HYDROCARBON-SUBSTITUTED SUCCINIC ACID ANHYDRIDE AND UREA, THEREBY FORMING A FIRST INTERMEDIATE, (B) REACTING THE FIRST INTERMEDIATE AND AN ALKYLENE POLYAMINE HAVING THE FORMULA H2N (-ALKYLENE-NH)NH IN WHICH N IS AN INTEGER FROM 1 TO 5 AND "ALKYLENE" IS A SATURATED DIVALENT HYDROCARBON CONTAINING FROM ABOUT 2 TO ABOUT 6 CARBON ATOMS, THEREBY FORMING A SECOND INTERMEDIATE, AND (C) REACTING THE SECOND INTERMEDIATE WITH A STRONG BASE. THIS COMPOSITION IS USEFUL IN KEEPING HARMFUL MATERIALS SUSPENDED IN MOTOR OIL, SO THAT THESE MATERIALS WILL NOT INTERFERE WITH THE OPERATION OF AN INTERNAL COMBUSTION ENGINE.
Abstract:
Oil-soluble products, suitable as dispersant additives for lubricants, are obtained by reacting (a) a high molecular weight olefin polymer, having an average molecular weight of at least about 600, with acrylonitrile, a halogen, e.g., chlorine, in the presence of a catalyst, e.g., iodine, (b) reacting the product of (a) with a primary aliphatic amine, (c) reacting the resultant product of (b) with maleic anhydride, and (d) reacting the product resulting from (c) with an aliphatic amine or polyamine containing at least one primary amino group per anhydride function on the product (c).
Abstract:
Oil-soluble alkane hydroxy amine derivatives of alkenes containing at least ten carbon atoms, particularly low molecular weight unsaturated polymers of propene and butene, are useful as chemical intermediates and as additives in petroleum products. The amine derivatives are produced by nitrating the alkene with nitrogen tetraoxide under non-oxidizing conditions to form the corresponding nitro-nitrito alkane and reducing the nitro-nitrito alkane with hydrogen in the presence of a metallic hydrogenation catalyst.
Abstract:
OIL-SOLUBLE COMPOUNDS AE PAREPARED BY HEATING A MIXTURE COMPRISING (A) A REDUCED NITRO-NITRITO ALKANE, CONTAINING AT LEAST TEN CARBON ATOMS, (B) AN ORGANIC POLYBASIC ALIPHATIC OR AROMATIC ACID OR ANHYDRIDE, OR LONG CHAIN ALKENYL SUBSTITUTED DERIVATIVES THEREOF, AND (C) A POLYALKYLENE AMINE, IN THE MOLAR RATIO OF FROM ABOUT 1:1:0 TO ABOUT 1:1:0.5, RESPECTIVELY; COMPOUNDS SO FORMED ARE USEFUL ADDITIVES IN OLEAGINOUS COMPOSITIONS.