Novel alternating copolymer of multisubstituted conjugated vinyl compound and unsaturated compound and process for producing same
    1.
    发明授权
    Novel alternating copolymer of multisubstituted conjugated vinyl compound and unsaturated compound and process for producing same 失效
    多元联用的乙烯基化合物和不饱和化合物的新型交替共聚物及其生产方法

    公开(公告)号:US3637611A

    公开(公告)日:1972-01-25

    申请号:US3637611D

    申请日:1970-03-20

    CPC分类号: C08F4/12

    摘要: A NOVEL ALTERNATING COPOLYMER COMPOSED OF THE GROUP (B) MONOMER CONSISTING OF AT LEAST ONE A-,B-OR A,B-MULTISUBSTITUTED CONJUGATED VINYL COMPOUND, AND THE GROUP (A) MONOMER CONSISTING OF AT LEAST ONE MONOMER SELECTED FROM THE GROUP OF OLEFINS, HALOOLEFINS, INTERNAL OLEFINS, POLYENES, ACETYLENES, AND CARBONYL COMPOUNDS OR THIOCARBONYL COMPOUNDS; THE UNITS FROM THE GROUP (A) MONOMER ALWAYS ALTERNATING WITH THE UNITS FROM THE GROUP (B) MONOMER. SAID ALTERNATING COPOLYMER IS PRODUCED BY CONTACTING AT LEAST THE GROUP (B) MONOMER OF THE TWO GROUPS WITH AN ORGANOALUMINUM OR ORGANOBORON HALIDE TO FORM A COMPLEX AND THEN CONTACTING THE REMAINING MONOMER WITH THE COMPLEX FORMED. WHEN MONOMERS OF BOTH GROUPS (A) AND (B) ARE PROPERLY CHOSEN, SAID NOVEL ALTERNATING COPOLYMER CAN BE USEFUL AS A MATERIAL FOR THE PRODUCTION OF FILM, FIBER AND MOLDED ARTICLES, AND AS AN ADDITIVE FOR THE PLASTICS PROCESSING.

    Novel alternating copolymer having sulfonic acid group and a method for producing thereof
    2.
    发明授权
    Novel alternating copolymer having sulfonic acid group and a method for producing thereof 失效
    具有磺酸类的新型交替共聚物及其生产方法

    公开(公告)号:US3657201A

    公开(公告)日:1972-04-18

    申请号:US3657201D

    申请日:1970-03-24

    IPC分类号: C08F28/00 C08F13/00

    CPC分类号: C08F28/00

    摘要: AN ALTERNATING COPOLYMER COMPRISING UNSATURATED COMPOUNDS CONTAINING A SULFONIC ACID GROUP (MONOMER OF GROUP A) AND NON-SUBSTITUTED OR SUBSTITUTED CONJUGATED VINYL COMPOUNDS (MONOMER OF GROUP B) IS PREPARED FROM THE MONOMERS OF GROUP A SUCH AS VNYLSULFONIC ACIDS, ALLYLSULFONIC ACIDS, STYRENESULFONIC ACIDS, VINYLOXYSULFONIC ACIDS, AND ALLYLOXYSULFONIC ACIDS AND THE MONOMERS OF GROUP B SUCH AS ACRYLONITRILE, ACRYLIC ACID, THIOACRYLIC ACID, OR THEIR DERIVATIVES USING AN ORGANOMETALLIC HALIDE SUCH AS ORGANOALUMINUM HALIDE OR ORGANOBORON HALIDE OR MODIFIED CATALYST THEREOF. THE PRODUCE COPOLYMER IS USEFUL FOR SHAPING A FILM, FIBERS, OR OTHER MOLDING OR FOR MODIFYING THE MOLDINGS, OR USEFUL AS AN ION EXCHANGE RESIN OR A READILY DYEABLE POLYMER.

    Production of acrylonitrile polymers

    公开(公告)号:US3574177A

    公开(公告)日:1971-04-06

    申请号:US3574177D

    申请日:1968-05-08

    CPC分类号: C08F20/42 C08F20/44

    摘要: THE SOLUTION POLYMERIZATION OF ACRYLONITRILE POLYMERS AND COPOLYMERS IS FACILITATED WHEN IT IS CONDUCTED UNDER AGITATION IN THE PRESENCE OF AN INERT DISPERSION MEDIUM. THE SOLVENT USED IS ONE THAT WILL DISSOLVE BOTH THE MONOMER AND THE RESULTING POLYMER. THE DISPERSION MEDIUM IS A LIQUID THAT IS NOT UNIFORMLY MISCIBLE WITH THE SOLVENT AND IT WILL NOT DISSOLVE EITHER THE MONOMER OR THE POLYMER. UPON PERMITTING THE REACTION PRODUCT, A DISPERSION, TO STAND QUIETLY IT SEPARATES INTO TWO LIQUID PHASES THAT CAN BE SEPARATED BY DECANTATION. THE PREFERRED DISPERSION MEDIA ARE LIQUID HYDROCARBONS HALOGENATED OR NOT, THAT HAVE A BOILING POINT ABOVE 268*C.

    Production of acrylonitrile unsaturated sulfonic acid copolymers
    5.
    发明授权
    Production of acrylonitrile unsaturated sulfonic acid copolymers 失效
    丙烯酸不饱和磺酸共聚物的生产

    公开(公告)号:US3679641A

    公开(公告)日:1972-07-25

    申请号:US3679641D

    申请日:1970-05-27

    发明人: TAKEYA KENJI

    CPC分类号: C08F220/46 C08F28/00

    摘要: COPOLYMERS OF AT LEAST 80% OF ACRYLONITRILE, ABOUT 0.1 TO 5% OF AN ETHYLENICALLY UNSATURATED ORGANIC SULFONIC ACID OR SALT THEREOF AND UP TO 19.9% OF AT LEAST ONE ETHYLENICALLY UNSTURATED MONOMER WHICH IS COPOLYMERIZABLE WITH ACRYLONITRILE AND THE AFORESAID SULFONIC ACID OR ITS SALT, ARE PREPARED IN AQUEOUS POLYMERIZATION MEDIUM IN THE PRESENCE OF AN ORGANIC COMPOUND WHICH IS A NON-SOLVENT FOR THE COPOLYMER BUT IS A SOLVENT FOR THE MONOMER(S) OTHER THAN THE SULFONIC ACID O ITS SALT.

    Flame-resistant acrylonitrile copolymers with high receptivity to acid dyes
    6.
    发明授权
    Flame-resistant acrylonitrile copolymers with high receptivity to acid dyes 失效
    对酸性染料具有高亲和力的抗阻抗丙烯腈共聚物

    公开(公告)号:US3580878A

    公开(公告)日:1971-05-25

    申请号:US3580878D

    申请日:1968-06-13

    CPC分类号: C08F20/42 C08F220/44

    摘要: ACRYLONITRILE COPOLYMERS WHICH HAVE HIGH RECEPTIVITY TO ACID DYES AND ARE FLAME RESISTANT, AND ARE THUS USEFUL IN MAKING CARPETING, CURTAINS, ETC. AS WELL AS WEARING APPEREL, ETC., ARE TERNARY POLYMERS COMPOSED OF ACRYLONITRILE, VINYLIDENE CHLORIDE, AND A BASIC MONOMER OF THE TYPE OF THE DIMETHYLAMINOETHYL AND DIETHYLAMINOETHYL ESTERS OF ACRYLIC ACID AND OF METHACRYLIC ACID, AND THE CORRESPONDING N-SUBSTITUTED AMINOPROPL AND AMINOBUTYL ESTERS, ETC.; OR COPOLYMERS CONSISTING OF ACRYLONITRILE, VINYLIDENE CHLORIDE, A BASIC MONOMER OF THE AFORE-INDICATED TYPE AND ONE OR MORE NEUTRAL ETHYLENCIALLY UNSATURATED COMPOUNDS (I.E. METHYL ACRYLATE, METHYL METHACRYLATE, VINYL ACETAT, STYRENE).