摘要:
The present invention relates to novel polysiloxane-polyether-based copolymers which contain T units and comprise randomly linked organopolysiloxane units and linear polyether units, to a method for their preparation and their use.
摘要:
Siloxanes containing epoxy groups having the formula 1 ##STR1## Formula 1 whereinA means a C.sub.1 -C.sub.20 alkyl radical with epoxy groupsB means R.sup.1 or AR.sup.1, R.sup.2 independently of each other, means C.sub.1 -C.sub.20 alkyl or C.sub.6 -C.sub.10 aryla means zero or a whole number from 1-100b means zero or a whole number from 1-100c means a whole number from 1-5.
摘要:
Disclosed herein is a process for the production of a polysiloxane-polyorgano block copolymer. The process includes reacting a reaction mixture containing (a) an ester-functional polydiorganosiloxane and (b) a bisphenolic compound or a bisphenolic compound oligomer. This process has the advantage of yielding block copolymers with controlled block structures and avoiding the impurities that may be carried over from the conventional hydroxyaryloxy-terminated-polydiorganosiloxanes.
摘要:
Novel liquid organopolysiloxane resins of the average composition �R.sup.1 Si(CH.sub.3).sub.2 O.sub.1/2 !.sub.a �(CH.sub.3).sub.3 SiO.sub.1/2 !.sub.b �R.sup.2 O.sub.1/2 !.sub.c �R.sup.1 Si(CH.sub.3)O!.sub.d �(CH.sub.3).sub.2 SiO!.sub.e �SiO.sub.2 !,whereinR.sup.1 is a C.sub.2 -C.sub.8 -alkenyl group,R.sup.2 is an optionally substituted, linear or branched C.sub.1 -C.sub.8 -alkyl group or a mixture thereof,a+b+c+d+e is about 1 to 6,d+e is about 0 to 3,the resin has a viscosity of 0.1 to 1000 Pas at 25.degree. C., andthe alkenyl or vinyl content of the resin is in the range of 0.4 to 4 mmol/g,and their preparation by reacting at least one of tetraalkoxysilane and its partial hydrolyzate with at least one organosiloxane and a strong acid as catalyst in the presence of water and optionally an organic solvent at a temperature of about >40.degree. C. They are formulated into novel low viscosity polydiorganosiloxane compositions.
摘要翻译:具有平均组成[R1Si(CH3)2O + E,fra1 / 2 + EE] a [(CH3)3SiO + E,fra1 / 2 + EE] b [R2O + E,fra 1/2]的新型液体有机聚硅氧烷树脂 + EE] c [R 1 Si(CH 3)O] d [(CH 3)2 SiO] e [SiO 2],其中R 1是C 2 -C 8 - 烯基,R 2是任选取代的直链或支链C 1 -C 8烷基或 其混合物,+ b + c + d + e为约1〜6,d + e约为0〜3,树脂在25℃下的粘度为0.1〜1000Pa·s,烯基或乙烯基含量 的树脂在0.4〜4mmol / g的范围内,并且通过使四烷氧基硅烷及其部分水解产物中的至少一种与至少一种有机硅氧烷和强酸作为催化剂在水和任选的有机溶剂的存在下反应而制备 在约> 40℃的温度下,将它们配制成新的低粘度聚二有机硅氧烷组合物。
摘要:
Disclosed herein is a process for the production of a polysiloxane-polyorgano block copolymer. The process includes reacting a reaction mixture containing (a) an ester-functional polydiorganosiloxane and (b) a bisphenolic compound or a bisphenolic compound oligomer. This process has the advantage of yielding block copolymers with controlled block structures and avoiding the impurities that may be carried over from the conventional hydroxyaryloxy-terminated-polydiorganosiloxanes.Also disclosed are ester-functional polysiloxanes and polysiloxane-polyorgano block copolymers prepared by the process of the invention. These copolymers exhibit advantageous properties such as improved low temperature properties, improved rheological properties during molding, improved clarity, chemical, scratch resistance, and improved electrical insulation properties.
摘要:
The invention relates to a process for manufacturing chlorosilanes, in which methyl-rich disilane, polysilane and siloxane residues from the Müller-Rochow synthesis or a chlorosilane synthesis are reduced in quantity. It comprises the steps: a) reaction of silicon with alkyl halogenides, aryl halogenides or hydrogen chloride, b) reaction of at least one high-boiling product fraction from step a) with at least one halogenide and c) reaction of at least one high-boiling product fraction resulting from step b) with alkyl halogenides, aryl halogenides and/or chlorosilanes.
摘要:
Process for the preparation of organofunctional polysiloxanes, which comprises reacting cyclic dialkylsiloxanes with at least one compound of the type HO—R′—X, wherein X═—OH, —COOH, —NR″2—, —CR″═CR″2, and R═alkyl, aryl, alkylene, oxyalkylene or arylene, in the presence of an equilibration catalyst.
摘要:
The invention relates to novel polyorganosiloxanes, methods for their preparation and their use, in particular as force and/or heat transmitting liquids, such as hydraulic liquids, and in cosmetic compositions.
摘要:
The present invention relates to novel processes for the manufacture of poly-organosiloxanes comprising (C6-C60)-alkylmethylsiloxy-groups and dimethyl-siloxy groups, polyorganosiloxanes obtainable by such processes, preferably aqueous emulsions comprising such polyorganosiloxanes and the use of such polyorganosiloxanes.