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公开(公告)号：US06444096B1
公开(公告)日：2002-09-03
申请号：US09639540
申请日：2000-08-16
申请人： Scott Donald Barnicki , Timothy Richard Nolen , Robert Sterling Kline , Dewey Wayne Fuller, Jr. , Mary Kathleen Foster , Stephen Neal Falling
发明人： Scott Donald Barnicki , Timothy Richard Nolen , Robert Sterling Kline , Dewey Wayne Fuller, Jr. , Mary Kathleen Foster , Stephen Neal Falling
IPC分类号： B01D334
摘要： A process for the recovery and purification of cyclobutanone from a crude product mixture obtained from an oxidation product mixture resulting from the oxidation of cyclobutanol to cyclobutanone in the presence of water. The process provides for the recovery of cyclobutanone in a purity of at least 90 weight percent by a combination of distillation steps.
摘要翻译： 从在水存在下由环丁醇氧化成环丁酮得到的氧化产物混合物得到的粗产物混合物回收和纯化环丁酮的方法。 该方法通过蒸馏步骤的组合提供纯度至少为90重量％的环丁酮。
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公开(公告)号：US08709376B2
公开(公告)日：2014-04-29
申请号：US12889045
申请日：2010-09-23
申请人： Scott Donald Barnicki , Stephen Neal Falling , Jeffrey Scott Kanel , Robert Sterling Kline , Peter Borden Mackenzie
发明人： Scott Donald Barnicki , Stephen Neal Falling , Jeffrey Scott Kanel , Robert Sterling Kline , Peter Borden Mackenzie
IPC分类号： C01B17/90 , C07C309/30 , C07C59/06 , C07C51/42
CPC分类号： B01D11/0492 , B01J31/0225 , B01J31/0227 , B01J31/4092 , C07C51/48 , C07C303/44 , C07C315/06 , Y02P20/584 , C07C59/06 , C07C309/06 , C07C309/05 , C07C317/04
摘要： Disclosed is a process for the extractive recovery of an acid catalyst from an aqueous mixture of glycolic acid with an extraction solvent comprising a tertiary amine or an onium carboxylate compound, a modifier, and a diluent. The acid catalyst, which can comprise strong acids such as sulfuric acid, alkyl sulfonic acids, and fluoroalkyl sulfonic acids, can be recovered by back extraction with aqueous formaldehyde and recycled to a process for the preparation of glycolic acid by the acid-catalyzed carbonylation of formaldehyde.
摘要翻译： 公开了一种从乙醇酸的水性混合物与包含叔胺或羧酸铝化合物，改性剂和稀释剂的萃取溶剂萃取回收酸催化剂的方法。 可以包含强酸如硫酸，烷基磺酸和氟代烷基磺酸的酸催化剂可以通过用甲醛水溶液反萃取回收，并循环至通过酸催化的羰基化反应制备乙醇酸的方法 甲醛。
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公开(公告)号：US08785686B2
公开(公告)日：2014-07-22
申请号：US13431335
申请日：2012-03-27
申请人： Scott Donald Barnicki , Stephen Neal Falling , Jeffrey Scott Kanel , Robert Sterling Kline , Peter Borden Mackenzie , Andrew James Vetter
发明人： Scott Donald Barnicki , Stephen Neal Falling , Jeffrey Scott Kanel , Robert Sterling Kline , Peter Borden Mackenzie , Andrew James Vetter
CPC分类号： B01D11/0492 , B01J31/0225 , B01J31/0227 , B01J31/40 , B01J2231/321 , C07C51/12 , C07C51/48 , Y02P20/584 , C07C59/06
摘要： Disclosed is a process for the extractive recovery of an acid catalyst from an aqueous mixture of glycolic acid with an extraction solvent comprising a tertiary amine or an onium carboxylate compound, a modifier, and a diluent. The acid catalyst, which can comprise strong acids such as sulfuric acid, alkyl sulfonic acids, and fluoroalkyl sulfonic acids, can be recovered by back extraction with aqueous formaldehyde and recycled to a process for the preparation of glycolic acid by the acid-catalyzed carbonylation of formaldehyde. Also disclosed is a process for the preparation of glycolic acid by the acid-catalyzed hydrocarboxylation of formaldehyde.
摘要翻译： 公开了一种从乙醇酸的水性混合物与包含叔胺或羧酸铝化合物，改性剂和稀释剂的萃取溶剂萃取回收酸催化剂的方法。 可以包含强酸如硫酸，烷基磺酸和氟代烷基磺酸的酸催化剂可以通过用甲醛水溶液反萃取回收，并循环至通过酸催化的羰基化反应制备乙醇酸的方法 甲醛。 还公开了通过酸催化的甲醛加氢制备乙醇酸的方法。
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公开(公告)号：US20120215027A1
公开(公告)日：2012-08-23
申请号：US13431335
申请日：2012-03-27
申请人： Scott Donald Barnicki , Stephen Neal Falling , Jeffrey Scott Kanel , Robert Sterling Kline , Peter Borden Mackenzie , Andrew James Vetter
发明人： Scott Donald Barnicki , Stephen Neal Falling , Jeffrey Scott Kanel , Robert Sterling Kline , Peter Borden Mackenzie , Andrew James Vetter
IPC分类号： C07C51/12
CPC分类号： B01D11/0492 , B01J31/0225 , B01J31/0227 , B01J31/40 , B01J2231/321 , C07C51/12 , C07C51/48 , Y02P20/584 , C07C59/06
摘要： Disclosed is a process for the extractive recovery of an acid catalyst from an aqueous mixture of glycolic acid with an extraction solvent comprising a tertiary amine or an onium carboxylate compound, a modifier, and a diluent. The acid catalyst, which can comprise strong acids such as sulfuric acid, alkyl sulfonic acids, and fluoroalkyl sulfonic acids, can be recovered by back extraction with aqueous formaldehyde and recycled to a process for the preparation of glycolic acid by the acid-catalyzed carbonylation of formaldehyde. Also disclosed is a process for the preparation of glycolic acid by the acid-catalyzed hydrocarboxylation of formaldehyde.
摘要翻译： 公开了一种从乙醇酸的水性混合物与包含叔胺或羧酸铝化合物，改性剂和稀释剂的萃取溶剂萃取回收酸催化剂的方法。 可以包含强酸如硫酸，烷基磺酸和氟代烷基磺酸的酸催化剂可以通过用甲醛水溶液反萃取回收，并循环至通过酸催化的羰基化反应制备乙醇酸的方法 甲醛。 还公开了通过酸催化的甲醛加氢制备乙醇酸的方法。
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公开(公告)号：US20120078010A1
公开(公告)日：2012-03-29
申请号：US12889045
申请日：2010-09-23
申请人： Scott Donald Barnicki , Stephen Neal Falling , Jeffrey Scott Kanel , Robert Sterling Kline , Peter Borden Mackenzie
发明人： Scott Donald Barnicki , Stephen Neal Falling , Jeffrey Scott Kanel , Robert Sterling Kline , Peter Borden Mackenzie
IPC分类号： C07C51/10
CPC分类号： B01D11/0492 , B01J31/0225 , B01J31/0227 , B01J31/4092 , C07C51/48 , C07C303/44 , C07C315/06 , Y02P20/584 , C07C59/06 , C07C309/06 , C07C309/05 , C07C317/04
摘要： Disclosed is a process for the extractive recovery of an acid catalyst from an aqueous mixture of glycolic acid with an extraction solvent comprising a tertiary amine or an onium carboxylate compound, a modifier, and a diluent. The acid catalyst, which can comprise strong acids such as sulfuric acid, alkyl sulfonic acids, and fluoroalkyl sulfonic acids, can be recovered by back extraction with aqueous formaldehyde and recycled to a process for the preparation of glycolic acid by the acid-catalyzed carbonylation of formaldehyde.
摘要翻译： 公开了一种从乙醇酸的水性混合物与包含叔胺或羧酸铝化合物，改性剂和稀释剂的萃取溶剂萃取回收酸催化剂的方法。 可以包含强酸如硫酸，烷基磺酸和氟代烷基磺酸的酸催化剂可以通过用甲醛水溶液反萃取回收，并循环至通过酸催化的羰基化反应制备乙醇酸的方法 甲醛。
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公开(公告)号：US5821384A
公开(公告)日：1998-10-13
申请号：US826451
申请日：1997-03-27
申请人： Joseph Robert Zoeller , Donald Wayne Lane , Eleanor Hawkins Cwirko , Dewey Wayne Fuller, Jr. , Scott Donald Barnicki
发明人： Joseph Robert Zoeller , Donald Wayne Lane , Eleanor Hawkins Cwirko , Dewey Wayne Fuller, Jr. , Scott Donald Barnicki
CPC分类号： C07C67/00 , Y02P20/127
摘要： Disclosed is a process for making vinyl carboxylate esters such as vinyl acetate and vinyl propionate, by a reactive distillation process comprising a reaction zone wherein a vinyl carboxylate ester is formed from a carbonyl compound selected from aliphatic aldehydes and ketones and an anhydride of an aliphatic carboxylic acid and a distillation zone from which the vinyl carboxylate ester is recovered and substantially separated from other compounds contained within the column. The process requires significantly less equipment than known, analogous processes and thus the cost of constructing a plant for the operation of the present process is substantially reduced.
摘要翻译： 公开了一种通过反应蒸馏方法制备乙烯基羧酸酯如乙酸乙烯酯和丙酸乙烯酯的方法，该方法包括反应区，其中乙烯基羧酸酯由选自脂族醛和酮的羰基化合物和脂族羧酸的酐形成 酸和蒸馏区，从其中回收羧酸乙烯酯，并与塔内的其它化合物基本上分离。 该方法需要比已知的类似方法少得多的设备，因此大大减少了用于本方法操作的构建设备的成本。
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7.发明授权公开(公告)号：US08829234B2
公开(公告)日：2014-09-09
申请号：US13431358
申请日：2012-03-27
申请人： Scott Donald Barnicki , Robert Thomas Hembre , Stephen Neal Falling , Mesfin Ejerssa Janka , Kelley Margaret Moran
发明人： Scott Donald Barnicki , Robert Thomas Hembre , Stephen Neal Falling , Mesfin Ejerssa Janka , Kelley Margaret Moran
IPC分类号： C07C51/10 , C07C59/00 , C07C51/42 , C07C51/12 , C07C51/09 , C07C67/58 , C07C51/48 , C07C51/493 , C07C67/36
CPC分类号： C07C51/12 , C07C29/149 , C07C51/09 , C07C51/48 , C07C51/493 , C07C67/08 , C07C67/36 , C07C67/58 , Y02P20/52 , C07C59/06 , C07C31/202 , C07C69/675 , C07C69/67
摘要： Disclosed is a process for the production and purification of glycolic acid or glycolic acid derivatives by the carbonylation of formaldehyde in the presence of a solid acid catalyst and a carboxylic acid. This invention discloses hydrocarboxylations and corresponding glycolic acid separations wherein the glycolic acid stream is readily removed from the carboxylic acid and the carboxylic acid is recycled.
摘要翻译： 公开了一种在固体酸催化剂和羧酸存在下通过甲醛羰基化生产和纯化乙醇酸或乙醇酸衍生物的方法。 本发明公开了加氢羧化和相应的乙醇酸分离，其中乙醇酸流容易地从羧酸中除去并且羧酸被再循环。
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8.发明申请HYDROCARBOXYLATION OF METHYLENE DIPROPIONATE IN THE PRESENCE OF A PROPIONIC ACID AND A HOMOGENEOUS CATALYST 有权丙酸与均相催化剂存在下亚甲基二苯甲酸的烷基化反应公开(公告)号：US20130261329A1
公开(公告)日：2013-10-03
申请号：US13431402
申请日：2012-03-27
IPC分类号： C07C67/36 , C07C29/149 , C07C51/12
CPC分类号： C07C51/12 , C07C29/149 , C07C51/09 , C07C67/08 , C07C67/36 , C07C59/06 , C07C69/24 , C07C69/675 , C07C31/202
摘要： Disclosed is a process for the production and purification of glycolic acid or glycolic acid derivatives by the carbonylation of methylene dipropionate in the presence of a homogeneous acid catalyst and propionic acid. This invention discloses hydrocarboxylations and corresponding homogeneous acid catalyst and glycolic acid separations. The homogeneous acid catalyst is readily separated from the hydrocarboxylation reaction effluent and recycled and the propionic acid is readily removed from the glycolic acid and the propionic acid is recycled
摘要翻译： 公开了一种在均相酸催化剂和丙酸存在下通过二丙酸亚甲酯的羰基化生产和纯化乙醇酸或乙醇酸衍生物的方法。 本发明公开了加氢羧化和相应的均相酸催化剂和乙醇酸分离。 均相酸催化剂容易从加氢羧化反应流出物中分离并再循环，丙酸容易从乙醇酸中除去，丙酸被再循环
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9.发明申请HYDROCARBOXYLATION OF METHYLENE DIPROPIONATE IN THE PRESENCE OF PROPIONIC ACID AND A HETEROGENEOUS CATALYST 有权在丙酸和异构催化剂存在下亚甲基二苯甲酸酯的甲基化公开(公告)号：US20130261337A1
公开(公告)日：2013-10-03
申请号：US13431386
申请日：2012-03-27
申请人： Scott Donald Barnicki , Robert Thomas Hembre , Stephen Neal Falling , Mesfin Ejerssa Janka , Kelley Margaret Moran
发明人： Scott Donald Barnicki , Robert Thomas Hembre , Stephen Neal Falling , Mesfin Ejerssa Janka , Kelley Margaret Moran
IPC分类号： C07C51/347
CPC分类号： C07C51/09 , C07C67/00 , C07C67/36 , C07C59/06 , C07C53/122 , C07C69/675 , C07C69/24
摘要： Disclosed is a process for the production and purification of glycolic acid or glycolic acid derivatives by the carbonylation of methylene dipropionate in the presence of a solid acid catalyst and propionic acid. This invention discloses hydrocarboxylations and corresponding glycolic acid separations wherein the propionic acid stream is readily removed from the glycolic acid and the propionic acid is recycled.
摘要翻译： 公开了一种在固体酸催化剂和丙酸存在下通过二丙酸亚甲酯的羰基化生产和纯化乙醇酸或乙醇酸衍生物的方法。 本发明公开了加氢羧化和相应的乙醇酸分离，其中丙酸流容易从乙醇酸中除去，丙酸被再循环。
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10.发明申请公开(公告)号：US20130261328A1
公开(公告)日：2013-10-03
申请号：US13431369
申请日：2012-03-27
IPC分类号： C07C67/36 , C07C29/149 , C07C51/12
CPC分类号： C07C67/58 , C07C51/09 , C07C51/493 , C07C67/00 , C07C67/36 , C07C59/06 , C07C69/675 , C07C69/24
摘要： Disclosed is a process for the production and purification of glycolic acid or glycolic acid derivatives by the carbonylation of formaldehyde in the presence of a homogeneous acid catalyst and a carboxylic acid. This invention discloses hydrocarboxylations and corresponding homogeneous acid catalyst and glycolic acid separations. The homogeneous acid catalyst is readily separated from the hydrocarboxylation reaction effluent and recycled and the carboxylic acid is readily removed from the glycolic acid and the carboxylic acid is recycled.
摘要翻译： 公开了一种在均相酸催化剂和羧酸存在下通过甲醛羰基化生产和纯化乙醇酸或乙醇酸衍生物的方法。 本发明公开了加氢羧化和相应的均相酸催化剂和乙醇酸分离。 均匀的酸催化剂容易从加氢羧化反应流出物中分离并再循环，羧酸容易从乙醇酸中除去，羧酸被再循环。
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