摘要:
In a process for separating propylene from a mixture comprising propylene and propane, the mixture is passed through a bed of an adsorbent comprising a porous crystalline material having (i) a diffusion time constant for propylene of at least 0.1 sec−1, when measured at a temperature of 373° K and a propylene partial pressure of 8 kPa, and (ii) a diffusion time constant for propane, when measured at a temperature of 373° K and a propane partial pressure of 8 kPa, less than 0.02 of said diffusion time constant for propylene. The bed preferentially adsorbs propylene from the mixture. The adsorbed propylene is then desorbed from the bed either by lowering the pressure or raising the temperature of the bed.
摘要:
The present invention is a separation process for producing a methanol, ethanol and/or dimethyl ether stream from a first stream containing C3+ hydrocarbons. The first stream comprises C3+ hydrocarbons, methanol, ethanol and/or dimethyl ether. The process comprises the step of passing the first stream through an adsorbent bed having a crystalline microporous material that preferentially adsorbs methanol, ethanol and/or dimethyl ether over the C3+ hydrocarbons.
摘要:
A process for making an improved bulk catalyst having a Group VIII metal, such catalyst being useful in producing H.sub.2 O.sub.2 from H.sub.2 and O.sub.2 and/or in producing H.sub.2 from water. The method incorporates the Group VIII metal within the "pillars" of the porous catalyst, without leaving a significant amount of the Group VIII metal on or near the outside surface of the catalyst, by hydrothermal incorporation of the Group VIII metal into the porous pillars.
摘要翻译:制备具有VIII族金属的改进的本体催化剂的方法,该催化剂可用于从H 2和O 2生产H 2 O 2和/或从水中产生H 2。 该方法通过多孔催化剂的“支柱”中的VIII族金属,通过将VIII族金属水热掺入到多孔柱中,而不在催化剂的外表面上或附近留下大量的VIII族金属。
摘要:
A method for the production of hydrogen peroxide from a source of hydrogen and oxygen in the presence of a dispersion of a catalyst in an organic reaction medium, the catalyst being composed of inert particles of between 1 and 100 microns, the particles having coated thereon about three to ten layers of a zirconium or hafnium complex, the organic reaction medium having a pH of less than about 3 and composed of at least 50% of a lower alkyl alcohol, a lower alkyl ketone or a mixture thereof, water and a mineral acid.