公开(公告)号：US5298373A

公开(公告)日：1994-03-29

申请号：US803039

申请日：1991-12-06

申请人： Senzo Sasaoka ,  Katsumi Hayashi ,  Kota Fukui ,  Tetsuro Kojima

发明人： Senzo Sasaoka ,  Katsumi Hayashi ,  Kota Fukui ,  Tetsuro Kojima

IPC分类号： G03C5/29 ,  G03C5/38 ,  G03C5/18 ,  G03C1/76 ,  G03C5/26

CPC分类号： G03C5/38 ,  Y10S430/14

摘要： Silver halide black-and-white photosensitive material is processed with a fixer which contains 0.5 to 2.0 mol/liter of a thiosulfate and 0.003 to 0.3 mol/liter of a meso-ionic compound, the moles of the meso-ionic compound divided by the moles of the thiosulfate being from 0.003 to 0.2. The fixer accelerates fixing speed, enabling rapid processing of photographic material.

摘要翻译： 卤化银黑白感光材料用含有0.5-2.0mol / l硫代硫酸盐和0.003-0.3mol /升内消旋离子化合物的定影剂加工，内消旋体化合物的摩尔数除以 硫代硫酸盐的摩尔数为0.003至0.2。 定影剂加速定影速度，可以快速处理照相材料。

公开(公告)号：US4920029A

公开(公告)日：1990-04-24

申请号：US235805

申请日：1988-08-23

申请人： Nobuaki Inoue ,  Senzo Sasaoka ,  Yoshio Inagaki ,  Tetsuro Kojima ,  Morio Yagihara

发明人： Nobuaki Inoue ,  Senzo Sasaoka ,  Yoshio Inagaki ,  Tetsuro Kojima ,  Morio Yagihara

IPC分类号： G03C5/29 ,  G03C1/06

CPC分类号： G03C1/061 ,  Y10S430/15

摘要： A negative type silver halide photographic material and a process for forming a super high contrast negative image using said material are described. This photographic material comprises a support having provided thereon at least one silver halide emulsion layer which has a substantial influence upon image density and at least one light-insensitive hydrophilic colloid layer, wherein a hydrophilic colloid layer other than said silver halide emulsion layer contains a hydrazine derivative in a non-diffusing condition. With this photographic material, a super high contrast negative image can be obtained without decreasing sensitivity and gamma by the use of a developer containing not less than 0.15 mol/liter of sulfite ions and having a pH of from 10.5 to 12.3.

摘要翻译： 描述负型卤化银照相材料和使用所述材料形成超高对比度负像的方法。 该照相材料包括其上设置有至少一个卤化银乳剂层的载体，其对图像密度具有实质影响，并且至少一个不透光的亲水胶体层，其中除了所述卤化银乳剂层之外的亲水胶体层含有肼 衍生物在非扩散条件下。 利用该照相材料，可以通过使用含有不低于0.15mol / l亚硫酸根离子并且pH为10.5〜12.3的显影剂，而不降低灵敏度和γ而获得超高对比度负像。

公开(公告)号：US06541192B2

公开(公告)日：2003-04-01

申请号：US09989416

申请日：2001-11-21

申请人： Yasuhiro Kato ,  Hisashi Mikoshiba ,  Naoto Matsuda ,  Tetsuro Kojima

发明人： Yasuhiro Kato ,  Hisashi Mikoshiba ,  Naoto Matsuda ,  Tetsuro Kojima

IPC分类号： G03C108

CPC分类号： C07D487/04 ,  G03C7/383

摘要： A silver halide color photographic lightsensitive material comprising at least one layer on a support, wherein the at least one layer contains a coupler represented by formula (I) below wherein X represents a hydrogen atom, halogen atom, arylthio group, carbamoyloxy group, heterocyclic carbonyloxy group, etc., each of R1 and R2 represents an electron-attracting group having a Hammett's substituent constant &sgr;p value of not less than 0.20, the sum of the &sgr;p values of R1 and R2 being not less than 0.65, each of R3 and R4 represents a alkyl group, alkenyl group, alkynyl group, cycloalkyl group, cycloalkenyl group, etc., or alternatively, R3 and R4 may bond together to form a ring structure; and each of R11 to R15 independently represents a hydrogen atom or a substituent.

摘要翻译： 一种卤化银彩色照相感光材料，其在载体上包含至少一层，其中所述至少一层包含由下式（I）表示的成色剂，其中X表示氢原子，卤素原子，芳硫基，氨基甲酰氧基，杂环羰氧基 等等，R1和R2各自表示哈米特取代基常数sigmap值不小于0.20的吸电子基团，R1和R2的sigmap值之和不小于0.65，R3和R4各自表示 烷基，烯基，炔基，环烷基，环烯基等，或者R3和R4可以键合在一起形成环结构; R 11〜R 15各自独立地表示氢原子或取代基。

公开(公告)号：US5278025A

公开(公告)日：1994-01-11

申请号：US931508

申请日：1992-08-21

申请人： Hisashi Okamura ,  Kazunobu Katoh ,  Tetsuro Kojima

发明人： Hisashi Okamura ,  Kazunobu Katoh ,  Tetsuro Kojima

IPC分类号： G03C1/06 ,  G03C1/34 ,  G03C1/43 ,  G03C5/305 ,  G03C5/26 ,  G03C5/30

CPC分类号： G03C1/061 ,  G03C1/34 ,  G03C1/43 ,  G03C5/305 ,  Y10S430/158

摘要： A method for forming an image comprising the steps of: (a) imagewise exposing silver halide photographic materials; where said photographic material contains (1) a compound represented by formula (I) ##STR1## wherein R.sub.1 represents an aliphatic group or an aromatic group; R.sub.2 represents a hydrogen atom, an alkyl group, or an aryl group, an alkoxy group, an aryloxy group, an amino group, a carbamoyl group, or an oxycarbonyl group; G.sub.1 represents a carbonyl group, a sulfonyl group, a sulfoxy group, ##STR2## or an iminomethylene group; and A.sub.1 and A.sub.2 both represent a hydrogen atom, or one of A.sub.1 or A.sub.2 represents a hydrogen atom and the other represents a substituted or unsubstituted alkylsulfonyl group, a substituted or unsubstituted arylsulfonyl group, or a substituted or unsubstituted acyl group, and (2) a redox compound that can release a development inhibitor when oxidized; and (b) subjecting said imagewise exposed silver halide photographic materials to development-processing where a bath used in said development-processing contains a nucleation development accelerator.

摘要翻译： 一种用于形成图像的方法，包括以下步骤：（a）成像曝光卤化银照相材料; 其中所述照相材料包含（1）由式（I）表示的化合物（*化学结构*）（I）其中R 1表示脂族基团或芳族基团; R2表示氢原子，烷基或芳基，烷氧基，芳氧基，氨基，氨基甲酰基或氧羰基; G1表示羰基，磺酰基，磺氧基，（*化学结构*）或亚氨基亚甲基; 和A1和A2均表示氢原子，或A1或A2中的一个表示氢原子，另一个表示取代或未取代的烷基磺酰基，取代或未取代的芳基磺酰基或取代或未取代的酰基，（2） 氧化还原化合物，当氧化时可释放显影抑制剂; 和（b）对所述成像曝光的卤化银照相材料进行显影处理，其中所述显影处理中使用的浴含有成核显影促进剂。

公开(公告)号：US5194368A

公开(公告)日：1993-03-16

申请号：US427831

申请日：1989-09-06

申请人： Shinji Ueda ,  Tetsuro Kojima ,  Tohru Kitahara ,  Tomokazu Yasuda ,  Yoshihiro Fujita ,  Takatoshi Ishikawa

发明人： Shinji Ueda ,  Tetsuro Kojima ,  Tohru Kitahara ,  Tomokazu Yasuda ,  Yoshihiro Fujita ,  Takatoshi Ishikawa

IPC分类号： G03C5/395 ,  G03C7/42 ,  G03C5/38

CPC分类号： G03C5/3956 ,  G03C7/42

摘要： The present invention relates to a method for processing a silver halide photographic light-sensitive material having at least one silver halide emulsion layer containing silver iodide with a processing solution having fixing ability after developing the light-sensitive material. The object of the present invention is to speed up the fixing process in the foregoing method and to reduce the amount of waste liquor from the fixing process. The present invention is characterized in that the processing with the processing solution having fixing ability is performed while the processing solution is brought into contact with an anion-exchange resin and that 20 to 2,000 l of the processing solution per liter of the anion-exchange resin is brought into contact with the resin.

公开(公告)号：US5120635A

公开(公告)日：1992-06-09

申请号：US613044

申请日：1990-11-15

申请人： Hirotomo Sasaki ,  Tetsuro Kojima ,  Shinji Ueda

发明人： Hirotomo Sasaki ,  Tetsuro Kojima ,  Shinji Ueda

IPC分类号： G03C5/38 ,  G03C5/44 ,  G03C7/42

CPC分类号： G03C5/38 ,  G03C5/44 ,  G03C7/421

摘要： A method for processing a silver halide photographic material which comprises processing an imagewise exposed silver halide photographic material with a processing solution having a fixing ability containing (1) a thiosulfate As disclosed, wherein said processing solution having a fixing ability further contains at least one of (2) at least one compound selected from the group consisting of a bisulfite and a sulfite, and a compound represented by formula (A'): ##STR1## wherein R'.sub.1, R'.sub.2, R'.sub.3, R'.sub.4 and R'.sub.5 each represents a hydrogen atom or a substituent other than a hydroxyl group or a group containing a hydroxyl group, provided that at least one of R'.sub.1 to R'.sub.5 is at least one of a sulfo group and a group constaining a sulfo group and (3) at least one bisulfite addition product of a compound represented by formula (A'). In the method, a fixing solution having a pH of from 5.0 to 9.0 or a bleach-fixing solution with improved stability over time during continuous processing and exhibiting excellent desilvering performance is used. The method provides an image showing a reduced increase in stain with time and realizes improvements of the working environment.

公开(公告)号：US5059514A

公开(公告)日：1991-10-22

申请号：US415266

申请日：1989-08-23

申请人： Shinji Ueda ,  Tetsuro Kojima ,  Tohru Kitahara ,  Tomokazu Yasuda ,  Yoshihiro Fujita ,  Takatoshi Ishikawa

发明人： Shinji Ueda ,  Tetsuro Kojima ,  Tohru Kitahara ,  Tomokazu Yasuda ,  Yoshihiro Fujita ,  Takatoshi Ishikawa

IPC分类号： G03C5/395 ,  G03C7/42 ,  G03C7/44

CPC分类号： G03C7/44 ,  G03C5/3956 ,  G03C7/42 ,  Y10S430/164

摘要： The present invention relates to a method for bleaching a silver halide photographic light-sensitive material having at least one silver halide emulsion layer containing silver iodobromide after color-developing it. The object of the present invention is to speed up the bleaching treatment in the aforesaid method and to reduce the amount of waste liquor from the bleaching treatment. The present invention is characterized in that the bleaching is performed in the presence of a bleaching accelerator and that it is carried out while a bleaching solution is brought into contact with an anion-exchange resin.

摘要翻译： PCT No.PCT / JP88 / 01328 Sec。 371日期1989年8月23日 102（e）日期1989年8月23日PCT提交1988年12月24日PCT公布。 公开号WO89 / 06380 日本1987年7月13日。本发明涉及一种漂白卤化银照相感光材料的方法，该方法在显色后含有至少一种含有碘溴化银的卤化银乳剂层。 本发明的目的是加速上述方法的漂白处理，并减少漂白处理废液的量。 本发明的特征在于漂白在漂白促进剂的存在下进行，并且在漂白溶液与阴离子交换树脂接触的同时进行。

公开(公告)号：US4772546A

公开(公告)日：1988-09-20

申请号：US917643

申请日：1986-10-10

申请人： Naoyasu Deguchi ,  Tetsuro Kojima ,  Hideo Miyazaki ,  Shigeru Ohno ,  Koki Nakamura

发明人： Naoyasu Deguchi ,  Tetsuro Kojima ,  Hideo Miyazaki ,  Shigeru Ohno ,  Koki Nakamura

IPC分类号： G03C1/46 ,  G03C7/30 ,  G03C7/392 ,  G03C1/06 ,  G03C1/08 ,  G03C7/32

CPC分类号： G03C7/39276 ,  G03C1/46 ,  G03C7/30

摘要： A silver halide photographic material is described, having at least one light-sensitive silver halide emulsion layer containing an iodine-containing silver halide on a support and having one or more auxiliary layers on the outermost surface of a light-sensitive silver halide emulsion layer positioned farthest from the support, wherein at least one of the auxiliary layers contains a substantially non-light-sensitive silver halide emulsion or a silver halide emulsion containing grains whose inner part or surface part is fogged, and the material contains at least one compound represented by formula (I) ##STR1## wherein R, X, Y, Z, and n are described in the specification.

摘要翻译： 描述了一种卤化银照相材料，其具有至少一种感光卤化银乳剂层，其在载体上含有含碘卤化银并且在感光卤化银乳剂层的最外表面上具有一个或多个辅助层 最远离支持体，其中至少一个辅助层含有基本上不感光的卤化银乳剂或含有其内部或表面部分被雾化的颗粒的卤化银乳剂，并且该材料含有至少一种由 式（I）其中R，X，Y，Z和n在说明书中描述。

公开(公告)号：US4615970A

公开(公告)日：1986-10-07

申请号：US678906

申请日：1984-12-06

申请人： Tetsuro Kojima ,  Koki Nakamura ,  Takashi Toyoda

发明人： Tetsuro Kojima ,  Koki Nakamura ,  Takashi Toyoda

IPC分类号： C07D249/14 ,  C07D401/04 ,  C07D487/04 ,  G03C1/34

CPC分类号： C07D401/04 ,  C07D249/14 ,  C07D487/04 ,  G03C1/34

摘要： A silver halide photographic material containing at least one of compounds represented by formula (I) and salts thereof in at least one hydrophilic colloidal layer of the silver halide photographic material gives photographic images having stable and excellent quality without being accompanied by the increased formation of fog and increased changes of sensitivity and gradation upon high temperature processing: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 each represents a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted cycloalkyl group, a substituted or unsubstituted aryl group, or a substituted or unsubstituted heterocyclic ring group; or one or both of said R.sub.1 and R.sub.2 and said R.sub.3 and R.sub.4 combine with each other to form a ring.

摘要翻译： 在卤化银照相材料的至少一个亲水性胶体层中含有至少一种由式（I）表示的化合物及其盐的卤化银照相材料使摄影图像具有稳定和优异的质量，而不伴随增加的雾形成 并且在高温处理时增加灵敏度和灰度的变化：其中R1，R2，R3和R4各自表示取代或未取代的烷基，取代或未取代的烯基，取代或未取代的环烷基， 取代或未取代的芳基，或取代或未取代的杂环基团; 或者所述R 1和R 2中的一个或两个并且所述R 3和R 4彼此结合形成环。

公开(公告)号：US4455368A

公开(公告)日：1984-06-19

申请号：US484813

申请日：1983-04-14

申请人： Tetsuro Kojima ,  Shingo Ishimaru ,  Naohiko Sugimoto ,  Tadashi Ikeda

发明人： Tetsuro Kojima ,  Shingo Ishimaru ,  Naohiko Sugimoto ,  Tadashi Ikeda

IPC分类号： G03C7/26 ,  C07C67/00 ,  C07C229/30 ,  C07C253/00 ,  C07C255/30 ,  C07C313/00 ,  C07C317/28 ,  C07C317/44 ,  C07C317/48 ,  C08F12/00 ,  C08F12/06 ,  C08F20/00 ,  C08F20/10 ,  C08F20/26 ,  C08F20/34 ,  C08F20/38 ,  C08F20/52 ,  C08F20/54 ,  C08F22/32 ,  C08F36/00 ,  C08F36/04 ,  C09K3/00 ,  G03C1/04 ,  G03C1/06 ,  G03C1/815 ,  G03C1/78

CPC分类号： G03C1/815 ,  Y10S430/132

摘要： A silver halide photographic light-sensitive material comprising a support having thereon at least one light-sensitive silver halide emulsion and at least one light-insensitive layer is disclosed. One or more of the layers of the material contains an ultraviolet ray absorbing polymer latex which comprises a homopolymer or copolymer having a repeating unit derived from a monomer represented by the general formula (II) in which one or more ultraviolet ray absorbing compounds represented by the general formula (I) is loaded: ##STR1## the substituents within the general formula are defined within the specification. The material has excellent absorption characteristics in the 300 to 400 nm range and does not cause static marks caused by ultraviolet rays or undergo deterioration of color reproduction. In addition, the material has good film strength and reduced layer thickness and provides a color image having improved sharpness which is free from fading or discoloration due to light.

摘要翻译： 公开了一种卤化银照相感光材料，其包含其上具有至少一种感光卤化银乳剂和至少一种不透光层的载体。 材料的一层或多层包含一种紫外线吸收聚合物胶乳，其包含具有衍生自由通式（II）表示的单体的重复单元的均聚物或共聚物，其中一个或多个由 通式（I）被加载：通式（II）中的取代基在本说明书中定义。 该材料在300〜400nm的范围内具有优异的吸收特性，不会引起紫外线引起的静电痕迹或颜色再现的劣化。 此外，该材料具有良好的膜强度和降低的层厚度，并且提供了一种具有改善的清晰度的彩色图像，其不会因光而褪色或变色。