High purity 4,4′-isopropylidene-bis-(2,6 dibromophenol) and process for the preparation of such high purity 4,4′-isopropylidene-bis-(2,6 dibromophenol)
    1.
    发明授权
    High purity 4,4′-isopropylidene-bis-(2,6 dibromophenol) and process for the preparation of such high purity 4,4′-isopropylidene-bis-(2,6 dibromophenol) 有权
    高纯度4,4'-异亚丙基 - 双(2,6-二溴苯酚)和制备高纯度4,4'-异亚丙基 - 双(2,6-二溴苯酚)

    公开(公告)号:US06613947B1

    公开(公告)日:2003-09-02

    申请号:US10168454

    申请日:2002-10-21

    IPC分类号: C07C3916

    摘要: A high purity 4,4′-isopropylidine-bis-(2,6-dibromophenol) characterised by ionic bromides less than 10 ppm, colour in alkaline solution from 60-100 HU, HPLC purity about 99.9%, APHA of 20% MeOH solution less than 10.0 HU, Fe less than 1.0 ppm, turbidity of 20% MeOH solution less than 5 NTU, pH of 10% slurry 6.0-7.0, size of the crystal particles, 250 to 280 microns with angle of repose lower than 30°. The product is produced by reacting Bisphenol-A with bromine in a “water-immiscible” polar solvent in the presence of hydrogen peroxide, aging the reaction products after the reaction, eliminating the excess bromine by reducing agents, washing the product layer with a combination of anionic surfactant, alkali, reducing agent and demineralised water under controlled pH conditions, partially distilling the organic solvent chilling the medium containing the product, filtering the crude product, boiling the crude product with alkali, reducing agent and demineralised water, filtering the TBBA, washing the product with demineralised water and drying to obtain the final high purity TBBA with high yield.

    摘要翻译: 高纯度4,4'-异丙基 - 双 - (2,6-二溴苯酚),其特征在于离子型溴化物小于10ppm,碱性溶液中颜色为60-100HU,HPLC纯度约99.9%,APHA为20%MeOH溶液 小于10.0HU,Fe小于1.0ppm,浊度为20%MeOH溶液小于5NTU,pH为10%浆液6.0-7.0,晶粒尺寸为250至280微米,休止角低于30°。 该产物通过双酚A与溴在过氧化氢存在下在“与水不混溶”的极性溶剂中反应生成,使反应后的反应产物老化,通过还原剂消除过量的溴,用组合物洗涤产物层 的阴离子表面活性剂,碱,还原剂和软化水,部分蒸馏含有产物的培养基的有机溶剂,过滤粗产物,用碱,还原剂和软化水煮沸粗产物,过滤TBBA, 用软化水洗涤产物并干燥,以高产率获得最终的高纯度TBBA。

    Fluorescent brighteners, methods of preparation thereof, fluorescent brightener compositions, and methods of preparation and uses thereof
    6.
    发明授权
    Fluorescent brighteners, methods of preparation thereof, fluorescent brightener compositions, and methods of preparation and uses thereof 有权
    荧光增白剂,其制备方法,荧光增白剂组合物及其制备方法和用途

    公开(公告)号:US08183310B2

    公开(公告)日:2012-05-22

    申请号:US12561764

    申请日:2009-09-17

    IPC分类号: C08K5/3437

    摘要: A compound of Formula (I) wherein R1, R2, and R3 are independently at each occurrence hydrogen, a halogen, a cyano functionality, a C1-C20 aliphatic functionality, a C3-C10 cycloaliphatic functionality or a C3-C20 aromatic functionality, with the proviso that R2 and R3 are not hydrogen when R1 is a methyl or hydrogen; R4 and R5 are independently at each occurrence hydrogen, a halogen, a cyano functionality, a C1-C20 aliphatic functionality, a C3-C10 cycloaliphatic functionality or a C3-C10 aromatic functionality; R7 and R8 are independently at each occurrence, a halogen, a cyano functionality, a C1-C20 aliphatic functionality, a C3-C10 cycloaliphatic functionality or a C3-C10 aromatic functionality; R6 is a C2-C20 aliphatic functionality, a C3-C10 cycloaliphatic functionality or a C3-C20 aromatic functionality; and “n” and “m” are each independently integers having a value of 0 to 3.

    摘要翻译: 式(I)的化合物,其中R 1,R 2和R 3在每次出现时独立地为氢,卤素,氰基官能团,C 1 -C 20脂族官能团,C 3 -C 10脂环族官能团或C 3 -C 20芳族官能团,与 条件是当R 1是甲基或氢时,R 2和R 3不是氢; R4和R5各自独立地为氢,卤素,氰基官能团,C 1 -C 20脂族官能团,C 3 -C 10脂环族官能团或C 3 -C 10芳族官能团; R 7和R 8在每次出现时独立地为卤素,氰基官能团,C 1 -C 20脂族官能团,C 3 -C 10脂环族官能团或C 3 -C 10芳族官能团; R 6是C 2 -C 20脂族官能团,C 3 -C 10脂环族官能团或C 3 -C 20芳族官能团; “n”和“m”各自独立地为0〜3的整数。

    FLUORESCENT BRIGHTENERS, METHODS OF PREPARATION THEREOF, FLUORESCENT BRIGHTENER COMPOSITIONS, AND METHODS OF PREPARATION AND USES THEREOF
    9.
    发明申请
    FLUORESCENT BRIGHTENERS, METHODS OF PREPARATION THEREOF, FLUORESCENT BRIGHTENER COMPOSITIONS, AND METHODS OF PREPARATION AND USES THEREOF 有权
    荧光增白剂,其制备方法,荧光增白剂组合物及其制备方法及其用途

    公开(公告)号:US20110065843A1

    公开(公告)日:2011-03-17

    申请号:US12561764

    申请日:2009-09-17

    IPC分类号: C07D221/06 C08K5/3437

    摘要: A compound of Formula (I) wherein R1, R2, and R3 are independently at each occurrence hydrogen, a halogen, a cyano functionality, a C1-C20 aliphatic functionality, a C3-C10 cycloaliphatic functionality or a C3-C20 aromatic functionality, with the proviso that R2 and R3 are not hydrogen when R1 is a methyl or hydrogen; R4 and R5 are independently at each occurrence hydrogen, a halogen, a cyano functionality, a C1-C20 aliphatic functionality, a C3-C10 cycloaliphatic functionality or a C3-C10 aromatic functionality; R7 and R8 are independently at each occurrence, a halogen, a cyano functionality, a C1-C20 aliphatic functionality, a C3-C10 cycloaliphatic functionality or a C3-C10 aromatic functionality; R6 is a C2-C20 aliphatic functionality, a C3-C10 cycloaliphatic functionality or a C3-C20 aromatic functionality; and “n” and “m” are each independently integers having a value of 0 to 3.

    摘要翻译: 式(I)的化合物,其中R 1,R 2和R 3在每次出现时独立地为氢,卤素,氰基官能团,C 1 -C 20脂族官能团,C 3 -C 10脂环族官能团或C 3 -C 20芳族官能团,与 条件是当R 1是甲基或氢时,R 2和R 3不是氢; R4和R5各自独立地为氢,卤素,氰基官能团,C 1 -C 20脂族官能团,C 3 -C 10脂环族官能团或C 3 -C 10芳族官能团; R 7和R 8在每次出现时独立地为卤素,氰基官能团,C 1 -C 20脂族官能团,C 3 -C 10脂环族官能团或C 3 -C 10芳族官能团; R 6是C 2 -C 20脂族官能团,C 3 -C 10脂环族官能团或C 3 -C 20芳族官能团; “n”和“m”各自独立地为0〜3的整数。

    HOLOGRAPHIC STORAGE MEDIUM
    10.
    发明申请
    HOLOGRAPHIC STORAGE MEDIUM 审中-公开
    全息存储介质

    公开(公告)号:US20130071773A1

    公开(公告)日:2013-03-21

    申请号:US13234576

    申请日:2011-09-16

    摘要: Disclosed herein are novel amidic nitrone and a method of manufacturing a data storage media comprising mixing the amidic nitrone, as a photochromic dye, with an organic material or an inorganic material to form a holographic composition and molding the holographic composition into holographic data storage media. Disclosed herein too is an article comprising a photochromic dye and an organic material, wherein the article is used as a data storage media. Disclosed herein too is a method for recording information comprising irradiating an article that comprises a photochromic dye, wherein the irradiation is conducted with electromagnetic energy having a wavelength of about 350 to about 1,100 nanometers; and reacting the photochromic dye.

    摘要翻译: 本文公开了新的酰胺硝酮和制备数据存储介质的方法,包括将作为光致变色染料的酰胺硝酮与有机材料或无机材料混合以形成全息组合物并将全息组合物模塑成全息数据存储介质。 本文还公开了包含光致变色染料和有机材料的制品,其中该制品用作数据存储介质。 本文也公开了一种用于记录信息的方法,包括:对包含光致变色染料的物品进行照射,其中用约350至约1100纳米波长的电磁能照射; 并使光致变色染料反应。