公开(公告)号：US06211311B1

公开(公告)日：2001-04-03

申请号：US09318008

申请日：1999-05-25

申请人： Shaotian Wang ,  Bradley P. Etherton ,  Karen E. Meyer ,  Michael W. Lynch ,  Linda N. Winslow ,  Leonard V. Cribbs ,  Jia-Chu X. Liu

发明人： Shaotian Wang ,  Bradley P. Etherton ,  Karen E. Meyer ,  Michael W. Lynch ,  Linda N. Winslow ,  Leonard V. Cribbs ,  Jia-Chu X. Liu

IPC分类号： C08F442

CPC分类号： B01J31/165 ,  B01J31/0231 ,  B01J31/0272 ,  B01J31/0274 ,  B01J31/0275 ,  B01J31/14 ,  B01J31/1616 ,  B01J31/2295 ,  B01J2531/0225 ,  B01J2531/0233 ,  B01J2531/0236 ,  B01J2531/46 ,  B01J2531/48 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/6592 ,  C08F10/00 ,  C08F110/02 ,  C08F210/16 ,  C08F4/65916 ,  C08F210/08 ,  C08F210/14

摘要： A supported olefin polymerization catalyst system and a method of making it are disclosed. The catalyst system comprises: (a) a support chemically treated with an organoaluminum, organosilicon, organomagnesium, or organoboron compound; (b) a single-site catalyst that contains a polymerization-stable, heteroatomic ligand; and (c) an activator. Chemical treatment is a key to making supported heterometallocenes that have high activity and long shelf-lives, and can effectively incorporate comonomers.

摘要翻译： 公开了一种负载型烯烃聚合催化剂体系及其制备方法。 催化剂体系包括：（a）用有机铝，有机硅，有机镁或有机硼化合物化学处理的载体; （b）含有聚合稳定的杂原子配体的单中心催化剂; 和（c）活化剂。 化学处理是制备具有高活性和长保质期的负载型异金属茂并能有效掺入共聚单体的关键。

公开(公告)号：US07423098B2

公开(公告)日：2008-09-09

申请号：US11333576

申请日：2006-01-17

申请人： Philip J. Garrison ,  Charles S. Holland ,  Mark P. Mack ,  Linda N. Winslow ,  Everett O. Lewis ,  James R. Clark ,  Leonard V. Cribbs ,  Bradley P. Etherton ,  Jean A. Merrick-Mack ,  Paula L. Nygard

发明人： Philip J. Garrison ,  Charles S. Holland ,  Mark P. Mack ,  Linda N. Winslow ,  Everett O. Lewis ,  James R. Clark ,  Leonard V. Cribbs ,  Bradley P. Etherton ,  Jean A. Merrick-Mack ,  Paula L. Nygard

IPC分类号： C08F4/6192 ,  C08F4/6592 ,  C08F210/14 ,  C08F210/16

CPC分类号： C08F210/16 ,  Y10S526/905 ,  C08F2/001 ,  C08F2/14 ,  C08F210/08 ,  C08F2500/12 ,  C08F2500/26 ,  C08F210/14

摘要： An ethylene polymerization process is disclosed. Ethylene is polymerized in two slurry reaction zones with a C6-C10 alpha-olefin in the presence of a single-site catalyst capable of making a high molecular weight polyolefin. The process yields medium density and linear low density polyethylene having a bimodal molecular weight distribution and a melt index from about 0.10 to about 0.80. Films from the polyethylene have superior impact properties.

摘要翻译： 公开了一种乙烯聚合方法。 在能够制备高分子量聚烯烃的单中心催化剂的存在下，乙烯在两个浆料反应区中与C 6 -C 10α-烯烃聚合。 该方法产生具有双峰分子量分布和约0.10至约0.80的熔体指数的中密度和线性低密度聚乙烯。 聚乙烯薄膜具有优异的冲击性能。

公开(公告)号：US06759493B1

公开(公告)日：2004-07-06

申请号：US08872659

申请日：1997-06-10

申请人： Sandor Nagy ,  Leonard V. Cribbs ,  Bradley P. Etherton ,  Mary Cocoman ,  Ramesh Krishnamurti ,  John A. Tyrell

发明人： Sandor Nagy ,  Leonard V. Cribbs ,  Bradley P. Etherton ,  Mary Cocoman ,  Ramesh Krishnamurti ,  John A. Tyrell

IPC分类号： C08F444

CPC分类号： C08F10/00 ,  B01J31/181 ,  B01J31/1815 ,  B01J31/1825 ,  B01J31/2208 ,  B01J31/2226 ,  B01J31/226 ,  B01J31/2295 ,  B01J31/2404 ,  B01J2531/46 ,  B01J2531/48 ,  B01J2531/49 ,  B01J2531/56 ,  B01J2531/57 ,  B01J2531/62 ,  B01J2531/66 ,  B01J2531/828 ,  C07F7/003 ,  C07F7/28 ,  C07F17/00 ,  C08F4/659 ,  C08F4/65912 ,  C08F10/02 ,  C08F110/02 ,  C08F210/16 ,  C08F2420/04 ,  Y10S526/943 ,  C08F4/64 ,  C08F4/6592 ,  C08F2500/12 ,  C08F210/08 ,  C08F2500/07 ,  C08F2500/03 ,  C08F4/64048

摘要： Disclosed is a novel bidentate pyridine transition metal catalyst having the general formula where each R is independently hydrogen, C1-6 alkyl, or C6-14 aryl; where each R′ is independently R, C1-6 alkoxy, C7-20 alkaryl, C7-20 aralkyl, halogen, or CF3; where M is a Group 3 to 10 metal; where each X is independently halogen, C1-6 alkyl, C6-14 aryl, C7-20 alkaryl, C7-20 aralkyl, C1-6 alkoxy, or  L is X, cyclopentadienyl, C1-16 alkyl-substituted cyclopentadienyl, fluorenyl, indenyl, or  where n is an integer from 1 to 4; a is an integer from 1 to 3; b is an integer from 0 to 2; the sum of a+b≦3; c is an integer from 1 to 6; and the sum a+b+c equals the oxidation state of M.

摘要翻译： 公开了一种新颖的二齿吡啶过渡金属催化剂，其具有通式，其中每个R独立地为氢，C 1-6烷基或C 6-14芳基;其中每个R'独立地为R，C 1-6烷氧基，C 7-20烷芳基， 20芳烷基，卤素或CF 3;其中M是第3至10族金属;其中每个X独立地是卤素，C 1-6烷基，C 6-14芳基，C 7-20烷芳基，C 7-20芳烷基，C 1-6烷氧基， 或L是X，环戊二烯基，C 1-6烷基取代的环戊二烯基，芴基，茚基，或者是1至4的整数; a是1至3的整数; b是0至2的整数; a + b <= 3; c是1至6的整数; 和a + b + c之和等于M的氧化态。

公开(公告)号：US06410764B1

公开(公告)日：2002-06-25

申请号：US09764722

申请日：2001-01-18

申请人： Leonard V. Cribbs ,  Bradley P. Etherton

发明人： Leonard V. Cribbs ,  Bradley P. Etherton

IPC分类号： C07F502

CPC分类号： C07F17/00 ,  C07F5/027

摘要： A process for preparing boratabenzene derivatives is provided. The process includes the hydrogenation of a compound containing a boranaphthalene functional group to form a boratabenzene-containing compound. Depending on the compound containing a boranaphthalene functional group, the resulting boratabenzene compound may be converted into a catalyst suitable for olefin polymerization. A process for forming a boratabenzene derivative from a halo-dioxaborolane is also provided. In this process, a halo-dioxaborolane is reacted with a piperylide salt for form a pentadienyl dioxaborolane. The pentadienyl-dioxaborolane is reacted with a strong base to form an intermediate boratacyclohexanediene salt. The intermediate boratacyclohexanediene salt is then reacted with a trialkylaluminum compound to form an alkylboratabenzene salt.

摘要翻译： 提供了一种制备硼代苯衍生物的方法。 该方法包括含有硼烷官能团的化合物的氢化以形成含硼代苯的化合物。 根据含有硼烷官能团的化合物，所得的硼代苯化合物可以转化为适用于烯烃聚合的催化剂。 还提供了由卤代二氧硼烷制备硼代苯衍生物的方法。 在该方法中，将卤代二氧杂硼杂环戊烷与哌啶子盐反应形成戊二烯基二氧杂硼杂环戊烷。 将戊二烯基二氧杂硼杂环戊烷与强碱反应形成中间体硼烷环己烷二盐。 然后将中间体硼烷环己二烯盐与三烷基铝化合物反应以形成烷基硼代苯盐。

公开(公告)号：US06790918B2

公开(公告)日：2004-09-14

申请号：US10610212

申请日：2003-06-30

申请人： Sandor Nagy ,  Leonard V. Cribbs ,  Bradley P. Etherton ,  Mary Cocoman ,  Ramesh Krishnamurti ,  John A. Tyrell

发明人： Sandor Nagy ,  Leonard V. Cribbs ,  Bradley P. Etherton ,  Mary Cocoman ,  Ramesh Krishnamurti ,  John A. Tyrell

IPC分类号： C08F4642

CPC分类号： C08F10/00 ,  B01J31/181 ,  B01J31/1815 ,  B01J31/1825 ,  B01J31/2208 ,  B01J31/2226 ,  B01J31/226 ,  B01J31/2295 ,  B01J31/2404 ,  B01J2531/46 ,  B01J2531/48 ,  B01J2531/49 ,  B01J2531/56 ,  B01J2531/57 ,  B01J2531/62 ,  B01J2531/66 ,  B01J2531/828 ,  C07F7/003 ,  C07F7/28 ,  C07F17/00 ,  C08F4/659 ,  C08F4/65912 ,  C08F10/02 ,  C08F110/02 ,  C08F210/16 ,  C08F2420/04 ,  Y10S526/943 ,  C08F4/64 ,  C08F4/6592 ,  C08F2500/12 ,  C08F210/08 ,  C08F2500/07 ,  C08F2500/03 ,  C08F4/64048

摘要： Disclosed is a novel bidentate pyridine transition metal catalyst having the general formula each R is independently selected from hydrogen or C1 to C6 alkyl, or C6 to C14 aryl, each R′ is independently selected from R, C1 to C6 alkoxy, C6 to C14 aryl, C7 to C20 alkaryl, C7 to C20 aralkyl, halogen, or CF3, M is a Group 3 to 10 metal, each X is independently selected from halogen, C1 to C6 alkyl, C6 to C14 aryl, C7 to C20 alkaryl, C7 to C20aralkyl, C1 to C6 alkoxy, or L is X, cyclopentadienyl, C1 to C6 alkyl substituted cyclopentadienyl, indenyl, fluorenyl, or “n” is 1 to 4; “a” is 1 to 3; “b” is 0 to 2; a+b≦3; “c” is 1 to 6; and a+b+c equals the oxidation state of M.

摘要翻译： 公开了一种新颖的二齿吡啶过渡金属催化剂，其通式为R独立地选自氢或C1至C6烷基，或C6至C14芳基，每个R'独立地选自R，C1至C6烷氧基，C6至C14芳基， C7至C20烷芳基，C7至C20芳烷基，卤素或CF3，M为第3至10族金属，每个X独立地选自卤素，C 1至C 6烷基，C 6至C 14芳基，C 7至C 20烷芳基，C 7至C 20芳烷基 ，C1〜C6烷氧基，或L为X，环戊二烯基，C1至C6烷基取代的环戊二烯基，茚基，芴基或“n”为1至4;“a”为1至3;“b”为0至2; a + b <= 3;“c”为1至6; anda + b + c等于M的氧化态。

公开(公告)号：US6127484A

公开(公告)日：2000-10-03

申请号：US302059

申请日：1999-04-29

申请人： Leonard V. Cribbs ,  Bradley P. Etherton ,  Mark P. Mack ,  James H. Meas, Jr.

发明人： Leonard V. Cribbs ,  Bradley P. Etherton ,  Mark P. Mack ,  James H. Meas, Jr.

IPC分类号： C08L23/04 ,  C08F8/00 ,  C08L23/00

CPC分类号： C08L23/04 ,  C08L2205/02 ,  C08L2314/02 ,  C08L2314/06

摘要： A multiple stage or multiple zone process for making olefin polymers is disclosed. A single-site catalyst, preferably one that contains a heteroatomic ligand, is used in the first stage or zone, and a Ziegler-Natta catalyst is used at a higher temperature in later stages or zones. A parallel multiple zone process is also described. The processes, which can be performed adiabatically, give polymers with improved thermal processing ability.

摘要翻译： 公开了制备烯烃聚合物的多级或多区域方法。 在第一阶段或区域中使用单中心催化剂，优选含有杂原子配体的单中心催化剂，并且在后期阶段或区域中以更高的温度使用齐格勒 - 纳塔催化剂。 还描述了并行多区域过程。 可以绝热地进行的方法给具有改进的热处理能力的聚合物。

公开(公告)号：US5202397A

公开(公告)日：1993-04-13

申请号：US923147

申请日：1992-07-31

申请人： Leonard V. Cribbs ,  Michael W. Lynch

发明人： Leonard V. Cribbs ,  Michael W. Lynch

摘要： A multiple site solid catalyst component capable of producing polyolefins having a broad or multimodal molecular weight distribution, such as a bimodal molecular weight distribution, is prepared by contacting a particulate solid support with a zirconium compound or complex to bind the zirconium compound or complex to the support, optionally followed by contacting the supported zirconium compound or complex with a Lewis acid to produce an intermediate product, optionally isolating and washing the supported zirconium compound or complex or resulting intermediate product to remove soluble by-products therefrom, and reacting the washed or unwashed supported zirconium compound or complex or intermediate product with a titanium or vanadium compound to produce a solid catalyst component.

公开(公告)号：US5155079A

公开(公告)日：1992-10-13

申请号：US712206

申请日：1991-06-07

申请人： Leonard V. Cribbs ,  Michael W. Lynch

发明人： Leonard V. Cribbs ,  Michael W. Lynch

IPC分类号： C08F2/06 ,  C08F4/60 ,  C08F4/633 ,  C08F4/64 ,  C08F4/659 ,  C08F4/685 ,  C08F10/00 ,  C08F10/02

CPC分类号： C08F10/02

摘要： A multiple site solid catalyst component capable of producing polyolefins having a broad or multimodal molecular weight distribution, such as a bi-modal molecular weight distribution, is prepared by contacting a particulate solid support with a zirconium compound or complex to bind the zirconium compound or complex to the support, optionally followed by contacting the supported zirconium compound or complex with a Lewis acid to produce an intermediate product, optionally isolating and washing the supported zirconium compound or complex or resulting intermediate product to remove soluble by-products therefrom, and reacting the washed or unwashed supported zirconium compound or complex or intermediate product with a titanium or vanadium compound to produce a solid catalyst component.

公开(公告)号：US5369194A

公开(公告)日：1994-11-29

申请号：US23135

申请日：1993-02-24

申请人： Leonard V. Cribbs ,  Michael W. Lynch

发明人： Leonard V. Cribbs ,  Michael W. Lynch

IPC分类号： C08F2/06 ,  C08F4/60 ,  C08F4/633 ,  C08F4/64 ,  C08F4/659 ,  C08F4/685 ,  C08F10/00 ,  C08F10/02 ,  C08F4/68

CPC分类号： C08F10/02

摘要： A multiple site solid catalyst component capable of producing polyolefins having a broad or multimodal molecular weight distribution, such as a bimodal molecular weight distribution, is prepared by contacting a particulate solid support with a zirconium compound or complex to bind the zirconium compound or complex to the support, optionally followed by contacting the supported zirconium compound or complex with a Lewis acid to produce an intermediate product, optionally isolating and washing the supported zirconium compound or complex or resulting intermediate product to remove soluble by-products therefrom, and reacting the washed or unwashed supported zirconium compound or complex or intermediate product with a titanium or vanadium compound to produce a solid catalyst component.

摘要翻译： 通过使颗粒状固体载体与锆化合物或络合物接触，将锆化合物或络合物与锆的化合物或络合物接触，制备能够生产具有宽或多峰分子量分布如双峰分子量分布的聚烯烃的多部位固体催化剂组分 任选地将负载的锆化合物或络合物与路易斯酸接触以产生中间产物，任选地分离和洗涤负载的锆化合物或络合物或所得中间产物以从其中除去可溶性副产物，并将洗涤或未洗涤的 负载的锆化合物或复合物或中间产物与钛或钒化合物反应以产生固体催化剂组分。

公开(公告)号：US06770715B2

公开(公告)日：2004-08-03

申请号：US10242191

申请日：2002-09-12

申请人： Philip J. Garrison ,  Lawrence R. Wallace ,  Danny L. Wise ,  James H. Meas ,  Leonard V. Cribbs ,  Jean A. Merrick-Mack ,  Paula L. Nygard

发明人： Philip J. Garrison ,  Lawrence R. Wallace ,  Danny L. Wise ,  James H. Meas ,  Leonard V. Cribbs ,  Jean A. Merrick-Mack ,  Paula L. Nygard

IPC分类号： C08F21002

CPC分类号： C08F297/08 ,  C08F210/16 ,  C08F255/00 ,  C08L23/0815 ,  C08L2205/02 ,  C08L2308/00 ,  C08L2314/06 ,  Y10S526/905 ,  C08F2/001 ,  C08L2666/04 ,  C08F210/08 ,  C08F2500/12 ,  C08F2500/05 ,  C08F2500/26

摘要： A high molecular weight, medium density polyethylene (HMW, MDPE) is disclosed. The polyethylene comprises from about 85 to about 98 wt % of recurring units of ethylene and about 2 to about 15 wt % of a C3-C10 &agr;-olefin. It has a density from about 0.92 to about 0.944 g/cc, a melt index MI2 from about 0.01 to about 0.5 dg/min, and a melt flow ratio MFR from about 50 to about 300. It has a multimodal molecular weight distribution comprising a high molecular weight component and a low molecular weight component. The low molecular weight component has an MI2 from about 50 to about 600 dg/min and a density from about 0.94 to about 0.97 g/cc. A process for making the medium density polyethylene is also disclosed. The process uses a Ziegler catalyst and applies multiple reaction zones.

摘要翻译： 公开了高分子量，中密度聚乙烯（HMW，MDPE）。 聚乙烯包含约85至约98重量％的乙烯重复单元和约2至约15重量％的C 3 -C 10α-烯烃。 其密度为约0.92至约0.944g / cc，熔体指数MI2为约0.01至约0.5dg / min，熔体流动比MFR为约50至约300.它具有多峰分子量分布，其包含 高分子量组分和低分子量组分。 低分子量组分具有约50至约600dg / min的MI2和约0.94至约0.97g / cc的密度。 还公开了制备中密度聚乙烯的方法。 该方法使用齐格勒催化剂并应用多个反应区。