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    Sulfated phenolic resins and printing plate precursors comprising sulfated phenolic resins
    5.
    发明申请
    Sulfated phenolic resins and printing plate precursors comprising sulfated phenolic resins 失效
    硫酸酚醛树脂和包含硫酸化酚醛树脂的印版前体

    公开(公告)号：US20050008965A1

    公开(公告)日：2005-01-13

    申请号：US10615358

    申请日：2003-07-08

    申请人： Ting Tao ,  Scott Beckley ,  John Kalamen ,  Kevin Ray

    发明人： Ting Tao ,  Scott Beckley ,  John Kalamen ,  Kevin Ray

    IPC分类号： B41C1/10 ,  B41M5/40 ,  B41M5/46 ,  B41N1/08 ,  B41N1/20 ,  G03C1/76

    CPC分类号： B41C1/1008 ,  B41C2210/04 ,  B41C2210/08 ,  B41C2210/20 ,  B41C2210/22 ,  B41C2210/24 ,  B41C2210/262 ,  B41M5/465 ,  B41N1/083 ,  B41N1/20 ,  Y10S430/145 ,  Y10S430/146 ,  Y10S430/165

    摘要： The present invention provides a thermally sensitive composition that may be coated as a water-borne material onto a substrate to yield a printing plate precursor having an imageable coating. The thermally sensitive composition comprises a sulfated phenolic resin. The sulfated phenolic resin may be a sulfated novolak resin or a sulfated resole resin, for example. The thermally sensitive composition may include a water-soluble binder, such as polyvinyl pyrrolidone, and a radiation-absorbing component. The invention also provides a printing plate precursor that is developed in water after imaging. The precursor does not require chemical development with a developing solution containing organic solvents or inorganic additives. The imaged precursor is on-press-developable when used with a fountain solution. Methods for making and using the precursor are also provided.

    摘要翻译： 本发明提供了一种热敏组合物，其可以作为水性材料涂覆在基材上以产生具有可成像涂层的印版前体。 热敏组合物包含硫酸化酚醛树脂。 硫酸化酚醛树脂可以是例如硫酸化酚醛清漆树脂或硫酸化甲阶酚醛树脂。 热敏组合物可以包括水溶性粘合剂，例如聚乙烯吡咯烷酮和辐射吸收组分。 本发明还提供了一种在成像后在水中显影的印版前体。 该前体不需要用含有机溶剂或无机添加剂的显影溶液进行化学显影。 当与润版液一起使用时，成像的前体是可压制显影的。 还提供了制备和使用前体的方法。

    NEGATIVE-WORKING IMAGEABLE ELEMENTS
    6.
    发明申请
    NEGATIVE-WORKING IMAGEABLE ELEMENTS 有权
    负责成像的元素

    公开(公告)号：US20100316850A1

    公开(公告)日：2010-12-16

    申请号：US12483293

    申请日：2009-06-12

    申请人： Ting Tao ,  Eric Clark ,  John Kalamen

    发明人： Ting Tao ,  Eric Clark ,  John Kalamen

    IPC分类号： G03F7/20 ,  G03F7/004 ,  B32B3/10

    CPC分类号： G03F7/032 ,  B41C1/1008 ,  B41C1/1016 ,  B41C2201/02 ,  B41C2201/14 ,  B41C2210/04 ,  B41C2210/06 ,  B41C2210/10 ,  B41C2210/22 ,  B41C2210/24 ,  G03F7/029 ,  G03F7/033 ,  Y10T428/24802

    摘要： Negative-working imageable elements have an imageable layer comprising a free radically polymerizable component, an initiator composition capable of generating radicals sufficient to initiate polymerization of the free radically polymerizable component upon exposure to imaging radiation, a radiation absorbing compound, one or more polymeric binders, and at least 5 weight % of core-shell particles comprising a hydrophobic polymeric core and a hydrophilic polymeric shell that is covalently bound to the polymeric core. The hydrophilic polymeric shell has one or more zwitterionic functional groups. These elements can be imaged such as by IR lasers to provide lithographic printing plates.

    摘要翻译： 负性可成像元件具有包含自由基可自由基的组分的可成像层，能够产生足以在暴露于成像辐射时引发自由基可聚合组分聚合的自由基的引发剂组合物，辐射吸收化合物，一种或多种聚合物粘合剂， 和至少5重量％的包含疏水聚合物芯和共价结合到聚合物芯的亲水聚合物壳的核 - 壳颗粒。 亲水聚合物壳具有一个或多个两性离子官能团。 这些元件可以通过IR激光器成像，以提供平版印刷版。

    Negative-working imageable elements
    8.
    发明授权
    Negative-working imageable elements 有权
    负面的可成像元素

    公开(公告)号：US08257907B2

    公开(公告)日：2012-09-04

    申请号：US12483293

    申请日：2009-06-12

    申请人： Ting Tao ,  Eric E. Clark ,  John Kalamen

    发明人： Ting Tao ,  Eric E. Clark ,  John Kalamen

    IPC分类号： G03F7/00 ,  G03F7/26 ,  B41F7/00

    CPC分类号： G03F7/032 ,  B41C1/1008 ,  B41C1/1016 ,  B41C2201/02 ,  B41C2201/14 ,  B41C2210/04 ,  B41C2210/06 ,  B41C2210/10 ,  B41C2210/22 ,  B41C2210/24 ,  G03F7/029 ,  G03F7/033 ,  Y10T428/24802

    摘要： Negative-working imageable elements have an imageable layer comprising a free radically polymerizable component, an initiator composition capable of generating radicals sufficient to initiate polymerization of the free radically polymerizable component upon exposure to imaging radiation, a radiation absorbing compound, one or more polymeric binders, and at least 5 weight % of core-shell particles comprising a hydrophobic polymeric core and a hydrophilic polymeric shell that is covalently bound to the polymeric core. The hydrophilic polymeric shell has one or more zwitterionic functional groups. These elements can be imaged such as by IR lasers to provide lithographic printing plates.

    摘要翻译： 负性可成像元件具有包含自由基可自由基的组分的可成像层，能够产生足以在暴露于成像辐射时引发自由基可聚合组分聚合的自由基的引发剂组合物，辐射吸收化合物，一种或多种聚合物粘合剂， 和至少5重量％的包含疏水聚合物芯和共价结合到聚合物芯的亲水聚合物壳的核 - 壳颗粒。 亲水聚合物壳具有一个或多个两性离子官能团。 这些元件可以通过IR激光器成像，以提供平版印刷版。

    Positive-working, thermally sensitive imageable element
    10.
    发明申请
    Positive-working, thermally sensitive imageable element 失效

    公开(公告)号：US20050227163A1

    公开(公告)日：2005-10-13

    申请号：US11072486

    申请日：2005-03-04

    申请人： Kevin Ray ,  Anthony Kitson ,  John Kalamen

    发明人： Kevin Ray ,  Anthony Kitson ,  John Kalamen

    IPC分类号： B41C1/10 ,  B41M5/36 ,  C08F212/32 ,  C08F220/42 ,  C08F220/44 ,  C08F220/56 ,  G03C8/00

    CPC分类号： C08F220/44 ,  B41C1/1008 ,  B41C1/1016 ,  B41C2210/02 ,  B41C2210/06 ,  B41C2210/14 ,  B41C2210/20 ,  B41C2210/22 ,  B41C2210/24 ,  B41C2210/262 ,  B41M5/368 ,  C08F220/56 ,  Y10S430/145

    摘要： Alkali soluble copolymers, imageable elements useful as lithographic printing plate precursors that contain the alkali soluble copolymers, and methods for forming images using the imageable elements are disclosed. The alkali soluble copolymers comprise, in polymerized form: (a) N-phenylmaleimide, N-cyclohexylmaleimide, N-benzylmaleimide, or a mixture thereof; (b) acrylamide, methacrylamide, or a mixture thereof; (c) acrylonitrile, methacrylonitrile, or a mixture thereof; and (d) one or more monomers selected from the group consisting of monomers of the structure: CH2═C(R)-Z-X—NHC(O)NH—Y—R′, in which: X is —[C(CH3)2]— or —[(CH2)n]—, in which n is 0 to 12; Y is o-, m-, or p-—[C6H4]—; Z is —[C(O)O]—, —[C(O)NH]—, or o-, m-, or p-[—C6H4]—; R is hydrogen or C1 to C4 alkyl; R′ is —OC(O)—OR″, —OC(O)—Ar, or —OSO2—Ar; R″ is C1 to C12 alkyl, C1 to C12 arylalkyl, C1 to C12 aryl, C1 to C12 alkenyl, or trimethylsilyl; Ar is C6H5-n′Tn′, in which Ar has a total of six to ten carbon atoms; each T is independently selected from the group consisting of C1 to C4 alkyl, fluoro, chloro, bromo, iodo, trifluoromethyl, methoxy, and cyano; and n′ is an integer from 0 to 5; and in which the copolymer is soluble in alkaline solutions having a pH greater than at least about 11.