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公开(公告)号：US06500964B2
公开(公告)日：2002-12-31
申请号：US09815487
申请日：2001-03-23
IPC分类号： C07D32314
CPC分类号： C07D319/06 , C07D317/20 , C07D317/54
摘要： This invention relates to a process for preparing alditol acetals, such as dibenzylidene sorbitols, monobenzylidene sorbitols, and the like, through the reaction of unsubstituted or substituted benzaldehydes with alditols (such as sorbitol, xylitol, and ribitol) in the presence of a mineral acid and at least one surfactant having at least one pendant group of 6 carbon chains in length. Such a reaction provides a cost-effective, relatively safe procedure that provides excellent high yields of alditol acetal product. Furthermore, such a specific reaction is also the best known procedure for the production of certain compounds which can be easily separated from other formed isomers. Additionally, such a procedure facilitates the production of certain asymmetric alditol acetal compounds and compositions in acceptable yields as well. Such alditol acetals are useful as nucleating and clarifying agents for polyolefin formulations and articles, as one example.
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2.发明授权公开(公告)号：US06518339B1
公开(公告)日：2003-02-11
申请号：US09663901
申请日：2000-09-18
申请人： Shawn R. Sheppard , John G. Lever
发明人： Shawn R. Sheppard , John G. Lever
IPC分类号： C08K525
CPC分类号： C08K5/25 , C08K5/1575 , C08K5/24 , C08L23/10
摘要： An additive that is used in conjunction with certain dibenzylidene sorbitol-type (DBS) clarifiers and acid scavengers within polyolefin resins to reduce the release of aldehydes from polypropylene material is disclosed. Hydrazides have been shown to be effective at removing residual aldehyde from polyolefins, such as polypropylene. This function can be accomplished with a minimal impact on optical transparent properties imparted to the polypropylene by the clarifying agent. The net effect is an improvement in the organoleptic performance of resins containing clarifiers, and a reduction in the UV-absorbing extractables. Particularly, adipic dihydrazide, when co-compounded into polypropylene homopolymer with 4-methyl DBS, improves the organoleptic performance of the clarifier. Incorporation of dihydrazides into polypropylene pellets reduced air-released aldehyde by nearly 100%.
摘要翻译： 公开了与聚烯烃树脂中的某些二亚苄基山梨醇型（DBS）澄清剂和酸清除剂结合使用以减少聚丙烯材料中醛的释放的添加剂。 已经证明，酰肼有效地从聚烯烃如聚丙烯中除去残余的醛。 该功能可以通过对澄清剂赋予聚丙烯的光学透明性的影响最小化来实现。 净效果是含有澄清剂的树脂的感官性能的改善，以及UV吸收可提取物的减少。 特别地，当与4-甲基DBS共混于聚丙烯均聚物时，己二酸二酰肼改善澄清器的感官性能。 将二酰肼引入聚丙烯颗粒中将空气释放的醛减少近100％。
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公开(公告)号：US06984740B2
公开(公告)日：2006-01-10
申请号：US10305537
申请日：2002-11-27
IPC分类号： C07D323/04 , C08K5/1575
摘要： Plastic additives which are useful as nucleating agents and which are especially useful for improving the optical properties of polymeric materials are provided. More particularly, this invention relates to certain alkyl (or alkoxy) substituted halo-benzylidene sorbitol acetals and polymer compositions thereof which may be utilized within, as merely examples, food or cosmetic containers and packaging. These inventive halogenated (that is, chlorinated, brominated, or iodinated) and alkylated benzylidene sorbitol acetals are also useful as gelling agents for water and organic solvents, particularly those used in the preparation of antiperspirant gel sticks.
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4.发明授权Asymmetric halogen-alkyl alditol derivatives as nucleators and clarifiers for polyolefins, and polyolefin plastic compositions containing same 有权作为聚烯烃的成核剂和澄清剂的不对称卤代烷基糖醇衍生物和含有它们的聚烯烃塑料组合物公开(公告)号：US06548581B2
公开(公告)日：2003-04-15
申请号：US09815732
申请日：2001-03-23
IPC分类号： C08K515
CPC分类号： A61K8/042 , A61K8/498 , A61Q15/00 , C07D493/04 , C08L23/10
摘要： This invention relates to plastic additives which are useful as nucleating agents and which are especially useful for improving the optical properties of polymeric materials. More particularly, this invention relates to certain bis-halogen-alkyl-benzylidene alditol acetals and polymer compositions thereof which are useful as materials for food or cosmetic containers and packaging. These bis-halogen-alkylbenzylidene alditol acetals are also useful as gelling agents for organic solvents, particularly those used in the preparation of antiperspirant gel sticks.
摘要翻译： 本发明涉及可用作成核剂的塑料添加剂，其特别可用于改善聚合物材料的光学性能。 更具体地说，本发明涉及可用作食品或化妆品容器和包装材料的某些双卤代烷基 - 亚苄基糖醇缩醛及其聚合物组合物。 这些双卤代烷基亚苄基糖醇缩醛也可用作有机溶剂的胶凝剂，特别是用于制备止汗凝胶棒的那些。
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5.发明授权Symmetrical halogenated and alkylated alditol derivatives and compositions and articles containing same 失效对称的卤代和烷基化的糖醇衍生物和含有它们的组合物和制品公开(公告)号：US06547988B2
公开(公告)日：2003-04-15
申请号：US09815630
申请日：2001-03-23
IPC分类号： G09K1506
摘要： Plastic additives which are useful as nucleating agents and which are especially useful for improving the optical properties of polymeric materials are provided. More particularly, this invention relates to certain alkyl (or alkoxy) substituted halo-benzylidene sorbitol acetals and polymer compositions thereof which may be utilized within, as merely examples, food or cosmetic containers and packaging. These inventive halogenated (that is, chlorinated, brominated, or iodinated) and alkylated benzylidene sorbitol acetals are also useful as gelling agents for water and organic solvents, particularly those used in the preparation of antiperspirant gel sticks.
摘要翻译： 提供可用作成核剂并且可用于改善聚合物材料的光学性能的塑料添加剂。 更具体地说，本发明涉及某些烷基（或烷氧基）取代的卤代 - 亚苄基山梨糖醇缩醛及其聚合物组合物，其仅可用作食品或化妆品容器和包装。 这些本发明的卤代（即，氯化，溴化或碘化）和烷基化亚苄基山梨糖醇缩醛也可用作水和有机溶剂的胶凝剂，特别是用于制备止汗凝胶棒的那些。
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6.发明授权Method and compositions for reducing plate-out in the manufacture of plastic articles 有权用于减少塑料制品制造中的平板的方法和组合物公开(公告)号：US08003720B2
公开(公告)日：2011-08-23
申请号：US11045760
申请日：2005-01-28
申请人： Dave Keegan , Shawn R. Sheppard , Dale W. Chandler , Jiannong Xu , Jiang Li , Keith Alan Keller
发明人： Dave Keegan , Shawn R. Sheppard , Dale W. Chandler , Jiannong Xu , Jiang Li , Keith Alan Keller
IPC分类号： C08K5/15 , C08F2/44 , C08F2/00 , C08F210/00
CPC分类号： C08L23/02 , C08K5/1575 , C08L23/04 , C08L23/0892 , C08L23/10 , C08L2310/00 , C08L2666/06 , C08L2666/14 , C08L2666/18
摘要： Chemical additives disclosed for reducing “plate-out” which have applications in polymers, such as polyolefins. It is possible to provide for a composition and a process for producing parts, sheet and film from polyolefin extrusion applications wherein the polyolefins are processed with a minimal quantity of “plate-out.” A polyolefin composition may contain a sorbitol-based clarifying system of a derivative of Dibenzylidene, along with one or more co-additives to achieve a reduction in undesirable plate-out.
摘要翻译： 公开了用于减少聚合物（例如聚烯烃）中应用的“平板化”的化学添加剂。 可以提供一种用于从聚烯烃挤出应用生产部件，片材和薄膜的组合物和方法，其中聚烯烃以最小量的“平板”进行加工。聚烯烃组合物可以含有基于山梨糖醇的澄清系统 二亚苄基衍生物，以及一种或多种共添加剂，以实现不期望的平板化的减少。
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7.发明授权公开(公告)号：US06844382B2
公开(公告)日：2005-01-18
申请号：US10286220
申请日：2002-11-01
IPC分类号： A61K8/49 , A61Q15/00 , C07D493/04 , C08G18/18 , C08J9/00 , C08L23/10 , C08K5/15 , C07D323/04
CPC分类号： A61K8/042 , A61K8/498 , A61Q15/00 , C07D493/04 , C08G18/1825 , C08J9/0023 , C08J2375/04 , C08L23/10
摘要： Certain multi-substituted dibenzylidene sorbitol acetals having electron withdrawing groups as constituents and electron donating groups on the other such that the compounds are asymmetric in structure and are dipolar in nature are provided. Polymer compositions comprising such compounds, are also contemplated which may be utilized within, as merely examples, food or cosmetic containers and packaging. These inventive asymmetric dipolar dibenzylidene sorbitol acetals are also useful as gelling agents for water and organic solvents, particularly those used in the preparation of antiperspirant gel sticks.
摘要翻译： 提供了一些具有吸电子基团作为组分和给电子基团的多取代二亚苄基山梨糖醇缩醛，使得化合物在结构上是不对称的并且在本质上是偶极性的。 包含这些化合物的聚合物组合物也被设想为仅作为例子使用的食品或化妆品容器和包装。 这些本发明的不对称偶极二亚苄基山梨糖醇缩醛也可用作水和有机溶剂的胶凝剂，特别是用于制备止汗凝胶棒的那些。
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8.发明授权Compositions and articles comprising asymmetric dipolar multi-substituted alditol derivatives 有权包含不对称偶极多取代的糖醇衍生物的组合物和制品公开(公告)号：US06972306B2
公开(公告)日：2005-12-06
申请号：US10286293
申请日：2002-11-01
CPC分类号： A61K8/042 , A61K8/498 , A61Q15/00 , C07D493/04 , C08G18/1825 , C08J9/0023 , C08J2375/04 , C08L23/10
摘要： Certain multi-substituted dibenzylidene sorbitol acetals having electron withdrawing groups as constituents and electron donating groups on the other such that the compounds are asymmetric in structure and are dipolar in nature are provided. Polymer compositions comprising such compounds, are also contemplated which may be utilized within, as merely examples, food or cosmetic containers and packaging. These inventive asymmetric dipolar dibenzylidene sorbitol acetals are also useful as gelling agents for water and organic solvents, particularly those used in the preparation of antiperspirant gel sticks.
摘要翻译： 提供了一些具有吸电子基团作为组分和给电子基团的多取代二亚苄基山梨糖醇缩醛，使得化合物在结构上是不对称的并且在本质上是偶极性的。 包含这些化合物的聚合物组合物也被设想为仅作为例子使用的食品或化妆品容器和包装。 这些本发明的不对称偶极二亚苄基山梨糖醇缩醛也可用作水和有机溶剂的胶凝剂，特别是用于制备止汗凝胶棒的那些。
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9.发明授权Reaction product mixtures including both symmetric compounds and asymmetric dipolar multi-substituted alditol derivatives 失效反应产物混合物包括对称化合物和不对称偶极多取代的糖醇衍生物公开(公告)号：US06894176B2
公开(公告)日：2005-05-17
申请号：US10286217
申请日：2002-11-01
IPC分类号： A61K8/49 , A61Q15/00 , C07D493/04 , C08G18/18 , C08J9/00 , C08L23/10 , C07D323/04 , C07D319/14 , C08K5/1575 , C08K5/159
CPC分类号： A61K8/042 , A61K8/498 , A61Q15/00 , C07D493/04 , C08G18/1825 , C08J9/0023 , C08J2375/04 , C08L23/10
摘要： Certain multi-substituted dibenzylidene sorbitol acetals having electron withdrawing groups as constituents and electron donating groups on the other such that the compounds are asymmetric in structure and are dipolar in nature are provided. Polymer compositions comprising such compounds, are also contemplated which may be utilized within, as merely examples, food or cosmetic containers and packaging. These inventive asymmetric dipolar dibenzylidene sorbitol acetals are also useful as gelling agents for water and organic solvents, particularly those used in the preparation of antiperspirant gel sticks.
摘要翻译： 提供了一些具有吸电子基团作为组分和给电子基团的多取代二亚苄基山梨糖醇缩醛，使得化合物在结构上是不对称的并且在本质上是偶极性的。 包含这些化合物的聚合物组合物也被设想为仅作为例子使用的食品或化妆品容器和包装。 这些本发明的不对称偶极二亚苄基山梨糖醇缩醛也可用作水和有机溶剂的胶凝剂，特别是用于制备止汗凝胶棒的那些。
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公开(公告)号：US06555696B2
公开(公告)日：2003-04-29
申请号：US09815485
申请日：2001-03-23
IPC分类号： C07D32314
CPC分类号： A61K8/042 , A61K8/498 , A61Q15/00 , C07D493/04 , C08G18/1825 , C08J9/0023 , C08J2375/04 , C08L23/10
摘要： Certain multi-substituted dibenzylidene sorbitol acetals having electron withdrawing groups as constituents and electron donating groups on the other such that the compounds are asymmetric in structure and are dipolar in nature are provided. Polymer compositions comprising such compounds, are also contemplated which may be utilized within, as merely examples, food or cosmetic containers and packaging. These inventive asymmetric dipolar dibenzylidene sorbitol acetals are also useful as gelling agents for water and organic solvents, particularly those used in the preparation of antiperspirant gel sticks.
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