公开(公告)号：US5558814A

公开(公告)日：1996-09-24

申请号：US337007

申请日：1994-11-07

申请人： Shigeo Itoh ,  Yoshihisa Yonezawa ,  Hitoshi Toki

发明人： Shigeo Itoh ,  Yoshihisa Yonezawa ,  Hitoshi Toki

IPC分类号： C09K11/08 ,  C09K11/00 ,  C09K11/62 ,  H01J29/20 ,  H01J61/44

CPC分类号： C09K11/623

摘要： A phosphor capable of exhibiting luminescence with high efficiency by excitation due to impingement of electrons accelerated under an anode voltage of hundreds volts to about 2 kV thereon and a method for preparing the same are disclosed. Mn is ion-implanted in ZnGa.sub.2 O.sub.4 which is a matrix crystal of the phosphor deposited on a substrate. Three kinds of implantation energy of 150 keV, 90 keV and 30 keV are selected and the ion implantation is effected three times in the order of the level of the implantation energy. A concentration of Mn is rendered substantially constant within a depth range between 100 angstrom and 1000 angstrom of a depth of 2000 angstrom or less in a luminous region of the phosphor. The ion implantation thus carried out three times permits the phosphor to exhibit increased luminous efficiency as compared with one-time ion implantation. The ion implantation permits Mn acting as a luminous center to be dispersed over a desired depth of the phosphor, resulting in lattice defects in the phosphor being widely distributed, leading to a decrease in the concentration of defects in the phosphor.

摘要翻译： 公开了一种荧光体，其能够通过在数百伏特至约2kV的阳极电压下加速的电子冲击而通过激发而以高效率显示发光，以及其制备方法。 在作为沉积在基板上的荧光体的矩阵晶体的ZnGa 2 O 4中离子注入Mn。 选择150keV，90keV和30keV的三种注入能量，并且按照注入能级的顺序进行三次离子注入。 在荧光体的发光区域中，在浓度为100埃至1000埃的深度范围内，Mn的浓度基本上保持恒定。 这样进行三次离子注入使得荧光体与一次离子注入相比表现出增加的发光效率。 离子注入允许作为发光中心的Mn分散在荧光体的所需深度上，导致荧光体中的晶格缺陷广泛分布，导致荧光体中缺陷的浓度降低。

公开(公告)号：US5746589A

公开(公告)日：1998-05-05

申请号：US439272

申请日：1995-05-11

申请人： Shigeo Itoh ,  Yoshihisa Yonezawa ,  Hitoshi Toki ,  Yoshitaka Satoh

发明人： Shigeo Itoh ,  Yoshihisa Yonezawa ,  Hitoshi Toki ,  Yoshitaka Satoh

IPC分类号： B01J19/00 ,  C09K11/08 ,  C09K11/62 ,  F27D15/02

CPC分类号： C09K11/08

摘要： A phosphor heat-treating method and an apparatus therefor capable of providing a phosphor exhibiting improved crystallizability and increased in concentration of a luminous center therein. A phosphor is heated and rapidly cooled in atmosphere gas of a predetermined pressure. The pressure substantially restrains decomposition and scattering of the phosphor during heating and cooling of the phosphor.

摘要翻译： 一种荧光体热处理方法及其装置，其能够提供显示改善的结晶性并且增加其中的发光中心的浓度的荧光体。 将磷光体在预定压力的气氛气体中加热并快速冷却。 该压力基本上抑制在荧光体的加热和冷却期间磷光体的分解和散射。

公开(公告)号：US5347133A

公开(公告)日：1994-09-13

申请号：US82460

申请日：1993-06-25

申请人： Hitoshi Toki ,  Yoshihisa Yonezawa ,  Shigeo Itoh

发明人： Hitoshi Toki ,  Yoshihisa Yonezawa ,  Shigeo Itoh

IPC分类号： C23C14/00 ,  B01F11/00 ,  C23C14/50 ,  H01J5/00

CPC分类号： B01F11/0094

摘要： A powder agitator used for an ion implantation device or an ionized beam deposition device capable of exhibiting satisfactory powder agitating characteristics and minimizing positive charging on powders. The powder agitator includes a base, a vessel for receiving powders therein, a plurality of supports for supporting the vessel on the base, and a pair of piezoelectric elements arranged on the supports and functioning as a vibration generating section. Application of a voltage to the piezoelectric elements causes the vessel to be oscillated in a direction of rotation of the vessel and a speed of oscillation of the vessel to be varied depending on a direction of oscillation of the vessel, resulting in agitating the powders in the vessel.

摘要翻译： 用于离子注入装置或电离束沉积装置的粉末搅拌器，其能够表现出令人满意的粉末搅拌特性并使粉末上的正电荷最小化。 粉末搅拌器包括基座，用于容纳粉末的容器，用于将容器支撑在基座上的多个支撑件和布置在支撑件上并用作振动产生部分的一对压电元件。 向压电元件施加电压使得容器在容器的旋转方向上振荡并且容器的振荡速度根据容器的振荡方向而变化，从而使粉末在 船只。

公开(公告)号：US5510154A

公开(公告)日：1996-04-23

申请号：US160166

申请日：1993-12-02

申请人： Shigeo Itoh ,  Hitoshi Toki ,  Yoshihisa Yonezawa

发明人： Shigeo Itoh ,  Hitoshi Toki ,  Yoshihisa Yonezawa

IPC分类号： C09K11/08 ,  C23C14/48 ,  B05D3/06

CPC分类号： C23C14/48 ,  C09K11/08

摘要： A low-velocity electron excited phosphor capable of exhibiting increased luminance and a method for producing the same. A matrix crystal for the phosphor is doped therein with an activator at implantation energy of 50 KeV by ion implantation, resulting in the activator entering a portion of the matrix crystal extending to a depth as small as 0.5 .mu.m from a surface thereof. Then, the phosphor is annealed for a reduced period of time as short as 10 seconds at a temperature of 900.degree. C. Such short-time annealing effectively prevents distribution of the activator in the matrix crystal formed during the implantation from being deeply spread into the matrix crystal by thermal diffusion. Thus, the activator concentratedly exists at only a portion of the matrix crystal in proximity to the surface thereof. Thus, the phosphor exhibits increased luminance as compared with a prior art, because luminescence of the phosphor is limited to the portion thereof in proximity to the surface.

摘要翻译： 能够显示增加的亮度的低速电子激发荧光体及其制造方法。 通过离子注入，用50KV的注入能量在其中掺杂荧光体的矩阵晶体，其中激活剂进入基体晶体的一部分延伸到距其表面0.5μm的深度。 然后，在900℃的温度下，将荧光体退火短时间为10秒的时间。这种短时间退火有效地防止了在植入过程中形成的基体晶体中的活化剂分布深入到 矩阵晶体通过热扩散。 因此，活化剂仅在其表面附近仅存在于基体晶体的一部分。 因此，与现有技术相比，荧光体的亮度增加，因为荧光体的发光被限制在靠近表面的部分。

公开(公告)号：US6163108A

公开(公告)日：2000-12-19

申请号：US118090

申请日：1998-07-17

申请人： Hitoshi Toki ,  Shigeo Itoh

发明人： Hitoshi Toki ,  Shigeo Itoh

IPC分类号： C09K11/02 ,  C09K11/08 ,  C09K11/54 ,  C09K11/66 ,  C09K11/77 ,  H01J29/20 ,  H01J31/12 ,  H01J31/15 ,  H01J1/62

CPC分类号： C09K11/7774 ,  C09K11/025 ,  C09K11/54 ,  C09K11/663

摘要： A fluorescent luminous device capable of providing a fluorescent luminous device including a non-sulfide phosphor which is reduced in resistance and emits light of a reddish luminous color. The fluorescent luminous device is so constructed that the phosphor layer is made of a non-sulfide phosphor excited by luminescence of a ZnO:Zn phosphor to emit light of a yellowish red luminous color. The ZnO:Zn phosphor is deposited on the non-sulfide phosphor.

摘要翻译： 一种荧光发光装置，其能够提供包含耐硫化物荧光体的荧光发光装置，该荧光体的电阻降低并发出红色发光的光。 荧光发光器件的结构使得荧光体层由通过ZnO：Zn荧光体的发光激发的非硫化物荧光体制成，以发出淡黄色发光的光。 ZnO：Zn荧光体沉积在非硫化物荧光体上。

公开(公告)号：US5619098A

公开(公告)日：1997-04-08

申请号：US529058

申请日：1995-09-15

申请人： Hitoshi Toki ,  Shigeo Itoh ,  Fumiaki Kataoka

发明人： Hitoshi Toki ,  Shigeo Itoh ,  Fumiaki Kataoka

IPC分类号： C09K11/67 ,  C09K11/77 ,  H01J29/20 ,  H01J31/15 ,  H01J1/62 ,  C09K11/08

CPC分类号： C09K11/7703 ,  C09K11/7718 ,  C09K11/7731 ,  C09K11/7746

摘要： A phosphor is disclosed which is suitable for use for a fluorescent display device and driven at a driving voltage as low as 1 kV or less and free of S and Cd. Compounds of Ti, alkaline earth metal and an element of Group 13 of the periodic table in predetermined amounts are heated at 1100.degree. to 1400.degree. C. for calcination, resulting in a solid solution of the rare earth element and one element of Group 13 being formed in a phosphor matrix made of an oxide of alkaline earth metal and Ti. An example of the phosphor is SrTiO.sub.3 :Pr,Al exhibiting a red luminous color.

摘要翻译： 公开了一种适用于荧光显示装置并在低至1kV或更低的驱动电压下驱动且不含S和Cd的荧光体。 将Ti，碱土金属和元素周期表第13族元素的化合物预定量加热至1100℃至1400℃进行煅烧，得到稀土元素的固溶体，第13族的一个元素为 形成在由碱土金属和Ti的氧化物制成的荧光体基体中。 荧光体的例子是SrTiO 3：Pr，Al，表现出红色发光色。

公开(公告)号：US20060006789A1

公开(公告)日：2006-01-12

申请号：US10887050

申请日：2004-07-08

申请人： Shigeo Itoh ,  Hitoshi Toki ,  Hirokazu Takanashi ,  Hisamitsu Takahashi ,  Yoshitaka Sato ,  Kazuhiko Itakura ,  Takuya Hamada ,  Takao Shiraga ,  Kiyoshi Tamura ,  Tatsuo Yamaura

发明人： Shigeo Itoh ,  Hitoshi Toki ,  Hirokazu Takanashi ,  Hisamitsu Takahashi ,  Yoshitaka Sato ,  Kazuhiko Itakura ,  Takuya Hamada ,  Takao Shiraga ,  Kiyoshi Tamura ,  Tatsuo Yamaura

IPC分类号： H01J1/62

CPC分类号： H01J29/94 ,  H01J2329/00 ,  H01J2329/20 ,  H01J2329/948

摘要： A fluorescent display tube is provided, which employs a non-evaporation type getter, instead of the evaporation-type Ba getter, whereby the serviceable life of the fluorescent substance containing SrTiO3 as a base component is prolonged. At least one or more elements selected from the group consisting of Zr, V, Fe, Ti, Ma, Mn, and La are used for the getter for fluorescent display tubes, each which employs a fluorescent substance containing SrTiO3 as a base component. This feature allows carbon series residual gases remaining in the tube to be removed, so that the serviceable operation can be prolonged.

摘要翻译： 提供了一种使用非蒸发型吸气剂代替蒸发型Ba吸气剂的荧光显示管，由此延长含有SrTiO 3作为基础成分的荧光物质的使用寿命。 用于荧光显示管的吸气剂中使用选自Zr，V，Fe，Ti，Ma，Mn和La中的至少一种或多种元素，每种荧光显示管采用含有SrTiO 3作为基础成分的荧光物质。 该特征允许除去管中剩余的碳系列残留气体，从而可以延长可使用的操作。

公开(公告)号：US06168729A

公开(公告)日：2001-01-02

申请号：US08720154

申请日：1996-09-25

申请人： Hitoshi Toki ,  Fumiaki Kataoka ,  Shigeo Itoh ,  Yoshitaka Sato

发明人： Hitoshi Toki ,  Fumiaki Kataoka ,  Shigeo Itoh ,  Yoshitaka Sato

IPC分类号： H01J2720

CPC分类号： C09K11/7755 ,  C09K11/595 ,  C09K11/642 ,  C09K11/7774

摘要： A fluorescent material and a display device incorporating the fluorescent material are described. The fluorescent material is a mixture including a phosphor which is excitable at a voltage of 1 kV or higher for emitting light and a phosphor which is excitable at a voltage of 1 kV or lower for emitting light, wherein each phosphor emits light of the same color and the fluorescent material is luminous at an anode voltage of 2 kV or lower. The fluorescent display device accelerates electrons emitted from an electron source at an anode voltage of 2 kV or lower and rushes these electrons against an anode for exciting the fluorescent material present on the anode. The fluorescent material is a mixture as set forth above.

摘要翻译： 描述了荧光材料和包含荧光材料的显示装置。 荧光材料是包括在1kV或更高的电压下可激发的用于发射光的荧光体和在1kV或更低的电压下可发光的荧光体用于发射光的混合物，其中每个荧光体发射相同颜色的光 并且荧光材料在阳极电压为2kV以下发光。 荧光显示装置加速在2kV或更低的阳极电压下从电子源发射的电子，并将这些电子冲击阳极，以激发存在于阳极上的荧光材料。 荧光材料是如上所述的混合物。

公开(公告)号：US06113807A

公开(公告)日：2000-09-05

申请号：US191524

申请日：1998-11-13

申请人： Tatsuo Yamaura ,  Shigeo Itoh ,  Hitoshi Toki ,  Vladimir Mordkovich

发明人： Tatsuo Yamaura ,  Shigeo Itoh ,  Hitoshi Toki ,  Vladimir Mordkovich

IPC分类号： C09K11/58 ,  B82B1/00 ,  B82B3/00 ,  C09K11/62 ,  C09K11/65 ,  C09K11/78

CPC分类号： B82Y30/00 ,  C09K11/65 ,  Y10T428/12875

摘要： A method for producing a phosphor made of luminous inorganic particles of a nanostructure which is capable of keeping a surface of the phosphor from being polluted by any by-product and controlling a particle diameter distribution of the phosphor as desired. A carbon material and an inorganic salt are mixed together to prepare a mixture, which is then heated, to thereby form an interlaminar compound. Then, the interlaminar compound is subject to a treatment using an eliminating agent, leading to production of luminous inorganic compound particles adhered to the carbon material.

摘要翻译： 一种用于制造由纳米结构的发光无机颗粒制成的荧光体的方法，其能够保持荧光体的表面被任何副产物污染并且根据需要控制荧光体的粒径分布。 将碳材料和无机盐混合在一起制备混合物，然后将其加热，从而形成层间化合物。 然后，使用消除剂进行层间化合物的处理，导致附着在碳材料上的发光性无机化合物粒子的制造。

公开(公告)号：US5789856A

公开(公告)日：1998-08-04

申请号：US379990

申请日：1995-01-27

申请人： Shigeo Itoh ,  Hitoshi Toki ,  Tatsuo Yamaura ,  Yukio Ogawa ,  Teruo Watanabe

发明人： Shigeo Itoh ,  Hitoshi Toki ,  Tatsuo Yamaura ,  Yukio Ogawa ,  Teruo Watanabe

IPC分类号： H01J29/20 ,  H01J29/08 ,  H01J29/32 ,  H01J31/12 ,  H01J1/62

CPC分类号： H01J31/127 ,  H01J29/085 ,  H01J2329/08

摘要： A field emission type fluorescent display device capable of carrying out luminous display with increased reliability at an anode voltage 200V to 1000V and providing a desired luminous color by means of a filter. The fluorescent display device includes a luminous display section consisting of three display elements. The display elements include filters of red, green and blue colors on which light-permeable anode conductors are deposited, respectively. Then, the anode conductors have phosphors of the same colors as the filters deposited thereon, respectively. The blue phosphor is made of ZnO:Zn substantially containing a blue color component. Thus, a combination of the blue filter and phosphor provides light of a blue color with increased efficiency.

摘要翻译： 一种场致发射型荧光显示装置，其能够在200V至1000V的阳极电压下实现具有增加的可靠性的发光显示，并且通过滤光器提供期望的发光颜色。 荧光显示装置包括由三个显示元件构成的发光显示部。 显示元件包括分别在其上沉积透光阳极导体的红色，绿色和蓝色滤色片。 然后，阳极导体分别具有与沉积在其上的滤光器相同颜色的荧光体。 蓝色荧光体由基本上含有蓝色成分的ZnO：Zn制成。 因此，蓝色滤光片和荧光体的组合提供蓝色的光，效率提高。