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1.发明公开公开(公告)号：US20240262943A1
公开(公告)日：2024-08-08
申请号：US18322680
申请日：2023-05-24
发明人： Yuki Miyake , Yusuke Nagae , Takeru Watanabe
IPC分类号： C08F36/04
CPC分类号： C08F36/04
摘要： The present invention relates to A process for preparing a conjugated diene compound, the process comprising: subjecting, to an intramolecular sigmatropic rearrangement reaction, a conjugated diene compound (1) of the following general formula (1), wherein Z represents a halogen atom, a methyl group, a hydroxy group, an acetoxy group, a formyl group, or an acetal, and n and m are, independently of each other, integers of 0 to 14, or a conjugated diene compound (2) of the following general formula (2), wherein Z, n, and m are as defined above, to obtain, respectively, a conjugated diene compound (3) of the following general formula (3), wherein Z is as defined above, and n and m are, independently of each other, integers of 0 to 14, with the proviso that m−1 is an integer of zero or more, or a conjugated diene compound (4) of the following general formula (4), wherein Z is as defined above, and n and m are, independently of each other, integers of 0 to 14, with the proviso that n−1 is an integer of zero or more.
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2.发明公开公开(公告)号：US20230312454A1
公开(公告)日：2023-10-05
申请号：US18303008
申请日：2023-04-19
发明人： Yuki Miyake , Takeshi Kinsho , Yusuke Nagae
IPC分类号： C07C67/08 , C07C29/132 , C07C41/22 , C07C41/24 , C07C41/30 , C07C43/178
CPC分类号： C07C67/08 , C07C29/132 , C07C41/22 , C07C41/24 , C07C41/30 , C07C43/178
摘要： The present invention relates to a 6-hydroxy-3-hexenyl alkoxymethyl ether compound of the following general formula (1): HOCH2CH2CH=CHCH2CH2OCH2OCH2R1 (1), R1 representing a hydrogen atom, an n-alkyl group having 1 to 9 carbon atoms, or a phenyl group; and also relates to a process for preparing a 3,13-octadecadien-1-ol compound of the following formula (6): CH3(CH2)3CH=CH(CH2)8CH=CHCH2CH2OH (6) from the 6-hydroxy-3-hexenyl alkoxymethyl ether compound (1).
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公开(公告)号：US11685703B2
公开(公告)日：2023-06-27
申请号：US18058316
申请日：2022-11-23
发明人： Yuki Miyake , Takeru Watanabe , Takeshi Kinsho
IPC分类号： C07C5/44
CPC分类号： C07C5/44
摘要： The present invention relates to a process for preparing a 3,7-dimethylalkane compound (3): wherein n is 5 or 6, the process comprising: subjecting a nucleophilic reagent, 2,6-dimethyloctyl compound (1): wherein M1 represents Li, Mg Z1, CuZ1, or CuLiZ1, wherein Z1 represents a halogen atom or a 2,6-dimethyloctyl group, to a coupling reaction with an electrophilic alkyl reagent (2): wherein X1 represents a halogen atom or a p-toluenesulfonate group, and “n” is as defined above, to form the 3,7-dimethylalkane compound (3).
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公开(公告)号：US20230159412A1
公开(公告)日：2023-05-25
申请号：US18058316
申请日：2022-11-23
发明人： Yuki Miyake , Takeru Watanabe , Takeshi Kinsho
IPC分类号： C07C5/44
CPC分类号： C07C5/44
摘要： The present invention relates to a process for preparing a 3,7-dimethylalkane compound (3): wherein n is 5 or 6, the process comprising: subjecting a nucleophilic reagent, 2,6-dimethyloctyl compound (1): wherein M1 represents Li, Mg Z1, CuZ1, or CuLiZ1, wherein Z1 represents a halogen atom or a 2,6-dimethyloctyl group, to a coupling reaction with an electrophilic alkyl reagent (2): wherein X1 represents a halogen atom or a p-toluenesulfonate group, and “n” is as defined above, to form the 3,7-dimethylalkane compound (3).
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公开(公告)号：US20210061745A1
公开(公告)日：2021-03-04
申请号：US17010236
申请日：2020-09-02
发明人： Yuki Miyake , Naoki Ishibashi , Takeshi Kinsho
IPC分类号： C07C45/42
摘要： A process for preparing 4-penten-2-ynal of the following formula (2): CH2═CHC≡CCHO (2) the process comprising a step of hydrolyzing a 5,5-dialkoxy-1-penten-3-yne compound of the following general formula (1): CH2═CHC≡CCH(OR1)(OR2) (1) wherein R1 and R2 represent, independently of each other, a monovalent hydrocarbon group having 1 to 15 carbon atoms, preferably 1 to 8, more preferably 1 to 4, or R1 and R2 may be bonded to each other to form a divalent hydrocarbon group, R1-R2, having from 2 to 10 carbon atoms, to obtain 4-penten-2-ynal (2).
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公开(公告)号：US10882806B2
公开(公告)日：2021-01-05
申请号：US16722138
申请日：2019-12-20
发明人： Yuki Miyake , Takeshi Kinsho , Ryo Komatsu
IPC分类号： C07C29/143 , C07C17/16 , C07C51/56 , C07C45/45 , C07C51/487
摘要： The present invention provides a process for preparing 4-methyl-5-nonanone of the following formula (3), the process comprising at least a step of subjecting pentanoic anhydride of the following formula (1) and a 2-pentyl nucleophilic reagent of the following general formula (2), in which M represents Li, MgZ1, or ZnZ1, wherein Z1 represents a halogen atom or a 2-pentyl group, to a nucleophilic substitution reaction to produce 4-methyl-5-nonanone (3), as well as a process for preparing 4-methyl-5-nonanol of the following formula (7), the process comprising at least steps of preparing 4-methyl-5-nonanone and subjecting the obtained 4-methyl-5-nonanone and a reducing agent to a reduction reaction to produce 4-methyl-5-nonanol (7).
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公开(公告)号：US10676417B2
公开(公告)日：2020-06-09
申请号：US16388309
申请日：2019-04-18
发明人： Yuki Miyake , Takeshi Kinsho , Yusuke Nagae
IPC分类号： C07C41/54 , B01J23/80 , B01J37/00 , B01J37/04 , B01J37/08 , B01J37/18 , C07C17/354 , C07C29/17 , C07C41/20 , C07F7/12
摘要： A halide compound having one or more carbon-carbon unsaturated bonds is catalytically reduced with substantially no dehalogenation to produce a reduced halide compound in which at least one of the one or more unsaturated bonds is reduced. Specifically provided is a method for producing a reduced halide compound including steps of: reacting a nickel compound, a zinc compound, and a borohydride compound in a solvent to obtain a reduction catalyst; and subjecting a halide compound having one or more carbon-carbon unsaturated bonds to catalytic reduction in the presence of the reduction catalyst to reduce at least one of the one or more carbon-carbon unsaturated bonds to thereby obtain a reduced halide compound.
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公开(公告)号：US09845304B2
公开(公告)日：2017-12-19
申请号：US15014598
申请日：2016-02-03
发明人： Yuki Miyake , Takeshi Kinsho , Miyoshi Yamashita , Naoki Ishibashi , Yusuke Nagae , Akihiro Baba
IPC分类号： C07C17/266 , C07C17/269 , C07C2/86 , C07C29/10 , C07C29/32 , C07C41/48 , C07C45/26 , C07C45/51 , C07C67/08 , C07C67/40 , C07D309/12
CPC分类号： C07D309/12 , C07B2200/09 , C07C2/861 , C07C17/266 , C07C17/269 , C07C29/103 , C07C29/32 , C07C41/48 , C07C45/26 , C07C45/515 , C07C67/08 , C07C67/40 , C07C2527/122 , C07C33/04 , C07C21/22 , C07C43/303 , C07C43/30 , C07C47/21 , C07C33/02 , C07C69/145 , C07C11/22 , C07C2/32
摘要： Provided are a method for efficiently producing an asymmetric conjugated diyne from an inexpensive and safe alternative compound to hydroxylamine hydrochloride and a method for producing a Z,Z-conjugated diene compound from the asymmetric conjugated diyne compound thus obtained. More specifically, provided is a method for producing an asymmetric conjugated diyne compound comprising a step of subjecting a terminal alkyne compound (1): HC≡C—Z1—Y1 to a coupling reaction with an alkynyl halide (2): Y2—Z2—C≡C—X by using sodium borohydride in water and an organic solvent in the presence of a copper catalyst and a base to obtain the asymmetric conjugated diyne compound (3): Y2—Z2—C≡C—C≡C—Z1—Y1. In addition, provided is a method for producing a Z,Z-conjugated diene compound by reducing the resulting asymmetric conjugated diyne compound, or the like.
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公开(公告)号：US09845273B2
公开(公告)日：2017-12-19
申请号：US14189373
申请日：2014-02-25
摘要： Provided is a method for producing a chlorohydrocarbon having conjugated double bonds by stereoselectively chlorinating an alcohol having conjugated double bonds. More specifically, provided is a method for producing a chlorohydrocarbon having conjugated double bonds, the method including a step of chlorinating an alcohol having conjugated double bonds with a chlorinating agent in a solvent in the presence of a base and in the absence of metal salt for chlorination of the alcohol, and the alcohol being represented by the formula (1): RCH═CHCH═CH—Z—OH (1) wherein R represents a hydrogen atom or a linear, branched or cyclic C1-17 monovalent hydrocarbon group which may have at least one double bond or at least one triple bond; and Z represents a linear, branched or cyclic C1-17 divalent hydrocarbon group which may have at least one double bond or at least one triple bond.
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公开(公告)号：US20220411358A1
公开(公告)日：2022-12-29
申请号：US17848592
申请日：2022-06-24
IPC分类号： C07C47/222 , C07C47/21 , A01N31/04
摘要： There are provided a composition which has a larger attracted number than (9Z)-9,13-tetradecadien-11-ynal alone; and others. More specifically, there are provided a composition bioactive to Stenoma catenifer (STENCA), the composition including (9Z)-9,13-tetradecadien-11-ynal and (9E)-9,13-tetradecadien-11-ynal; a sustained release preparation for controlling STENCA, the preparation including the composition and a carrier or container for sustainedly releasing the (9Z)-9,13-tetradecadien-11-ynal and the (9E)-9,13-tetradecadien-11-ynal; and a method for controlling STENCA, the method including a step of installing the sustained release preparation in a field to release the (9Z)-9,13-tetradecadien-11-ynal and the (9E)-9,13-tetradecadien-11-ynal into the field.
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