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公开(公告)号：US07084295B2
公开(公告)日：2006-08-01
申请号：US10499305
申请日：2002-12-20
IPC分类号： C07C69/00
CPC分类号： C07C69/653 , C07C35/52 , C07C2603/74 , C08F297/04 , C08L33/04 , C08L33/06 , C08L33/08 , C08L53/02 , C08L53/025 , C08L2666/24 , C08L33/00 , C08L2666/04 , C08L2666/02
摘要： A perfluoroadamantyl acrylate compound which is highly useful as a raw material for functional resins,etc.;and an intermediate therefore. The perfluoroadamantyl acrylate compound comprises perfluoroadamantane having a CH2═C(R)COO group(wherein R is a hydrogen atom, a methyl group or a trifluoromethyl group) at the 1-position, at each of the 1- and 3-positions, at each of the 1-, 3- and 5-positions, at each of the 1-, 3-, 5- and 7-positions, or at the 2-position.
摘要翻译： 作为功能性树脂的原料高度有用的丙烯酸全氟金刚烷酯化合物等;以及中间体。 全氟金刚烷基丙烯酸酯化合物包括在1位上具有CH 2 -S（R）COO基团（其中R是氢原子，甲基或三氟甲基）的全氟金刚烷， 在1-，3-，5-和7-位，或2-位中的每个位置，1-和3-位上的1-和3-位。
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公开(公告)号：US20050131247A1
公开(公告)日：2005-06-16
申请号：US10499305
申请日：2002-12-20
IPC分类号： C07C69/54 , C07C35/52 , C07C69/00 , C07C69/013 , C07C69/653 , C08F20/22 , C08F297/04 , C08L33/06 , C08L33/08 , C08L53/02 , C07C69/62 , C07C35/22 , C07C69/52
CPC分类号： C07C69/653 , C07C35/52 , C07C2603/74 , C08F297/04 , C08L33/04 , C08L33/06 , C08L33/08 , C08L53/02 , C08L53/025 , C08L2666/24 , C08L33/00 , C08L2666/04 , C08L2666/02
摘要： A perfluoroadamantyl acrylate compound which is highly useful as a raw material for functional resins,etc.;and an intermediate therefore. The perfluoroadamantyl acrylate compound comprises perfluoroadamantane having a CH2═C(R)COO group(wherein R is a hydrogen atom, a methyl group or a trifluoromethyl group) at the 1-position, at each of the 1- and 3-positions, at each of the 1-,3- and 5-positions, at each of the 1-,3-,5- and 7-positions, or at the 2-position.
摘要翻译： 作为功能性树脂的原料高度有用的丙烯酸全氟金刚烷酯化合物等;以及中间体。 全氟金刚烷基丙烯酸酯化合物包括在1位上具有CH 2 -C（R）COO基团（其中R是氢原子，甲基或三氟甲基）的全氟金刚烷， 在1 - ，3 - ，5 - 和7 - 位，或2-位的每个位置上，在1 - ，3 - 和5 - 位的每个位置上有1 - 和3 - 位。
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公开(公告)号：US20060149073A1
公开(公告)日：2006-07-06
申请号：US10540547
申请日：2003-12-18
IPC分类号： C07C43/18
CPC分类号： C07C43/12 , C07C43/192 , C07C49/517 , C07C2603/74 , G03F7/0045
摘要： Provided is an adamantane derivative represented by Formula (I) or (II): wherein X represents a halogen atom; Y represents an alkyl group having 1 to 10 carbon atoms, a halogenated alkyl group having 1 to 10 carbon atoms, a halogen atom or a hetero atom-containing group; R1 to R4 represent independently hydrogen, a halogen atom, an alkyl group having 1 to 10 carbon atoms or a halogenated alkyl group having 1 to 10 carbon atoms; m represents an integer of 0 to 15, and n represents an integer of 0 to 10; and excluded is a case where in Formula (I), m and n are 0 at the same time and R3 and R4 are a hydrogen atom at the same time. Capable of being provided is a novel adamantane derivative which is useful as a modifying agent for a resin for a photoresist and a dry etching resistance-improving agent in the photolithography field, agricultural and medical intermediates and other various industrial products.
摘要翻译： 提供由式（I）或（II）表示的金刚烷衍生物：其中X表示卤素原子; Y表示碳原子数1〜10的烷基，碳原子数1〜10的卤代烷基，卤原子或含杂原子的基团。 R 1至R 4独立地表示氢，卤素原子，具有1至10个碳原子的烷基或具有1至10个碳原子的卤代烷基; m表示0〜15的整数，n表示0〜10的整数。 并且排除是在式（I）中同时m和n同时为0并且R 3和R 4同时为氢原子的情况。 可以提供的是一种新颖的金刚烷衍生物，其可用作光刻胶树脂和光刻领域的干蚀刻抗蚀剂改性剂，农业和医疗中间体等各种工业产品的改性剂。
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公开(公告)号：US07402712B2
公开(公告)日：2008-07-22
申请号：US10862423
申请日：2004-06-08
IPC分类号： C07C43/18
CPC分类号： C07C43/30 , C07C43/313 , C07C49/753 , C07C2603/74
摘要： Provided by the present invention are an adamantyl vinyl ether compound which is useful as a monomer for functional resins in the photolithography field or a raw material therefor and medical and agricultural intermediates and a production process for the same.The present invention relates to a production process for an adamantyl vinyl ether compound, characterized by subjecting an adamantyl vinyl ether compound having a specific structure and alcohol having an eliminating group in a β position to chloroalkyl-etherification, then subjecting it to etherification to form an adamantyl group-containing ether and then subjecting it to vinyl-etherification.
摘要翻译： 由本发明提供的金刚烷基乙烯基醚化合物可用作光刻领域中的功能性树脂的单体或其原料，医药和农业中间体及其生产方法。 金刚烷基乙烯基醚化合物的制造方法技术领域本发明涉及一种金刚烷基乙烯基醚化合物的制造方法，其特征在于，将具有特定结构的金刚烷基乙烯基醚化合物和具有消除基团的醇在β位置进行氯代烷基醚化，然后使其进行醚化，形成 含有金刚烷基的醚，然后使其进行乙烯基醚化。
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公开(公告)号：US07470824B2
公开(公告)日：2008-12-30
申请号：US10540547
申请日：2003-12-18
IPC分类号： C07C43/18
CPC分类号： C07C43/12 , C07C43/192 , C07C49/517 , C07C2603/74 , G03F7/0045
摘要： Provided is an adamantane derivative represented by Formula (I) or (II): wherein X represents a halogen atom; Y represents an alkyl group having 1 to 10 carbon atoms, a halogenated alkyl group having 1 to 10 carbon atoms, a halogen atom or a hetero atom-containing group; R1 to R4 represent independently hydrogen, a halogen atom, an alkyl group having 1 to 10 carbon atoms or a halogenated alkyl group having 1 to 10 carbon atoms; m represents an integer of 0 to 15, and n represents an integer of 0 to 10; and excluded is a case where in Formula (I), m and n are 0 at the same time and R3 and R4 are a hydrogen atom at the same time. Capable of being provided is a novel adamantane derivative which is useful as a modifying agent for a resin for a photoresist and a dry etching resistance-improving agent in the photolithography field, agricultural and medical intermediates and other various industrial products.
摘要翻译： 提供由式（I）或（II）表示的金刚烷衍生物：其中X表示卤素原子; Y表示碳原子数1〜10的烷基，碳原子数1〜10的卤代烷基，卤原子或含杂原子的基团。 R 1〜R 4分别独立地表示氢，卤素原子，碳原子数1〜10的烷基或碳原子数1〜10的卤代烷基。 m表示0〜15的整数，n表示0〜10的整数。 并且排除是在式（I）中同时m和n同时为0且R3和R4同时为氢原子的情况。 可以提供的是一种新颖的金刚烷衍生物，其可用作光刻胶树脂和光刻领域的干蚀刻抗蚀剂改性剂，农业和医疗中间体等各种工业产品的改性剂。
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公开(公告)号：US20050004391A1
公开(公告)日：2005-01-06
申请号：US10862423
申请日：2004-06-08
IPC分类号： C07C43/162 , C07C43/16 , C07C43/30 , C07C43/313 , C07C49/753 , C07C69/52
CPC分类号： C07C43/30 , C07C43/313 , C07C49/753 , C07C2603/74
摘要： Provided by the present invention are an adamantyl vinyl ether compound which is useful as a monomer for functional resins in the photolithography field or a raw material therefor and medical and agricultural intermediates and a production process for the same. The present invention relates to a production process for an adamantyl vinyl ether compound, characterized by subjecting an adamantyl vinyl ether compound having a specific structure and alcohol having an eliminating group in a β position to chloroalkyl-etherification, then subjecting it to etherification to form an adamantyl group-containing ether and then subjecting it to vinyl-etherification.
摘要翻译： 由本发明提供的金刚烷基乙烯基醚化合物可用作光刻领域中的功能性树脂的单体或其原料，医药和农业中间体及其生产方法。 金刚烷基乙烯基醚化合物的制造方法技术领域本发明涉及一种金刚烷基乙烯基醚化合物的制造方法，其特征在于，将具有特定结构的金刚烷基乙烯基醚化合物和具有消除基团的醇在β位置进行氯代烷基醚化，然后使其进行醚化，形成 含有金刚烷基的醚，然后使其进行乙烯基醚化。
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7.发明授权Bis(3-amino-4-hydroxyphenyl)adamantane derivatives and process for production thereof 失效双（3-氨基-4-羟基苯基）金刚烷衍生物及其制备方法公开(公告)号：US07423180B2
公开(公告)日：2008-09-09
申请号：US10547553
申请日：2004-02-26
IPC分类号： C07C211/00
CPC分类号： C07C215/80 , C07C2603/74 , H05K3/285 , H05K3/4676
摘要： The invention provides compounds which are excellent in terms of heat resistance, mechanical characteristics, electric characteristics, physical properties, etc. and which provide a novel material useful for, for example, interlayer insulating film or protective film for use in semiconductor devices, interlayer insulating film for use in multilayer wiring boards, cover coating in flexible printed circuits, or a liquid crystal alignment layer.The compounds are bis(3-amino-4-hydroxyphenyl)adamantane derivatives having a structure represented by formula (I) or (II): (each of R1 to R4 represents a halogen atom, a hydroxyl group, an alkyl group, an alkoxyl group, a carboxyl group, or an alkoxycarbonyl group, each of m and a is an integer of 0 to 3, and each of n and b is an integer of 0 to 14, with the proviso that the case where the following three conditions in formula (I) are met is excluded: R2 is methyl and present at a bridgehead; m is 0; and n is 2).
摘要翻译： 本发明提供了在耐热性，机械特性，电特性，物理性质等方面优异的化合物，其提供了用于例如用于半导体器件的层间绝缘膜或保护膜的新型材料，层间绝缘 用于多层布线板的膜，柔性印刷电路中的覆盖层或液晶取向层。 这些化合物是具有由式（I）或（II）表示的结构的双（3-氨基-4-羟基苯基）金刚烷衍生物：（R 1至R 4中的每一个） >表示卤素原子，羟基，烷基，烷氧基，羧基或烷氧基羰基，m和a分别为0〜3的整数，n和b分别为 0至14，条件是满足式（I）中的以下三个条件的情况除外：R 2是甲基并存在于桥头堡; m是0; n是2 ）。
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8.发明申请Bis(3-amino-4-hydroxyphenyl)adamantane derivatives and process for production thereof 失效双（3-氨基-4-羟基苯基）金刚烷衍生物及其制备方法公开(公告)号：US20060161016A1
公开(公告)日：2006-07-20
申请号：US10547553
申请日：2004-02-26
IPC分类号： C07C229/54 , C07C213/10
CPC分类号： C07C215/80 , C07C2603/74 , H05K3/285 , H05K3/4676
摘要： The invention provides compounds which are excellent in terms of heat resistance, mechanical characteristics, electric characteristics, physical properties, etc. and which provide a novel material useful for, for example, interlayer insulating film or protective film for use in semiconductor devices, interlayer insulating film for use in multilayer wiring boards, cover coating in flexible printed circuits, or a liquid crystal alignment layer. The compounds are bis(3-amino-4-hydroxyphenyl)adamantane derivatives having a structure represented by formula (I) or (II): (each of R1 to R4 represents a halogen atom, a hydroxyl group, an alkyl group, an alkoxyl group, a carboxyl group, or an alkoxycarbonyl group, each of m and a is an integer of 0 to 3, and each of n and b is an integer of 0 to 14, with the proviso that the case where the following three conditions in formula (I) are met is excluded: R2 is methyl and present at a bridgehead; m is 0; and n is 2).
摘要翻译： 本发明提供了在耐热性，机械特性，电特性，物理性质等方面优异的化合物，其提供了用于例如用于半导体器件的层间绝缘膜或保护膜的新型材料，层间绝缘 用于多层布线板的膜，柔性印刷电路中的覆盖层或液晶取向层。 这些化合物是具有由式（I）或（II）表示的结构的双（3-氨基-4-羟基苯基）金刚烷衍生物：（R 1至R 4中的每一个） >表示卤素原子，羟基，烷基，烷氧基，羧基或烷氧基羰基，m和a分别为0〜3的整数，n和b分别为 0至14，条件是满足式（I）中的以下三个条件的情况除外：R 2是甲基并存在于桥头堡; m是0; n是2 ）。
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公开(公告)号：US06833388B2
公开(公告)日：2004-12-21
申请号：US10480255
申请日：2003-12-17
IPC分类号： A61K31215
CPC分类号： C07C69/753 , C07C2603/74 , C08K5/12 , G03F7/0045 , G03F7/0392
摘要： There is provided a trisadamantane based compound which is useful not only as a photoresist additive but also as pharmaceuticals, an agrochemical intermediate, a resin additive (heat resistance improver) and the like, and which is represented by the general formula (I): wherein R1 and R2 are each an alkyl group having 1 to 8 carbon atoms; X1 and X2 are each hydrogen atom, a halogen atom, an alkyl group having 1 to 8 carbon atoms, hydroxyl group, an alkoxy group having 1 to 8 carbon atoms, carboxyl group or COOR3 in which R3 is an alkyl group having 1 to 8 carbon atoms.
摘要翻译： 提供了三金刚烷类化合物，其不仅可用作光致抗蚀剂添加剂，而且可用作药物，农药中间体，树脂添加剂（耐热改进剂）等，并且由通式（I）表示：其中 R 1和R 2各自为具有1至8个碳原子的烷基; X 1和X 2各自为氢原子，卤素原子，具有1至8个碳原子的烷基，羟基，具有1至8个碳原子的烷氧基，羧基或COOR 3，其中 R 3是具有1至8个碳原子的烷基。
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10.发明授权公开(公告)号：US07193106B2
公开(公告)日：2007-03-20
申请号：US10511600
申请日：2003-04-28
IPC分类号： C07C69/03
CPC分类号： C07C69/63 , C07C67/14 , C07C2603/74
摘要： Provided are a novel halogenoacetoxyadamantane derivative which is useful as a modifying agent for a resin for a photoresist and a dry etching resistance-improving agent in the photolithography field, agricultural and medical intermediates and a compound for other various industrial products and a process for producing the same. To be specific, provided are a halogenoacetoxyadamantane derivative having a halogenoacetoxy group in an adamantane skeleton and a process for producing a halogenoacetoxyadamantane derivative, comprising the step of reacting a hydroxyl group of an adamantane skeleton with halogenoacetic halide or reacting the above hydroxyl group with a lithiation agent to derive it into a lithiumoxy group and then reacting halogenoacetic halide to introduce a halogenoacetoxy group.
摘要翻译： 提供了一种新的卤代乙酰氧基金刚烷衍生物，其可用作光刻胶树脂中的改性剂和光刻领域中的耐干蚀刻性改进剂，农业和医疗中间体以及其它各种工业产品的化合物和用于制备 相同。 具体而言，提供在金刚烷骨架中具有卤代乙酰氧基的卤代乙酰氧基金刚烷衍生物和卤代乙酰氧基金刚烷衍生物的制造方法，包括使金刚烷骨架的羟基与卤代乙酰卤反应或使上述羟基与锂化反应的步骤 将其衍生为锂氧基，然后使卤代乙酰卤反应引入卤代乙酰氧基。
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