摘要:
Alkoxy silane oligomers which have a non-hydrolyzable carbon bridged bond to another silane functionality are taught herein, as well as their manufacture and utility.
摘要:
Alkoxy silane oligomers which have a non-hydrolyzable carbon bridged bond to another silane functionality are taught herein, as well as their manufacture and utility.
摘要:
Powder coating or adhesive formulations include as a component thereof a silane of formula (I) or hydrolyzates or condensates thereof where R1 is a hydrocarbon, acyl, alkylsilyl, or alkoxysilyl group, R2 is a monovalent hydrocarbon group; R3 is alkylene, optionally interrupted with one or more ether oxygen atoms; a is 0 or 1; Z is a direct bond or a divalent linking group; X is an m-valent organic group or H; and m is 1-20. The silanes are useful as crosslinkers, property modifiers and/or adhesion promoters. Powder adhesives may be similarly formed with the silanes of formula (I). Fillers or pigments, such as titanium dioxide fillers, which are treated with silanes, especially silanes having alkyl, epoxy, acryl, methacryl, polyether, amino, acid anhydride, hydroxyalkyl, carbamato or ureido functionality, may also be usefully employed in powder coating formulations.
摘要:
Oligomers of the formula: [R3SiO1/2]m[O1/2Si(R2)O1/2]n[SiO3/2R]o[SiO4/2]p (I) wherein each R is selected individually from the group consisting of B, R1, —OR2, R3 and R4; B is an organosilyl functional group bridged to the Si atom of the siloxane oligomer backbone by an Si—C bond; each R1 is independently a saturated aliphatic hydrocarbon group of 1 to 16 carbon atoms; each R2 is independently a group as defined for R1, an aromatic hydrocarbon group or an acyl group; each R3 is independently a monovalent organic radical containing an aliphatically unsaturated hydrocarbon group and each R4 is a monovalent organic radical linked to the Si atom of the siloxane oligomer backbone by an Si—C bond, which does not include an aliphatically unsaturated hydrocarbon group and which has thereon one or more members of the group selected from aromatic hydrocarbon, ether, ester, carbamate, thioether, polysulfide, blocked mercaptan, amide, epoxy, cyano and oximato groups; and with the provisos that at least one quarter of all R groups are —OR2; either at least one silicon atom of the oligomer has an R3 group thereon or at least one R is a B, or both; if there is a group R3 which is a vinyl group, there is at least one other group which is a B group, an R3 group other than vinyl, or an R4 group; m=2 to 20; n=0 to 50; o=0 to 20; and p=0 to 10, are useful as coupling agents in curable compositions of filled organic polymers used for wire and cable insulation. The oligomers also have utility as crosslinkers, as adhesion promoters, to provide a dual radical/moisture cure mechanism, and/or to provide moisture resistance in coating, in other compositions, such as curable adhesives and coatings.
摘要:
A polysiloxane having pendant, sterically-hindered heterocyclic moieties attached to a siloxane chain, and their use in stabilizing synthetic polymer compositions.
摘要:
The present invention is directed to a method for crosslinking reactive polyolefins using a rhodium catalyzed hydrosilation reaction and novel siloxanes as crosslinkers.Also disclosed are novel siloxane compounds which are useful in the crosslinking of polyolefins and polyolefin compositions which have been crosslinked through use of the claimed process and siloxane crosslinkers.
摘要:
The present invention relates to olefin polymers stabilized with polysiloxanes containing sterically hindered heterocyclic moieties, said polysiloxanes represented by the general formula M*.sub.v D.sub.x D*.sub.y T.sub.z Q.sub.w M*.sub.v.
摘要:
N-substituted aminoalkylsilanes are obtained via a selective process which comprises reacting a cyanoalkylsilane with a primary or secondary amine in the presence of a heterogeneous hydrogenation catalyst selected from the group consisting of rhodium, platinum and palladium.
摘要:
A two-stage process for producing gamma-mercaptopropyltrialkoxysilane which comprises reacting beta-cyanoethyltrialkoxysilane with hydrogen sulfide in the presence of an amide to form a novel gamma-trialkoxysilylthiopropionamide intermediate followed by reducing said intermediate with hydrogen in the presence of a transition metal polysulfide.
摘要:
Oligomers of the formula: [R3SiO½]m[O½Si(R2)O½]n[SiO{fraction (3/2)}R]o[SiO{fraction (4/2)}]p (I) wherein each R is selected individually from the group consisting of B, R1,—OR2, R3 and R4; B is an organosilyl functional group bridged to the Si atom of the siloxane oligomer backbone by an Si—C bond; each R1 is independently a saturated or aromatic hydrocarbon group of 1 to 16 carbon atoms; each R2 is independently a group as defined for R1 or an acyl group; and each R3 is independently a monovalent organic radical containing an aliphatically unsaturated hydrocarbon group and each R4 is a monovalent organic radical linked to the Si atom of the siloxane oligomer backbone by an Si—C bond, which does not include an aliphatically unsaturated hydrocarbon group and which has thereon one or more members of the group selected from ether, polyether, ester, polyester, carbamate, polyurethane, isocyanurate, thioether, polysulfide, blocked mercaptan, amide, cyano and oximato groups; with the provisos that at least one R is a B, at least one quarter of all R groups are —OR2, and at least one silicon atom of the oligomer has an R3 group thereon; m=2 to 10; n=0 to 20; o=0 to 20; and p=0 to 10, are useful as coupling agents in curable compositions of filled organic polymers used for wire and cable insulation. The oligomers also have utility as crosslinkers, as adhesion promoters, to provide a dual radical/moisture cure mechanism, and/or to provide moisture resistance in coating, in other compositions, such as curable adhesives and coatings.
摘要翻译:下式的低聚物:其中R独立地选自B,R 1,-OR 2,R 3和R 4; B是通过Si-C键桥接到硅氧烷低聚物主链的Si原子上的有机甲硅烷基官能团; 每个R 1独立地是1至16个碳原子的饱和或芳族烃基; 每个R 2独立地是如R1或酰基所定义的基团; 并且每个R 3独立地是含有脂族不饱和烃基的单价有机基团,并且每个R 4是通过不包含脂族不饱和烃基的Si-C键与硅氧烷低聚物主链的Si原子连接的一价有机基团, 其具有一个或多个选自醚,聚醚,酯,聚酯,氨基甲酸酯,聚氨酯,异氰脲酸酯,硫醚,多硫化物,封端的硫醇,酰胺,氰基和肟基的基团的成员; 条件是至少一个R是B,所有R基团的至少四分之一是-OR 2,并且低聚物的至少一个硅原子在其上具有R3基团; m = 2〜10; n = 0〜20; o = 0〜20; 和p = 0至10,可用作用于电线和电缆绝缘的填充有机聚合物的可固化组合物中的偶联剂。 低聚物在其它组合物如可固化粘合剂和涂料中也可用作交联剂,作为粘合促进剂,以提供双自由基/湿度固化机理和/或提供涂层中的耐湿性。