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公开(公告)号：US4615829A
公开(公告)日：1986-10-07
申请号：US671155
申请日：1984-11-13
申请人： Shohei Tamura , Sadamitsu Sasaki , Masao Abe , Hitoshi Nakazawa , Hisashi Ichinose , Keiji Nakamoto , Satoshi Yumoto
发明人： Shohei Tamura , Sadamitsu Sasaki , Masao Abe , Hitoshi Nakazawa , Hisashi Ichinose , Keiji Nakamoto , Satoshi Yumoto
CPC分类号： H01M4/60 , C08G73/00 , C08G73/026 , C08G73/0266 , C08L79/00 , H01B1/128 , H01L51/0035
摘要： An electroconductive organic polymer exhibiting outstanding electroconductivity is described, containing an electron acceptor as a dopant, and having electroconductivity of not less than 10.sup.-6 S/cm, substantially comprising a linear polymer having as a main repeating unit thereof a quinonediimine structure represented by formula (III) ##STR1## wherein R represents a hydrogen atom or an alkyl group. This polymer can be obtained by oxidative polymerization of an aniline compound or a water-soluble salt thereof with an oxidizing agent in a reaction medium containing a protonic acid.
摘要翻译： 描述了显示出优异的导电性的导电有机聚合物，其含有电子受体作为掺杂剂，并且具有不小于10 -6 S / cm的导电率，基本上包含具有作为主要重复单元的线性聚合物，由式 （III）其中R表示氢原子或烷基。 该聚合物可以通过苯胺化合物或其水溶性盐与含有质子酸的反应介质中的氧化剂进行氧化聚合而获得。
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公开(公告)号：US4556623A
公开(公告)日：1985-12-03
申请号：US688119
申请日：1984-12-31
申请人： Shohei Tamura , Sadamitsu Sasaki , Takeshi Sasaki , Hisashi Ichinose , Keiji Nakamoto , Masao Abe , Hitoshi Nakazawa
发明人： Shohei Tamura , Sadamitsu Sasaki , Takeshi Sasaki , Hisashi Ichinose , Keiji Nakamoto , Masao Abe , Hitoshi Nakazawa
摘要： An electroconductive porous film is described comprising a porous film substrate having deposited thereon an electroconductive organic polymer containing an electron acceptor as a doptant, substantially comprising a linear polymer having as a main repeating unit thereof a quinonediimine structure represented by formula (III). ##STR1## wherein R.sub.1 and R.sub.2, which are the same or different, each represents a hydrogen atom or an alkyl group.
摘要翻译： 描述了一种导电多孔膜，其包括在其上沉积有包含电子受体作为试剂的导电有机聚合物的多孔膜基材，其基本上包含作为其主要重复单元的线性聚合物为由式（III）表示的醌二亚胺结构。 （III）其中相同或不同的R 1和R 2各自表示氢原子或烷基。
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公开(公告)号：US4354017A
公开(公告)日：1982-10-12
申请号：US277429
申请日：1981-06-25
申请人： Masao Abe , Hisashi Ichinose , Yuzuru Noda
发明人： Masao Abe , Hisashi Ichinose , Yuzuru Noda
CPC分类号： C08G73/0694
摘要： A process for the production of polyquinazolone-based polymers by reacting bisquinazolone with a diamine or a diamine substituted with a carboxylic acid, sulfonic acid or metal salt thereof in the presence of a Lewis acid catalyst or a phosphorus-containing dehydrating agent, where the polymers are useful to produce permselective membranes.
摘要翻译： 在路易斯酸催化剂或含磷脱水剂存在下，使双喹那唑与二胺或二羧酸或其金属盐取代的二胺反应生产聚喹唑酮类聚合物的方法，其中聚合物 可用于生产渗透膜。
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4.发明授权Organic polymer, conducting organic polymer, production methods and uses of the same 失效有机聚合物，导电有机聚合物，其制备方法和用途相同
公开(公告)号：US5728321A
公开(公告)日：1998-03-17
申请号：US471256
申请日：1995-06-06
申请人： Masao Abe , Akira Ohtani , Hiroyuki Higuchi , Minoru Ezoe , Shinya Akizuki , Keiji Nakamoto , Keiko Mochizuki , Yasuhiro Umemoto , Michio Umeda
发明人： Masao Abe , Akira Ohtani , Hiroyuki Higuchi , Minoru Ezoe , Shinya Akizuki , Keiji Nakamoto , Keiko Mochizuki , Yasuhiro Umemoto , Michio Umeda
CPC分类号： H01B1/128 , C08G73/0266 , H01M4/60 , Y10T428/29 , Y10T428/2913
摘要： This invention relates to a conducting organic polymer formed by doping an organic polymer with a protonic acid having a dissociation constant value pKa of less than 4.8, wherein the organic polymer has, as the main repeating unit, a compound represented by the general formula: ##STR1## wherein, m and n, respectively, show the molar fraction of the quinonediimine structural unit and phenylenediamine structural unit in the repeating unit, and 0
摘要翻译： 本发明涉及通过用解离常数值pKa小于4.8的质子酸掺杂有机聚合物而形成的导电有机聚合物，其中有机聚合物具有作为主要重复单元的由以下通式表示的化合物： 其中，m和n分别表示重复单元中醌二亚胺结构单元和苯二胺结构单元的摩尔分数，0
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5.发明授权Organic polymer, conducting organic polymer, production methods and uses of the same 失效有机聚合物，导电有机聚合物，其制备方法和用途相同
公开(公告)号：US5264552A
公开(公告)日：1993-11-23
申请号：US413502
申请日：1989-09-27
申请人： Masao Abe , Akira Ohtani , Hiroyuki Higuchi , Minoru Ezoe , Shinya Akizuki , Keiji Nakamoto , Keiko Mochizuki , Yasuhiro Umemoto , Michio Umeda
发明人： Masao Abe , Akira Ohtani , Hiroyuki Higuchi , Minoru Ezoe , Shinya Akizuki , Keiji Nakamoto , Keiko Mochizuki , Yasuhiro Umemoto , Michio Umeda
CPC分类号： H01M4/60 , C08G73/0266 , H01B1/128
摘要： This invention relates to an organic polymer having, as the main repeating unit, the compound represented by the general formula: ##STR1## (wherein, m and n respectively show the molar fraction of quinonediimine structure unit and phenylenediamine structure unit in the repeating unit, and 0
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6.发明授权
公开(公告)号：US4529793A
公开(公告)日：1985-07-16
申请号：US505635
申请日：1983-06-20
申请人： Masao Abe , Akio Iwama , Yuzuru Noda , Hisashi Ichinose
发明人： Masao Abe , Akio Iwama , Yuzuru Noda , Hisashi Ichinose
CPC分类号： C08G73/0694 , B01D71/62
摘要： A selective permeable membrane comprising a polyquinazolone-based polymer including a repeating unit represented by the formula ##STR1## wherein R.sup.1 is a tetravalent aromatic group, R.sup.2a and R.sup.2b are each independently, an alkyl group or aromatic group, and R.sup.3 is a divalent organic group.
摘要翻译： 一种选择性渗透膜，其包含基于聚喹氮酮的聚合物，其包含由式（IMAGE）表示的重复单元，其中R 1为四价芳族基团，R 2a和R 2b各自独立地为烷基或芳基，R 3为二价有机基团 。
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7.发明授权Conductive polyaniline composition, film thereof and processes for producing these 失效导电聚苯胺组合物，其膜及其制备方法公开(公告)号：US07538165B2
公开(公告)日：2009-05-26
申请号：US10499064
申请日：2002-06-26
申请人： Masao Abe
发明人： Masao Abe
CPC分类号： C08J5/18 , C08J2379/02 , C08L61/06 , C08L61/14 , C08L79/02 , H01G9/028 , C08L2666/16
摘要： The invention provides an electrically conductive polyaniline composition comprising polyaniline which contains at least one of novolac resins selected from the group consisting of phenolsulfonic acid novolac resin and naphtholsulfonic acid novolac resin as a dopant. The electrically conductive polyaniline composition is obtained by contacting polyaniline with an aqueous solution of the novolac resin to dope the polyaniline with the novolac resin.The invention further provides an electrically conductive polyaniline film which comprises the polyaniline containing the novolac resin as a dopant. The electrically conductive polyaniline film is obtained by contacting film of polyaniline with an aqueous solution of the novolac resin to dope the polyaniline.
摘要翻译： 本发明提供一种包含聚苯胺的导电聚苯胺组合物，其包含选自苯酚磺酸酚醛清漆树脂和萘酚磺酚醛清漆树脂作为掺杂剂的酚醛树脂中的至少一种。 导电聚苯胺组合物是通过使聚苯胺与酚醛清漆树脂的水溶液接触以将聚苯胺与酚醛清漆树脂掺合而获得的。 本发明还提供一种导电聚苯胺膜，其包含含有酚醛清漆树脂作为掺杂剂的聚苯胺。 导电聚苯胺膜是通过使聚苯胺的膜与酚醛清漆树脂的水溶液接触来得到聚苯胺。
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8.发明申请公开(公告)号：US20080157026A1
公开(公告)日：2008-07-03
申请号：US12071792
申请日：2008-02-26
申请人： Masao Abe
发明人： Masao Abe
IPC分类号： H01B1/12
CPC分类号： C08J5/18 , C08J2379/02 , C08L61/06 , C08L61/14 , C08L79/02 , H01G9/028 , C08L2666/16
摘要： The invention provides an electrically conductive polyaniline composition comprising polyaniline which contains at least one of novolac resins selected from the group consisting of phenolsulfonic acid novolac resin and naphtholsulfonic acid novolac resin as a dopant. The electrically conductive polyaniline composition is obtained by contacting polyaniline with an aqueous solution of the novolac resin to dope the polyaniline with the novolac resin.The invention further provides an electrically conductive polyaniline film which comprises the polyaniline containing the novolac resin as a dopant. The electrically conductive polyaniline film is obtained by contacting film of polyaniline with an aqueous solution of the novolac resin to dope the polyaniline.
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9.发明申请Conductive polyaniline composition, film thereof and processes for producing these 失效导电聚苯胺组合物，其膜及其制备方法公开(公告)号：US20050062020A1
公开(公告)日：2005-03-24
申请号：US10499064
申请日：2002-06-26
申请人： Masao Abe
发明人： Masao Abe
CPC分类号： C08J5/18 , C08J2379/02 , C08L61/06 , C08L61/14 , C08L79/02 , H01G9/028 , C08L2666/16
摘要： The invention provides an electrically conductive polyaniline composition comprising polyaniline which contains at least one of novolac resins selected from the group consisting of phenolsulfonic acid novolac resin and naphtholsulfonic acid novolac resin as a dopant. The electrically conductive polyaniline composition is obtained by contacting polyaniline with an aqueous solution of the novolac resin to dope the polyaniline with the novolac resin. The invention further provides an electrically conductive polyaniline film which comprises the polyaniline containing the novolac resin as a dopant. The electrically conductive polyaniline film is obtained by contacting film of polyaniline with an aqueous solution of the novolac resin to dope the polyaniline.
摘要翻译： 本发明提供一种包含聚苯胺的导电聚苯胺组合物，其包含选自苯酚磺酸酚醛清漆树脂和萘酚磺酚醛清漆树脂作为掺杂剂的酚醛树脂中的至少一种。 导电聚苯胺组合物是通过使聚苯胺与酚醛清漆树脂的水溶液接触以将聚苯胺与酚醛清漆树脂掺合而获得的。 本发明还提供一种导电聚苯胺膜，其包含含有酚醛清漆树脂作为掺杂剂的聚苯胺。 导电聚苯胺膜是通过使聚苯胺的膜与酚醛清漆树脂的水溶液接触来得到聚苯胺。
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10.发明授权
公开(公告)号：US5578249A
公开(公告)日：1996-11-26
申请号：US442225
申请日：1995-05-16
申请人： Akira Ohtani , Yoshihiro Uetani , Masao Abe , Yasuhito Funada , Keisuke Kii
发明人： Akira Ohtani , Yoshihiro Uetani , Masao Abe , Yasuhito Funada , Keisuke Kii
CPC分类号： C08G73/0266 , C08L79/02 , H01B1/128
摘要： An organic polymer solution composition and a process for producing an electrically conductive organic polymer using the composition are disclosed. The composition comprising in organic polymer having an imino-p-phenylene structural unit represented by formula (I): ##STR1## as the main repeating unit, a protonic acid salt, and an organic solvent, the polymer and the salt being dissolved in the organic solvent.
摘要翻译： 公开了一种有机聚合物溶液组合物和使用该组合物制备导电有机聚合物的方法。 该组合物包含在由式（I）表示的亚氨基对亚苯基结构单元作为主要重复单元的有机聚合物中，质子酸盐和有机溶剂，聚合物和盐溶于 有机溶剂。
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