公开(公告)号：US4419497A

公开(公告)日：1983-12-06

申请号：US378680

申请日：1982-05-17

申请人： Shozo Tsuchiya ,  Akio Oshima ,  Hideo Hayashi

发明人： Shozo Tsuchiya ,  Akio Oshima ,  Hideo Hayashi

IPC分类号： C08F8/04 ,  C08F232/00 ,  C08L45/00 ,  C08L55/04

CPC分类号： C08F8/04 ,  C08F232/00 ,  C08L45/00 ,  C08L55/04 ,  Y10T428/2804 ,  Y10T428/2878 ,  Y10T428/2883

摘要： According to the present invention, there is disclosed a process for producing a novel resin which comprises the step of copolymerizing a five-member cyclic compound (component A) having a conjugated double bond and represented by the general formula (A) given below: ##STR1## wherein R is an alkyl group having from 1 to 3 carbon atoms; m and n are zero or integers not less than 1 and are in the relation of m+n=6; and/or a Diels-Alder addition product thereof (A) with a co-dimer (component B) of said five-member cyclic compound and 1,3-butadiene by heating a mixture of 20 to 90 parts by weight of said component A and 80 to 10 parts by weight of said component B at a temperature of from 200.degree. C. to 350.degree. C. Also disclosed are a process for hydrogenating said novel resin to produce a novel hydrogenated resin and resin compositions containing said hydrogenated resin.

摘要翻译： 根据本发明，公开了一种新型树脂的制造方法，该方法包括使由具有共轭双键并由下述通式（A）表示的五元环状化合物（A成分）共聚的步骤： 图像>通式（A）其中R是具有1至3个碳原子的烷基; m和n为零或不小于1的整数，并且为m + n = 6的关系; 和/或其狄尔斯 - 阿尔德加成产物（A）与所述五元环化合物的共二聚体（组分B）和1,3-丁二烯通过加热20至90重量份所述组分A 和80〜10重量份的所述组分B，温度为200℃至350℃。还公开了一种用于氢化所述新型树脂以制备新型氢化树脂的方法和含有所述氢化树脂的树脂组合物。

公开(公告)号：US4315842A

公开(公告)日：1982-02-16

申请号：US164504

申请日：1980-07-02

申请人： Shozo Tsuchiya ,  Akio Oshima ,  Hideo Hayashi

发明人： Shozo Tsuchiya ,  Akio Oshima ,  Hideo Hayashi

IPC分类号： C08L45/00 ,  C09J131/04 ,  C09J133/04 ,  C09J145/00 ,  C09J191/06 ,  C08L91/00

CPC分类号： C09J133/04 ,  C09J131/04 ,  C09J145/00 ,  C09J191/06 ,  C08L45/00 ,  C09J2201/61

摘要： According to the invention there is provided a hot melt composition comprising (A) a hydrogenated resin having a softening point ranging from 60.degree. C. to 130.degree. C., said hydrogenated resin (A) being prepared by hydrogenating a resin at a hydrogenation percentage of aromatic rings of from 10 to 90%, said resin being prepared by copolymerizing at least two components comprising (a) 100 parts by weight of cyclopentadiene or its derivative selected from the group consisting of cyclopentadiene and dicyclopentadiene and an alkyl substituent thereof and (b) 5 to 50 parts by weight of indene or its derivative selected from the group consisting of indene and an alkyl substituent thereof and (B) one or more compound selected from the group consisting of ethylene-unsaturated ester copolymers, polyester resins and waxes.

摘要翻译： 根据本发明，提供一种热熔组合物，其包含（A）软化点为60℃至130℃的氢化树脂，所述氢化树脂（A）通过以氢化百分比将树脂氢化制备 所述树脂通过共聚合至少两种组分来制备，所述组分包含（a）100重量份的环戊二烯或其选自环戊二烯和二环戊二烯的衍生物及其烷基取代基和（b ）5〜50重量份的茚或其衍生物，其选自茚及其烷基取代基，（B）一种或多种选自乙烯 - 不饱和酯共聚物，聚酯树脂和蜡的化合物。

公开(公告)号：US4028291A

公开(公告)日：1977-06-07

申请号：US617486

申请日：1975-09-29

申请人： Shozo Tsuchiya ,  Hisatake Sato ,  Akio Oshima ,  Hideo Hayashi

发明人： Shozo Tsuchiya ,  Hisatake Sato ,  Akio Oshima ,  Hideo Hayashi

IPC分类号： C08F8/14 ,  C09D11/10 ,  C08L91/00

CPC分类号： C08F8/14 ,  C09D11/108 ,  C08F2810/20 ,  Y10S260/38

摘要： Resins for printing ink and particularly offset ink, are produced by reacting a resin obtained by heat polymerizing at least one of cyclopentadiene, dicyclopentadiene or their alkyl substituted derivatives with 1-3 carbons and an unsaturated alcohol or unsaturated alcohol ester of an organic acid at a temperature of 150-350.degree. C. in the presence or in the absence of an inert hydrocarbon solvent with a higher monohydric saturated fatty acid or higher monohydric unsaturated fatty acid or their mixtures to produce a resin having a softening point of 100.degree. C or more.

摘要翻译： 通过将环戊二烯，二环戊二烯或其烷基取代的衍生物中的至少一种与1-3个碳原子进行热聚合而得到的树脂与有机酸的不饱和醇或不饱和醇酯反应，得到用于印刷油墨，特别是胶印油墨的树脂。 温度为150-350℃，在存在或不存在具有较高一元饱和脂肪酸或更高级一元不饱和脂肪酸的惰性烃溶剂或其混合物的情况下，生产软化点为100℃以上的树脂 。

公开(公告)号：US4205145A

公开(公告)日：1980-05-27

申请号：US887280

申请日：1978-03-16

申请人： Shozo Tsuchiya ,  Akio Oshima ,  Hideo Hayashi

发明人： Shozo Tsuchiya ,  Akio Oshima ,  Hideo Hayashi

IPC分类号： C08G8/00 ,  C08F2/60 ,  C08G8/28 ,  C08G83/00 ,  C09D11/00 ,  C09D11/10 ,  C08F283/00 ,  C08L61/06 ,  C08L61/10

CPC分类号： C09D11/103 ,  C09D11/10 ,  Y10S260/38

摘要： A resin for printing inks, prepared by the reaction of (A) a conjugated double bond-containing five-membered cyclic compound such as dicyclopentadiene, (B) a phenolic compound such as phenol, (C) an unsaturated carboxylic acid such as maleic anhydride and (D) a resol-type phenol resin obtained from phenol or an alkyl-substituted phenol and formaldehyde. In one embodiment, this invention relates to a process for the preparation of said resin for printing inks.

摘要翻译： 通过（A）含有共轭双键的五元环化合物如二环戊二烯，（B）酚类化合物如苯酚，（C）不饱和羧酸如马来酸酐反应制备的油墨用树脂 和（D）由苯酚或烷基取代的酚和甲醛获得的甲阶酚醛树脂型酚醛树脂。 在一个实施方案中，本发明涉及制备用于印刷油墨的所述树脂的方法。

公开(公告)号：US4048132A

公开(公告)日：1977-09-13

申请号：US710659

申请日：1976-08-02

申请人： Shozo Tsuchiya ,  Hideo Hayashi ,  Akio Oshima

发明人： Shozo Tsuchiya ,  Hideo Hayashi ,  Akio Oshima

IPC分类号： C08F220/00 ,  C08F32/00 ,  C08F220/04 ,  C08L45/00 ,  C09D11/00 ,  C09D11/037 ,  C09D11/10 ,  C09D11/106 ,  C09D11/108 ,  C08F232/06 ,  C08F232/08 ,  C08K5/01

CPC分类号： C09D11/108

摘要： Printing ink composition characterized by containing as a vehicle a resin having a softening point of 100.degree. C. or more and acid value of 5 to 50, said resin being obtained by reacting the following three components A, B and C, i.e., cyclopentadiene, dicyclopentadiene or their alkyl substituted derivatives as the A component an .alpha.,.beta.-unsaturated monocarboxylic acid as the B component and alkyl esters of said monocarboxylic acid as the C component, in proportions of such amounts as to satisfy the following formulae, ##EQU1## at a temperature in the range of 150.degree. - 350.degree. C. in the absence of a catalyst.

摘要翻译： 印刷油墨组合物，其特征在于，作为载体含有软化点为100℃以上，酸值为5〜50的树脂，所述树脂是通过使以下三种成分A，B和C，即环戊二烯， 二环戊二烯或其作为A成分的烷基取代的衍生物，作为B成分的α，β-不饱和一元羧酸和作为C成分的所述一元羧酸的烷基酯，按照满足下式的比例， IMAGE>在不存在催化剂的情况下在150-350℃的温度下进行。

公开(公告)号：US4552923A

公开(公告)日：1985-11-12

申请号：US671796

申请日：1984-11-14

申请人： Shozo Tsuchiya ,  Makoto Sasaki ,  Akio Oshima ,  Hideo Hayashi

发明人： Shozo Tsuchiya ,  Makoto Sasaki ,  Akio Oshima ,  Hideo Hayashi

IPC分类号： C09D11/00 ,  C08G81/00 ,  C08G81/02 ,  C09D11/10 ,  C08L61/10

CPC分类号： C09D11/10

摘要： The present invention is directed to a printing ink composition containing the reaction product of 5 to 100 parts by weight of a phenolic resin and about 100 parts by weight of a resin modified with an acid. The phenolic resin is prepared by condensing an appropriate 4-9 carbon alkylphenol with formalin. The modified resin is prepared by reacting 1 to 15 parts by weight of an appropriate unsaturated carboxylic acid and/or anhydride with about 100 parts by weight of the reaction product of 5 to 100 parts by weight straight-chain .alpha.-olefin with about 100 parts by weight of an appropriate pentacyclic compound, such as cyclopentadiene and/or dicyclopentadiene.

摘要翻译： 本发明涉及一种印刷油墨组合物，其含有5至100重量份酚醛树脂和约100重量份用酸改性的树脂的反应产物。 酚醛树脂通过将合适的4-9碳烷基酚与福尔马林缩合来制备。 改性树脂通过使1〜15重量份的适当的不饱和羧酸和/或酸酐与约100重量份的5-100重量份直链α-烯烃的反应产物与约100重量份 的适当的五环化合物，例如环戊二烯和/或二环戊二烯。

公开(公告)号：US4413067A

公开(公告)日：1983-11-01

申请号：US378682

申请日：1982-05-17

申请人： Shozo Tsuchiya ,  Akio Oshima ,  Hideo Hayashi

发明人： Shozo Tsuchiya ,  Akio Oshima ,  Hideo Hayashi

IPC分类号： C08F8/04 ,  C08F232/00 ,  C08L45/00 ,  C08L55/04

CPC分类号： C08F8/04 ,  C08F232/00 ,  C08L45/00 ,  C08L55/04 ,  Y10T428/2804 ,  Y10T428/2878 ,  Y10T428/2883

摘要： According to the present invention, there is disclosed a process for producing a novel resin which comprises the step of copolymerizing a five-member cyclic compound (component A) having a conjugated double bond and represented by the general formula (A) given below:GENERAL FORMULA (A): ##STR1## wherein R is an alkyl group having from 1 to 3 carbon atoms; m and n are zero or integers not less than 1 and are in the relation of m+n=6; and/or a Diels-Alder addition product thereof (A) with a co-dimer (component B) of said five-member cyclic compound and 1,3-butadiene by heating a mixture of 20 to 90 parts by weight of said component A and 80 to 10 parts by weight of said component B at a temperature of from 200.degree. C. to 350.degree. C. Also disclosed are a process for hydrogenating said novel resin to produce a novel hydrogenated resin and resin compositions containing said hydrogenated resin.

摘要翻译： 根据本发明，公开了一种新型树脂的制造方法，该方法包括使由具有共轭双键且由下述通式（A）表示的五元环状化合物（A成分）共聚的步骤：通用 式（A）：其中R是具有1至3个碳原子的烷基; m和n为零或不小于1的整数，并且为m + n = 6的关系; 和/或其狄尔斯 - 阿尔德加成产物（A）与所述五元环化合物的共二聚体（组分B）和1,3-丁二烯通过加热20至90重量份所述组分A 和80〜10重量份的所述组分B，温度为200℃至350℃。还公开了一种用于氢化所述新型树脂以制备新型氢化树脂的方法和含有所述氢化树脂的树脂组合物。

公开(公告)号：US4385149A

公开(公告)日：1983-05-24

申请号：US290287

申请日：1981-08-06

申请人： Shozo Tsuchiya ,  Makoto Sasaki ,  Hideo Hayashi

发明人： Shozo Tsuchiya ,  Makoto Sasaki ,  Hideo Hayashi

IPC分类号： C09D11/00 ,  C08G81/00 ,  C08G81/02 ,  C09D11/10

CPC分类号： C09D11/10 ,  Y10S260/38

摘要： An offset printing ink composition is provided which contains a vehicle resin (III) prepared by reacting 5 to 100 parts by weight of a phenolic resin (component D) with 100 parts by weight of a modified resin (II) modified with an acid, said phenolic resin (component D) being prepared by the condensation of a phenol including an alkyl substituent group having 4 to 9 carbon atoms with formalin, said modified resin (II) modified with an acid being prepared by reacting 1 to 15 parts by weight of a component C selected from the group consisting of unsaturated carboxylic acids, unsaturated carboxylic acid anhydrides and mixtures thereof with 100 parts by weight of a resin (I) obtained by copolymerizing 5 to 50 parts by weight of a component B selected from the group consisting of drying oils, fatty acids and mixtures thereof with 100 parts by weight of a five-member cyclic compound (component A) having a conjugated double bond or bonds and a Diels-Alder addition product thereof, such as cyclopentadiene or dicyclopentadiene.

摘要翻译： 提供了一种胶版印刷油墨组合物，其包含通过使5至100重量份的酚醛树脂（组分D）与100重量份的用酸改性的改性树脂（II）反应制备的载体树脂（III），所述改性树脂 酚醛树脂（D成分）是通过使含有4〜9个碳原子的烷基取代基的苯酚与福尔马林缩合制备的，所述改性树脂（II）用酸改性，其通过使1〜15重量份的 选自不饱和羧酸，不饱和羧酸酐及其混合物的组分C与100重量份通过共聚5-50重量份选自干燥中的组分B获得的树脂（I） 油，脂肪酸及其混合物与100重量份具有共轭双键或键的五元环状化合物（组分A）和Diels-Alder加成产物如Cyc 戊二烯或二环戊二烯。

公开(公告)号：US3984381A

公开(公告)日：1976-10-05

申请号：US586805

申请日：1975-06-13

申请人： Shozo Tsuchiya ,  Hideo Hayashi ,  Hisatake Sato

发明人： Shozo Tsuchiya ,  Hideo Hayashi ,  Hisatake Sato

IPC分类号： C08C19/28 ,  C08F8/14 ,  C09D11/10 ,  C08F18/14 ,  C08F110/00 ,  C08G63/00 ,  C08L91/00

CPC分类号： C09D11/108 ,  C08C19/28 ,  C08F8/14

摘要： A method for producing a resin for printing ink, which comprises reacting a dicylopentadiene resin with an unsaturated carboxylic acid or its anhydride, the proportion of the unsaturated carboxylic acid or its anhydride being 0.01 to 0.5 mol per 100 g of the dicyclopentadiene resin, and then esterifying the acid-modified resin so obtained with an aliphatic monohydric alcohol in an amount of 0.2 to 2.0 mols per mol of the unsaturated carboxylic acid or its anhydride used in the reaction.

摘要翻译： 一种用于印刷油墨的树脂的制造方法，其特征在于，使二氯二烯树脂与不饱和羧酸或其酸酐反应，不饱和羧酸或其酸酐的比例为0.01〜0.5摩尔/ 100g二环戊二烯树脂，然后 用脂肪族一元醇酯化所得到的酸改性树脂，其量为每摩尔反应中使用的不饱和羧酸或其酸酐为0.2〜2.0摩尔。

公开(公告)号：US4085085A

公开(公告)日：1978-04-18

申请号：US754983

申请日：1976-12-28

申请人： Shozo Tsuchiya ,  Hideo Hayashi ,  Kazuyoshi Iida ,  Kiyoshi Goto

发明人： Shozo Tsuchiya ,  Hideo Hayashi ,  Kazuyoshi Iida ,  Kiyoshi Goto

IPC分类号： C08F2/00 ,  C08F2/46 ,  C08F2/48 ,  C08F2/54 ,  C08F8/00 ,  C08F8/14 ,  C08F30/00 ,  C08F30/02 ,  C08F290/00 ,  C08F299/00 ,  C08F299/02 ,  C08G61/02 ,  C08G81/02 ,  C08L45/00 ,  C09D4/00 ,  C09D11/00 ,  C09D11/10 ,  C08L61/14 ,  C08L9/00 ,  C08L29/06

CPC分类号： C08F8/14 ,  C08G61/02 ,  C08G81/024 ,  C09D11/10 ,  C08F2810/20 ,  C08F2810/30

摘要： Curable coating compositions particularly suitable as a vehicle for printing inks, comprising a resin obtained by esterifying with acrylic or methacrylic acid a hydroxyl group-containing resin prepared either by reacting ingredients (A) and (B) to form a reaction mixture which is then reacted with ingredient (C) or by reacting the ingredients (A), (B) and (C). The ingredient (A) is a five-membered cyclic compound having conjugated double bonds or a Diels-Alder's reaction product thereof, the ingredient (B) a compound having both a polymerizable double bond and a hydroxyl group in the molecule and (C) a resol type phenolic resin.

摘要翻译： 特别适合作为印刷油墨载体的可固化涂料组合物，包括通过用丙烯酸或甲基丙烯酸酯化含羟基的树脂获得的树脂，所述树脂通过使成分（A）和（B）反应形成反应混合物，所述反应混合物然后反应 与成分（C）或通过使成分（A），（B）和（C）反应。 成分（A）是具有共轭双键的五元环化合物或狄尔斯 - 阿尔德的反应产物，成分（B）分子中具有可聚合双键和羟基的化合物和（C）a 酚醛树脂型酚醛树脂。