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    Soluble polythiophene derivatives
    1.
    发明授权
    Soluble polythiophene derivatives 有权
    可溶性聚噻吩衍生物

    公开(公告)号：US07754847B2

    公开(公告)日：2010-07-13

    申请号：US12130917

    申请日：2008-05-30

    申请人： Shu-Hua Chan ,  Teng-Chih Chao ,  Bao-Tsan Ko ,  Chih-Ping Chen ,  Chin-Sheng Lin ,  Yi-Ling Chen

    发明人： Shu-Hua Chan ,  Teng-Chih Chao ,  Bao-Tsan Ko ,  Chih-Ping Chen ,  Chin-Sheng Lin ,  Yi-Ling Chen

    IPC分类号： C08G75/00

    CPC分类号： C08F128/06 ,  C09B57/00 ,  C09B69/109

    摘要： The present invention discloses a soluble polythiophene derivative containing highly coplanar repeating units. The coplanar characteristic of the TPT (thiophene-phenylene-thiophene) units improves the degree of intramolecular conjugation and intermolecular π-π interaction. The polythiophene derivative exhibits good carrier mobility and is suitable for use in optoelectronic devices such as organic thin film transistors (OTFTs), organic light-emitting diodes (OLEDs), and organic solar cells (OSCs).

    摘要翻译： 本发明公开了含有高共面重复单元的可溶性聚噻吩衍生物。 TPT（噻吩 - 亚苯基 - 噻吩）单体的共面特性提高了分子内共轭的程度和分子间的结合程度。 相互作用。 聚噻吩衍生物具有良好的载流子迁移率，适用于有机薄膜晶体管（OTFT），有机发光二极管（OLED）和有机太阳能电池（OSC）等光电器件。

    NANOSCALE HELICAL MICROSTRUCTURES AND CHANNELS FROM CHIRAL POLY(L-LACTIDE) BLOCK CONTAINING BLOCK COPOLYMERS
    7.
    发明申请
    NANOSCALE HELICAL MICROSTRUCTURES AND CHANNELS FROM CHIRAL POLY(L-LACTIDE) BLOCK CONTAINING BLOCK COPOLYMERS 失效
    包含嵌段共聚物的聚合物（L-LACTIDE）嵌段的纳米尺寸螺旋微结构和通道

    公开(公告)号：US20060211816A1

    公开(公告)日：2006-09-21

    申请号：US10799845

    申请日：2004-03-12

    申请人： Rong-Ming Ho ,  Yeo-Wan Chiang ,  Chu-Chieh Lin ,  Bao-Tsan Ko ,  Yi-Chun Chen ,  Tsai-Ming Chung ,  Hsi-Hsin Shih ,  Jassy Wang

    发明人： Rong-Ming Ho ,  Yeo-Wan Chiang ,  Chu-Chieh Lin ,  Bao-Tsan Ko ,  Yi-Chun Chen ,  Tsai-Ming Chung ,  Hsi-Hsin Shih ,  Jassy Wang

    IPC分类号： C08F8/00

    CPC分类号： C08L53/00 ,  C08F293/005 ,  G03F7/0002

    摘要： A method for making a series of nanoscale microstructures, including helical microstructures and cylindrical microstructures. This method includes the steps of: (1) forming a chiral block copolymer containing a plurality of chiral first polymer blocks and a second polymer blocks wherein the chiral first polymer blocks have a volume fraction ranging from 20 to 49%; (2) causing a phase separation in the chiral block copolymer. In a preferred embodiment, the chiral block copolymer is poly(styrene)-poly(L-lactide) (PS-PLLA) chiral block copolymer, and the copolymerization process is a living copolymerization process which includes the following steps: (a) mixing styrene with BPO and 4-OH-TEMPO to form 4-hydroxy-TEMPO-terminated polystyrene; and (2) mixing the 4-hydroxy-TEMPO-terminated polystyrene with [(η3-EDBP)Li2]2[(η3-nBu)Li(0.5Et2O)]2 and L-lactide in an organic solvent preferably CH2Cl2 to form the poly(styrene)-poly(L-lactide) chiral block copolymer. Transmission electron microscopy (TEM) and small X-ray scattering (SAXS) studies show that when the volume fraction of poly(L-lactide) is about 35-37%, nanoscale helices with a pitch of 43.8 nanometers and a diameter of 34.4 nanometers were observed.

    摘要翻译： 制备一系列纳米级微观结构的方法，包括螺旋微结构和圆柱微结构。 该方法包括以下步骤：（1）形成含有多个手性第一聚合物嵌段的手性嵌段共聚物和第二聚合物嵌段，其中手性第一聚合物嵌段具有20至49％的体积分数; （2）引起手性嵌段共聚物中的相分离。 在优选的实施方案中，手性嵌段共聚物是聚（苯乙烯） - 聚（L-丙交酯）（PS-PLLA）手性嵌段共聚物，共聚方法是一种活性共聚方法，其包括以下步骤：（a） 用BPO和4-OH-TEMPO形成4-羟基-TEMPO封端的聚苯乙烯; 和（2）将4-羟基-TEMPO封端的聚苯乙烯与[（η3 -EBP）Li 2 N 2 [（η 在有机溶剂中，Li（0.5Et 2 O）] 2 N和L - 丙交酯 优选CH 2 2 Cl 2以形成聚（苯乙烯） - 聚（L-丙交酯）手性嵌段共聚物。 透射电子显微镜（TEM）和小X射线散射（SAXS）研究表明，当聚（L-丙交酯）的体积分数为约35-37％时，具有43.8纳米的间距和34.4纳米的直径的纳米级螺旋 被观察到。

    Nanopatterned templates from oriented degradable diblock copolymer thin films
    8.
    发明授权
    Nanopatterned templates from oriented degradable diblock copolymer thin films 有权
    来自定向可降解二嵌段共聚物薄膜的纳米图案模板

    公开(公告)号：US07632544B2

    公开(公告)日：2009-12-15

    申请号：US10850169

    申请日：2004-05-18

    申请人： Rong-Ming Ho ,  Hui-Wen Fan ,  Wen-Hsien Tseng ,  Yeo-Wan Chiang ,  Chu-Chien Lin ,  Bao-Tsan Ko ,  Bor-Hunn Huang ,  Hsi-Hsin Shih ,  Joung-Yei Chen

    发明人： Rong-Ming Ho ,  Hui-Wen Fan ,  Wen-Hsien Tseng ,  Yeo-Wan Chiang ,  Chu-Chien Lin ,  Bao-Tsan Ko ,  Bor-Hunn Huang ,  Hsi-Hsin Shih ,  Joung-Yei Chen

    IPC分类号： B05D3/00 ,  B05D5/00

    CPC分类号： C08F8/50 ,  B82Y30/00 ,  C08J5/005 ,  Y10T428/24802 ,  Y10T428/31786 ,  C08F297/00

    摘要： A nanopatterned template for use in manufacturing nanoscale objects. The nanopatterned template contains a nanoporous thin film with a periodically ordered porous geomorphology which is made from a process comprising the steps of: (a) using a block copolymerization process to prepare a block copolymer comprising first and second polymer blocks, the first and second polymer blocks being incompatible with each other; (b) forming a thin film under conditions such that the first polymer blocks form into a periodically ordered topology; and (c) selectively degrading the first polymer blocks to cause the thin film to become a nanoporous material with a periodically ordered porous geomorphology. In a preferred embodiment, the block copolymer is poly(styrene)-poly(L-lactide) (PS-PLLA) chiral block copolymer, the first polymer is poly(L-lactide), and the second polymer is polystyrene. Experimental results show that the first polymer blocks can be formed into a hexagonal cylindrical geomorphology with its axis perpendicular to a surface of the thin film. After hydrolysis to selectively degrade the first polymer blocks, a thin film having a series of repeated nanoscale hexagonal-cylindrical channels is obtained.

    摘要翻译： 用于制造纳米尺度物体的纳米图案模板。 纳米图案模板包含具有周期性排序的多孔地貌的纳米多孔薄膜，其由包括以下步骤的方法制备：（a）使用嵌段共聚方法制备包含第一和第二聚合物嵌段的嵌段共聚物，第一和第二聚合物 块相互不兼容; （b）在使第一聚合物嵌段形成周期排序的拓扑的条件下形成薄膜; 和（c）选择性降解第一聚合物嵌段以使薄膜成为具有定期多孔的地貌的纳米多孔材料。 在优选的实施方案中，嵌段共聚物是聚（苯乙烯） - 聚（L-丙交酯）（PS-PLLA）手性嵌段共聚物，第一聚合物是聚（L-丙交酯），第二聚合物是聚苯乙烯。 实验结果表明，第一聚合物嵌段可以形成六边形圆柱形地貌，其轴线垂直于薄膜表面。 在水解以选择性降解第一聚合物嵌段之后，获得具有一系列重复的纳米级六边形柱形通道的薄膜。

    Highly conductive ink composition and method for fabricating a metal conductive pattern
    9.
    发明申请
    Highly conductive ink composition and method for fabricating a metal conductive pattern 有权
    高导电性油墨组合物和金属导电图案的制造方法

    公开(公告)号：US20070154644A1

    公开(公告)日：2007-07-05

    申请号：US11439242

    申请日：2006-05-24

    申请人： Gue-Wuu Hwang ,  Bao-Tsan Ko ,  Yi-Shin Lin

    发明人： Gue-Wuu Hwang ,  Bao-Tsan Ko ,  Yi-Shin Lin

    IPC分类号： B05D3/12 ,  B05D5/00 ,  B05D3/02

    CPC分类号： H05K1/097 ,  C09D11/102 ,  H01B1/22 ,  H05K2203/121

    摘要： A viscosity controllable highly conductive ink composition. The highly conductive ink composition comprises an organic solvent, nanoscale metal particles or metallo-organic decomposition compounds, and a thermally decomposable organic polymer. Specifically, since the thermally decomposable polymer can increase the viscosity of the highly conductive ink composition and be removed by subsequent thermal treatment, so as to decrease the impact on conductivity by organic polymer. Therefore, a viscosity-controllable conductive ink composition is obtained.

    摘要翻译： 粘度可控的高导电油墨组合物。 高导电性油墨组合物包含有机溶剂，纳米金属颗粒或金属有机分解化合物，以及可热分解的有机聚合物。 具体地说，由于可热分解的聚合物可以增加高导电性油墨组合物的粘度并且通过后续的热处理去除，以便减少有机聚合物对导电性的影响。 因此，获得了粘度可控的导电油墨组合物。

    Highly conductive ink composition and method for fabricating a metal conductive pattern
    10.
    发明授权
    Highly conductive ink composition and method for fabricating a metal conductive pattern 有权
    高导电性油墨组合物和金属导电图案的制造方法

    公开(公告)号：US07806974B2

    公开(公告)日：2010-10-05

    申请号：US11439242

    申请日：2006-05-24

    申请人： Gue-Wuu Hwang ,  Bao-Tsan Ko ,  Yi-Shin Lin

    发明人： Gue-Wuu Hwang ,  Bao-Tsan Ko ,  Yi-Shin Lin

    IPC分类号： C09D11/00

    CPC分类号： H05K1/097 ,  C09D11/102 ,  H01B1/22 ,  H05K2203/121

    摘要： A viscosity controllable highly conductive ink composition. The highly conductive ink composition comprises an organic solvent, nanoscale metal particles or metallo-organic decomposition compounds, and a thermally decomposable organic polymer. Specifically, since the thermally decomposable polymer can increase the viscosity of the highly conductive ink composition and be removed by subsequent thermal treatment, so as to decrease the impact on conductivity by organic polymer. Therefore, a viscosity-controllable conductive ink composition is obtained.

    摘要翻译： 粘度可控的高导电油墨组合物。 高导电性油墨组合物包含有机溶剂，纳米金属颗粒或金属有机分解化合物，以及可热分解的有机聚合物。 具体地说，由于可热分解的聚合物可以增加高导电性油墨组合物的粘度并且通过后续的热处理去除，以便减少有机聚合物对导电性的影响。 因此，获得了粘度可控的导电油墨组合物。