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    Single site catalyst with methyl aluminoxane or borate free and their applications for the preparation of polyolefins
    4.
    发明授权
    Single site catalyst with methyl aluminoxane or borate free and their applications for the preparation of polyolefins 失效
    具有甲基铝氧烷或无硼酸盐的单中心催化剂及其在制备聚烯烃中的应用

    公开(公告)号：US6150529A

    公开(公告)日：2000-11-21

    申请号：US249511

    申请日：1999-02-12

    申请人： Shian-Jy Wang ,  Yi-Chun Chen ,  Shu-Hua Chan ,  Jing-Cherng Tsai ,  Ching Ting

    发明人： Shian-Jy Wang ,  Yi-Chun Chen ,  Shu-Hua Chan ,  Jing-Cherng Tsai ,  Ching Ting

    IPC分类号： C07F5/02 ,  C07F7/00 ,  C07F17/00 ,  C07F19/00 ,  C08F4/64

    CPC分类号： C08F10/00 ,  C08F110/02 ,  C08F4/65912 ,  Y10S526/943

    摘要： A novel organometallic compound is disclosed which can be used, in conjunction with a trialkyl or bialkyl aluminum cocatalyst, for catalyzing the polymerization and copolymerization of ethylene without requiring the use of either methyl aluminoxane or borate as cocatalyst. The organometallic compound is represented by the formula of (C.sub.5 R.sub.n H.sub.5-n)(L)MX.sub.a Y.sub.b ; wherein: (a) C.sub.5 R.sub.n H.sub.5-n is a substituted or unsubstituted cyclopentadienyl group, in which n is an integer between 0 and 5, and R is C.sub.1 to C.sub.6 alkyl group; (b) L is tetrapyrazolyl borate, hydrotrispyrazolyl borate, dihydrobispyrazolyl borate or hydrotris(3,5-dimethylpyrazolyl) borate; (c) M is a Group IIIB, Grcup IVB, or Group VB transitional metal; (d) a and b are integers such that a+b=m-2, where m is the valance of M; and (e) X and Y, which can be the same of different from each other, are halogen atoms or ligands represented by the formula of ER.sup.1 or ER.sup.1 R.sup.2, where E is a Group VA or VIA element, and R.sup.1 and R.sup.2, which can be the same or different from each other, are C.sub.1 to C.sub.6 alkyl group or substituted aryl group. Preferably, M is a Group IVB transitional metal and a=b=1, and the organometallic compound is then represented by the formula of (C.sub.5 R.sub.n H.sub.5-n)(L)MXY.

    摘要翻译： 公开了一种可与三烷基或双烷基铝助催化剂结合使用的用于催化乙烯的聚合和共聚而不需要使用甲基铝氧烷或硼酸盐作为助催化剂的新型有机金属化合物。 有机金属化合物由式（C5RnH5-n）（L）MXaYb表示; 其中：（a）C5RnH5-n是取代或未取代的环戊二烯基，其中n是0和5之间的整数，R是C1-C6烷基; （b）L是四吡唑基硼酸盐，氢四唑基硼酸盐，二氢双吡唑基硼酸盐或氢化三（3,5-二甲基吡唑基）硼酸盐; （c）M是IIIB族，Grcup IVB族或VB族过渡金属; （d）a和b是整数，使得a + b = m-2，其中m是M的化合价; 和（e）可以彼此不同的X和Y是由式ER1或ER1R2表示的卤素原子或配体，其中E是VA族或VIA族，R1和R2可以 彼此相同或不同，为C1至C6烷基或取代的芳基。 优选地，M是IVB族过渡金属，a = b = 1，有机金属化合物由式（C5RnH5-n）（L）MXY表示。

    Single site catalysts with MAO or borate free and their application for polyolefins
    5.
    发明授权
    Single site catalysts with MAO or borate free and their application for polyolefins 失效
    具有MAO或无硼酸盐的单中心催化剂及其在聚烯烃中的应用

    公开(公告)号：US5891816A

    公开(公告)日：1999-04-06

    申请号：US897862

    申请日：1997-07-21

    申请人： Shian-Jy Wang ,  Yi-Chun Chen ,  Shu-Hua Chan ,  Jing-Cherng Tsai ,  Ching Ting

    发明人： Shian-Jy Wang ,  Yi-Chun Chen ,  Shu-Hua Chan ,  Jing-Cherng Tsai ,  Ching Ting

    IPC分类号： C07F5/02 ,  C07F7/00 ,  C07F17/00 ,  C07F19/00 ,  C08F4/64

    CPC分类号： C08F10/00 ,  C08F110/02 ,  C08F4/65912 ,  Y10S526/943

    摘要： A novel organometallic compound is disclosed which can be used, in conjunction with a trialkyl or bialkyl aluminum cocatalyst, for catalyzing the polymerization and copolymerization of ethylene without requiring the use of either methyl aluminoxane or borate as cocatalyst. The organometallic compound is represented by the formula of (CR.sub.5 R.sub.n H.sub.5-n)(L)MX.sub.a Y.sub.b ; wherein: (a) C.sub.5 R.sub.n H.sub.5-n is a substituted or unsubstituted cyclopentadienyl group, in which n is an integer between 0 and 5, and R is C.sub.1 to C.sub.6 alkyl group; (b) L is tetrapyrazolyl borate, hydrotrispyrazolyl borate, dihydrobispyrazolyl borate or hydrotris(3,5-dimethylpyrazolyl) borate; (c) M is a Group IIIB, Group IVB, or Group VB transitional metal; (d) a and b are integers such that a+b=m-2, where m is the valance of M; and (e) X and Y, which can be the same of different from each other, are halogen atoms or ligands represented by the formula of ER.sup.1, where E is a Group VA or VIA element, and R.sup.1 is C.sub.1 to C.sub.6 alkyl group, aryl group or halogen-substituted aryl group. Preferably, M is a Group IVB transitional metal and a=b=1, and the organometallic compound is then represented by the formula of (C.sub.5 R.sub.n H.sub.5-n)(L)MXY.

    摘要翻译： 公开了一种可与三烷基或双烷基铝助催化剂结合使用的用于催化乙烯的聚合和共聚而不需要使用甲基铝氧烷或硼酸盐作为助催化剂的新型有机金属化合物。 有机金属化合物由式（CR5RnH5-n）（L）MXaYb表示; 其中：（a）C5RnH5-n是取代或未取代的环戊二烯基，其中n是0和5之间的整数，R是C1-C6烷基; （b）L是四吡唑基硼酸盐，氢四唑基硼酸盐，二氢双吡唑基硼酸盐或氢化三（3,5-二甲基吡唑基）硼酸盐; （c）M是IIIB族，IVB族或VB族过渡金属; （d）a和b是整数，使得a + b = m-2，其中m是M的化合价; 和（e）可以彼此不同的X和Y是由式ER1表示的卤素原子或配体，其中E是VA族或VIA族，R1是C1-C6烷基， 芳基或卤素取代的芳基。 优选地，M是IVB族过渡金属，a = b = 1，有机金属化合物由式（C5RnH5-n）（L）MXY表示。

    Process for the polymerization or copolymerization of ethylene using mao- or borate-free single site catalysts
    6.
    发明授权
    Process for the polymerization or copolymerization of ethylene using mao- or borate-free single site catalysts 失效
    使用无硼酸盐或无硼酸盐的单中心催化剂聚合或共聚乙烯的方法

    公开(公告)号：US5684098A

    公开(公告)日：1997-11-04

    申请号：US602206

    申请日：1996-02-15

    申请人： Shian-Jy Wang ,  Yi-Chun Chen ,  Shu-Hua Chan ,  Jing-Cheing Tsai ,  Ching Ting

    发明人： Shian-Jy Wang ,  Yi-Chun Chen ,  Shu-Hua Chan ,  Jing-Cheing Tsai ,  Ching Ting

    IPC分类号： C08F4/619 ,  C08F4/6192 ,  C08F4/62 ,  C08F4/622 ,  C08F4/64 ,  C08F4/642 ,  C08F10/00 ,  C08F10/02

    CPC分类号： C08F10/00 ,  C08F10/02 ,  C08F4/61908 ,  C08F4/61912 ,  C08F4/6192 ,  Y10S526/943

    摘要： A novel organometallic compound is disclosed which can be used, in conjunction with a trialkyl or bialkyl aluminum cocatalyst, for catalyzing the polymerization and copolymerization of ethylene without requiring the use of either methyl aluminoxane or borate as cocatalyst. The organometallic compound is represented by the formula of (C.sub.5 R.sub.n H.sub.5-n)(L)MX.sub.a Y.sub.b ; wherein: (a) C.sub.5 R.sub.n H.sub.5-n is a substituted or unsubstituted cyclopentadienyl group, in which n is an integer between 0 and 5, and R is C.sub.1 to C.sub.6 alkyl group; (b) L is tetrapyrazolyl borate, hydrotrispyrazolyl borate, dihydrobispyrazolyl borate or hydrotris(3,5-dimethylpyrazolyl) borate; (c) M is a Group IIIB, Group IVB, or Group VB transitional metal; (d) a and b are integers such that a+b=m-2, where m is the valance of M; and (e) X and Y, which can be the same of different from each other, are halogen atoms or ligands represented by the formula of ER.sup.1, where E is a Group VA or VIA element, and R.sup.1 is C.sub.1 to C.sub.6 alkyl group, aryl group or halogen-substituted aryl group. Preferably, M is a Group IVB transitional metal and a=b=1, and the organometallic compound is then represented by the formula of (C.sub.5 R.sub.n H.sub.5-n)(L)MXY.

    摘要翻译： 公开了一种可与三烷基或双烷基铝助催化剂结合使用的用于催化乙烯的聚合和共聚而不需要使用甲基铝氧烷或硼酸盐作为助催化剂的新型有机金属化合物。 有机金属化合物由式（C5RnH5-n）（L）MXaYb表示; 其中：（a）C5RnH5-n是取代或未取代的环戊二烯基，其中n是0和5之间的整数，R是C1-C6烷基; （b）L是四吡唑基硼酸盐，氢四唑基硼酸盐，二氢双吡唑基硼酸盐或氢化三（3,5-二甲基吡唑基）硼酸盐; （c）M是IIIB族，IVB族或VB族过渡金属; （d）a和b是整数，使得a + b = m-2，其中m是M的化合价; 和（e）可以彼此不同的X和Y是由式ER1表示的卤素原子或配体，其中E是VA族或VIA族，R1是C1-C6烷基， 芳基或卤素取代的芳基。 优选地，M是IVB族过渡金属，a = b = 1，有机金属化合物由式（C5RnH5-n）（L）MXY表示。

    Nanoscale helical microstructures and channels from chiral poly(L-lactide) block containing block copolymers
    7.
    发明授权
    Nanoscale helical microstructures and channels from chiral poly(L-lactide) block containing block copolymers 失效
    来自手性聚（L-丙交酯）嵌段的嵌段共聚物的纳米级螺旋微结构和通道

    公开(公告)号：US07135523B2

    公开(公告)日：2006-11-14

    申请号：US10799845

    申请日：2004-03-12

    申请人： Rong-Ming Ho ,  Yeo-Wan Chiang ,  Chu-Chieh Lin ,  Bao-Tsan Ko ,  Yi-Chun Chen ,  Tsai-Ming Chung ,  Hsi-Hsin Shih ,  Jassy S. J. Wang

    发明人： Rong-Ming Ho ,  Yeo-Wan Chiang ,  Chu-Chieh Lin ,  Bao-Tsan Ko ,  Yi-Chun Chen ,  Tsai-Ming Chung ,  Hsi-Hsin Shih ,  Jassy S. J. Wang

    IPC分类号： C08G63/08

    CPC分类号： C08L53/00 ,  C08F293/005 ,  G03F7/0002

    摘要： A method for making a series of nanoscale microstructures, including helical microstructures and cylindrical microstrustures. This method includes the steps of: (1) forming a chiral block copolymer containing a plurality of chiral first polymer blocks and a second polymer blocks wherein the chiral first polymer blocks have a volume fraction ranging from 20 to 49%; (2) causing a phase separation in the chiral block copolymer. In a preferred embodiment, the chiral block copolymer is poly(styrene)-poly(L-lactide) (PS-PLLA) chiral block copolymer, and the copolymerization process is a living copolymerization process which includes the following steps: (a) mixing styrene with BPO and 4-OH-TEMPO to form 4-hydroxy-TEMPO-terminated polystyrene; and (2) mixing the 4-hydroxy-TEMPO-terminated polystyrene with [η3-EDBP)Li2]2[(η3-nBu)Li(0.5Et2O)]2 and L-lactide in an organic solvent preferably CH2Cl2 to form the poly(styrene)-poly(L-lactide) chiral block copolymer. Transmission electron microscopy (TEM) and small X-ray scattering (SAXS) studies show that when the volume fraction of poly(L-lactide) is about 35–37%, nanoscale helices with a pitch of 43.8 nanometers and a diameter of 34.4 nanometers were observed.

    摘要翻译： 一种制备一系列纳米级微观结构的方法，包括螺旋微结构和圆柱形微结构。 该方法包括以下步骤：（1）形成含有多个手性第一聚合物嵌段的手性嵌段共聚物和第二聚合物嵌段，其中手性第一聚合物嵌段具有20至49％的体积分数; （2）引起手性嵌段共聚物中的相分离。 在优选的实施方案中，手性嵌段共聚物是聚（苯乙烯） - 聚（L-丙交酯）（PS-PLLA）手性嵌段共聚物，共聚方法是一种活性共聚方法，其包括以下步骤：（a） 用BPO和4-OH-TEMPO形成4-羟基-TEMPO封端的聚苯乙烯; 和（2）将4-羟基-TEMPO封端的聚苯乙烯与[η3 -EDBP] Li 2 N 2 [2] 优选的有机溶剂中的L 3→N 2→Bu）Li（0.5E 2 O 2）2 N 2和L-丙交酯 CH 2 2 Cl 2以形成聚（苯乙烯） - 聚（L-丙交酯）手性嵌段共聚物。 透射电子显微镜（TEM）和小X射线散射（SAXS）研究表明，当聚（L-丙交酯）的体积分数为约35-37％时，具有43.8纳米的间距和34.4纳米的直径的纳米级螺旋 被观察到。

    NANOSCALE HELICAL MICROSTRUCTURES AND CHANNELS FROM CHIRAL POLY(L-LACTIDE) BLOCK CONTAINING BLOCK COPOLYMERS
    8.
    发明申请
    NANOSCALE HELICAL MICROSTRUCTURES AND CHANNELS FROM CHIRAL POLY(L-LACTIDE) BLOCK CONTAINING BLOCK COPOLYMERS 失效
    包含嵌段共聚物的聚合物（L-LACTIDE）嵌段的纳米尺寸螺旋微结构和通道

    公开(公告)号：US20060211816A1

    公开(公告)日：2006-09-21

    申请号：US10799845

    申请日：2004-03-12

    申请人： Rong-Ming Ho ,  Yeo-Wan Chiang ,  Chu-Chieh Lin ,  Bao-Tsan Ko ,  Yi-Chun Chen ,  Tsai-Ming Chung ,  Hsi-Hsin Shih ,  Jassy Wang

    发明人： Rong-Ming Ho ,  Yeo-Wan Chiang ,  Chu-Chieh Lin ,  Bao-Tsan Ko ,  Yi-Chun Chen ,  Tsai-Ming Chung ,  Hsi-Hsin Shih ,  Jassy Wang

    IPC分类号： C08F8/00

    CPC分类号： C08L53/00 ,  C08F293/005 ,  G03F7/0002

    摘要： A method for making a series of nanoscale microstructures, including helical microstructures and cylindrical microstructures. This method includes the steps of: (1) forming a chiral block copolymer containing a plurality of chiral first polymer blocks and a second polymer blocks wherein the chiral first polymer blocks have a volume fraction ranging from 20 to 49%; (2) causing a phase separation in the chiral block copolymer. In a preferred embodiment, the chiral block copolymer is poly(styrene)-poly(L-lactide) (PS-PLLA) chiral block copolymer, and the copolymerization process is a living copolymerization process which includes the following steps: (a) mixing styrene with BPO and 4-OH-TEMPO to form 4-hydroxy-TEMPO-terminated polystyrene; and (2) mixing the 4-hydroxy-TEMPO-terminated polystyrene with [(η3-EDBP)Li2]2[(η3-nBu)Li(0.5Et2O)]2 and L-lactide in an organic solvent preferably CH2Cl2 to form the poly(styrene)-poly(L-lactide) chiral block copolymer. Transmission electron microscopy (TEM) and small X-ray scattering (SAXS) studies show that when the volume fraction of poly(L-lactide) is about 35-37%, nanoscale helices with a pitch of 43.8 nanometers and a diameter of 34.4 nanometers were observed.

    摘要翻译： 制备一系列纳米级微观结构的方法，包括螺旋微结构和圆柱微结构。 该方法包括以下步骤：（1）形成含有多个手性第一聚合物嵌段的手性嵌段共聚物和第二聚合物嵌段，其中手性第一聚合物嵌段具有20至49％的体积分数; （2）引起手性嵌段共聚物中的相分离。 在优选的实施方案中，手性嵌段共聚物是聚（苯乙烯） - 聚（L-丙交酯）（PS-PLLA）手性嵌段共聚物，共聚方法是一种活性共聚方法，其包括以下步骤：（a） 用BPO和4-OH-TEMPO形成4-羟基-TEMPO封端的聚苯乙烯; 和（2）将4-羟基-TEMPO封端的聚苯乙烯与[（η3 -EBP）Li 2 N 2 [（η 在有机溶剂中，Li（0.5Et 2 O）] 2 N和L - 丙交酯 优选CH 2 2 Cl 2以形成聚（苯乙烯） - 聚（L-丙交酯）手性嵌段共聚物。 透射电子显微镜（TEM）和小X射线散射（SAXS）研究表明，当聚（L-丙交酯）的体积分数为约35-37％时，具有43.8纳米的间距和34.4纳米的直径的纳米级螺旋 被观察到。

    Organometallic catalysts containing hydrotris(pyrazolyl) borate and cyclopentadienyl groups, and processes of employing the same
    9.
    发明授权
    Organometallic catalysts containing hydrotris(pyrazolyl) borate and cyclopentadienyl groups, and processes of employing the same 失效
    含有氢三（吡唑基）硼酸酯和环戊二烯基的有机金属催化剂及其应用方法

    公开(公告)号：US5519099A

    公开(公告)日：1996-05-21

    申请号：US481113

    申请日：1995-06-07

    申请人： Shian-Jy Wang ,  Yi-Chun Chen ,  Shu-Hua Chan ,  Jing-Cherng Tsai ,  Yu-Hwa E. Sheu

    发明人： Shian-Jy Wang ,  Yi-Chun Chen ,  Shu-Hua Chan ,  Jing-Cherng Tsai ,  Yu-Hwa E. Sheu

    IPC分类号： C08F4/619 ,  C08F4/6192 ,  C08F4/62 ,  C08F4/622 ,  C08F4/64 ,  C08F4/642 ,  C08F10/00 ,  C08F10/02

    CPC分类号： C08F10/00 ,  C08F10/02 ,  C08F4/61908 ,  C08F4/61912 ,  C08F4/6192 ,  Y10S526/943

    摘要： A catalyst composition is disclosed for catalyzing the polymerization and copolymerization reactions of ethylene monomers, with or without another olefin monomer. The catalyst composition comprises a metallocene compound represented by the the formula of (C.sub.5 R.sub.n H.sub.5-n)(L)MXY or the formula of (C.sub.5 R.sub.n H.sub.5-n)(L)MX.sup.+ A.sup.- ; wherein: (a) C.sub.5 R.sub.n H.sub.5-n is a substituted or unsubstituted cyclopendadienyl group; (b) L is tetrapyrazolyl borate, hydrotrispyrazolyl borate, dihydrotrispyrazolyl borate or hydrotris-3,5-dimethyl; (c) M is Group IIIB, Group IVB, or Group VB transitional metal; (d) X is a C.sub.1 to C.sub.4 alkyl or alkenyl group, an aromatic group, an alkylaryl, a halogen, a hydrogen, or a silane group; (e) Y, which can the same as or different from X, is a C.sub.1 to C.sub.4 alkyl or alkenyl group, an aromatic group, an alkylaryl, a halogen, a hydrogen, or a silane group; and (f) A.sup.- is non-coordinated or loosely coordinated bulky anion. Examples of the (C.sub.5 R.sub.n H.sub.5-n)(L)MXY and (C.sub.5 R.sub.n H.sub.5-n)(L)MX.sup.+ A.sup.- metallocene compounds are represented by the following formulas: ##STR1## respectively.

    摘要翻译： 公开了用于催化乙烯单体与或不与其它烯烃单体的聚合和共聚反应的催化剂组合物。 催化剂组合物包含由式（C5RnH5-n）（L）MXY或式（C5RnH5-n）（L）MX + A-表示的茂金属化合物; 其中：（a）C5RnH5-n是取代或未取代的环戊二烯基; （b）L是四吡唑基硼酸盐，氢四唑基硼酸盐，二氢四吡啶基硼酸盐或氢化三-3,5-二甲基; （c）M为IIIB族，IVB族或VB族过渡金属; （d）X是C1-C4烷基或烯基，芳基，烷基芳基，卤素，氢或硅烷基; （e）与X相同或不同的Y为C1-C4烷基或烯基，芳基，烷基芳基，卤素，氢或硅烷基; 和（f）A-是非协调或松散配位的大体积阴离子。 （C5RnH5-n）（L）MXY和（C5RnH5-n）（L）MX + A-茂金属化合物的实例分别由下式表示：和。