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公开(公告)号：US06979756B2
公开(公告)日：2005-12-27
申请号：US10281645
申请日：2002-10-28
申请人： Shun C. Fung , Marcel J. G. Janssen , Stephen N. Vaughn , Machteld M. Mertens , Albert Edward Schweizer , Cornelius W. M. Van Oorschot , Luc R. M. Martens , Richard B. Hall , Wilfried J. Mortier , Ronald G. Searle , Yi-Gang Xiong
发明人： Shun C. Fung , Marcel J. G. Janssen , Stephen N. Vaughn , Machteld M. Mertens , Albert Edward Schweizer , Cornelius W. M. Van Oorschot , Luc R. M. Martens , Richard B. Hall , Wilfried J. Mortier , Ronald G. Searle , Yi-Gang Xiong
CPC分类号： C01B39/02 , B01J29/04 , B01J29/85 , B01J37/084 , B01J2229/14 , B01J2229/24 , B01J2229/40 , B01J2229/42 , C01B37/00 , C07C1/20 , C07C2529/85 , C07C11/02
摘要： Disclosed is a method of heat treating a molecular sieve. The method comprises providing a template-containing molecular sieve, heating the molecular sieve under conditions effective to remove a portion of the template from the molecular sieve, and cooling the heated molecular sieve to leave an amount of template effective to cover catalytic sites within the molecular sieve. A catalyst composition is also provided which comprises a molecular sieve having a microporous structure and a binder, wherein between 10 and 90 vol % of the microporous structure is occupied by a material, the material comprising a template or a carbonaceous residue of a template, and the catalyst composition exhibits a Davison Index of not greater than 30.
摘要翻译： 公开了分子筛热处理方法。 该方法包括提供含模板的分子筛，在有效从分子筛除去一部分模板的条件下加热分子筛，并冷却加热的分子筛，留下一定量的模板，以有效地覆盖分子内的催化位点 筛。 还提供了一种催化剂组合物，其包括具有微孔结构和粘合剂的分子筛，其中10至90体积％的微孔结构被材料占据，所述材料包含模板或模板的碳质残余物，以及 催化剂组合物的Davison指数不大于30。
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公开(公告)号：US06503863B2
公开(公告)日：2003-01-07
申请号：US09929949
申请日：2001-08-15
申请人： Shun C. Fung , Marcel J. G. Janssen , Stephen N. Vaughn , Machteld M. Mertens , Albert Edward Schweizer , Luc R. M. Martens , Richard B. Hall , Wilfried J. Mortier , Ronald G. Searle , Yi-Gang Xiong
发明人： Shun C. Fung , Marcel J. G. Janssen , Stephen N. Vaughn , Machteld M. Mertens , Albert Edward Schweizer , Luc R. M. Martens , Richard B. Hall , Wilfried J. Mortier , Ronald G. Searle , Yi-Gang Xiong
IPC分类号： B01J27182
CPC分类号： C01B39/02 , B01J29/04 , B01J29/85 , B01J37/084 , B01J2229/14 , B01J2229/24 , B01J2229/40 , B01J2229/42 , C01B37/00 , C07C1/20 , C07C2529/85 , C07C11/02
摘要： Disclosed is a method of heat treating a molecular sieve. The method comprises providing a template-containing molecular sieve, heating the molecular sieve under conditions effective to remove a portion of the template from the molecular sieve, and cooling the heated molecular sieve to leave an amount of template effective to cover catalytic sites within the molecular sieve. A catalyst composition is also provided which comprises a molecular sieve having a microporous structure and a binder, wherein between 10 and 90 vol % of the microporous structure is occupied by a material, the material comprising a template or a carbonaceous residue of a template, and the catalyst composition exhibits a Davison Index of not greater than 30.
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公开(公告)号：US06395674B1
公开(公告)日：2002-05-28
申请号：US09399675
申请日：1999-09-21
申请人： Shun C. Fung , Marcel J. G. Janssen , Stephen N. Vaughn , Machteld M. Mertens , Albert E. Schweizer , Luc R. M. Martens , Richard B. Hall , Wilfried J. Mortier , Ronald G. Searle , Yi-Gang Xiong
发明人： Shun C. Fung , Marcel J. G. Janssen , Stephen N. Vaughn , Machteld M. Mertens , Albert E. Schweizer , Luc R. M. Martens , Richard B. Hall , Wilfried J. Mortier , Ronald G. Searle , Yi-Gang Xiong
IPC分类号： B01J27182
CPC分类号： C01B39/02 , B01J29/04 , B01J29/85 , B01J37/084 , B01J2229/14 , B01J2229/24 , B01J2229/40 , B01J2229/42 , C01B37/00 , C07C1/20 , C07C2529/85 , C07C11/02
摘要： Disclosed is a method of heat treating a molecular sieve. The method comprises providing a template-containing molecular sieve, heating the molecular sieve under conditions effective to remove a portion of the template from the molecular sieve, and cooling the heated molecular sieve to leave an amount of template effective to cover catalytic sites within the molecular sieve. A catalyst composition is also provided which comprises a molecular sieve having a microporous structure and a binder, wherein between 10 and 90 vol % of the microporous structure is occupied by a material, the material comprising a template or a carbonaceous residue of a template, and the catalyst composition exhibits a Davison Index of not greater than 30.
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公开(公告)号：US20060086645A1
公开(公告)日：2006-04-27
申请号：US10974666
申请日：2004-10-27
申请人： Kerry Rock , Yi-Gang Xiong , Arvids Judzis
发明人： Kerry Rock , Yi-Gang Xiong , Arvids Judzis
CPC分类号： C10G45/00 , C10G2400/02
摘要： A process for the production of low sulfur, low olefin gasoline wherein a cracked naphtha, such as a full boiling range cracked naphtha, is first separated by fractional distillation into at least two fractions while simultaneously selectively hydrogenating the polyunsaturated compounds contained therein. The mono olefins in the light fraction are then subjected to etherification with alcohol to produce ethers or hydration with water to produce alcohols. The heavy fraction is subjected to sulfur removal by hydrodesulfurization or chemisorption. The two fractions are then combined to produce a low sulfur, low olefin gasoline.
摘要翻译： 一种生产低硫低烯烃汽油的方法，其中裂解石脑油，例如全沸点裂化石脑油首先通过分馏分离成至少两个馏分，同时选择性地氢化其中所含的多不饱和化合物。 然后将轻馏分中的单烯烃与醇进行醚化，以产生醚或与水合成以产生醇。 重馏分通过加氢脱硫或化学吸附进行除硫。 然后将两个级分组合以产生低硫，低烯烃汽油。
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公开(公告)号：US20090193710A1
公开(公告)日：2009-08-06
申请号：US12025476
申请日：2008-02-04
IPC分类号： C10L1/185
CPC分类号： C10L1/1852 , C10G2300/30 , C10G2300/305 , C10L1/023
摘要： A fuel or fuel blendstock comprising ethanol, ethyl ethers, olefins, and alkanes. In some embodiments, the fuel or fuel blendstock of claim 1, wherein the fuel or fuel blendstock may have an octane number greater than 92 (RON+MON)/2). In other embodiments, the fuel or fuel blendstock may have a Reid vapor pressure less than 7.2 psi. Also disclosed is a process for the production of a fuel, the process including: contacting ethanol and at least one gasoline fraction including alkanes and olefins in the presence of a catalyst to form a fuel mixture including ethyl ethers, alkanes, unreacted olefins, and unreacted ethanol; and recovering the fuel mixture for use as a gasoline or gasoline blendstock without separation of the ethanol from the fuel mixture.
摘要翻译： 包含乙醇，乙醚，烯烃和烷烃的燃料或燃料混合料。 在一些实施方案中，权利要求1的燃料或燃料混合原料，其中所述燃料或燃料混合原料可具有大于92（RON + MON）/ 2的辛烷值。 在其它实施方案中，燃料或燃料混合原料可具有小于7.2psi的Reid蒸气压。 还公开了一种生产燃料的方法，该方法包括：在催化剂存在下使乙醇和至少一种包含烷烃和烯烃的汽油馏分接触，形成包括乙醚，烷烃，未反应烯烃和未反应的燃料混合物 乙醇; 以及回收燃料混合物以用作汽油或汽油混合料，而不将乙醇与燃料混合物分离。
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公开(公告)号：US07431827B2
公开(公告)日：2008-10-07
申请号：US10974666
申请日：2004-10-27
申请人： Kerry L. Rock , Yi-Gang Xiong , Arvids Judzis, Jr.
发明人： Kerry L. Rock , Yi-Gang Xiong , Arvids Judzis, Jr.
IPC分类号： C10G45/02
CPC分类号： C10G45/00 , C10G2400/02
摘要： A process for the production of low sulfur, low olefin gasoline wherein a cracked naphtha, such as a full boiling range cracked naphtha, is first separated by fractional distillation into at least two fractions while simultaneously selectively hydrogenating the polyunsaturated compounds contained therein. The mono olefins in the light fraction are then subjected to etherification with alcohol to produce ethers or hydration with water to produce alcohols. The heavy fraction is subjected to sulfur removal by hydrodesulfurization or chemisorption. The two fractions are then combined to produce a low sulfur, low olefin gasoline.
摘要翻译： 一种生产低硫低烯烃汽油的方法，其中裂解石脑油，例如全沸点裂化石脑油首先通过分馏分离成至少两个馏分，同时选择性地氢化其中所含的多不饱和化合物。 然后将轻馏分中的单烯烃与醇进行醚化，以产生醚或与水合成以产生醇。 重馏分通过加氢脱硫或化学吸附进行除硫。 然后将两个级分组合以产生低硫，低烯烃汽油。
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7.发明授权公开(公告)号：US06448197B1
公开(公告)日：2002-09-10
申请号：US09615526
申请日：2000-07-13
申请人： Zhongmin Liu , Lixin Yang , Lei Xu , Chenglin Sun , Yi-Gang Xiong
发明人： Zhongmin Liu , Lixin Yang , Lei Xu , Chenglin Sun , Yi-Gang Xiong
IPC分类号： B01J2985
CPC分类号： B01J29/85 , B01J29/76 , B01J29/90 , B01J37/086 , B01J38/50 , B01J38/52 , B01J2229/18 , C07C1/20 , C07C2529/83 , C07C2529/85 , C10G3/45 , C10G3/49 , C10G2300/4006 , C10G2300/703 , C10G2300/708 , C10G2400/20 , Y02P20/584 , Y02P30/20 , Y02P30/42 , Y10S423/30 , C07C11/02
摘要： A molecular sieve and a molecular sieve catalyst containing a surface heat impregnated with a metal. The molecular sieve is heated in the presence of a metal containing solution at a temperature between 30° C. and 400° C. then separated from the metal containing solution. The molecular sieve and molecular sieve catalyst is used to make olefin from an oxygenate feedstock.
摘要翻译： 分子筛和含有浸渍有金属的表面热分子筛催化剂。 分子筛在含金属溶液的存在下在30℃和400℃之间的温度下加热，然后与含金属溶液分离。 分子筛和分子筛催化剂用于从含氧化合物原料制备烯烃。
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