公开(公告)号：US06979756B2

公开(公告)日：2005-12-27

申请号：US10281645

申请日：2002-10-28

申请人： Shun C. Fung ,  Marcel J. G. Janssen ,  Stephen N. Vaughn ,  Machteld M. Mertens ,  Albert Edward Schweizer ,  Cornelius W. M. Van Oorschot ,  Luc R. M. Martens ,  Richard B. Hall ,  Wilfried J. Mortier ,  Ronald G. Searle ,  Yi-Gang Xiong

发明人： Shun C. Fung ,  Marcel J. G. Janssen ,  Stephen N. Vaughn ,  Machteld M. Mertens ,  Albert Edward Schweizer ,  Cornelius W. M. Van Oorschot ,  Luc R. M. Martens ,  Richard B. Hall ,  Wilfried J. Mortier ,  Ronald G. Searle ,  Yi-Gang Xiong

IPC分类号： B01J29/04 ,  B01J29/85 ,  B01J35/00 ,  B01J37/08 ,  C01B37/00 ,  C01B39/02 ,  C07C1/20 ,  C07C1/02

CPC分类号： C01B39/02 ,  B01J29/04 ,  B01J29/85 ,  B01J37/084 ,  B01J2229/14 ,  B01J2229/24 ,  B01J2229/40 ,  B01J2229/42 ,  C01B37/00 ,  C07C1/20 ,  C07C2529/85 ,  C07C11/02

摘要： Disclosed is a method of heat treating a molecular sieve. The method comprises providing a template-containing molecular sieve, heating the molecular sieve under conditions effective to remove a portion of the template from the molecular sieve, and cooling the heated molecular sieve to leave an amount of template effective to cover catalytic sites within the molecular sieve. A catalyst composition is also provided which comprises a molecular sieve having a microporous structure and a binder, wherein between 10 and 90 vol % of the microporous structure is occupied by a material, the material comprising a template or a carbonaceous residue of a template, and the catalyst composition exhibits a Davison Index of not greater than 30.

摘要翻译： 公开了分子筛热处理方法。 该方法包括提供含模板的分子筛，在有效从分子筛除去一部分模板的条件下加热分子筛，并冷却加热的分子筛，留下一定量的模板，以有效地覆盖分子内的催化位点 筛。 还提供了一种催化剂组合物，其包括具有微孔结构和粘合剂的分子筛，其中10至90体积％的微孔结构被材料占据，所述材料包含模板或模板的碳质残余物，以及 催化剂组合物的Davison指数不大于30。

公开(公告)号：US06503863B2

公开(公告)日：2003-01-07

申请号：US09929949

申请日：2001-08-15

申请人： Shun C. Fung ,  Marcel J. G. Janssen ,  Stephen N. Vaughn ,  Machteld M. Mertens ,  Albert Edward Schweizer ,  Luc R. M. Martens ,  Richard B. Hall ,  Wilfried J. Mortier ,  Ronald G. Searle ,  Yi-Gang Xiong

发明人： Shun C. Fung ,  Marcel J. G. Janssen ,  Stephen N. Vaughn ,  Machteld M. Mertens ,  Albert Edward Schweizer ,  Luc R. M. Martens ,  Richard B. Hall ,  Wilfried J. Mortier ,  Ronald G. Searle ,  Yi-Gang Xiong

IPC分类号： B01J27182

CPC分类号： C01B39/02 ,  B01J29/04 ,  B01J29/85 ,  B01J37/084 ,  B01J2229/14 ,  B01J2229/24 ,  B01J2229/40 ,  B01J2229/42 ,  C01B37/00 ,  C07C1/20 ,  C07C2529/85 ,  C07C11/02

摘要： Disclosed is a method of heat treating a molecular sieve. The method comprises providing a template-containing molecular sieve, heating the molecular sieve under conditions effective to remove a portion of the template from the molecular sieve, and cooling the heated molecular sieve to leave an amount of template effective to cover catalytic sites within the molecular sieve. A catalyst composition is also provided which comprises a molecular sieve having a microporous structure and a binder, wherein between 10 and 90 vol % of the microporous structure is occupied by a material, the material comprising a template or a carbonaceous residue of a template, and the catalyst composition exhibits a Davison Index of not greater than 30.

公开(公告)号：US06395674B1

公开(公告)日：2002-05-28

申请号：US09399675

申请日：1999-09-21

申请人： Shun C. Fung ,  Marcel J. G. Janssen ,  Stephen N. Vaughn ,  Machteld M. Mertens ,  Albert E. Schweizer ,  Luc R. M. Martens ,  Richard B. Hall ,  Wilfried J. Mortier ,  Ronald G. Searle ,  Yi-Gang Xiong

发明人： Shun C. Fung ,  Marcel J. G. Janssen ,  Stephen N. Vaughn ,  Machteld M. Mertens ,  Albert E. Schweizer ,  Luc R. M. Martens ,  Richard B. Hall ,  Wilfried J. Mortier ,  Ronald G. Searle ,  Yi-Gang Xiong

IPC分类号： B01J27182

CPC分类号： C01B39/02 ,  B01J29/04 ,  B01J29/85 ,  B01J37/084 ,  B01J2229/14 ,  B01J2229/24 ,  B01J2229/40 ,  B01J2229/42 ,  C01B37/00 ,  C07C1/20 ,  C07C2529/85 ,  C07C11/02

摘要： Disclosed is a method of heat treating a molecular sieve. The method comprises providing a template-containing molecular sieve, heating the molecular sieve under conditions effective to remove a portion of the template from the molecular sieve, and cooling the heated molecular sieve to leave an amount of template effective to cover catalytic sites within the molecular sieve. A catalyst composition is also provided which comprises a molecular sieve having a microporous structure and a binder, wherein between 10 and 90 vol % of the microporous structure is occupied by a material, the material comprising a template or a carbonaceous residue of a template, and the catalyst composition exhibits a Davison Index of not greater than 30.

公开(公告)号：US06316683B1

公开(公告)日：2001-11-13

申请号：US09391770

申请日：1999-09-08

申请人： Marcel J. G. Janssen ,  Cornelius W. M. Van Oorschot ,  Shun C. Fung ,  Luc R. M. Martens ,  Wilfried J. Mortier ,  Ronald G. Searle ,  Machteld M. Mertens ,  Stephen N. Vaughn

发明人： Marcel J. G. Janssen ,  Cornelius W. M. Van Oorschot ,  Shun C. Fung ,  Luc R. M. Martens ,  Wilfried J. Mortier ,  Ronald G. Searle ,  Machteld M. Mertens ,  Stephen N. Vaughn

IPC分类号： C07C120

CPC分类号： B01J37/08 ,  B01J29/85 ,  B01J2229/24 ,  B01J2229/40 ,  C07C1/20 ,  C07C2529/85 ,  C10G3/49 ,  C10G2300/4018 ,  C10G2400/20 ,  Y02P30/42 ,  C07C11/02

摘要： This invention is directed to a method of making an olefin product from an oxygenate feedstock and a method of protecting catalytic activity of a silicoaluminophosphate molecular sieve. The methods comprise providing a silicoaluminophosphate molecular sieve having catalytic sites within the molecular sieve; shielding the catalytic sites to protect from loss of catalytic activity; and contacting the protected sieve in its activated state with an oxygenate feedstock under conditions effective to produce an olefin product before undesirable loss of catalytic activity. Undesirable loss in catalytic activity occurs when activated molecular sieve contacting the oxygenate feedstock has a methanol uptake index of at least 0.15.

公开(公告)号：US07345213B2

公开(公告)日：2008-03-18

申请号：US10615753

申请日：2003-07-09

申请人： Marcel J. G. Janssen ,  Cornelius W. M. Van Oorschot ,  Shun C. Fung ,  Luc R. M. Martens ,  Wilfried J. Mortier ,  Ronald G. Searle ,  Machteld M. Mertens ,  Stephen N. Vaughn

发明人： Marcel J. G. Janssen ,  Cornelius W. M. Van Oorschot ,  Shun C. Fung ,  Luc R. M. Martens ,  Wilfried J. Mortier ,  Ronald G. Searle ,  Machteld M. Mertens ,  Stephen N. Vaughn

IPC分类号： C01C1/00 ,  B01J27/82

CPC分类号： B01J29/85 ,  B01J37/08 ,  B01J2229/24 ,  B01J2229/40 ,  B23K1/002 ,  B23K2101/06 ,  C07C1/20 ,  C07C2529/85 ,  Y02P30/20 ,  Y10S502/514 ,  Y10S585/906 ,  C07C11/02

摘要： This invention is directed to a method of making an olefin product from an oxygenate feedstock and a method of protecting catalytic activity of a silicoaluminophosphate molecular sieve. The methods comprise providing a silicoaluminophosphate molecular sieve having catalytic sites within the molecular sieve; shielding the catalytic sites to protect from loss of catalytic activity; and contacting the protected sieve in its activated state with an oxygenate feedstock under conditions effective to produce an olefin product before undesirable loss of catalytic activity. Undesirable loss in catalytic activity occurs when activated molecular sieve contacting the oxygenate feedstock has a methanol uptake index of at least 0.15.

摘要翻译： 本发明涉及从含氧化合物原料制备烯烃产物的方法和保护硅铝磷酸盐分子筛的催化活性的方法。 所述方法包括提供在分子筛内具有催化位点的硅铝磷酸盐分子筛; 屏蔽催化部位以防止催化活性的丧失; 并且在有效产生烯烃产物的条件下，在不期望的催化活性丧失之前，将处于其活化状态的受保护筛与含氧化合物原料接触。 当活化分子筛与含氧化合物原料接触的甲醇吸收指数至少为0.15时，催化活性就会出现不希望的损失。

公开(公告)号：US06455748B2

公开(公告)日：2002-09-24

申请号：US09760289

申请日：2001-01-12

申请人： Marcel J. G. Janssen ,  Cornelius W. M. Van Oorschot ,  Shun C. Fung ,  Luc R. M. Martens ,  Wilfried J. Mortier ,  Ronald G. Searle ,  Machteld M. Mertens ,  Stephen N. Vaughn

发明人： Marcel J. G. Janssen ,  Cornelius W. M. Van Oorschot ,  Shun C. Fung ,  Luc R. M. Martens ,  Wilfried J. Mortier ,  Ronald G. Searle ,  Machteld M. Mertens ,  Stephen N. Vaughn

IPC分类号： C07C100

CPC分类号： B01J37/08 ,  B01J29/85 ,  B01J2229/24 ,  B01J2229/40 ,  C07C1/20 ,  C07C2529/85 ,  C10G3/49 ,  C10G2300/4018 ,  C10G2400/20 ,  Y02P30/42 ,  C07C11/02

摘要： This invention is directed to a method of making an olefin product from an oxygenate feedstock and a method of protecting catalytic activity of a silicoaluminophosphate molecular sieve. The methods comprise providing a silicoaluminophosphate molecular sieve having catalytic sites within the molecular sieve; shielding the catalytic sites to protect from loss of catalytic activity; and contacting the protected sieve in its activated state with an oxygenate feedstock under conditions effective to produce an olefin product before undesirable loss of catalytic activity. Undesirable loss in catalytic activity occurs when activated molecular sieve contacting the oxygenate feedstock has a methanol uptake index of at least 0.15.

摘要翻译： 本发明涉及从含氧化合物原料制备烯烃产物的方法和保护硅铝磷酸盐分子筛的催化活性的方法。 所述方法包括提供在分子筛内具有催化位点的硅铝磷酸盐分子筛; 屏蔽催化部位以防止催化活性的丧失; 并且在有效产生烯烃产物的条件下，在不期望的催化活性丧失之前，将处于其活化状态的受保护筛与含氧化合物原料接触。 当活化分子筛与含氧化合物原料接触的甲醇吸收指数至少为0.15时，催化活性就会出现不希望的损失。

公开(公告)号：US06797852B2

公开(公告)日：2004-09-28

申请号：US10206574

申请日：2002-07-26

申请人： Marcel J. G. Janssen ,  Cornelius W. M. Van Oorschot ,  Shun C. Fung ,  Luc R. M. Martens ,  Wilfried J. Mortier ,  Ronald G. Searle ,  Machteld M. Mertens ,  Stephen N. Vaughn

发明人： Marcel J. G. Janssen ,  Cornelius W. M. Van Oorschot ,  Shun C. Fung ,  Luc R. M. Martens ,  Wilfried J. Mortier ,  Ronald G. Searle ,  Machteld M. Mertens ,  Stephen N. Vaughn

IPC分类号： C07C100

CPC分类号： B01J29/85 ,  B01J37/08 ,  B01J2229/24 ,  B01J2229/40 ,  B23K1/002 ,  B23K2101/06 ,  C07C1/20 ,  C07C2529/85 ,  Y02P30/20 ,  Y10S502/514 ,  Y10S585/906 ,  C07C11/02

摘要： This invention is directed to a method of making an olefin product from an oxygenate feedstock and a method of protecting catalytic activity of a silicoaluminophosphate molecular sieve. The methods comprise providing a silicoaluminophosphate molecular sieve having catalytic sites within the molecular sieve; shielding the catalytic sites to protect from loss of catalytic activity; and contacting the protected sieve in its activated state with an oxygenate feedstock under conditions effective to produce an olefin product before undesirable loss of catalytic activity. Undesirable loss in catalytic activity occurs when activated molecular sieve contacting the oxygenate feedstock has a methanol uptake index of at least 0.15.

公开(公告)号：US06482999B2

公开(公告)日：2002-11-19

申请号：US09251142

申请日：1999-02-17

申请人： Shun C. Fung ,  James R. Lattner ,  Stephen N. Vaughn ,  Richard B. Hall ,  Hsiang-Ning Sun ,  Ron G. Searle ,  Luc R. M. Martens

发明人： Shun C. Fung ,  James R. Lattner ,  Stephen N. Vaughn ,  Richard B. Hall ,  Hsiang-Ning Sun ,  Ron G. Searle ,  Luc R. M. Martens

IPC分类号： C07C1207

CPC分类号： B01J38/12 ,  B01J29/04 ,  B01J29/85 ,  B01J29/90 ,  C07C1/20 ,  C07C2529/85 ,  C10G3/49 ,  C10G3/50 ,  C10G3/57 ,  C10G3/62 ,  C10G2300/708 ,  C10G2300/802 ,  C10G2300/805 ,  C10G2400/20 ,  Y02P20/584 ,  Y02P30/20 ,  Y10S585/905 ,  Y10S585/906 ,  C07C11/02

摘要： A method for converting oxygenates to light olefins. The method comprises contacting, in a reactor, a feedstock comprising oxygenates with a molecular sieve catalyst under conditions effective to convert the feedstock to a product including light olefins and by-products, the contacting causing carbonaceous deposits to form on at least a portion of the molecular sieve catalyst producing deactivated catalyst; removing a portion of the deactivated catalyst from the reactor; regenerating the portion of the deactivated catalyst under conditions effective to remove at least a portion of the carbonaceous deposits from the deactivated catalyst to form an at least partially regenerated catalyst; exposing at least a portion of the at least partially regenerated catalyst to at least a portion of the by-products to selectivate the portion of the at least partially regenerated catalyst to form light olefins; and contacting the selectivated portion of the at least partially regenerated catalyst with the feedstock to form the product.

摘要翻译： 将含氧物转化为轻质烯烃的方法。 该方法包括在反应器中将包含含氧化合物的原料与分子筛催化剂在有效将原料转化为包含轻质烯烃和副产物的产物的条件下接触，使得碳质沉积物形成在至少一部分 分子筛催化剂产生失活催化剂; 从反应器中除去一部分失活的催化剂; 在有效地从失活的催化剂除去至少一部分碳质沉积物以形成至少部分再生的催化剂的条件下，使失活催化剂的部分再生; 将所述至少部分再生的催化剂的至少一部分暴露于所述副产物的至少一部分以选择所述至少部分再生催化剂的所述部分以形成轻质烯烃; 并使至少部分再生的催化剂的选定部分与原料接触以形成产物。

公开(公告)号：US07914760B2

公开(公告)日：2011-03-29

申请号：US12576062

申请日：2009-10-08

申请人： Machteld M. Mertens ,  An Verberckmoes ,  Marcel J. Janssen ,  Yun Feng Chang ,  Luc R. M. Martens ,  Stephen Neil Vaughn ,  Kenneth Ray Clem ,  Wilfried J. Mortier

发明人： Machteld M. Mertens ,  An Verberckmoes ,  Marcel J. Janssen ,  Yun Feng Chang ,  Luc R. M. Martens ,  Stephen Neil Vaughn ,  Kenneth Ray Clem ,  Wilfried J. Mortier

IPC分类号： C01B25/36 ,  C01B25/45 ,  B01J21/12 ,  B01J27/18 ,  B01J27/182

CPC分类号： B01J29/85 ,  C01B39/54 ,  C07C1/20 ,  C07C2529/70 ,  C07C2529/85 ,  Y02P30/20 ,  Y02P30/42 ,  Y10S423/30 ,  Y10T428/2982 ,  C07C11/02

摘要： A silicoaluminophosphate molecular sieve is disclosed that comprises first and second intergrown phases of a CHA framework type and an AEI framework type, wherein said first intergrown phase has an AEI/CHA ratio of from about 5/95 to about 40/60 as determined by DIFFaX analysis, the second intergrown phase has an AEI/CHA ratio of about 30/70 to about as determined by DIFFaX analysis and said molecular sieve has a silica to alumina molar ratio (Si/Al2) from about 0.13 to about 0.24.

摘要翻译： 公开了一种硅铝磷酸盐分子筛，其包含CHA骨架型和AEI骨架型的第一和第二共生相，其中所述第一共生相的AEI / CHA比为约5/95至约40/60，如通过DIFFaX 分析中，第二共生相具有通过DIFFaX分析确定的约30/70至约的AEI / CHA比，并且所述分子筛具有约0.13至约0.24的二氧化硅与氧化铝的摩尔比（Si / Al 2）。

公开(公告)号：US07622624B2

公开(公告)日：2009-11-24

申请号：US11072830

申请日：2005-03-04

申请人： Machteld M. Mertens ,  An Verberckmoes ,  Marcel J. Janssen ,  Yun Feng Chang ,  Luc R. M. Martens ,  Stephen Neil Vaughn ,  Kenneth Ray Clem ,  Wilfried J. Mortier

发明人： Machteld M. Mertens ,  An Verberckmoes ,  Marcel J. Janssen ,  Yun Feng Chang ,  Luc R. M. Martens ,  Stephen Neil Vaughn ,  Kenneth Ray Clem ,  Wilfried J. Mortier

IPC分类号： C07C1/00 ,  C01B37/08

CPC分类号： B01J29/85 ,  C01B39/54 ,  C07C1/20 ,  C07C2529/70 ,  C07C2529/85 ,  Y02P30/20 ,  Y02P30/42 ,  Y10S423/30 ,  Y10T428/2982 ,  C07C11/02

摘要： A silicoaluminophosphate molecular sieve is disclosed that comprises first and second intergrown phases of a CHA framework type and an AEI framework type, wherein said first intergrown phase has an AEI/CHA ratio of from about 5/95 to about 40/60 as determined by DIFFaX analysis, the second intergrown phase has an AEI/CHA ratio of about 30/70 to about 55/45 as determined by DIFFaX analysis and said molecular sieve has a silica to alumina molar ratio (Si/Al2) from about 0.13 to about 0.24.

摘要翻译： 公开了一种硅铝磷酸盐分子筛，其包含CHA骨架型和AEI骨架型的第一和第二共生相，其中所述第一共生相的AEI / CHA比为约5/95至约40/60，如通过DIFFaX 分析表明，第二共生相具有通过DIFFaX分析确定的约30/70至约55/45的AEI / CHA比，并且所述分子筛具有约0.13至约0.24的二氧化硅与氧化铝的摩尔比（Si / Al 2）。