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公开(公告)号：US06210464B1
公开(公告)日：2001-04-03
申请号：US09305528
申请日：1999-05-05
IPC分类号： B01D5322
CPC分类号： B01D63/02 , B01D53/22 , B01D63/027 , B01D2313/025 , B01D2313/23
摘要： A mixed gas-separating membrane module having a high separating efficiency includes a cylindrical container having a mixed gas-feed section, a non-permeated gas-delivery section, and a middle section; a bundle of a plurality of hollow fibers each extending through the middle section and each having an end portion opening to the mixed gas-feed section and an opposite end portion opening to the non-permeated gas-delivery section; a pair of a first disk supporting the hollow fiber end portion opening to the mixed gas-feed section and partitioning the middle section from the mixed gas-feed section, and a second disk supporting the opposite hollow fiber end portions opening to the non-permeated gas-delivery section and partitioning the middle section from the non-permeated gas-delivery section, the first and second disks supporting the hollow fibers so that the hollow fibers are spaced from each other, to leave a continuous space between the hollow fibers; and a cylindrical film member surrounding the hollow fiber bundle to such an extent that the continuous space formed between the hollow fibers is connected to a permeated gas-delivery outlet of the middle section, the middle section, having a permeated gas-delivery outlet located close to the first disk and a carrier gas-feed inlet located close to or in the second disk, to allow the carrier gas fed into the middle section to flow through the continuous space, countercurrently to the flow of the mixed gas through the hollow fibers.
摘要翻译： 具有高分离效率的混合气体分离膜组件包括具有混合气体供给部分，非渗透气体输送部分和中间部分的圆柱形容器; 多个中空纤维束，每个中空纤维各自延伸穿过中间部分，并且每个中空纤维具有通向混合供气部分的端部部分和与非渗透气体输送部分开口的相对端部; 一对第一盘，其支承通向所述混合气体供给部的中空纤维端部，并且将所述中间部分与所述混合气体供给部隔开;以及第二盘，其支撑所述相对的中空纤维端部， 气体输送部分并且将中间部分与非渗透气体输送部分分隔开，第一和第二圆盘支撑中空纤维，使得中空纤维彼此间隔开，以在中空纤维之间留下连续空间; 以及围绕中空纤维束的圆柱形薄膜构件，使得形成在中空纤维之间的连续空间连接到中间部分的渗透气体输送出口，中间部分具有位于关闭位置的渗透气体输送出口 位于靠近或位于第二盘的第一盘和载气进料入口，以允许进入中间部分的载气与通过中空纤维的混合气体的流动逆流地流过连续空间。
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公开(公告)号：US06464755B2
公开(公告)日：2002-10-15
申请号：US09766116
申请日：2001-01-19
IPC分类号： B01D5322
CPC分类号： B01D69/02 , B01D53/228 , B01D53/268 , B01D71/64
摘要： An asymmetric membrane is formed using a mixture of two or more different polymers including at least one type of polyimide. It is thereby possible to produce a gas separation membrane with low permeation resistance (a high permeation rate) for permeate gases passing through the porous layer of the membrane, which also maintains a practical level of mechanical strength of the membrane and has excellent water resistance and hot water resistance.
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3.发明授权Method of enhancing gas separation performance of an aromatic polyimide membrane 失效提高芳族聚酰亚胺膜气体分离性能的方法
公开(公告)号：US5246743A
公开(公告)日：1993-09-21
申请号：US978635
申请日：1992-11-19
CPC分类号： B01D67/009 , B01D71/64 , B29C59/14 , C08L79/08 , B29K2079/00 , B29L2031/755
摘要： A method of enhancing the gas-separation performance of an aromatic polyimide membrane with high reproducibility, by plasma-treating an asymmetric aromatic polyimide membrane comprising 80 to 100 molar % of at least one type of recurring units selected from those of the formulae (A) and (B) and 0 to 20 molar % of recurring units of the formula (C): ##STR1## in the formulae of which, R.sup.1, R.sup.2, R.sup.3 =an aromatic residue derived from an aromatic diamine compound and R=a tetravalent aromatic residue derived from an aromatic tetracarboxylic acid compound and different from tetravalent the aromatic tetracarboxylic acid residues appearing in the formulae (A) and (B), and has a helium gas-permeation rate [P.sub.He ] of 1.times.10.sup.-4 cm.sup.3 /cm.sup.2.sec.cmHg or more at 80.degree. C. and a ratio [P.sub.He ]/[P.sub.N2 ] of the helium gaspermeation rate [P.sub.He ] to a nitrogen gas-permeation rate [P.sub.N2 ] of 20 or more at 80.degree. C., in an atmosphere comprising ammonia.
摘要翻译： 通过等离子体处理包含80-100摩尔％的至少一种选自式（A）的重复单元的重复单元的不对称芳族聚酰亚胺膜，提高了具有高再现性的芳族聚酰亚胺膜的气体分离性能的方法， 和（B）和（B）和（C）中的（B）和0至20摩尔％的式（C）的重复单元：其中R 1，R 2，R 3 = 衍生自芳族二胺化合物的芳族残基，R =衍生自芳族四羧酸化合物的四价芳香族残基，与式（A）和（B）中出现的四价芳香族四羧酸残基不同，具有氦气 - 在80℃下渗透速率[PHe]为1×10 -4 cm 3 / cm 2·sec·cmHg或更高，氦气渗透速率[PHe]与氮气渗透速率[PN2]的比[PHe] / [PN2] ]在80℃下在包含氨的气氛中为20以上。
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公开(公告)号：US5744575A
公开(公告)日：1998-04-28
申请号：US659330
申请日：1996-06-06
申请人： Shunsuke Nakanishi , Kenji Ito , Yoshihiro Kusuki
发明人： Shunsuke Nakanishi , Kenji Ito , Yoshihiro Kusuki
CPC分类号： C08G73/1078 , B01D71/64 , Y10T428/29 , Y10T428/2913 , Y10T428/2971 , Y10T428/31504 , Y10T428/31721
摘要： An aromatic polyimide having a recurring unit of the formula (I): ##STR1## wherein Ar is a divalent aromatic group having one or two benzene rings which has a sulfonate group of --SO.sub.3 H, --SO.sub.3 M, and --SO.sub.3 N(L).sub.4 on the ring, wherein M is an alkali metal and L is a hydrogen atom or an alkyl group having 1 to 5 carbon atoms, is favorably employed in the form of a semipermeable film for gas separation.
摘要翻译： 具有式（I）的重复单元的芳族聚酰亚胺：其中Ar是具有一个或两个具有-SO 3 H，-SO 3 M和-SO 3 N（L ）4，其中M为碱金属，L为氢原子或碳原子数为1〜5的烷基，优选以气体分离用的半透膜形式使用。
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公开(公告)号：US08129573B2
公开(公告)日：2012-03-06
申请号：US12920039
申请日：2009-03-02
申请人： Masao Kikuchi , Shunsuke Nakanishi
发明人： Masao Kikuchi , Shunsuke Nakanishi
CPC分类号： C07C29/76 , B01D3/005 , B01D3/4205 , C07C29/80 , Y02P20/126 , C07C31/08
摘要： The present invention relates to a method for purifying an aqueous solution of fermentation alcohol to give anhydrous alcohol, wherein a mash column is controlled such a manner that an alcohol concentration of an alcohol/water mixed vapor distilled from a mash column is less than 50% by weight and a reflux amount of a condensate to a distillation column is controlled such a manner that an alcohol concentration of an alcohol/water mixed vapor that is distilled from the distillation column is 65 to 85% by weight. According to the present method, the purification for obtaining an anhydrous alcohol from an aqueous solution of a fermentation alcohol with the use of a mash column, a distillation column, an evaporator and a membrane separator can be more conveniently carried out with an extremely high energy efficiency as the whole process.
摘要翻译： 本发明涉及一种纯化发酵酒精水溶液以提供无水酒精的方法，其中控制麦芽汁，使得从糊状物柱蒸馏出的醇/水混合蒸气的醇浓度小于50％ 并将回流量的冷凝物加入到蒸馏塔中，使得从蒸馏塔蒸馏的醇/水混合蒸气的醇浓度为65〜85重量％。 根据本方法，可以更方便地以极高的能量进行从发酵醇的水溶液中使用糊状物柱，蒸馏塔，蒸发器和膜分离器得到无水醇的纯化 效率为整体。
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公开(公告)号：US08053610B2
公开(公告)日：2011-11-08
申请号：US12935567
申请日：2009-03-31
申请人： Masao Kikuchi , Shunsuke Nakanishi
发明人： Masao Kikuchi , Shunsuke Nakanishi
摘要： The present invention relates to a method for purifying an aqueous solution of fermentation alcohol to give anhydrous alcohol, wherein a mash column is controlled such a manner that an alcohol concentration of an alcohol/water mixed vapor distilled from a mash column is less than 50% by weight and a reflux amount of a condensate to a distillation column is controlled such a manner that an alcohol concentration of an alcohol/water mixed vapor that is distilled from the distillation column is 55 to 85% by weight. According to the present method, the purification for obtaining an anhydrous alcohol from an aqueous solution of a fermentation alcohol with the use of a mash column, a pressurized distillation column and a membrane separator can be more conveniently carried out with an extremely high energy efficiency as the whole process.
摘要翻译： 本发明涉及一种纯化发酵酒精水溶液以提供无水酒精的方法，其中控制麦芽汁，使得从糊状物柱蒸馏出的醇/水混合蒸气的醇浓度小于50％ 并且将回收量的冷凝物加入到蒸馏塔中，使得从蒸馏塔蒸馏的醇/水混合蒸气的醇浓度为55〜85重量％。 根据本方法，可以以极高的能量效率更方便地进行使用糊状柱，加压蒸馏塔和膜分离器从发酵醇的水溶液中获得无水醇的纯化，作为 整个过程。
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公开(公告)号：US20110009677A1
公开(公告)日：2011-01-13
申请号：US12920039
申请日：2009-03-02
申请人： Masao Kikuchi , Shunsuke Nakanishi
发明人： Masao Kikuchi , Shunsuke Nakanishi
IPC分类号： C07C31/00
CPC分类号： C07C29/76 , B01D3/005 , B01D3/4205 , C07C29/80 , Y02P20/126 , C07C31/08
摘要： The present invention relates to a method for purifying an aqueous solution of fermentation alcohol to give anhydrous alcohol, wherein a mash column is controlled such a manner that an alcohol concentration of an alcohol/water mixed vapor distilled from a mash column is less than 50% by weight and a reflux amount of a condensate to a distillation column is controlled such a manner that an alcohol concentration of an alcohol/water mixed vapor that is distilled from the distillation column is 65 to 85% by weight. According to the present method, the purification for obtaining an anhydrous alcohol from an aqueous solution of a fermentation alcohol with the use of a mash column, a distillation column, an evaporator and a membrane separator can be more conveniently carried out with an extremely high energy efficiency as the whole process.
摘要翻译： 本发明涉及一种纯化发酵酒精水溶液以提供无水酒精的方法，其中控制麦芽汁，使得从糊状物柱蒸馏出的醇/水混合蒸气的醇浓度小于50％ 并将回流量的冷凝物加入到蒸馏塔中，使得从蒸馏塔蒸馏的醇/水混合蒸气的醇浓度为65〜85重量％。 根据本方法，可以更方便地以极高的能量进行从发酵醇的水溶液中使用糊状物柱，蒸馏塔，蒸发器和膜分离器得到无水醇的纯化 效率为整体。
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公开(公告)号：US20110028767A1
公开(公告)日：2011-02-03
申请号：US12935567
申请日：2009-03-31
申请人： Masao Kikuchi , Shunsuke Nakanishi
发明人： Masao Kikuchi , Shunsuke Nakanishi
IPC分类号： C07C29/88
摘要： The present invention relates to a method for purifying an aqueous solution of fermentation alcohol to give anhydrous alcohol, wherein a mash column is controlled such a manner that an alcohol concentration of an alcohol/water mixed vapor distilled from a mash column is less than 50% by weight and a reflux amount of a condensate to a distillation column is controlled such a manner that an alcohol concentration of an alcohol/water mixed vapor that is distilled from the distillation column is 55 to 85% by weight. According to the present method, the purification for obtaining an anhydrous alcohol from an aqueous solution of a fermentation alcohol with the use of a mash column, a pressurized distillation column and a membrane separator can be more conveniently carried out with an extremely high energy efficiency as the whole process.
摘要翻译： 本发明涉及一种纯化发酵酒精水溶液以提供无水酒精的方法，其中控制麦芽汁，使得从糊状物柱蒸馏出的醇/水混合蒸气的醇浓度小于50％ 并且将回收量的冷凝物加入到蒸馏塔中，使得从蒸馏塔蒸馏的醇/水混合蒸气的醇浓度为55〜85重量％。 根据本方法，可以以极高的能量效率更方便地进行使用糊状柱，加压蒸馏塔和膜分离器从发酵醇的水溶液中获得无水醇的纯化，作为 整个过程。
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公开(公告)号：US08182592B2
公开(公告)日：2012-05-22
申请号：US12521745
申请日：2007-12-27
IPC分类号： B01D53/22
CPC分类号： B01D63/02 , B01D53/22 , B01D63/024 , B01D2313/02
摘要： A gas separation membrane module has a vessel housing a hollow fiber element including a hollow fiber bundle consisting of a number of hollow fiber membranes (1) and a tube sheet (2) holding one end of the hollow fiber bundle. The interior of the vessel is partitioned by the tube sheet (2) into two spaces consisting of a raw gas chamber and a permeate gas chamber. A high-pressure mixed gas is fed into the raw gas chamber where gas separation is carried out. The gas separation membrane module has a configuration where during operation, the tube sheet (2) is supported by means of a perforated plate (8) in the vessel by a pressure from the mixed gas fed to maintain airtightness between the two spaces and when the tube sheet (2) receives a pressure in the reverse direction to that applied during the operation of the gas separation membrane module, the tube sheet (2) is forced to move within the vessel by the pressure in the reverse direction, thereby losing airtightness between the two spaces.
摘要翻译： 气体分离膜组件具有容纳中空纤维元件的容器，该中空纤维元件包括由许多中空纤维膜（1）和保持中空纤维束的一端的管板（2）组成的中空纤维束。 容器的内部由管板（2）分隔成由原始气体室和渗透气体室组成的两个空间。 将高压混合气体供给到进行气体分离的原料气室中。 气体分离膜组件具有这样的结构，其中在操作期间，管板（2）通过来自供给的混合气体的压力在容器中由穿孔板（8）支撑以保持两个空间之间的气密性，并且当 管板（2）接收与气体分离膜组件操作相反的方向的压力，管板（2）被迫在相反方向的压力下在容器内移动，从而导致管板 两个空格。
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公开(公告)号：US20100326278A1
公开(公告)日：2010-12-30
申请号：US12521745
申请日：2007-12-12
IPC分类号： B01D53/22
CPC分类号： B01D63/02 , B01D53/22 , B01D63/024 , B01D2313/02
摘要： A gas separation membrane module has a vessel housing a hollow fiber element including a hollow fiber bundle consisting of a number of hollow fiber membranes (1) and a tube sheet (2) holding one end of the hollow fiber bundle. The interior of the vessel is partitioned by the tube sheet (2) into two spaces consisting of a raw gas chamber and a permeate gas chamber. A high-pressure mixed gas is fed into the raw gas chamber where gas separation is carried out. The gas separation membrane module has a configuration where during operation, the tube sheet (2) is supported by means of a perforated plate (8) in the vessel by a pressure from the mixed gas fed to maintain airtightness between the two spaces and when the tube sheet (2) receives a pressure in the reverse direction to that applied during the operation of the gas separation membrane module, the tube sheet (2) is forced to move within the vessel by the pressure in the reverse direction, thereby losing airtightness between the two spaces.
摘要翻译： 气体分离膜组件具有容纳中空纤维元件的容器，该中空纤维元件包括由许多中空纤维膜（1）和保持中空纤维束的一端的管板（2）组成的中空纤维束。 容器的内部由管板（2）分隔成由原始气体室和渗透气体室组成的两个空间。 将高压混合气体供给到进行气体分离的原料气室中。 气体分离膜组件具有这样的结构，其中在操作期间，管板（2）通过来自供给的混合气体的压力在容器中由穿孔板（8）支撑以保持两个空间之间的气密性，并且当 管板（2）接收与气体分离膜组件操作相反的方向的压力，管板（2）被迫在相反方向的压力下在容器内移动，从而导致管板 两个空格。
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