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公开(公告)号：US09764283B2
公开(公告)日：2017-09-19
申请号：US14414110
申请日：2013-07-08
CPC分类号： B01D53/8671 , B01D53/1475 , B01D53/1493 , B01D53/62 , B01D53/78 , B01D2251/306 , B01D2251/606 , B01D2252/10 , B01D2252/204 , B01D2252/20484 , B01D2252/20494 , B01D2252/602 , B01D2255/209 , B01D2257/504 , B01D2258/0283 , Y02A50/2342 , Y02C10/04 , Y02C10/06
摘要： A scrubbing solution is provided having an absorbent for carbon dioxide based on amines, or ethanolamines, or amino acid salts, or potash, or a combination thereof, and an additive activating the absorption rate, wherein the activating additive is a germanium dioxide. A corresponding method for accelerating the absorption of carbon dioxide is also provided, wherein a carbon dioxide-containing gas is contacted with such a scrubbing solution, wherein the carbon dioxide is physically dissolved in the scrubbing solution and is chemically absorbed with the participation of the absorbent, and wherein the germanium dioxide acts catalytically for at least one reaction step of the chemical absorption of the carbon dioxide.
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2.发明申请ABSORPTION MEDIUM, PROCESS FOR PRODUCING AN ABSORPTION MEDIUM, AND ALSO PROCESS AND APPARATUS FOR SEPARATING HYDROGEN SULFIDE FROM AN ACIDIC GAS 审中-公开吸收介质，用于生产吸收介质的方法，以及用于从酸性气体分离氢化硫的方法和装置公开(公告)号：US20160074804A1
公开(公告)日：2016-03-17
申请号：US14784116
申请日：2014-02-18
发明人： Kevin Brechtel , Ralph Joh , Markus Kinzl , Hans Wolfgang Nickelfeld , Katrin Raake , Matthias Renger , Henning Schramm
IPC分类号： B01D53/14
CPC分类号： B01D53/1493 , B01D53/1418 , B01D53/1425 , B01D53/1462 , B01D53/1468 , B01D2252/20494 , B01D2252/602 , B01D2257/304 , B01D2258/05 , C01B17/05 , C02F1/725 , C02F1/727 , C02F1/74 , C02F2101/101 , C02F2103/18 , C02F2303/16 , C10L3/103 , Y02P20/152 , Y02P20/584
摘要： An absorption medium contains a dissolved amino acid salt and a dissolved metal. The absorption medium is brought into contact with the acidic gas in an absorber. In the absorber, the H2S goes over from the gas phase into the liquid phase. In addition, carbon dioxide (CO2) is likewise absorbed from the gas as a function of the contact time. The scrubbing solution is conveyed from the absorber into a regeneration tank. In the regeneration tank, the solution is treated with air, with oxygen (O2)-enriched air or with pure O2. As a result of the introduction of O2 into the solution, the H2S present in the solution is reacted at the dissolved metal catalyst. After the regeneration, possible solids are separated off and the regenerated scrubbing solution is recirculated to the absorber.
摘要翻译： 吸收介质含有溶解的氨基酸盐和溶解的金属。 吸收介质与吸收器中的酸性气体接触。 在吸收器中，H 2 S从气相转移到液相中。 此外，二氧化碳（CO 2）同样作为接触时间的函数从气体中吸收。 洗涤溶液从吸收器输送到再生罐中。 在再生槽中，溶液用空气，氧（O 2）富集的空气或纯的O2进行处理。 由于将O 2引入溶液中，溶液中存在的H 2 S在溶解的金属催化剂下反应。 在再生之后，将可能的固体分离出来并将再生的洗涤溶液再循环到吸收器。
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3.发明授权公开(公告)号：US09643122B2
公开(公告)日：2017-05-09
申请号：US14394095
申请日：2013-04-02
发明人： Rainald Forbert , Stefan Hauke , Ralph Joh , Markus Kinzl , Rudiger Schneider
CPC分类号： B01D53/1425 , B01D9/0013 , B01D9/0036 , B01D9/0059 , B01D53/1475 , B01D53/62 , B01D53/96 , B01D2257/504 , B01D2258/0283 , Y02C10/04 , Y02C10/06
摘要： A device and method for separating off carbon dioxide is provided, including an absorption unit, desorption unit assigned thereto and a separation unit for separating off salts from a scrubbing solution. The absorption and desorption units are connected to each other via a first conduit for a regenerated scrubbing solution and a second conduit for a loaded scrubbing solution. The separation unit includes a crystallizer for forming salt crystals and a first separator unit on the downstream side for separating off salt crystals. A separation unit is provided for separating off salts from a scrubbing solution, having a crystallizer and a first separator unit downstream thereof. The crystallizer has a crystallization chamber for forming salt crystals and a countercurrent classifier for separating salt crystals according to particle size. A first branch conduit is connected to the crystallization chamber, which opens out into the countercurrent classifier via a second separator unit.
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4.发明申请SEPARATION DEVICE FOR CARBON DIOXIDE, METHOD FOR THE OPERATION THEREOF, AND SEPARATING UNIT 有权二氧化碳分离装置，其操作方法和分离装置公开(公告)号：US20150075376A1
公开(公告)日：2015-03-19
申请号：US14394095
申请日：2013-04-02
发明人： Rainald Forbert , Stefan Hauke , Ralph Joh , Markus Kinzl , Rudiger Schneider
IPC分类号： B01D53/14
CPC分类号： B01D53/1425 , B01D9/0013 , B01D9/0036 , B01D9/0059 , B01D53/1475 , B01D53/62 , B01D53/96 , B01D2257/504 , B01D2258/0283 , Y02C10/04 , Y02C10/06
摘要： A device and method for separating off carbon dioxide is provided, including an absorption unit, desorption unit assigned thereto and a separation unit for separating off salts from a scrubbing solution. The absorption and desorption units are connected to each other via a first conduit for a regenerated scrubbing solution and a second conduit for a loaded scrubbing solution. The separation unit includes a crystallizer for forming salt crystals and a first separator unit on the downstream side for separating off salt crystals. A separation unit is provided for separating off salts from a scrubbing solution, having a crystallizer and a first separator unit downstream thereof. The crystallizer has a crystallization chamber for forming salt crystals and a countercurrent classifier for separating salt crystals according to particle size. A first branch conduit is connected to the crystallization chamber, which opens out into the countercurrent classifier via a second separator unit.
摘要翻译： 提供一种用于分离二氧化碳的装置和方法，包括吸收单元，分配给它的解吸单元和用于从洗涤溶液中分离出盐的分离单元。 吸收和解吸单元通过用于再生洗涤溶液的第一管道和用于负载的洗涤溶液的第二管道彼此连接。 分离单元包括用于形成盐晶的结晶器和在下游侧的用于分离盐晶体的第一分离器单元。 提供了分离单元，用于从洗涤溶液中分离出盐，其具有结晶器和在其下游的第一分离器单元。 结晶器具有用于形成盐晶的结晶室和用于根据粒径分离盐晶体的逆流分级器。 第一分支管道连接到结晶室，该结晶室经由第二分离器单元打开到逆流分级器中。
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公开(公告)号：US10858598B2
公开(公告)日：2020-12-08
申请号：US16089617
申请日：2017-03-02
发明人： Markus Kinzl , Ansgar Kursawe , Sebastian Löw
摘要： A method for purifying an asphaltene-containing fuel where the asphaltene-containing fuel is supplied to a deasphalting unit in which asphaltene contained in the fuel is separated using a solvent, thereby forming a substantially deasphalted fuel. The solvent is separated from the deasphalted fuel in a solvent recovery unit after a successful separation of the asphaltene from the fuel, and the waste heat of turbine exhaust gas produced in a gas turbine when converting fuel into electricity is used in order to purify the asphaltene-containing fuel. A corresponding device is used for purifying an asphaltene-containing fuel.
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公开(公告)号：US20190300797A1
公开(公告)日：2019-10-03
申请号：US16315738
申请日：2017-06-28
发明人： Markus Kinzl , Ansgar Kursawe , Sebastian Löw
摘要： A method and a device for preparing a vanadium-containing combustible in a de-asphalting device. In this way, a vanadium-containing combustible is supplied to a de-asphalting unit via a supply line in a de-asphalting device, wherein the vanadium-containing combustible supplied into the de-asphalting unit forms a first mass flow and a substantially de-asphalted combustible is discharged from the de-asphalting unit via a discharge line. A bypass line is connected to the supply line, wherein, via the bypass line, a second mass flow of the vanadium-containing combustible is directed past the de-asphalting unit in parallel to the first mass flow and supplied to the discharge line, such that a combined mass flow is formed in the discharge line.
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公开(公告)号：US20180148655A1
公开(公告)日：2018-05-31
申请号：US15575515
申请日：2016-04-21
发明人： Sebastian Löw , Markus Kinzl , Ralph Joh , Ansgar Kursawe , Herbert Fahrnbauer , Thomas Fuchs , Jochen Petersen , Rüdiger Schneider , Nicolas Vortmeyer
CPC分类号： C10G21/003 , C10G21/14 , C10G21/28 , C10G2300/206 , C10L1/04 , C10L2270/04
摘要： A method for separating asphaltenes from an asphaltene-containing fuel, wherein fuel is supplied to a separation unit in which a sub-stream with low-boiling fuel components of the fuel is separated. After separation of the sub-stream the fuel is supplied to a deasphalting unit in which asphaltenes contained in the fuel are separated by a solvent. After the separation of the asphaltenes from the fuel, the solvent is separated therefrom in a solvent recovery unit. The separated solvent is circulated back into the deasphalting unit, and a solvent fraction is obtained from the sub-stream that has been separated from the fuel, which is supplied to the deasphalting unit in addition to the solvent recirculated from the solvent recovery unit. A device is adapted for separating asphaltenes from an asphaltene-containing fuel.
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公开(公告)号：US20180119026A1
公开(公告)日：2018-05-03
申请号：US15567804
申请日：2016-02-12
发明人： Markus Kinzl , Ansgar Kursawe
IPC分类号： C10G21/00
摘要： An apparatus for separation of asphaltenes from an oil-containing fuel, has a mixing element for intensive mixing of the oil-containing fuel with a solvent to form a solution supersaturated with asphaltenes, a vessel for reducing the oversaturation by depositing the asphaltenes out of the supersaturated solution, a growth zone formed within the vessel for growth of asphaltene particles present via the asphaltenes separated out of the supersaturated solution, and a classifying unit connected in terms of flow to the vessel for separation of the asphaltene particles grown in the growth zone in terms of their particle size, wherein the vessel is formed and set up such that a stream containing asphaltene particles circulates between the mixing element and the growth zone of the vessel. A corresponding process has a stream containing asphaltene particles that circulates between the mixing element and the growth zone of the vessel.
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9.发明授权公开(公告)号：US10532293B2
公开(公告)日：2020-01-14
申请号：US15304599
申请日：2015-03-25
发明人： Ansgar Kursawe , Stefan Hauke , Ralph Joh , Markus Kinzl , Rüdiger Schneider
摘要： A processing unit for a liquid washing medium contaminated with sulphur oxides and/or nitrogen oxides, has an evaporation stage for concentrating the active components of the washing medium by an evaporator and/or by a heat exchanger, and has a collecting tank connected to the evaporator and/or to the heat exchanger. The collecting tank is configured as a crystallizer for removing sulfur oxides from the washing medium by crystallization of a sulphate, in particular of potassium sulphate. A separating device for carbon dioxide has a corresponding processing unit, and a method for processing a washing medium contaminated with sulphur oxides and/or nitrogen oxides uses a corresponding processing unit.
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10.发明申请SCRUBBING SOLUTION FOR ABSORPTION OF CARBON DIOXIDE AND METHOD FOR ACCELERATING THE ABSORPTION BY GERMANIUM DIOXIDE 有权用于吸收二氧化碳的洗涤溶液和用于加速二氧化锗吸收的方法公开(公告)号：US20150165375A1
公开(公告)日：2015-06-18
申请号：US14414110
申请日：2013-07-08
CPC分类号： B01D53/8671 , B01D53/1475 , B01D53/1493 , B01D53/62 , B01D53/78 , B01D2251/306 , B01D2251/606 , B01D2252/10 , B01D2252/204 , B01D2252/20484 , B01D2252/20494 , B01D2252/602 , B01D2255/209 , B01D2257/504 , B01D2258/0283 , Y02A50/2342 , Y02C10/04 , Y02C10/06
摘要： A scrubbing solution is provided having an absorbent for carbon dioxide based on amines, or ethanolamines, or amino acid salts, or potash, or a combination thereof, and an additive activating the absorption rate, wherein the activating additive is a germanium dioxide. A corresponding method for accelerating the absorption of carbon dioxide is also provided, wherein a carbon dioxide-containing gas is contacted with such a scrubbing solution, wherein the carbon dioxide is physically dissolved in the scrubbing solution and is chemically absorbed with the participation of the absorbent, and wherein the germanium dioxide acts catalytically for at least one reaction step of the chemical absorption of the carbon dioxide.
摘要翻译： 提供洗涤溶液，其具有基于胺或乙醇胺或氨基酸盐或钾盐或其组合的二氧化碳吸收剂和活化吸收速率的添加剂，其中活化添加剂是二氧化锗。 还提供了用于加速二氧化碳吸收的相应方法，其中使含二氧化碳的气体与这种洗涤溶液接触，其中二氧化碳物理地溶解在洗涤溶液中并在吸收剂的参与下被化学吸收 ，并且其中所述二氧化锗对于二氧化碳的化学吸收的至少一个反应步骤催化作用。
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