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公开(公告)号：US4797196A
公开(公告)日：1989-01-10
申请号：US160680
申请日：1988-02-26
IPC分类号： C10G65/10
CPC分类号： C10G65/10
摘要： Disclosed is a hydrocracking process wherein the feedstock is first contacted with a first catalyst containing a nickel component and a tungsten component supported on a support containing alumina and a crystalline molecular sieve followed by subsequent contact with a second hydrocracking catalyst containing a cobalt component and a molybdenum component supported on a support containing silica-alumina and a crystalline molecular sieve and the first catalyst. This subsequent contact with the second and first catalysts is carried out either serially or in one step wherein the first and second catalysts are physically mixed.
摘要翻译： 公开了加氢裂化方法，其中原料首先与含有镍组分的第一催化剂和负载在含有氧化铝和结晶分子筛的载体上的钨组分接触，随后与含有钴组分和钼的第二加氢裂化催化剂接触 负载在含有二氧化硅 - 氧化铝和结晶分子筛和第一催化剂的载体上的组分。 随后与第二和第一催化剂的接触是连续地或一个步骤进行，其中第一和第二催化剂被物理混合。
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公开(公告)号：US5221656A
公开(公告)日：1993-06-22
申请号：US857336
申请日：1992-03-25
CPC分类号： C10G49/04 , B01J23/85 , B01J35/1019 , B01J35/1042 , B01J35/1061 , B01J35/108
摘要： A hydroprocessing catalyst and process of using such catalyst wherein such catalyst has at least one hydrogenation metal deposited on an inorganic oxide support and is further characterized by a surface area of greater than about 220 m.sup.2 /g, a pore volume of about 0.23-0.30 cc/g in pores greater than about 600 Angstroms radius, an average pore radius of about 30-70 Angstroms in pores less than 600 Angstroms, and an incremental pore volume curve with a maximum at about 25-50 Angstroms radius.
摘要翻译： 加氢处理催化剂和使用这种催化剂的方法，其中这种催化剂具有沉积在无机氧化物载体上的至少一种氢化金属，其进一步特征在于表面积大于约220m 2 / g，孔体积为约0.23-0.30cc / g在大于约600埃半径的孔中，平均孔半径在小于600埃的孔中约30-70埃，以及在约25-50埃半径处具有最大值的增量孔体积曲线。
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公开(公告)号：US4980328A
公开(公告)日：1990-12-25
申请号：US509488
申请日：1990-04-16
CPC分类号： B01J29/084 , B01J29/166 , B01J29/80 , C10G47/20 , B01J2229/16
摘要： The present invention relates to a hydrocracking catalyst that contains a combination of two ultrastable zeolite Y components wherein one of the zeolites is relatively more dealuminated than the other.
摘要翻译： 本发明涉及一种加氢裂化催化剂，其包含两种超稳定沸石Y组分的组合，其中一种沸石比另一种沸石相对更为脱铝。
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公开(公告)号：US4954241A
公开(公告)日：1990-09-04
申请号：US287398
申请日：1988-12-20
CPC分类号： C10G65/10
摘要： Disclosed is a multiple stage process wherein a hydrocarbon feedstock is hydrotreated in a hydrotreating stage. After removal of ammonia and hydrogen sulfide from the hydrotreated feedstock, the hydrotreated feedstock is hydrocracked in a three zone hydrocracking stage.
摘要翻译： 公开了一种多阶段方法，其中烃原料在加氢处理阶段进行加氢处理。 从加氢处理的原料中除去氨和硫化氢后，加氢处理的原料在三区加氢裂化阶段加氢裂化。
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公开(公告)号：US4925546A
公开(公告)日：1990-05-15
申请号：US406262
申请日：1989-09-12
CPC分类号： C10G47/20 , B01J29/084 , B01J29/166 , B01J29/80 , B01J2229/16
摘要： The present invention relates to a hydrocracking process that utilizes a catalyst that contains a combination of two ultrastable zeolite Y components providing improved naphtha yield and catalyst activity.
摘要翻译： 本发明涉及利用含有两种超稳定沸石Y组分的组合的催化剂的提供改善的石脑油产率和催化剂活性的加氢裂化方法。
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公开(公告)号：US4940530A
公开(公告)日：1990-07-10
申请号：US312205
申请日：1989-02-21
摘要： A two-stage hydrocarbon process is disclosed wherein a hydrocarbon feedstock is first hydrotreated followed by a hydrocracking step wherein a portion of the hydrotreated feedstock is hydrocracked in the presence of a catalyst having a nickel component, a tungsten component, and a support component containing a crystalline molecular sieve material present in an amount ranging from 25 to 60 wt. % based on the weight of the support component with the balance being alumina.
摘要翻译： 公开了两阶段烃法，其中烃原料首先被加氢处理，之后是加氢裂化步骤，其中一部分加氢处理的原料在催化剂存在下进行加氢裂化，所述催化剂具有镍组分，钨组分和含有 结晶分子筛材料的存在量为25至60wt。 基于载体组分的重量％，余量为氧化铝。
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公开(公告)号：US5338878A
公开(公告)日：1994-08-16
申请号：US11246
申请日：1993-01-29
CPC分类号： C07C68/005 , C07C68/08
摘要： A process is provided for separating alkyl carbonate from a feedstock comprising at least one alkyl carbonate and at least one alkanol comprising extracting the alkyl carbonate from the feedstock in a liquid-liquid extraction step comprising a first extraction solvent comprising hydrocarbon selective for extracting alkyl carbonates relative to alkanol in an amount sufficient to extract a substantial portion of the alkyl carbonate from the feedstock and a second solvent comprising water in an amount sufficient to extract a substantial portion of the alkanol from the feedstock.
摘要翻译： 提供了一种从包含至少一种碳酸烷基酯和至少一种链烷醇的原料分离碳酸酯的方法，其包括在液 - 液萃取步骤中从原料中提取碳酸烷基酯，所述液 - 液萃取步骤包括第一提取溶剂，所述第一萃取溶剂包含选择性烃，用于提取相对于 以足以从原料中提取大部分碳酸烷基酯的量的链烷醇和含有足以从原料中提取大部分烷醇的量的水的第二溶剂。
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公开(公告)号：US4456699A
公开(公告)日：1984-06-26
申请号：US485308
申请日：1983-04-15
CPC分类号： B01J37/10 , B01J21/02 , B01J21/12 , B01J27/16 , B01J35/10 , B01J35/1019 , B01J35/1047 , B01J35/1061 , C10G2300/107
摘要： A catalyst support is prepared from a composite comprising alumina and one or more oxides of phosphorus by forming the composite into a shaped support material having at least 0.8 cc/gm of its pore volume in pores having diameters of 0 nm (0 .ANG.) to 120 nm (1,200 .ANG.) and at least 0.1 cc/gm of its pore volume in pores having diameters of 120 nm (1,200 .ANG.) to 5,000 nm (50,000 .ANG.) and heating said shaped support material in the presence of steam at sufficient elevated temperature, steam pressure, and time period to increase the average pore diameter of said shaped support in the absence of any appreciable reduction in pore volume.A catalyst is prepared by impregnating the steam-treated support with at least one hydrogenating metal.The catalyst can be used suitably in hydrocarbon conversion processes, such as a process for the hydrodemetallization of a hydrocarbon stream containing asphaltenes and a substantial amount of metals.
摘要翻译： 催化剂载体由包含氧化铝和一种或多种磷的氧化物的复合材料制成，通过将复合材料形成为直径为0nm（0安格姆）至120的孔中至少具有0.8cc / gm孔体积的成形载体材料 nm（1200 ANGSTROM），并且在直径为120nm（1,200）至5,000nm（50,000）的孔中，其孔体积至少为0.1cc / gm，并且在足够高的温度下在蒸汽存在下加热所述成形载体材料， 蒸汽压力和时间段，以在没有任何明显的孔体积减小的情况下增加所述成形支撑件的平均孔径。 通过用至少一种氢化金属浸渍蒸汽处理的载体来制备催化剂。 催化剂可以适用于烃转化方法，例如含有沥青质的烃物流和大量金属的加氢脱金属的方法。
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公开(公告)号：US4191635A
公开(公告)日：1980-03-04
申请号：US967416
申请日：1978-12-07
CPC分类号： B01J23/8878 , B01J23/28 , B01J35/10 , C10G69/04 , B01J35/1019 , B01J35/1042 , B01J35/1061 , B01J35/1085 , C10G2300/107
摘要： A heavy hydrocarbon stream containing metals, asphaltenes, nitrogen compounds, and sulfur compounds is (a) contacted with hydrogen and a hydrotreating catalyst containing molybdenum and chromium, either as metals, as oxides, as sulfides, or mixtures thereof, deposed on a large-pore, catalytically active alumina to reduce the metals content in said stream, to convert the asphaltenes, nitrogen compounds, and sulphur compounds in said stream, the catalyst has a pore volume within the range of about 0.4 cc/gm to about 0.8 cc/gm, a surface area within the range of about 150 m.sup.2 /gm to about 300 m.sup.2 /gm, and an average pore diameter within the range of about 100 A (10 nm) to about 200 A (20 nm); and (b) at least a portion of the hydrotreated stream is cracked with a cracking catalyst to produce gasoline and distillates in improved yields. The catalyst in step (a) may also contain cobalt.
摘要翻译： 含有金属，沥青质，氮化合物和硫化合物的重质烃流是（a）与氢气和含有钼和铬的加氢处理催化剂接触，所述催化剂含有钼和铬，作为氧化物，作为硫化物或其混合物， 孔，催化活性氧化铝以降低所述料流中的金属含量，以转化所述料流中的沥青质，氮化合物和硫化合物，催化剂的孔体积在约0.4cc / g至约0.8cc / g的范围内 ，约150m 2 / gm至约300m 2 / gm范围内的表面积和在约100A（10nm）至约200A（20nm）范围内的平均孔径; 和（b）加氢处理物流的至少一部分用裂解催化剂裂化，以提高产率生产汽油和馏出物。 步骤（a）中的催化剂也可以含有钴。
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公开(公告)号：US5154819A
公开(公告)日：1992-10-13
申请号：US597005
申请日：1990-10-15
CPC分类号： C10G49/02 , B01J23/90 , B01J38/20 , B01J38/64 , Y10S502/517 , Y10S502/521
摘要： The present invention relates to a hydroprocessing process that employs a catalyst that has been regenerated by subjecting the catalyst to an initial partial decoking step, followed by impregnation with a Group IIA metal-containing component and then subjected to a final decoking step.
摘要翻译： 本发明涉及一种加氢处理方法，其采用通过使催化剂进行初始部分脱焦步骤而再生的催化剂，然后用含IIA族金属的组分浸渍，然后进行最终的脱焦步骤。
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