公开(公告)号：US20070100033A1

公开(公告)日：2007-05-03

申请号：US10579441

申请日：2004-11-12

申请人： Simon Schambony ,  Alban Glaser ,  Rudiger Sens ,  Arno Bohm ,  Helmut Reichelt

发明人： Simon Schambony ,  Alban Glaser ,  Rudiger Sens ,  Arno Bohm ,  Helmut Reichelt

IPC分类号： C08K5/34

CPC分类号： C07D221/14

摘要： A description is given of the use of naphthalene-1,8-dicarboxylic monoimides of the formula (I), in which R1 is hydrogen, alkyl, alkenyl, cycloalkyl, cycloalkenyl, heterocycloalkyl, aryl or heteroaryl and R2 is a radical containing at least one π electron system containing a carbon atom and at least one further atom selected from carbon, oxygen, and nitrogen, with the proviso that the radical contains at least one atom other than carbon; to protect organic material from the damaging effects of light, of compositions which comprise at least one naphthalene-1,8-dicarboxylic monoimide of the formula (I) in an amount which provides protection from the damaging effects of light, and at least one organic material, and of new naphthalene-1,8-dicarboxylic monoimides (I).

摘要翻译： 描述了使用式（I）的萘-1,8-二羧酸单酰亚胺，其中R 1是氢，烷基，烯基，环烷基，环烯基，杂环烷基，芳基或杂芳基 并且R 2是含有至少一个含有碳原子和至少一个选自碳，氧和氮的另外的原子的π电子体系的基团，条件是该基团含有至少一个原子 除碳外; 以保护有机材料免受光的破坏性影响，所述组合物包含至少一种式（I）的萘-1,8-二羧酸单酰亚胺，其量提供防止光的破坏作用，以及至少一种有机物 材料和新的萘-1,8-二羧酸单酰亚胺（I）。

公开(公告)号：US20050075453A1

公开(公告)日：2005-04-07

申请号：US10629552

申请日：2003-07-30

申请人： Klemens Mathauer ,  Arno Bohm ,  Walter Machtle ,  Peter Rossmanith ,  Sabine Kielhorn-Bayer ,  Klaus Mullen ,  Ulrike Rohr ,  Friedrich-Wilhelm Raulfs ,  Ulrike Schlosser ,  Wolfgang Schrof ,  Harutyun Hanciogullari ,  Karl Siemensmeyer ,  Paul Delavier ,  Rudiger Sens ,  Torsten Freund ,  Takahiro Ikeda ,  Takanori Wakebe

发明人： Klemens Mathauer ,  Arno Bohm ,  Walter Machtle ,  Peter Rossmanith ,  Sabine Kielhorn-Bayer ,  Klaus Mullen ,  Ulrike Rohr ,  Friedrich-Wilhelm Raulfs ,  Ulrike Schlosser ,  Wolfgang Schrof ,  Harutyun Hanciogullari ,  Karl Siemensmeyer ,  Paul Delavier ,  Rudiger Sens ,  Torsten Freund ,  Takahiro Ikeda ,  Takanori Wakebe

IPC分类号： C07D221/18 ,  C07C69/54 ,  C07C271/12 ,  C07D213/85 ,  C08F2/22 ,  C08F2/32 ,  C08F2/44 ,  C09B69/10 ,  C09D5/02 ,  C09D5/03 ,  C09D11/00 ,  D21H19/00

CPC分类号： C08F2/32 ,  C08F2/44 ,  C08K3/00 ,  C09B69/102

摘要： The present invention relates to a process for preparing dye-comprising aqueous polymer dispersions by free-radical aqueous emulsion polymerization of ethylenically unsaturated monomers in the presence of free-radical initiators, in which at least some of the monomers are employed in the form of an oil-in-water emulsion E1 whose disperse phase comprises at least one oil-soluble dye, wherein the disperse phase of E1 is formed essentially of dye-comprising monomer droplets having a diameter

摘要翻译： 本发明涉及一种在自由基引发剂存在下通过烯键式不饱和单体的自由基水乳液聚合制备含染料的聚合物水分散体的方法，其中至少一些单体以 水包油乳液E1，其分散相包含至少一种油溶性染料，其中E1的分散相基本上由具有直径<500nm的含染料的单体液滴形成。 本发明还涉及如权利要求35所述的式III的苝染料。本发明除了含有染料的制剂外，还包括本发明的含染料的聚合物和着色剂，其包含 本发明包括荧光增白剂。

公开(公告)号：US20070218089A1

公开(公告)日：2007-09-20

申请号：US10592472

申请日：2005-03-09

申请人： Rainer Dyllick-Brenzinger ,  Alban Glaser ,  Arno Bohm

发明人： Rainer Dyllick-Brenzinger ,  Alban Glaser ,  Arno Bohm

IPC分类号： C08F2/22 ,  C08F2/44 ,  C08K5/00 ,  C08L33/12

CPC分类号： C08F2/22 ,  C08F2/44 ,  C08K5/0008 ,  C08L2312/00 ,  C09D133/04 ,  Y10T428/2998 ,  C08L33/12

摘要： Aqueous polymer dispersions comprising effect substance and having an average particle diameter of the dispersed particles of

摘要翻译： 包含效应物质并具有<500nm的分散颗粒的平均粒径的聚合物水分散体，其中聚合物颗粒包含由至少一种烯属不饱和单体作为核构成的聚合物基体，其表面至少部分地 可溶于形成颗粒的聚合物基质的单体中的作用物质，通过烯键式不饱和单体的细乳液聚合制备这种聚合物分散体的方法，其中制备具有<500nm乳化颗粒的平均粒径的细乳液 通过在至少一种效应物质和表面活性剂的存在下在水中乳化烯键式不饱和单体，并且在至少一种自由基聚合引发剂的存在下聚合，最初只有至多50％ 位于聚合区中的单体聚合，其中 效果物质迁移到乳化颗粒的表面，只有在所得聚合物颗粒的表面上广泛或完全积聚效应物质后，聚合才能完成，并且通过蒸发掉水分散体或其可获得的粉末， 在制造纸，皮革或纺织品期间以及用于动物营养的制剂中，在化妆品和药物配方中，在涂料涂层中稳定聚合物以抵抗UV辐射，氧气和热的影响。

公开(公告)号：US20090030206A1

公开(公告)日：2009-01-29

申请号：US11573948

申请日：2005-08-04

申请人： Martin Konemann ,  Arno Bohm ,  Hermann Bidlingmaier ,  Reinhold Rieger ,  Peter Blaschka ,  Helmut Reichelt ,  Matthias Krieger

发明人： Martin Konemann ,  Arno Bohm ,  Hermann Bidlingmaier ,  Reinhold Rieger ,  Peter Blaschka ,  Helmut Reichelt ,  Matthias Krieger

IPC分类号： C07D471/06

CPC分类号： C07D471/06 ,  C09B5/62

摘要： A process for preparing quaterrylene-3,4:13,14-tetracarboximides of the general formula I in which R, R′ are each independently hydrogen or optionally substituted C1-C30-alkyl, C5-C8-cycloalky or aryl or hetaryl; which comprises reacting a perylene-3,4-dicarboximide of the general formula IIa in the presence of a base-stable, high-boiling, organic solvent and of an alkali metal base or alkaline earth metal base, with a perylene-3,4-dicarboximide of the general formula IIb in which X is hydrogen, bromine or chlorine.

摘要翻译： 制备通式I的四亚甲基-3,4：13,14-四甲酰亚胺的方法，其中R，R'各自独立地为氢或任选取代的C 1 -C 30 - 烷基，C 5 -C 8 - 环烷基或芳基或杂芳基; 其包括在碱稳定的高沸点有机溶剂和碱金属碱金属或碱土金属碱的存在下使通式IIa的苝-3,4-二羧酰亚胺与苝-3,4 通式IIb的二酰亚胺，其中X是氢，溴或氯。

公开(公告)号：US20080167467A1

公开(公告)日：2008-07-10

申请号：US11994719

申请日：2006-07-06

申请人： Martin Konemann ,  Arno Bohm ,  Neil Gregory Pschirer ,  Jianqiang Qu ,  Gabriele Mattern

发明人： Martin Konemann ,  Arno Bohm ,  Neil Gregory Pschirer ,  Jianqiang Qu ,  Gabriele Mattern

IPC分类号： C07D221/18

CPC分类号： C07D493/06 ,  C07D471/06 ,  C08K5/0041 ,  C08K5/3437

摘要： Rylene derivatives of the general formula I in which the variables are each defined as follows: Rylene is a polycyclic conjugated ring system which comprises at least one perylene unit may comprise heteroatoms as ring atoms, may be functionalized by moieties comprising —CO— groups and/or may bear further substituents other than the A radicals; A is a radical of the formula X is oxygen or sulfur; R are identical or different radicals: optionally substituted alkyl, cycloalkyl, aryl, hetaryl, —U-aryl where U is an —O—, —S—, —NR2—, —CO—, —SO— or —SO2— moiety, or C1-C12-alkoxy, C1-C6-alkylthio, —C≡CR2, —CR2═CR22, hydroxy, mercapto, halogen, cyano, nitro, —NR3R4, —NR3COR4, —CONR3R4, —SO2NR3R4, —COOR3 or —SO3R3; R′ are identical or different radicals: hydrogen or one of the R radicals; R2 is hydrogen or alkyl, where the R2 radicals may be the same or different when they occur more than once; R3, R4 are each independently hydrogen; optionally substituted alkyl, aryl or hetaryl; n is from 1 to 8.

摘要翻译： 通式I的亚芳基衍生物各自定义如下：Rylene是多环共轭环系，其包含至少一个苝单元可以包含杂原子作为环原子，可以由包含-CO-基团和/ 或者可以承担除了A基团之外的其它取代基; A是式X的基团是氧或硫; R是相同或不同的基团：任选取代的烷基，环烷基，芳基，杂芳基，-U-芳基，其中U是-O - ， - S - ， - NR 2 - ， - CO-， - SO - 或-SO 2 - 部分，或C 1 -C 12 - 烷氧基，C 1 -C -C≡CR2，-CR 2 -CR 2，2 - ， - 羟基，巯基，卤素，氰基，硝基，-NR 3，R 4，-NR 3，COR 4， SO 2，SO 2，SO 2，SO 2，SO 3，SO 4，SO 2， >，-COOR 3或-SO 3 R 3; R'是相同或不同的基团：氢或R基团之一; R 2是氢或烷基，其中R 2个基团当它们不止一次出现时可以相同或不同; R 3，R 4各自独立地为氢; 任选取代的烷基，芳基或杂芳基; n为1至8。

公开(公告)号：US20070151478A1

公开(公告)日：2007-07-05

申请号：US10587361

申请日：2005-02-04

申请人： Peter Erk ,  Andreas Stohr ,  Arno Bohm ,  Walter Kurtz ,  Jin Mizuguchi ,  Benno Sens

发明人： Peter Erk ,  Andreas Stohr ,  Arno Bohm ,  Walter Kurtz ,  Jin Mizuguchi ,  Benno Sens

IPC分类号： C09D11/00

CPC分类号： C09B5/62 ,  C09B67/0034

摘要： Black perylene pigments which comprise one of the isomers of the formula Ia or Ib in which R1, R2 are each independently phenylene, naphthylene or pyridylene, each of which may be mono- or polysubstituted by C1-C12-alkyl, C1-C6-alkoxy, hydroxyl, nitro, and/or halogen; X is halogen; n Is from 0 to 4, or comprises a mixture of both isomers and has a blackness value ≧210 in an alkyd/melamine baking varnish.

摘要翻译： 包含式Ia或Ib的异构体之一的黑色苝颜料各自独立为亚苯基，亚萘基或亚吡啶基，其中每一个可以是 被C 1 -C 12 - 烷基，C 1 -C 6 - 烷氧基，C 1 -C 6 - 烷氧基，C 1 -C 12 - ，硝基和/或卤素; X是卤素; n为0〜4，或者在醇酸/三聚氰胺烘烤清漆中含有两种异构体的混合物，其黑度值> 210。

公开(公告)号：US20060075585A1

公开(公告)日：2006-04-13

申请号：US10522990

申请日：2003-07-25

申请人： Matthias Krieger ,  Arno Bohm ,  Lorenz Siggel ,  Stefan Becker ,  Klaus Mullen ,  Christopher Kohl

发明人： Matthias Krieger ,  Arno Bohm ,  Lorenz Siggel ,  Stefan Becker ,  Klaus Mullen ,  Christopher Kohl

IPC分类号： C09B49/00

CPC分类号： C09B5/62

摘要： Rylene dyes of the general formula I where the variables are defined as follows: R is hydrogen; optionally substituted C1-C30-alkyl, C5-C8-cycloalkyl, aryl or hetaryl; R′ is bromine; cyano; —NR32; optionally substituted aryloxy, arylthio, hetaryloxy or hetarylthio; optionally substituted C3-C18-alk-1-ynyl; X, Y are both hydrogen or together are a radical of the formula Ia n is 2, 3, 4 or additionally 1 when X and Y are a radical of the formula Ia; n′ is from 1 to 4; m is from 0 to 6.

摘要翻译： 通式I的Rylene染料，其中变量定义如下：R是氢; 芳基或杂芳基;任选取代的C 1 -C 30 - 烷基，C 5 -C 8 - 环烷基，芳基或杂芳基; R'是溴; 氰基; -NR 3 3; 任选取代的芳氧基，芳硫基，杂芳氧基或杂芳硫基; 任选取代的C 3 -C 18 - 烷-1-基; 当X和Y是式Ia的基团时，X，Y都是氢或一起是式Ia n的基团是2,3,4或另外1， n'为1至4; m为0〜6。

公开(公告)号：US20050131220A1

公开(公告)日：2005-06-16

申请号：US10510579

申请日：2003-04-15

申请人： Bernhard Dung ,  Felix Muller ,  Arno Bohm ,  Willi Helfer ,  Volker Wevrauch ,  Georg Henning

发明人： Bernhard Dung ,  Felix Muller ,  Arno Bohm ,  Willi Helfer ,  Volker Wevrauch ,  Georg Henning

IPC分类号： C07D221/14 ,  C07D487/06 ,  C09B5/62 ,  C09B57/08 ,  C07D471/02

CPC分类号： C09B5/62 ,  C09B57/08

摘要： A process for preparing perylene-3,4:9,10-tetracarboxylic diimides of the general formula I where R is C1-C30-alkyl whose carbon chain may be interrupted by one or more —O— moieties and/or which may be substituted by one or more substituents selected from the group consisting of C5-C8-cycloalkyl (which may be substituted by one or more C1-C6-alkyl substituents), phenyl or phenyl-C1-C6-alkyl (which may each be substituted by one or more C1-C18-alkyl and/or C1-C6-alkoxy substituents), —OCOR1, —N(R1)2, —SO2NH2, —SO2N(R1)2, —CON(R1)2 and —COOR1; C5-C8-cycloalkyl whose carbon skeleton may be interrupted by one or more moieties selected from the group consisting of —O—, —S— and —NR2- and/or which may be substituted by one or more C1-C6-alkyl substituents; phenyl, phenyl-C1-C6-alkyl, naphthyl or hetaryl, which may each be substituted by one or more substituents selected from the group consisting of C1-C18-alkyl, C1-C6-alkoxy, phenylazo, naphthylazo, pyridylazo, pyrimidylazo, cyano, —N(R1)2, —CON(R1)2 and —COOR1; R1 is C1-C6-alkyl, C5-C8-cycloalkyl, phenyl or phenyl-C1-C6-alkyl; R2 is C1-C6-alkyl, phenyl or phenyl-C1-C6-alkyl, by dimerizing a naphthalene-1,8-dicarboximide of the formula II comprises effecting said dimerizing in a reaction medium consisting essentially of an a polar aprotic organic solvent and an alkali metal base and subsequently reoxidizing the resulting alkali metal salt of the leuco form of the perylene-3,4:9,10-tetracarboxylic diimide in the presence of a polar solvent, and also preparation of perylene-3,4:9,10-tetracarboxylic dianhydride and naphthalene-1,8-dicarboximides.

公开(公告)号：US6124458A

公开(公告)日：2000-09-26

申请号：US335535

申请日：1999-06-18

申请人： Klaus Muellen ,  Heribert Quante ,  Arno Bohm

发明人： Klaus Muellen ,  Heribert Quante ,  Arno Bohm

IPC分类号： C07D221/18 ,  C07D471/06 ,  C09B5/62 ,  C09B57/08

CPC分类号： C07D221/18 ,  C09B5/62

摘要： Quaterrylenetetracarboxylic diimides I whereR is hydrogen;C.sub.1 -C.sub.30 -alkyl whose carbon chain may be interrupted by one or more of --O--, --S--, --NR.sup.1 --, --CO-- and/or --SO.sub.2 -- and which may be monosubstituted or polysubstituted by cyano, C.sub.1 -C.sub.6 -alkoxy or a 5-, 6- or 7-membered heterocyclic radical which is attached via a nitrogen atom and which may contain further heteroatoms and may be aromatic, whereR.sup.1 is hydrogen or C.sub.1 -C.sub.6 -alkyl;C.sub.5 -C.sub.8 -cycloalkyl whose carbon skeleton may be interrupted by one or more of --O--, --S-- and/or --NR.sup.1 --;aryl or hetaryl, which may each be monosubstituted or poly-substituted by C.sub.1 -C.sub.18 -alkyl, C.sub.1 -C.sub.6 -alkoxy, cyano, --CONHR.sup.2, --NHCOR.sup.2 and/or aryl- or hetaryl-azo, which may each be substituted by C.sub.1 -C.sub.10 -alkyl, C.sub.1 -C.sub.6 -alkoxy or cyano, whereR.sup.2 is hydrogen; C.sub.1 -C.sub.18 -alkyl; aryl or hetaryl, which may each be substituted by C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -alkoxy, halogen or cyano;X is halogen; C.sub.1 -C.sub.18 -alkyl; aryloxy, arylthio, hetaryloxy or hetarylthio, which may each be substituted by C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxy;n is from 2 to 12,their preparation and use as pigments or fluorescent dyes and also substituted 9-haloperylene-3,4-dicarbimides III as intermediates therefor.

摘要翻译： 四芳基四羧酸二酰亚胺I，其中R是氢; 其碳链可以被-O - ， - S - ， - NR 1 - ， - CO - 和/或-SO 2 - 中的一个或多个中断的C 1 -C 30 - 烷基，并且其可以被氰基，C 1 -C 6单取代或多取代 - 烷氧基或5-，6-或7-元杂环基，其通过氮原子连接并且可以含有另外的杂原子并且可以是芳族的，其中R 1是氢或C 1 -C 6 - 烷基; 碳骨架可被-O - ， - S-和/或-NR1-中的一个或多个中断的C 5 -C 8 - 环烷基; 芳基或杂芳基，其可以各自被C1-C18-烷基，C1-C6-烷氧基，氰基，-CONHR2，-NHCOR2和/或芳基 - 或杂芳基 - 偶氮基单取代或多取代，其可以各自被C1 -C 10 - 烷基，C 1 -C 6 - 烷氧基或氰基，其中R 2是氢; C1-C18-烷基; 芳基或杂芳基，其各自可被C 1 -C 6 - 烷基，C 1 -C 6 - 烷氧基，卤素或氰基取代; X是卤素; C1-C18-烷基; 芳氧基，芳硫基，杂芳氧基或杂芳硫基，其各自可被C 1 -C 4 - 烷基或C 1 -C 4 - 烷氧基取代; n为2至12，它们的制备和用作颜料或荧光染料，并且还取代了9-卤代亚烷基-3,4-二酰亚胺III作为其中间体。

公开(公告)号：US20090176985A1

公开(公告)日：2009-07-09

申请号：US12346262

申请日：2008-12-30

申请人： Peter ERK ,  Simone Schaefer ,  Arno Bohm ,  Peter Blaschka ,  Harald Arms ,  Willi Helfer

发明人： Peter ERK ,  Simone Schaefer ,  Arno Bohm ,  Peter Blaschka ,  Harald Arms ,  Willi Helfer

IPC分类号： C07D471/06

CPC分类号： C09B67/0014 ,  C09B67/0025

摘要： A process for converting perylene-3,4:9,10-tetracarboximides of the general formula I in which R1 and R2 are each unbranched, branched or cyclic C1-C8-alkyl to a form suitable for use as fluorescent dyes, which comprises a) dissolving or suspending the perylene-3,4:9,10-tetracarboximides whose molecules have a molecular volume of ≦230 Å3 in an organic or inorganic solvent at from 0 to 250° C., b1) cooling the solution obtained in step a) to or below the crystallization temperature and, in the case of an organic solvent, if desired at the same time removing excess solvent until the first crystals form, or, in the case of an inorganic solvent, adding water or dilute aqueous solutions of the solvent until the first crystals form, and maintaining the solution at this temperature for further crystallization or b2) cooling the suspension obtained in step a) to or below the crystallization temperature when the temperature in step a) was above the crystallization temperature, and maintaining the suspension at this temperature for further crystallization, c) isolating the solvate crystals formed in step b) and d) then removing the solvent from the solvate crystals, and also novel crystalline forms of perylene-3,4:9,10-tetracarboxylic diimides.

摘要翻译： 用于将通式I的苝-3,4：9,10-四甲酰亚胺转化为其中R 1和R 2各自是非支链，支链或环状的C 1 -C 8烷基的方法，其适于用作荧光染料，其包含 ）在0-250℃下将分子体积分数为<= 230的二萘嵌苯-3,4：9,10-四甲酰亚胺溶解或悬浮在有机或无机溶剂中，b1）冷却步骤 a）达到或低于结晶温度，并且在有机溶剂的情况下，如果需要，同时除去过量的溶剂直到形成第一晶体，或者在无机溶剂的情况下，加入水或稀的水溶液 溶剂直至形成第一晶体，并将溶液保持在该温度下进一步结晶，或b）当步骤a）中的温度高于结晶温度时，将步骤a）中获得的悬浮液冷却至或低于结晶温度，并维持 g在该温度下的悬浮液进一步结晶，c）分离步骤b）中形成的溶剂合物晶体，d）然后从溶剂合物晶体中除去溶剂，以及新型的苝-3,4：9,10-四羧酸的结晶形式 二酰亚胺