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公开(公告)号：US08835578B2
公开(公告)日：2014-09-16
申请号：US13579027
申请日：2011-02-22
IPC分类号： C08F4/649 , C08F110/06
CPC分类号： C08F110/06 , C08F4/6545 , C08F4/6465 , C08F4/651 , C08F2500/15
摘要： Catalyst component for the polymerization of olefins CH2═CHR in which R is hydrogen or a hydrocarbyl radical with 1-12 carbon atoms, comprising Mg, Ti, halogen and two electron donor compounds one of which selected from alkoxybenzenes and the other being selected from those of formula (II) where RI and RII are the same or different and are hydrogen or linear or branched C1-C18 hydrocarbon groups which can also form one or more cyclic structures; RIII groups, equal or different from each other, are hydrogen or C1-C18 hydrocarbon groups; RIV groups equal or different from each other, have the same meaning of RIII except that they cannot be hydrogen; each of RI to RIV groups can contain heteroatoms selected from halogens, N, O, S and Si.
摘要翻译： 用于烯烃CH 2 = CHR聚合的催化剂组分，其中R是氢或具有1-12个碳原子的烃基，包括Mg，Ti，卤素和两种电子给体化合物，其中一种选自烷氧基苯，另一种选自那些 其中R 1和R II相同或不同，为氢或可以形成一个或多个环状结构的直链或支链C 1 -C 18烃基; 相同或不同的RIII基团是氢或C 1 -C 18烃基; RIV基团相同或不同，具有与RIII相同的含义，不同之处在于它们不能是氢; 每个RI至RIV基团可以含有选自卤素，N，O，S和Si的杂原子。
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公开(公告)号：US08829126B2
公开(公告)日：2014-09-09
申请号：US13579029
申请日：2011-02-22
IPC分类号： C08F4/649 , C08F210/06
CPC分类号： C08F110/06 , C08F4/6545 , C08F4/651 , C08F4/6465 , C08F2500/15
摘要： Catalyst component for the polymerization of olefins comprising Mg, Ti, halogen and two electron donor compounds one of which selected those of formula (I) and the other being selected from succinates of formula (II):
摘要翻译： 包含Mg，Ti，卤素和两种电子给体化合物的烯烃聚合的催化剂组分，其中一种选自式（I），另一种选自式（II）的琥珀酸盐：
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公开(公告)号：US09593171B2
公开(公告)日：2017-03-14
申请号：US14111144
申请日：2012-03-29
申请人： Simona Guidotti , Giampiero Morini , Simona Esposito , Alessandro Mignogna , Joachim T. M. Pater , Fabrizio Piemontesi , Diego Brita
发明人： Simona Guidotti , Giampiero Morini , Simona Esposito , Alessandro Mignogna , Joachim T. M. Pater , Fabrizio Piemontesi , Diego Brita
CPC分类号： C08F4/16 , C08F10/06 , C08F4/651 , C08F110/06 , C08F2500/12 , C08F2500/15 , C08F2500/02 , C08F210/06 , C08F2/001
摘要： A porous solid catalyst component comprising a magnesium halide, a titanium compound having at least a Ti-halogen bond and at least two electron donor compounds one of which being selected from 1,3-diethers and the other being selected from succinates, characterized by the fact that the molar ratio ID/Ti is from 0.30 to 0.90, where ID is the total molar amount of succinate and 1,3-diether, the molar ratio of the 1,3-diether donor to the succinate donor is higher than, or equal to, 0.60.
摘要翻译： 一种多孔固体催化剂组分，其包含卤化镁，至少具有Ti-卤素键的钛化合物和至少两种电子给体化合物，其中一种选自1,3-二醚，另一种选自琥珀酸盐，其特征在于 事实上，ID / Ti的摩尔比为0.30〜0.90，其中ID是琥珀酸盐和1,3-二醚的总摩尔量，1,3-二醚供体与琥珀酸盐供体的摩尔比高于或 等于0.60。
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4.发明授权Magnesium dichloride-alcohol adducts and catalyst components obtained therefrom 失效二氯化镁 - 醇加合物和由其获得的催化剂组分公开(公告)号：US08481445B2
公开(公告)日：2013-07-09
申请号：US13394042
申请日：2010-09-03
CPC分类号： C08F110/06 , C08F10/06 , C08F4/022 , C08F4/651 , C08F4/6545
摘要： Solid adducts comprising a MgCl2, ethanol and a compound (A), said compounds being present in molar ratios defined by the following formula MgCl2.(EtOH)n(A)p in which n is from 0.1 to 6, p ranges from 0.001 to 0.5 and A is a compound selected from cyclic hydrocarbon structures which are substituted with at least two hydroxy groups.
摘要翻译： 包含MgCl 2，乙醇和化合物（A）的固体加合物，所述化合物以下式MgCl 2（EtOH）n（A）p定义的摩尔比存在，其中n为0.1至6，p为0.001至 0.5和A是选自被至少两个羟基取代的环状烃结构的化合物。
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5.发明授权公开(公告)号：US09068029B2
公开(公告)日：2015-06-30
申请号：US13509488
申请日：2010-11-15
申请人： Gianni Collina , Marco Ciarafoni , Ofelia Fusco , Benedetta Gaddi , Monica Galvan , Giampiero Morini , Roberto Pantaleoni , Joachim T. M. Pater , Fabrizio Piemontesi , Francesca Verrocchio
发明人： Gianni Collina , Marco Ciarafoni , Ofelia Fusco , Benedetta Gaddi , Monica Galvan , Giampiero Morini , Roberto Pantaleoni , Joachim T. M. Pater , Fabrizio Piemontesi , Francesca Verrocchio
IPC分类号： C08F10/06 , C08F210/06 , C08F110/06 , C08F210/16
CPC分类号： C08F10/06 , C08F110/06 , C08F210/06 , C08F210/16 , C08F2/001 , C08F4/6494 , C08F4/651 , C08F2500/12 , C08F2500/15 , C08F2500/05
摘要： A process for the preparation of propylene polymer compositions comprising from 50 to 90% by weight of a propylene polymer fraction insoluble in xylene at 25° C., and from 10 to 50% by weight of an ethylene copolymer fraction soluble in xylene at 25° C., said process being carried out in the presence of a specific catalyst system, is also characterized by the following step: (i) contacting the catalyst components (a), (b) and optionally (c) for a period of time ranging from 0.1 to 120 minutes, at a temperature ranging from 0 to 90° C.; (ii) polymerizing propylene in the optional presence of ethylene and/or C4-C10 alpha olefins producing a propylene (co)polymer being for at least 85% by weight of insoluble in xylene at 25° C. and (iii) in a successive step, carried out in gas-phase, in the presence of the product coming from (ii), polymerizing mixtures of ethylene with α-olefins CH2═CHR in which R is a hydrocarbon radical having 1-10 carbon atoms, to produce an ethylene copolymer. An increased reactivity in the last step is observed.
摘要翻译： 一种用于制备丙烯聚合物组合物的方法，其包含50至90重量％的在25℃下不溶于二甲苯的丙烯聚合物部分和10至50重量％在25℃下可溶于二甲苯的乙烯共聚物部分 所述方法在特定催化剂体系的存在下进行，其特征还在于以下步骤：（i）使催化剂组分（a），（b）和任选的（c）接触一段时间 0.1至120分钟，温度范围为0至90℃; （ii）在乙烯和/或C 4 -C 10α-烯烃任选存在下聚合丙烯，产生丙烯（共）聚合物，其至少85重量％在25℃下不溶于二甲苯，和（iii）连续 在（ii）产物存在下，在气相中进行步骤，将乙烯与α-烯烃CH 2 = CHR的混合物聚合，其中R是具有1-10个碳原子的烃基，得到乙烯 共聚物。 观察到在最后步骤中增加的反应性。
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公开(公告)号：US09034783B2
公开(公告)日：2015-05-19
申请号：US14125502
申请日：2012-06-15
申请人： Alessandro Mignogna , Davide Balboni , Antonio Cristofori , Simona Guidotti , Giampiero Morini , Joachim T. M. Pater
发明人： Alessandro Mignogna , Davide Balboni , Antonio Cristofori , Simona Guidotti , Giampiero Morini , Joachim T. M. Pater
IPC分类号： B01J37/00 , C08F4/02 , C08F4/60 , B01J27/06 , C08F4/44 , C08F2/00 , C08F4/50 , C08F10/00 , C08F4/16 , C08F110/06
CPC分类号： C08F4/50 , C08F4/16 , C08F10/00 , C08F110/06 , C08F4/651 , C08F2500/12 , C08F4/6541
摘要： Catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor compound of the following formula (I) In which R1 to R4 groups, equal to or different from each other, are hydrogen, C1-C15 hydrocarbon groups, optionally containing an heteroatom selected from halogen, P, S, N and Si, R6 group is selected from C1-C15 hydrocarbon groups optionally containing an heteroatom selected from halogen, P, S, N and Si, and R5 is selected from phenyl groups mono or poly substituted with halogens, said groups R1-R4 being also optionally linked to form a saturated or unsaturated mono or poly cycle.
摘要翻译： 包含Mg，Ti和下式（I）的电子给体化合物的烯烃聚合的催化剂组分，其中相同或不同的R 1至R 4基团为氢，任选地含有 选自卤素，P，S，N和Si的杂原子，R6基团选自任选含有选自卤素，P，S，N和Si的杂原子的C 1 -C 15烃基，R 5选自苯基单取代或多取代 通过卤素，所述基团R 1 -R 4也任选连接形成饱和或不饱和的单或多环。
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公开(公告)号：US08921253B2
公开(公告)日：2014-12-30
申请号：US14352251
申请日：2012-10-10
CPC分类号： C08F4/52 , C08F110/06 , C08F2500/12 , C08F4/651 , C08F4/6545
摘要： Catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor compound of the following formula (I) In which R to R4 groups, equal to or different from each other, are hydrogen, halogen or C1-C15 hydrocarbon groups, optionally containing an heteroatom selected from halogen, P, S, N and Si, which may be linked to form a saturated or unsaturated mono or polycycle and R5 groups are selected from C1-C15 hydrocarbon groups optionally containing an heteroatom selected from halogen, P, S, N and Si.
摘要翻译： 用于包含Mg，Ti和下式（I）的电子给体化合物的烯烃聚合的催化剂组分其中R至R 4基团彼此相同或不同的是氢，卤素或C 1 -C 15烃基，任选地 含有选自卤素，P，S，N和Si的杂原子，其可以连接形成饱和或不饱和的单环或多环和R 5基团，其选自任选地含有选自卤素，P，S的杂原子的C 1 -C 15烃基 ，N和Si。
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公开(公告)号：US20100160154A1
公开(公告)日：2010-06-24
申请号：US12308623
申请日：2007-06-01
申请人： Giampiero Morini , Antonio Cristofori , Benedetta Gaddi , Dario Liguori , Joachim T. M. Pater , Gianni Vitale
发明人： Giampiero Morini , Antonio Cristofori , Benedetta Gaddi , Dario Liguori , Joachim T. M. Pater , Gianni Vitale
CPC分类号： C08F10/00 , C08F110/02 , C08F110/06 , C08F210/16 , C08F4/6548 , C08F4/6555 , C08F4/651 , C08F2500/18 , C08F2500/12 , C08F210/06 , C08F210/08
摘要： Catalyst precursors comprising Mg, Cl, Ti, and OR groups that are in molar ratios defined by the formula MgClnTip(OR)(2-n)+4p in which n is from 0.3 to less than 1.7, p is lower than 0.6, the molar ratio (OR)/Cl is lower than 4 and R is C1-C15 hydrocarbon groups. The said precursor, just upon activation with organo-Al compounds, are able to advantageously polymerize ethylene and alpha olefins, and that upon reaction with halogenating compounds generate in high yields catalyst components with high polymerization activity particularly in the polymerization of propylene also in combination with 1,3-diethers.
摘要翻译： 包含Mg，Cl，Ti和OR基团的催化剂前体，其摩尔比由式MgClnTip（OR）（2-n）+ 4p定义，其中n为0.3至小于1.7，p低于0.6， 摩尔比（OR）/ Cl低于4，R为C1-C15烃基。 所述前体刚好在有机铝化合物活化后能够有利地聚合乙烯和α-烯烃，并且当与卤化化合物反应时，产生高产率的催化剂组分，具有高聚合活性，特别是在丙烯的聚合中也与 1,3-二醚。
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公开(公告)号：US10155825B2
公开(公告)日：2018-12-18
申请号：US13818626
申请日：2011-08-10
申请人： Joachim T. M. Pater , Dario Liguori , Gianni Vitale , Gianni Collina , Diego Brita , Tiziano Dall'Occo , Giampiero Morini
发明人： Joachim T. M. Pater , Dario Liguori , Gianni Vitale , Gianni Collina , Diego Brita , Tiziano Dall'Occo , Giampiero Morini
IPC分类号： C08F4/649 , C08F10/00 , C08F4/46 , C08F210/16
摘要： A solid catalyst component for olefin polymerization, and in particular for the preparation of LLDPE, comprising Mg, Ti, halogen and an electron donor compound (ID) belonging to cyclic ethers having 3-6 carbon atoms, characterized by having the molar ratio Mg/Ti higher than 5, the molar ratio Mg/ID lower than 3, and by a specific X-ray diffraction spectrum.
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10.发明授权公开(公告)号：US07871952B1
公开(公告)日：2011-01-18
申请号：US12587188
申请日：2009-10-02
CPC分类号： B01J31/143 , B01J31/0201 , B01J31/0232 , B01J31/0244 , B01J31/0271 , B01J2231/122 , B01J2531/46 , B01J2531/56 , C08F10/00 , C08F110/02 , C08F210/16 , C08F4/6355 , C08F4/631 , C08F210/08 , C08F2500/12 , C08F2500/04 , C08F2500/09 , C08F4/6295
摘要： A modified Ziegler-Natta catalyst system, a method for preparing the catalyst system, and a process for polymerizing an olefin in the presence of the catalyst system are disclosed. The catalyst system comprises a titanium or vanadium compound, an aluminum compound, and a 2-hydroxypyridine N-oxide. Improved properties such as increased molecular weight are obtained.
摘要翻译： 公开了改进的齐格勒 - 纳塔催化剂体系，制备催化剂体系的方法和在催化剂体系存在下使烯烃聚合的方法。 催化剂体系包括钛或钒化合物，铝化合物和2-羟基吡啶N-氧化物。 获得改进的性能，例如分子量增加。
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