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公开(公告)号:US07763098B2
公开(公告)日:2010-07-27
申请号:US11559514
申请日:2006-11-14
IPC分类号: B01D53/02
CPC分类号: C01B3/56 , B01D53/02 , B01D53/0473 , B01D2253/102 , B01D2253/104 , B01D2253/108 , B01D2256/16 , B01D2257/502 , B01D2259/403 , C01B2203/043 , C01B2203/0475
摘要: Embodiments of a rapid cycle PSA apparatus are described that are useful for producing a hydrogen enriched product gas comprising not more than about 50 ppm carbon monoxide by volume and with a hydrogen gas recovery of at least about 70% by adsorptive separation from a syngas feed gas mixture comprising at least about 50 percent hydrogen and at least about 1 percent carbon monoxide by volume. One disclosed embodiment of a rapid cycle PSA apparatus comprised at least 3 adsorber elements each having at least one thin adsorbent sheet material which comprises at least one adsorbent material therein, and a bed size factor less than about 4.0 seconds. Embodiments of a rapid cycle PSA process also are described that utilize disclosed embodiments of the rapid-cycle PSA device.
摘要翻译: 描述了一种快速循环PSA装置的实施方案,其可用于生产包含不超过约50ppm体积的一氧化碳和通过从合成气进料气体吸附分离至少约70%的氢气回收的富氢产物气体 包含至少约50%氢气和至少约1%体积的一氧化碳的混合物。 快速循环PSA装置的一个公开的实施方案包括至少3个吸附器元件,每个吸附器元件具有至少一个薄吸附片材料,其包含至少一种吸附材料,以及小于约4.0秒的床尺寸因子。 还描述了利用快速循环PSA装置的公开实施例的快速循环PSA方法的实施方案。
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公开(公告)号:US07645324B2
公开(公告)日:2010-01-12
申请号:US11326657
申请日:2006-01-06
申请人: Edward J. Rode , Andre J. J. Boulet , Aaron M. Pelman , Matthew L. Babicki , Bowie G. Keefer , James A. Sawada , Soheil Alizadeh-Khiavi , Surajit Roy , Andrea C. Gibbs , Steven M. Kuznicki
发明人: Edward J. Rode , Andre J. J. Boulet , Aaron M. Pelman , Matthew L. Babicki , Bowie G. Keefer , James A. Sawada , Soheil Alizadeh-Khiavi , Surajit Roy , Andrea C. Gibbs , Steven M. Kuznicki
IPC分类号: B01D53/02
CPC分类号: B01D53/02 , B01D53/0462 , B01D53/047 , B01D53/0473 , B01D2253/10 , B01D2253/108 , B01D2253/25 , B01D2253/304 , B01D2253/311 , B01D2256/10 , B01D2256/24 , B01D2257/504 , B01D2257/7022 , B01D2257/7025 , B01D2259/40005 , B01D2259/40007 , B01D2259/4148 , B01D2259/4575 , B01J20/28052 , Y02C10/08 , Y02C20/20
摘要: Improved adsorbent sheet based parallel passage adsorbent structures for enhancing the kinetic selectivity of certain kinetic-controlled adsorption processes, such as PSA, TSA and PPSA processes, and combinations thereof, are provided. The enhancements in kinetic selectivity made possible through the implementation of the present inventive improved adsorbent structures may unexpectedly enable significant intensification of selected kinetic adsorption processes relative to attainable performance with conventional adsorbent materials in beaded or extruded form. Such process intensification enabled by the present inventive adsorbent structures may provide for increased adsorption cycle frequencies, and increased gas flow velocities within the adsorbent beds, which may increase the productivity and/or recovery of a kinetic adsorption system incorporating the inventive adsorbent structures.
摘要翻译: 提供了改进的吸附片基平行通道吸附结构,用于增强某些动力学控制吸附过程(如PSA,TSA和PPSA方法)的动力学选择性及其组合。 通过实施本发明改进的吸附剂结构使得动力学选择性的增强可能出乎意料地能够使用常规的串联或挤出形式的吸附剂材料相对于可获得的性能而显着增强选定的动力学吸附过程。 通过本发明的吸附剂结构实现的这种过程强化可以提供增加的吸附循环频率和增加的吸附剂床内的气体流速,这可以增加并入本发明的吸附剂结构的动力学吸附系统的生产率和/或回收率。
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公开(公告)号:US20070125228A1
公开(公告)日:2007-06-07
申请号:US11559514
申请日:2006-11-14
IPC分类号: B01D53/02
CPC分类号: C01B3/56 , B01D53/02 , B01D53/0473 , B01D2253/102 , B01D2253/104 , B01D2253/108 , B01D2256/16 , B01D2257/502 , B01D2259/403 , C01B2203/043 , C01B2203/0475
摘要: Embodiments of a rapid cycle PSA apparatus are described that are useful for producing a hydrogen enriched product gas comprising not more than about 50 ppm carbon monoxide by volume and with a hydrogen gas recovery of at least about 70% by adsorptive separation from a syngas feed gas mixture comprising at least about 50 percent hydrogen and at least about 1 percent carbon monoxide by volume. One disclosed embodiment of a rapid cycle PSA apparatus comprised at least 3 adsorber elements each having at least one thin adsorbent sheet material which comprises at least one adsorbent material therein, and a bed size factor less than about 4.0 seconds. Embodiments of a rapid cycle PSA process also are described that utilize disclosed embodiments of the rapid-cycle PSA device.
摘要翻译: 描述了一种快速循环PSA装置的实施方案,其可用于生产包含不超过约50ppm体积的一氧化碳和通过从合成气进料气体吸附分离至少约70%的氢气回收的富氢产物气体 包含至少约50%氢气和至少约1%体积的一氧化碳的混合物。 快速循环PSA装置的一个公开的实施方案包括至少3个吸附器元件,每个吸附器元件具有至少一个薄吸附片材料,其包含至少一种吸附材料,以及小于约4.0秒的床尺寸因子。 还描述了利用快速循环PSA装置的公开实施例的快速循环PSA方法的实施方案。
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公开(公告)号:US07189280B2
公开(公告)日:2007-03-13
申请号:US10881775
申请日:2004-06-29
IPC分类号: B01D53/04
CPC分类号: B01D53/0423 , B01D53/0446 , B01D2256/16 , B01D2256/24 , B01D2257/502 , B01D2259/40086 , B01D2259/4146 , Y02E50/346
摘要: A method and system for adsorptive separation of a feed gas mixture provides for increased system efficiency and product recovery. The requirement for purge gas streams consuming desired product gas to regenerate adsorption beds is reduced through an inventive method for adsorbent selection and adsorption bed and process design.
摘要翻译: 用于进料气体混合物的吸附分离的方法和系统提供了提高的系统效率和产物回收率。 通过用于吸附剂选择和吸附床和工艺设计的本发明方法,减少了消耗所需产物气体以再生吸附床的吹扫气流的需求。
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公开(公告)号:US20050284291A1
公开(公告)日:2005-12-29
申请号:US10881775
申请日:2004-06-29
CPC分类号: B01D53/0423 , B01D53/0446 , B01D2256/16 , B01D2256/24 , B01D2257/502 , B01D2259/40086 , B01D2259/4146 , Y02E50/346
摘要: A method and system for adsorptive separation of a feed gas mixture provides for increased system efficiency and product recovery. The requirement for purge gas streams consuming desired product gas to regenerate adsorption beds is reduced through an inventive method for adsorbent selection and adsorption bed and process design.
摘要翻译: 用于进料气体混合物的吸附分离的方法和系统提供了提高的系统效率和产物回收率。 通过用于吸附剂选择和吸附床和工艺设计的本发明方法,减少了消耗所需产物气体以再生吸附床的吹扫气流的需求。
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公开(公告)号:US20100166645A1
公开(公告)日:2010-07-01
申请号:US12445934
申请日:2007-10-25
申请人: Rajeev Agnihotri , Soheil Alizadeh-Khiavi , Paul Berlowitz , Brooke Cox , Bruce Derites , Jeffrey Frederick , Jeffrey Grenda , Kamal Hatami , Frank Hershkowitz , Zhiguo Hou , Daryl Musselman , Novica Rados , John Siller , Richard Socha , George Walchuk
发明人: Rajeev Agnihotri , Soheil Alizadeh-Khiavi , Paul Berlowitz , Brooke Cox , Bruce Derites , Jeffrey Frederick , Jeffrey Grenda , Kamal Hatami , Frank Hershkowitz , Zhiguo Hou , Daryl Musselman , Novica Rados , John Siller , Richard Socha , George Walchuk
CPC分类号: B01J8/18 , C01B3/34 , C01B3/38 , C01B3/46 , C01B3/48 , C01B3/56 , C01B2203/0233 , C01B2203/0283 , C01B2203/043 , C01B2203/047 , C01B2203/0475 , C01B2203/0495 , C01B2203/066 , C01B2203/1211 , C01B2203/1223 , C01B2203/1288 , F01L7/00 , F01L2003/25 , F16K11/074 , F16K11/085 , Y10T156/10
摘要: Embodiments of a compact pressure swing reformer are disclosed. Certain embodiments have a construction comprising multiple rotating reformer beds, high temperature rotary valves at the bed ends, and E-seals to seal the beds to the valves. Several possible designs for introducing reactants into the beds also are disclosed. The multiple reformer beds are configured to provide for pressure equalization and ‘steam push’. The compact pressure swing reformer is suitable for use in fuel cell vehicle applications.
摘要翻译: 公开了紧凑型压力摆动重整器的实施例。 某些实施例具有包括多个旋转重整床,床端部的高温旋转阀和用于将床密封到阀的E形密封件的结构。 还公开了将反应物引入床中的几种可能的设计。 多个重整器床被配置成提供压力平衡和“蒸汽推动”。 紧凑型压力摆动重整器适用于燃料电池车辆应用。
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公开(公告)号:US20130270484A1
公开(公告)日:2013-10-17
申请号:US13630620
申请日:2012-09-28
IPC分类号: C01B3/34
CPC分类号: B01J8/18 , C01B3/34 , C01B3/38 , C01B3/46 , C01B3/48 , C01B3/56 , C01B2203/0233 , C01B2203/0283 , C01B2203/043 , C01B2203/047 , C01B2203/0475 , C01B2203/0495 , C01B2203/066 , C01B2203/1211 , C01B2203/1223 , C01B2203/1288 , F01L7/00 , F01L2003/25 , F16K11/074 , F16K11/085 , Y10T156/10
摘要: Embodiments of a compact pressure swing reformer are disclosed. Certain embodiments have a construction comprising multiple rotating reformer beds, high temperature rotary valves at the bed ends, and E-seals to seal the beds to the valves. Several possible designs for introducing reactants into the beds also are disclosed. The multiple reformer beds are configured to provide for pressure equalization and ‘steam push’. The compact pressure swing reformer is suitable for use in fuel cell vehicle applications.
摘要翻译: 公开了紧凑型压力摆动重整器的实施例。 某些实施例具有包括多个旋转重整床,床端部的高温旋转阀和用于将床密封到阀的E形密封件的结构。 还公开了将反应物引入床中的几种可能的设计。 多个重整器床被配置成提供压力平衡和“蒸汽推动”。 紧凑型压力摆动重整器适用于燃料电池车辆应用。
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公开(公告)号:US20050129952A1
公开(公告)日:2005-06-16
申请号:US10954251
申请日:2004-09-29
CPC分类号: B01J20/28035 , B01D53/02 , B01D53/0462 , B01D53/047 , B01D2253/102 , B01D2253/11 , B01D2253/25 , B01D2253/3425 , B01J20/18 , B01J20/20 , B01J20/28011 , B01J20/28033 , Y10T428/31
摘要: High density adsorbent structures may be constructed in parallel passage contactor configurations using improved high density adsorbent sheets. Improved high density adsorbent sheets may be formed using adsorptively active support or substrate materials upon which adsorbent material is applied, such as by coating processes, so that in the resulting high density adsorbent structure both the substrate and the coated adsorbent material are active in adsorption processes. Alternatively, improved high density adsorbent sheets may be formed comprising precursor materials, such as certain clays, which may be coated onto known support materials and thereafter converted to active adsorbent materials using known conversion techniques. This produces high-density adsorbent sheets comprising adsorbent material without inert binder material fractions. Improved self-supporting adsorbent sheets also may be formed without using support material, resulting in higher adsorbent densities relative to known adsorbent sheets.
摘要翻译: 高密度吸附剂结构可以使用改进的高密度吸附片材在平行通道接触器构造中构造。 改进的高密度吸附片材可以使用吸附性活性载体或其上施加吸附剂材料的基底材料,例如通过涂布方法形成,使得在所得到的高密度吸附剂结构中,基底和涂覆的吸附剂材料在吸附过程中是有活性的 。 或者,可以形成改进的高密度吸附片,其包含前体材料,例如某些粘土,其可涂覆在已知的载体材料上,然后使用已知的转化技术转化为活性吸附剂材料。 这产生了高密度吸附片材,其包括不含惰性粘合剂材料部分的吸附材料。 也可以在不使用载体材料的情况下形成改进的自支撑吸附片,导致相对于已知的吸附片材具有更高的吸附剂密度。
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公开(公告)号:US08551444B2
公开(公告)日:2013-10-08
申请号:US12445934
申请日:2007-10-25
申请人: Rajeev Agnihotri , Soheil Alizadeh-Khiavi , Paul Berlowitz , Brooke Cox , Bruce Derites , Jeffrey Frederick , Jeffrey Grenda , Kamal Hatami , Frank Hershkowitz , Zhiguo Hou , Daryl Musselman , Novica Rados , John Siller , Richard Socha , George Walchuk
发明人: Rajeev Agnihotri , Soheil Alizadeh-Khiavi , Paul Berlowitz , Brooke Cox , Bruce Derites , Jeffrey Frederick , Jeffrey Grenda , Kamal Hatami , Frank Hershkowitz , Zhiguo Hou , Daryl Musselman , Novica Rados , John Siller , Richard Socha , George Walchuk
CPC分类号: B01J8/18 , C01B3/34 , C01B3/38 , C01B3/46 , C01B3/48 , C01B3/56 , C01B2203/0233 , C01B2203/0283 , C01B2203/043 , C01B2203/047 , C01B2203/0475 , C01B2203/0495 , C01B2203/066 , C01B2203/1211 , C01B2203/1223 , C01B2203/1288 , F01L7/00 , F01L2003/25 , F16K11/074 , F16K11/085 , Y10T156/10
摘要: Embodiments of a compact pressure swing reformer are disclosed. Certain embodiments have a construction comprising multiple rotating reformer beds, high temperature rotary valves at the bed ends, and E-seals to seal the beds to the valves. Several possible designs for introducing reactants into the beds also are disclosed. The multiple reformer beds are configured to provide for pressure equalization and ‘steam push’. The compact pressure swing reformer is suitable for use in fuel cell vehicle applications.
摘要翻译: 公开了紧凑型压力摆动重整器的实施例。 某些实施例具有包括多个旋转重整床,床端部的高温旋转阀和用于将床密封到阀的E形密封件的结构。 还公开了将反应物引入床中的几种可能的设计。 多个重整器床被配置成提供压力平衡和“蒸汽推动”。 紧凑型压力摆动重整器适用于燃料电池车辆应用。
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公开(公告)号:US20060169142A1
公开(公告)日:2006-08-03
申请号:US11326657
申请日:2006-01-06
申请人: Edward Rode , Andre Boulet , Aaron Pelman , Matthew Babicki , Bowie Keefer , James Sawada , Soheil Alizadeh-Khiavi , Surajit Roy , Andrea Gibbs , Steven Kuznicki
发明人: Edward Rode , Andre Boulet , Aaron Pelman , Matthew Babicki , Bowie Keefer , James Sawada , Soheil Alizadeh-Khiavi , Surajit Roy , Andrea Gibbs , Steven Kuznicki
IPC分类号: B01D53/02
CPC分类号: B01D53/02 , B01D53/0462 , B01D53/047 , B01D53/0473 , B01D2253/10 , B01D2253/108 , B01D2253/25 , B01D2253/304 , B01D2253/311 , B01D2256/10 , B01D2256/24 , B01D2257/504 , B01D2257/7022 , B01D2257/7025 , B01D2259/40005 , B01D2259/40007 , B01D2259/4148 , B01D2259/4575 , B01J20/28052 , Y02C10/08 , Y02C20/20
摘要: Improved adsorbent sheet based parallel passage adsorbent structures for enhancing the kinetic selectivity of certain kinetic-controlled adsorption processes, such as PSA, TSA and PPSA processes, and combinations thereof, are provided. The enhancements in kinetic selectivity made possible through the implementation of the present inventive improved adsorbent structures may unexpectedly enable significant intensification of selected kinetic adsorption processes relative to attainable performance with conventional adsorbent materials in beaded or extruded form. Such process intensification enabled by the present inventive adsorbent structures may provide for increased adsorption cycle frequencies, and increased gas flow velocities within the adsorbent beds, which may increase the productivity and/or recovery of a kinetic adsorption system incorporating the inventive adsorbent structures.
摘要翻译: 提供了改进的吸附片基平行通道吸附结构,用于增强某些动力学控制吸附过程(如PSA,TSA和PPSA方法)的动力学选择性及其组合。 通过实施本发明改进的吸附剂结构使得动力学选择性的增强可能出乎意料地能够使用常规的串联或挤出形式的吸附剂材料相对于可获得的性能而显着增强选定的动力学吸附过程。 通过本发明的吸附剂结构实现的这种过程强化可以提供增加的吸附循环频率和增加的吸附剂床内的气体流速,这可以增加并入本发明的吸附剂结构的动力学吸附系统的生产率和/或回收率。
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