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    Production of hydrogen via a base-faciliated reaction of carbon monoxide
    6.
    发明申请
    Production of hydrogen via a base-faciliated reaction of carbon monoxide 失效
    通过一氧化碳的碱化反应生产氢气

    公开(公告)号：US20050163706A1

    公开(公告)日：2005-07-28

    申请号：US11079610

    申请日：2005-03-14

    申请人： Benjamin Reichman ,  William Mays ,  James Strebe

    发明人： Benjamin Reichman ,  William Mays ,  James Strebe

    IPC分类号： C10J3/00 ,  C25B1/02 ,  C01B3/12

    CPC分类号： C01B3/065 ,  C01B3/12 ,  C01B3/20 ,  C01D7/07 ,  C10J3/57 ,  C10J3/78 ,  C10J2300/0916 ,  C10J2300/1807 ,  C25B1/02 ,  Y02E60/362 ,  Y02P20/145

    摘要： A method of producing hydrogen gas from a reaction of carbon monoxide with a base. Hydrogen is produced in a reaction of a base with carbon monoxide that proceeds through the formation of a bicarbonate or carbonate compound as a by-product. In some embodiments, the reaction may occur in the presence of water and may produce carbon dioxide as a by-product. The instant base-facilitated hydrogen-producing reactions are thermodynamically more spontaneous than the water-gas shift reaction and are able to produce hydrogen gas from carbon monoxide at greater reaction rates than is possible with the water-gas shift reaction. Carbon monoxide in a purified or unpurified state or as a component within a mixture of gases is suitable for use in the instant invention. Metal hydroxides are the preferred base reactant. The base reactant can be in the solid phase, molten phase, liquid phase or solution phase.

    摘要翻译： 从一氧化碳与碱的反应产生氢气的方法。 在碱与一氧化碳的反应中产生氢气，其通过作为副产物形成碳酸氢盐或碳酸盐化合物而进行。 在一些实施方案中，反应可以在水的存在下进行，并且可以产生作为副产物的二氧化碳。 本发明的碱促进的产氢反应在热力学上比水煤气变换反应更自发，并且能够以比水煤气变换反应可能更大的反应速率从一氧化碳产生氢气。 纯化或未纯化状态的一氧化碳或作为气体混合物中的组分适用于本发明。 金属氢氧化物是优选的基础反应物。 基础反应物可以是固相，熔融相，液相或溶液相。

    Production of hydrogen via a base-facilitated reaction of carbon monoxide
    7.
    发明授权
    Production of hydrogen via a base-facilitated reaction of carbon monoxide 失效
    通过一氧化碳的碱促进反应生产氢气

    公开(公告)号：US07700071B2

    公开(公告)日：2010-04-20

    申请号：US11079610

    申请日：2005-03-14

    申请人： Benjamin Reichman ,  William Mays ,  James Strebe

    发明人： Benjamin Reichman ,  William Mays ,  James Strebe

    IPC分类号： C01B3/08

    CPC分类号： C01B3/065 ,  C01B3/12 ,  C01B3/20 ,  C01D7/07 ,  C10J3/57 ,  C10J3/78 ,  C10J2300/0916 ,  C10J2300/1807 ,  C25B1/02 ,  Y02E60/362 ,  Y02P20/145

    摘要： A method of producing hydrogen gas from a reaction of carbon monoxide with a base. Hydrogen is produced in a reaction of a base with carbon monoxide that proceeds through the formation of a bicarbonate or carbonate compound as a by-product. In some embodiments, the reaction may occur in the presence of water and may produce carbon dioxide as a by-product. The instant base-facilitated hydrogen-producing reactions are thermodynamically more spontaneous than the water-gas shift reaction and are able to produce hydrogen gas from carbon monoxide at greater reaction rates than is possible with the water-gas shift reaction. Carbon monoxide in a purified or unpurified state or as a component within a mixture of gases is suitable for use in the instant invention. Metal hydroxides are the preferred base reactant. The base reactant can be in the solid phase, molten phase, liquid phase or solution phase.

    摘要翻译： 从一氧化碳与碱的反应产生氢气的方法。 在碱与一氧化碳的反应中产生氢气，其通过作为副产物形成碳酸氢盐或碳酸盐化合物而进行。 在一些实施方案中，反应可以在水的存在下进行，并且可以产生作为副产物的二氧化碳。 本发明的碱促进的产氢反应在热力学上比水煤气变换反应更自发，并且能够以比水煤气变换反应可能更大的反应速率从一氧化碳产生氢气。 纯化或未纯化状态的一氧化碳或作为气体混合物中的组分适用于本发明。 金属氢氧化物是优选的基础反应物。 基础反应物可以是固相，熔融相，液相或溶液相。

    Production of hydrogen from non-cyclic organic substances having multiple alcohol functionality
    10.
    发明授权
    Production of hydrogen from non-cyclic organic substances having multiple alcohol functionality 失效
    从具有多个醇官能团的非环状有机物质制备氢气

    公开(公告)号：US07494581B2

    公开(公告)日：2009-02-24

    申请号：US11232272

    申请日：2005-09-21

    申请人： Benjamin Reichman ,  William Mays ,  James Strebe

    发明人： Benjamin Reichman ,  William Mays ,  James Strebe

    IPC分类号： C01B3/22 ,  C25B1/02

    CPC分类号： C01D7/07 ,  C01B3/02 ,  C01B3/323 ,  C01B2203/02 ,  C01B2203/1058 ,  C01B2203/1217 ,  C25B1/02

    摘要： A method of producing hydrogen gas from a reaction of an organic substance having multiple alcohol functionality with a base. Hydrogen can be produced in a reaction of a base with an organic substance having multiple alcohol functionality that may proceed through the formation of a bicarbonate or carbonate compound as a byproduct. In some embodiments, the reaction may occur in the presence of water. The preferred organic substances include diols, triols, and higher order alcohols. Non-cyclic (linear or branched) organic substances having multiple alcohol functionality are among the preferred reactants. The instant base-facilitated hydrogen-producing reactions are thermodynamically more spontaneous than the corresponding conventional reformation reactions of the organic substances and can produce hydrogen at less extreme reaction conditions. The preferred reactants further include low volatility organic substances having multiple alcohol functionality. Such reactants permit the efficient formation of hydrogen in a liquid phase system and enable a continuous reaction capability in the liquid phase without the need to condense volatilized reactant.

    摘要翻译： 从具有多个醇官能团的有机物质与碱的反应产生氢气的方法。 氢可以在碱与具有多个醇官能团的有机物质的反应中生成，所述有机物质可以通过形成作为副产物的碳酸氢盐或碳酸盐化合物而进行。 在一些实施方案中，反应可以在水的存在下进行。 优选的有机物质包括二醇，三醇和高级醇。 具有多个醇官能团的非环状（直链或支链）有机物质是优选的反应物。 本发明的碱促进的产氢反应在热力学上比有机物质的相应常规重整反应更自发，并且可在较不极端的反应条件下产生氢。 优选的反应物还包括具有多个醇官能团的低挥发性有机物质。 这样的反应物允许在液相体系中有效地形成氢气，并且能够在液相中具有连续的反应能力，而不需要使挥发的反应物冷凝。