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    Process for the hydroformylation of higher olefins using cobalt compounds as catalyst
    1.
    发明授权
    Process for the hydroformylation of higher olefins using cobalt compounds as catalyst 有权
    使用钴化合物作为催化剂的高级烯烃的羰基化方法

    公开(公告)号：US06720457B2

    公开(公告)日：2004-04-13

    申请号：US10200752

    申请日：2002-07-24

    申请人： Stefan Drees ,  Bernhard Scholz ,  Alfred Kaizik ,  Walter Toetsch ,  Wilfried Bueschken ,  Martin Trocha

    发明人： Stefan Drees ,  Bernhard Scholz ,  Alfred Kaizik ,  Walter Toetsch ,  Wilfried Bueschken ,  Martin Trocha

    IPC分类号： C07C4549

    CPC分类号： C07C29/16 ,  C07C45/50 ,  C07C31/125 ,  C07C47/02

    摘要： Olefins having from 5 to 24, in particular from 5 to 12, carbon atoms are hydroformylated by reacting an olefin or a mixture of olefins in the presence of an unmodified cobalt catalyst in a single-stage process in a reactor at a temperature of from 100° C. to 220° C. and a pressure of from 100 bar to 400 bar, to obtain an aldehyde, an alcohol or a mixture thereof. An aqueous bottom phase and an organic phase are present in the reactor, the aqueous bottom phase is mixed with the organic phase, and a concentration of the cobalt catalyst, calculated as metallic cobalt, in the aqueous bottom phase is in the range from 0.4 to 1.7% by mass based on the total weight of the aqueous bottom phase. A level of the aqueous bottom phase in the reactor is kept constant during steady-state operation.

    摘要翻译： 具有5至24个，特别是5至12个碳原子的烯烃通过使烯烃或烯烃混合物在未改性的钴催化剂存在下在反应器中的单级方法中在100℃的温度下进行加氢甲酰化 ℃至220℃，压力为100巴至400巴，得到醛，醇或其混合物。 含水底相和有机相存在于反应器中，底部水相与有机相混合，在底部水相中以钴金属计算的钴催化剂浓度在0.4至 相对于底部水相的总重量为1.7质量％。 在稳态运行期间，反应器中的底部水相的水平保持恒定。

    Process for preparing higher oxo alcohols from olefin mixtures by two-stage hydroformylation
    3.
    发明授权
    Process for preparing higher oxo alcohols from olefin mixtures by two-stage hydroformylation 失效
    通过两步加氢甲酰化由烯烃混合物制备高级羰基合成醇的方法

    公开(公告)号：US06331657B1

    公开(公告)日：2001-12-18

    申请号：US09396371

    申请日：1999-09-15

    申请人： Alfred Kaizik ,  Bernhard Scholz ,  Walter Toetsch ,  Wilfried Bueschken ,  Franz Nierlich

    发明人： Alfred Kaizik ,  Bernhard Scholz ,  Walter Toetsch ,  Wilfried Bueschken ,  Franz Nierlich

    IPC分类号： C07C2916

    CPC分类号： C07C31/125 ,  C07C29/141 ,  C07C45/50 ,  C07C47/02

    摘要： A process for preparing higher oxo alcohols from mixtures of isomeric olefins having from 5 to 24 carbon atoms by two-stage hydroformylation in the presence of a cobalt catalyst or rhodium catalyst at elevated temperature and at elevated pressure, which comprises selectively hydrogenating the first hydroformylation stage reaction mixture, separating the hydrogenation mixture in a distillation into crude alcohol and low-boilers predominantly consisting of olefins, passing these low-boilers to the second hydroformylation stage, again selectively hydrogenating the second hydroformylation stage reaction mixture, separating the hydrogenation mixture in one distillation into crude alcohol and low-boilers, working up the crude alcohol by distillation to pure alcohol and taking off at least some of the low-boilers to discharge saturated hydrocarbons.

    摘要翻译： 在钴催化剂或铑催化剂存在下，在升高的温度和升高的压力下，通过两步加氢甲酰化，从具有5至24个碳原子的异构烯烃的混合物制备高级羰基合成醇的方法，该方法包括选择性氢化第一加氢甲酰化阶段 将蒸馏中的氢化混合物分离成粗醇和主要由烯烃组成的低沸点，将这些低沸点通到第二加氢甲酰化阶段，再次选择性氢化第二加氢甲酰化反应混合物，在一次蒸馏中分离氢化混合物 进入粗酒精和低沸点锅炉，通过蒸馏将粗醇加工成纯酒精，并将至少一些低沸点物质排出饱和碳氢化合物。

    Multistage process for the preparation of oxo aldehydes and/or alcohols
    4.
    发明授权
    Multistage process for the preparation of oxo aldehydes and/or alcohols 有权
    用于制备羰基醛和/或醇的多步法

    公开(公告)号：US06482992B2

    公开(公告)日：2002-11-19

    申请号：US09904893

    申请日：2001-07-16

    申请人： Bernhard Scholz ,  Franz Nierlich ,  Alfred Kaizik ,  Dieter Hess ,  Wilfried Bueschken ,  Klaus-Diether Wiese ,  Dirk Roettger ,  Guido Protzmann

    发明人： Bernhard Scholz ,  Franz Nierlich ,  Alfred Kaizik ,  Dieter Hess ,  Wilfried Bueschken ,  Klaus-Diether Wiese ,  Dirk Roettger ,  Guido Protzmann

    IPC分类号： C07C4550

    CPC分类号： C07C45/50 ,  C07C29/16 ,  C07C31/125 ,  C07C47/02

    摘要： Olefins are hydroformylated to give alcohols and/or aldehydes in a plurality of hydroformylation stages, each of which comprises: a) hydroformylating olefins having a carbon atom content of 6 to 24 carbon atoms in the presence of a cobalt- or rhodium catalyst in a reactor to the point of conversion of olefin reactant to product of 20 to 98%; b) removing the catalyst from the resulting liquid discharged from the reactor; c) separating the resulting liquid hydroformylation mixture into a low-boiler fraction comprising olefins and paraffins, and a bottoms fraction comprising aldehydes and/or alcohols; and d) reacting the olefins present in the low-boiler fraction in subsequent process stages comprising steps a, b and c and combining the bottoms fractions of process steps c) of all process stages.

    摘要翻译： 烯烃被加氢甲酰化以在多个加氢甲酰化阶段中产生醇和/或醛，其各自包括：a）在反应器中的钴或铑催化剂存在下，碳原子含量为6至24个碳原子的烯烃加氢甲酰化 到烯烃反应物转化为产物的程度为20至98％; b）从从反应器排出的所得液体中除去催化剂; c）将所得液体加氢甲酰化混合物分离成包含烯烃和链烷烃的低沸点馏分，以及 包含醛和/或醇的底部馏分; 和在下列工艺阶段中存在的低沸点馏分中存在的烯烃反应，包括步骤a，b和c，并组合所有工艺步骤的工艺步骤c）的底部馏分。

    Process for the hydrogenation of hydroformylation mixtures
    8.
    发明授权
    Process for the hydrogenation of hydroformylation mixtures 失效
    加氢甲酰化混合物氢化的方法

    公开(公告)号：US06680414B2

    公开(公告)日：2004-01-20

    申请号：US10014517

    申请日：2001-12-14

    申请人： Cord Knoop ,  Bernhard Scholz ,  Alfred Kaizik ,  Dietmar Gubisch ,  Joachim Schuler ,  Walter Tötsch ,  Wilfried Büschken

    发明人： Cord Knoop ,  Bernhard Scholz ,  Alfred Kaizik ,  Dietmar Gubisch ,  Joachim Schuler ,  Walter Tötsch ,  Wilfried Büschken

    IPC分类号： C07C2700

    CPC分类号： C07C29/141 ,  C07C31/125

    摘要： The present invention provides a process, which includes: in a homogeneous liquid phase including water, and over a fixed-bed catalyst, continuously hydrogenating at least one hydroformylation product obtained from a hydroformylation of one or more C4-16 olefins to produce at least one output mixture; wherein the fixed-bed catalyst includes at least one element of transition group eight of the Periodic Table of the Elements; wherein the output mixture includes at least one corresponding alcohol and from 0.05 to 10% by weight of water; and wherein in a steady-state operation of the process, from 3 to 50% more hydrogen is fed to the hydrogenation than is consumed by the hydrogenation.

    摘要翻译： 本发明提供了一种方法，其包括：在均匀的液相中包括水，并且在固定床催化剂上，连续氢化由一种或多种C 4-6-16烯烃的加氢甲酰化得到的至少一种加氢甲酰化产物，以产生至少一种 输出混合物;其中固定床催化剂包括元素周期表第八族中至少一种元素;其中所述输出混合物包括至少一种相应的醇和0.05至10重量％的水;并且其中在 该方法的稳态操作，比氢化消耗更多的氢被加入到氢化中3至50％。

    Method for acquiring a 3D image dataset freed of traces of a metal object
    10.
    发明申请
    Method for acquiring a 3D image dataset freed of traces of a metal object 有权
    用于获取没有金属物体痕迹的3D图像数据集的方法

    公开(公告)号：US20120237115A1

    公开(公告)日：2012-09-20

    申请号：US13420706

    申请日：2012-03-15

    申请人： Christopher Rohkohl ,  Bernhard Scholz

    发明人： Christopher Rohkohl ,  Bernhard Scholz

    IPC分类号： G06K9/00

    CPC分类号： G06T19/00 ,  A61B6/03 ,  A61B6/12 ,  A61B6/5258 ,  G06T7/11 ,  G06T11/005 ,  G06T2210/41 ,  G06T2211/424

    摘要： An interpolation of data values is performed during the acquisition of a 3D image dataset which is free of traces of a metal object imaged in the underlying 2D image datasets. A target function is defined into which data values of the 3D image dataset that are dependent on said substitute data values are incorporated following preprocessing. The substitute data values are then varied iteratively until the value of the target function satisfies a predetermined criterion. Residual artifacts that still persist following the interpolation can thus be effectively reduced.

    摘要翻译： 在获取3D图像数据集的过程中执行数据值的内插，该3D图像数据集没有在下面的2D图像数据集中成像的金属物体的痕迹。 定义目标函数，其中在预处理之后并入依赖于所述替代数据值的3D图像数据集的数据值。 然后，替代数据值被迭代地改变，直到目标函数的值满足预定标准。 因此，可以有效地减少在插补之后仍然存在的残余伪影。