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    Highly crystalline propylene homopolymers
    1.
    发明授权
    Highly crystalline propylene homopolymers 失效
    高度结晶的丙烯均聚物

    公开(公告)号：US07022795B1

    公开(公告)日：2006-04-04

    申请号：US09041698

    申请日：1998-03-13

    申请人： Stephan Hüffer ,  Joachim Rösch ,  Stefan Seelert ,  Franz Langhauser ,  Dieter Lilge ,  Roland Hingmann ,  Günther Schweier

    发明人： Stephan Hüffer ,  Joachim Rösch ,  Stefan Seelert ,  Franz Langhauser ,  Dieter Lilge ,  Roland Hingmann ,  Günther Schweier

    IPC分类号： C08F110/06 ,  C08F4/646 ,  C08F4/649

    CPC分类号： C08F10/00 ,  C08F110/06 ,  C08F4/651 ,  C08F4/6546 ,  C08F2500/12

    摘要： Propylene homopolymers, wherein, in their separation according to tacticity by first dissolving the polymers in boiling xylene, then cooling the solution to 25° C. at a cooling rate of 10° C./h and then, with ascending temperature, separating the propylene homopolymers into fractions of different tacticity, either one or more of the conditions that i) the fraction of propylene homopolymers which remains undissolved on heating the cooled propylene homopolymer solution to 112° C. is greater than 20% by weight or ii) the fraction of propylene homopolymers which remains undissolved on heating the cooled propylene homopolymer solution to 117° C. is greater than 8% by weight or iii) the fraction of propylene homopolymers which remains undissolved on heating the cooled propylene homopolymer solution to 122° C. is greater than 1% by weight, are satisfied.

    摘要翻译： 丙烯均聚物，其中通过首先将聚合物溶解在沸腾的二甲苯中，根据立构规整度的分离，然后以10℃/小时的冷却速率将溶液冷却至25℃，然后在升高温度下分离丙烯 将均聚物分成不同立构规整度的一个或多个条件，i）在将冷却的丙烯均聚物溶液加热至112℃时保持未溶解的丙烯均聚物的分数大于20重量％或ii） 在将冷却的丙烯均聚物溶液加热至117℃时保持未溶解的丙烯均聚物大于8重量％或iii）在将冷却的丙烯均聚物溶液加热至122℃时保持未溶解的丙烯均聚物的分数大于 1重量％。

    Catalyst systems of the Ziegler-Natta type
    2.
    发明授权
    Catalyst systems of the Ziegler-Natta type 失效
    齐格勒 - 纳塔型催化剂系统

    公开(公告)号：US06524995B2

    公开(公告)日：2003-02-25

    申请号：US09750715

    申请日：2001-01-02

    申请人： Wolf Spaether ,  Stephan Hüffer ,  John Lynch ,  Wolfgang Bidell ,  Joachim Rösch ,  Günther Schweier ,  Roland Hingmann ,  Alexandre Segul ,  Rainer Hemmerich ,  Ingo Treffkorn

    发明人： Wolf Spaether ,  Stephan Hüffer ,  John Lynch ,  Wolfgang Bidell ,  Joachim Rösch ,  Günther Schweier ,  Roland Hingmann ,  Alexandre Segul ,  Rainer Hemmerich ,  Ingo Treffkorn

    IPC分类号： B01J2302

    CPC分类号： C08F10/00 ,  C08F110/06 ,  C08F4/025 ,  C08F4/6546 ,  C08F2500/12 ,  C08F2500/24

    摘要： Catalyst systems of the Ziegler-Natta type comprise as active constituents a) a solid component comprising a compound of titanium or vanadium, a compound of magnesium, a particulate inorganic oxide as support and an internal electron donor compound, and as cocatalyst b) an aluminum compound and c) if desired, a further, external electron donor compound, wherein the particulate, inorganic oxide used has a specific surface area of from 350 to 1000 m2/g and a mean particle diameter {overscore (D)} in the range from 5 to 60 &mgr;m and comprises particles which are composed of primary particles having a mean particle diameter {overscore (d)} in the range from 1 to 10 &mgr;m and contain voids or channels between the primary particles, where the macroscopic proportion of voids or channels having a diameter of greater than 1 &mgr;m in the particles of the inorganic oxides is in the range from 5 to 30% by volume and the molar ratio of the compound of magnesium to the particulate, inorganic oxide is from 0.5:1 to 2.0:1.

    摘要翻译： 齐格勒 - 纳塔型的催化剂体系包括作为活性成分的a）包含钛或钒的化合物的固体组分，镁的化合物，作为载体的颗粒状无机氧化物和内部电子给体化合物，以及作为助催化剂）铝化合物和 ），其中所用的颗粒状无机氧化物的比表面积为350〜1000m2 / g，平均粒径（超芯（D在5〜60μm的范围内）和 包含由平均粒径（超芯（d在1-10μm范围内）并且在初级颗粒之间含有空隙或通道的初级颗粒组成的颗粒，其中空隙或通道的宏观比例具有大于1的直径 无机氧化物颗粒中的母体在5至30体积％的范围内，镁与颗粒的无机氧化物的摩尔比为0.5:1至 2.0：1。

    Random propylene copolymers
    7.
    发明授权
    Random propylene copolymers 有权
    无规丙烯共聚物

    公开(公告)号：US07026421B2

    公开(公告)日：2006-04-11

    申请号：US10971079

    申请日：2004-10-25

    申请人： David Appleyard ,  Franz Langhauser ,  Murray Horton ,  Roland Hingmann ,  Günther Schweier ,  Volker Rauschenberger ,  Ingolf Hennig ,  Dieter Lilge ,  Werner Schöne ,  Meinolf Kersting

    发明人： David Appleyard ,  Franz Langhauser ,  Murray Horton ,  Roland Hingmann ,  Günther Schweier ,  Volker Rauschenberger ,  Ingolf Hennig ,  Dieter Lilge ,  Werner Schöne ,  Meinolf Kersting

    IPC分类号： C08F210/06 ,  C08F210/08

    CPC分类号： D01F6/30 ,  C08F210/06 ,  C08F210/16 ,  Y10T428/31938 ,  C08F4/6546 ,  C08F210/08 ,  C08F2500/12

    摘要： Random copolymers of propylene with other 1-alkenes having up to carbon atoms, whose content of comonomers is in the range from 0.7 to 1.4% by weight if the only comonomer present in the propylene copolymers is ethylene, or whose content of comonomers is in the range from 0.7 to 3.0% by weight if at least one C4–C10-1-alkene is present as comonomer, and whose cold-xylene-soluble fraction is from 1.0 to 2.5% by weight if ethylene is present as a comonomer in the propylene copolymers, or whose cold-xylene-soluble fraction is from 0.75 to 2.0% by weight if the only comonomers present are C4–C10-1-alkenes, and a process for preparing the random copolymers of propylene is described, as is their use for producing films, fibers or moldings, and also the films, fibers and moldings themselves and biaxially stretched films made from random propylene copolymers of this type and processes for their production.

    摘要翻译： 丙烯与具有至多碳原子的其它1-烯烃的无规共聚物，如果丙烯共聚物中存在的共聚单体中唯一的共聚单体为共聚单体，其共聚单体的含量为0.7-1.4重量％，或其共聚单体的含量为 如果至少一个C 4 -C 10 - 1-烯烃作为共聚单体存在，其冷二甲苯可溶成分为 如果乙烯作为丙烯共聚物中的共聚单体存在，则其重量为1.0至2.5重量％，或者如果仅存在共聚单体为C 4 - 4，则冷二甲苯可溶成分为0.75-2.0重量％ 描述了用于制备膜，纤维或模制品的方法，以及薄膜，纤维和模制品本身以及双轴的方法制备丙烯的无规共聚物的方法。 由这种类型的无规丙烯共聚物制成的拉伸薄膜及其生产方法。

    Catalyst systems of the Ziegler-Natta type
    9.
    发明授权
    Catalyst systems of the Ziegler-Natta type 失效
    齐格勒 - 纳塔型催化剂系统

    公开(公告)号：US06200922B1

    公开(公告)日：2001-03-13

    申请号：US08869761

    申请日：1997-06-05

    申请人： Stephan Hüffer ,  Wolfgang Bidell ,  Patrik Müller ,  Ulrich Moll ,  Roland Hingmann ,  Günther Schweier

    发明人： Stephan Hüffer ,  Wolfgang Bidell ,  Patrik Müller ,  Ulrich Moll ,  Roland Hingmann ,  Günther Schweier

    IPC分类号： B01J2106

    CPC分类号： C08F10/00 ,  C08F110/06 ,  C08F4/6465 ,  C08F4/025 ,  C08F4/6546 ,  C08F2500/12 ,  C08F2500/24

    摘要： The catalyst systems comprise as active constituents a) a titanium-containing solid component comprising a compound of titanium, a compound of magnesium, a halogen, an inorganic oxide as support and a carboxylic ester as electron donor compound, and also, as cocatalyst, b) an aluminum compound and c) optionally a further electron donor compound, wherein the inorganic oxide used has a pH of from 1 to 6, an average particle diameter of from 5 to 200 &mgr;m, an average primary particle diameter of from 1 to 20 &mgr;M and voids or channels having an average diameter of from 0.1 to 20 &mgr;m and a macroscopic share of the volume of the overall particle within the range from 5 to 30%.

    摘要翻译： 催化剂体系包括作为活性成分的含钛固体组分，其包含钛化合物，镁化合物，卤素，作为载体的无机氧化物和作为电子给体化合物的羧酸酯的化合物，以及作为助催化剂的b） 铝化合物和任选的另外的电子给体化合物，其中使用的无机氧化物的pH为1至6，平均粒径为5至200μm，平均一次粒径为1至20μm，空隙 或平均直径为0.1-20μm的通道，并且整个颗粒的体积的宏观份额在5至30％的范围内。