公开(公告)号：US06589905B1

公开(公告)日：2003-07-08

申请号：US09720881

申请日：2001-01-02

申请人： David Fischer ,  Wolfgang Bidell ,  Ulrich Moll ,  Joachim Rösch ,  Franz Langhauser ,  Roland Hingmann ,  Heike Gregorius ,  Carsten Süling ,  Günther Schweier

发明人： David Fischer ,  Wolfgang Bidell ,  Ulrich Moll ,  Joachim Rösch ,  Franz Langhauser ,  Roland Hingmann ,  Heike Gregorius ,  Carsten Süling ,  Günther Schweier

IPC分类号： B01J2300

CPC分类号： C08F10/06 ,  C08F4/65904 ,  C08F4/65912 ,  C08F4/65927 ,  C08F110/06 ,  C08F4/65916 ,  C08F4/025 ,  C08F2500/18 ,  C08F2500/24 ,  C08F2500/12 ,  C08F2500/17 ,  C08F2500/03

摘要： The invention relates to a method for producing a supported catalyst which contains metal, or a supported catalyst constituent which contains metal by impregnating a supporting material with an impregnating solution containing the metal constituent, whereby the impregnating solution flows through the supporting material.

摘要翻译： 本发明涉及含有金属的负载型催化剂的制造方法或通过用含有金属成分的浸渍溶液浸渍担载材料而含有金属的负载型催化剂成分，由此浸渍液流过支撑材料。

公开(公告)号：US06812185B2

公开(公告)日：2004-11-02

申请号：US10402301

申请日：2003-07-30

申请人： David Fischer ,  Wolfgang Bidell ,  Ulrich Moll ,  Joachim Rösch ,  Franz Langhauser ,  Roland Hingmann ,  Heike Gregorius ,  Carsten Süling ,  Günther Schweier

发明人： David Fischer ,  Wolfgang Bidell ,  Ulrich Moll ,  Joachim Rösch ,  Franz Langhauser ,  Roland Hingmann ,  Heike Gregorius ,  Carsten Süling ,  Günther Schweier

IPC分类号： C08F464

CPC分类号： C08F10/06 ,  C08F4/65904 ,  C08F4/65912 ,  C08F4/65927 ,  C08F110/06 ,  C08F4/65916 ,  C08F4/025 ,  C08F2500/18 ,  C08F2500/24 ,  C08F2500/12 ,  C08F2500/17 ,  C08F2500/03

摘要： In a process for preparing a metal-containing supported catalyst or a metal-containing supported catalyst component by impregnation of a support material with an impregnation solution comprising the metal component, the impregnation solution flows through the support material.

公开(公告)号：US06265339B1

公开(公告)日：2001-07-24

申请号：US09202534

申请日：1998-12-16

申请人： Wolfgang Bidell ,  Franz Langhauser ,  Ulrich Moll ,  Ian David McKenzie ,  David Fischer ,  Roland Hingmann ,  Günther Schweier ,  Bernd Lothar Marczinke ,  Meinolf Kersting ,  Peter John Vaughan Jones ,  John Russell Grasmeder

发明人： Wolfgang Bidell ,  Franz Langhauser ,  Ulrich Moll ,  Ian David McKenzie ,  David Fischer ,  Roland Hingmann ,  Günther Schweier ,  Bernd Lothar Marczinke ,  Meinolf Kersting ,  Peter John Vaughan Jones ,  John Russell Grasmeder

IPC分类号： C08F416

CPC分类号： C08F10/00 ,  C08F4/61908 ,  C08F4/61912 ,  C08F4/61916 ,  C08F4/6192 ,  C08F4/61927 ,  C08F110/06 ,  Y10S526/943 ,  C08F2500/12 ,  C08F2500/17 ,  C08F2500/03 ,  C08F2500/24

摘要： A process for preparing a supported transition metal catalyst comprising a particulate organic or inorganic support material, a transition metal complex and a compound capable of forming metallocenium ions comprises the following process steps: a) contacting a solution of a compound capable of forming metallocenium ions with a second solvent in which this compound is only sparingly soluble, in the presence of the support material, b) removing at least part of the solvent from the support material and c) contacting a solution of a mixture of a compound capable of forming metallocenium ions and a transition metal complex with a second solvent in which this mixture is only sparingly soluble, in the presence of the support material obtained as described in a) and b).

摘要翻译： 一种制备负载型过渡金属催化剂的方法，其包括颗粒状有机或无机载体材料，过渡金属络合物和能够形成金属茂离子的化合物包括以下工艺步骤：a）使能够形成金属茂离子的化合物的溶液与 在载体材料存在下，该化合物只有微溶的第二溶剂，b）从载体材料中除去至少一部分溶剂，和c）使能够形成金属茂离子的化合物的混合物和 在如a）和b）中所述获得的载体材料存在下，其中该混合物仅仅是微溶的第二溶剂的过渡金属络合物。

公开(公告)号：US06583253B1

公开(公告)日：2003-06-24

申请号：US09701943

申请日：2000-12-05

申请人： David Fischer ,  Peter John Vaughan Jones ,  Franz Langhauser ,  Wolfgang Bidell ,  Roland Hingmann ,  Günther Schweier ,  Bernd Lothar Marczinke ,  Meinolf Kersting ,  Ulrich Moll

发明人： David Fischer ,  Peter John Vaughan Jones ,  Franz Langhauser ,  Wolfgang Bidell ,  Roland Hingmann ,  Günther Schweier ,  Bernd Lothar Marczinke ,  Meinolf Kersting ,  Ulrich Moll

IPC分类号： C08F21000

CPC分类号： C08F210/16 ,  C08F4/65912 ,  C08F4/65927 ,  C08F210/06 ,  Y10S526/904 ,  Y10S526/943 ,  C08F4/65916 ,  C08F210/08 ,  C08F2500/03 ,  C08F210/14

摘要： Propene terpolymers consist of from 80 to 99.5 mol % of structural units derived from propene, from 0.1 to 15 mol % of structural units derived from ethene or a C4-C6-1-olefin (I) and from 0.1 to 15 mol % of structural units derived from a further C4-C12-1-olefin (II) which is different from the C4-C6-1-olefin (I), which propene terpolymers have a proportion of regioregular ′1-2′-inserted propene units corresponding to the formula (1) [ ′ ⁢ 1 - 2 ′ ] [ ′ ⁢ 1 - 2 ′ ] + [ ′ ⁢ 2 - 1 ′ ] + [ ′ ⁢ 1 - 3 ′ ] ( 1 ) of more than 0.99, have a melting point (TM), determined from the DSC peak maximum, of less than 135° C. and a weight average molecular weight (MW) of more than 80,000 g/mol and have a xylene-soluble proportion (XS) in % by weight of the propene terpolymer which obeys the following inequality (2) XS≦1411.21 exp(−0.0591 TM[° C.])−0.05  (2).

摘要翻译： 丙烯三元共聚物由80至99.5摩尔％的衍生自丙烯的结构单元，0.1至15摩尔％的衍生自乙烯或C 4 -C 6 -1-烯烃（I）的结构单元和0.1至15摩尔％的结构单元组成 衍生自不同于C 4 -C 6 -1-烯烃（I）的另外的C 4 -C 12 -1-烯烃（II）的单元，该丙烯三元共聚物具有对应于区域规则'1-2'插入的丙烯单元的比例 式（1）大于0.99，由DSC峰值最大值确定的熔点（TM）小于135℃，重均分子量（MW）大于80,000g / mol，具有 二甲苯可溶比例（XS）按丙烯三元共聚物的重量百分比计，遵循以下不等式（2）

公开(公告)号：US06562478B1

公开(公告)日：2003-05-13

申请号：US09701941

申请日：2000-12-05

申请人： David Fischer ,  Bernd Lothar Marczinke ,  Werner Schöne ,  Franz Langhauser ,  Wolfgang Bidell ,  Roland Hingmann ,  Ulrich Moll ,  Meinolf Kersting ,  Günther Schweier ,  Peter John Vaughan Jones

发明人： David Fischer ,  Bernd Lothar Marczinke ,  Werner Schöne ,  Franz Langhauser ,  Wolfgang Bidell ,  Roland Hingmann ,  Ulrich Moll ,  Meinolf Kersting ,  Günther Schweier ,  Peter John Vaughan Jones

IPC分类号： B32B2732

CPC分类号： B32B27/08 ,  B29C47/0021 ,  B29C47/065 ,  B29C47/145 ,  B29C55/023 ,  B29K2995/0022 ,  B32B27/32 ,  B32B27/327 ,  B32B38/0008 ,  B32B2038/0028 ,  B32B2310/14 ,  B32B2553/00 ,  C08F210/06 ,  C08F210/16 ,  Y10T428/2495 ,  Y10T428/31913 ,  C08F210/08 ,  C08F2500/03 ,  C08F2500/20 ,  C08F210/14

摘要： A sealable coextruded film is made from at least one outer layer and from at least one base layer, where the outer layer is composed of a propylene terpolymer comprising from 80 to 99.5 mol % of structural units derived from propylene, from 0.2 to 15 mol % of structural units derived from ethene or from a C4-C6 1-olefin (I) and from 0.3 to 15 mol % of structural units derived from another C4-C12 1-olefin (II) different from the C4-C6 1-olefin (I), and where the propylene terpolymer has been prepared using metallocene catalysts.

摘要翻译： 可密封的共挤出膜由至少一个外层和至少一个基层制成，其中外层由丙烯三元共聚物组成，丙烯三元共聚物包含80-99.5mol％的衍生自丙烯的结构单元，0.2-15mol％ 衍生自乙烯或来自C 4 -C 6 1-烯烃（I）的结构单元和0.3至15摩尔％的衍生自不同于C 4 -C 6 1-烯烃的另外的C 4 -C 12 1-烯烃（II）的结构单元（ I），并且其中使用茂金属催化剂制备丙烯三元共聚物。

公开(公告)号：US06593442B2

公开(公告)日：2003-07-15

申请号：US09737848

申请日：2000-12-18

申请人： Wolfgang Bidell ,  Roland Hingmann ,  Franz Langhauser ,  Dieter Lilge ,  Volker Rauschenberger ,  Günther Schweier ,  Florian Stricker ,  Jürgen Suhm

发明人： Wolfgang Bidell ,  Roland Hingmann ,  Franz Langhauser ,  Dieter Lilge ,  Volker Rauschenberger ,  Günther Schweier ,  Florian Stricker ,  Jürgen Suhm

IPC分类号： C08F1006

CPC分类号： C08F297/08 ,  C08F4/65904 ,  C08F4/65908 ,  C08F4/65916 ,  C08F10/06 ,  C08F110/06 ,  C08F210/06 ,  C08L23/14 ,  C08L2205/02 ,  C08L2314/06 ,  Y10S264/901 ,  Y10S428/91 ,  Y10S526/905 ,  C08F4/65927 ,  C08F2/001 ,  C08L2666/04 ,  C08F2500/26 ,  C08F210/16

摘要： A semicrystalline propylene polymer composition with good suitability for producing biaxially oriented films and prepared by polymerizing propylene, ethylene and/or C4-C18-1-alkenes, where at least 50 mol % of the monomer units present arise from the polymerization of propylene. Also described is the use of the semicrystalline propylene polymer composition for producing films, fibers or moldings, the films, fibers and moldings made from these compositions, biaxially stretched films made from the semicrystalline propylene polymer compositions, and also a method for characterizing the semicrystalline propylene polymer compositions.

摘要翻译： 一种半结晶丙烯聚合物组合物，其具有良好的适用于生产双轴取向薄膜并通过聚合丙烯，乙烯和/或C 4 -C 18 -1-烯烃制备，其中存在至少50摩尔％的单体单元来自丙烯的聚合。 还描述了使用半结晶丙烯聚合物组合物来生产膜，纤维或模制品，由这些组合物制成的膜，纤维和模制品，由半结晶丙烯聚合物组合物制成的双轴向拉伸膜，以及用于表征半结晶丙烯 聚合物组合物。

公开(公告)号：US07022795B1

公开(公告)日：2006-04-04

申请号：US09041698

申请日：1998-03-13

申请人： Stephan Hüffer ,  Joachim Rösch ,  Stefan Seelert ,  Franz Langhauser ,  Dieter Lilge ,  Roland Hingmann ,  Günther Schweier

发明人： Stephan Hüffer ,  Joachim Rösch ,  Stefan Seelert ,  Franz Langhauser ,  Dieter Lilge ,  Roland Hingmann ,  Günther Schweier

IPC分类号： C08F110/06 ,  C08F4/646 ,  C08F4/649

CPC分类号： C08F10/00 ,  C08F110/06 ,  C08F4/651 ,  C08F4/6546 ,  C08F2500/12

摘要： Propylene homopolymers, wherein, in their separation according to tacticity by first dissolving the polymers in boiling xylene, then cooling the solution to 25° C. at a cooling rate of 10° C./h and then, with ascending temperature, separating the propylene homopolymers into fractions of different tacticity, either one or more of the conditions that i) the fraction of propylene homopolymers which remains undissolved on heating the cooled propylene homopolymer solution to 112° C. is greater than 20% by weight or ii) the fraction of propylene homopolymers which remains undissolved on heating the cooled propylene homopolymer solution to 117° C. is greater than 8% by weight or iii) the fraction of propylene homopolymers which remains undissolved on heating the cooled propylene homopolymer solution to 122° C. is greater than 1% by weight, are satisfied.

摘要翻译： 丙烯均聚物，其中通过首先将聚合物溶解在沸腾的二甲苯中，根据立构规整度的分离，然后以10℃/小时的冷却速率将溶液冷却至25℃，然后在升高温度下分离丙烯 将均聚物分成不同立构规整度的一个或多个条件，i）在将冷却的丙烯均聚物溶液加热至112℃时保持未溶解的丙烯均聚物的分数大于20重量％或ii） 在将冷却的丙烯均聚物溶液加热至117℃时保持未溶解的丙烯均聚物大于8重量％或iii）在将冷却的丙烯均聚物溶液加热至122℃时保持未溶解的丙烯均聚物的分数大于 1重量％。

公开(公告)号：US06733717B1

公开(公告)日：2004-05-11

申请号：US09601356

申请日：2000-08-01

申请人： Bernd Lothar Marczinke ,  Peter John Vaughan Jones ,  Meinolf Kersting ,  David Fischer ,  Franz Langhauser ,  Ulrich Moll ,  Wolfgang Bidell

发明人： Bernd Lothar Marczinke ,  Peter John Vaughan Jones ,  Meinolf Kersting ,  David Fischer ,  Franz Langhauser ,  Ulrich Moll ,  Wolfgang Bidell

IPC分类号： B29C4906

CPC分类号： B29C49/0005 ,  B29B2911/1402 ,  B29B2911/14026 ,  B29B2911/14033 ,  B29B2911/1404 ,  B29B2911/14106 ,  B29B2911/14133 ,  B29C49/06 ,  C08F110/06 ,  C08F210/06 ,  Y10T428/1352 ,  C08F2500/12 ,  C08F2500/15 ,  C08F2500/03 ,  C08F210/16

摘要： Injection stretch blow molded containers are obtainable from olefin polymers, comprising homopolymers of propylene or copolymers of propylene with other C2-C10-alk-1-enes, which are obtainable by polymerizing the corresponding monomers with metallocene catalysts. Processes for producing injection stretch blow molded containers from olefin polymers, and also the use of olefin polymers for producing injection stretch blow molded containers, are described.

摘要翻译： 注射拉伸吹塑容器可从包含丙烯均聚物或丙烯与其它C 2 -C 10 - 烷-1-烯的共聚物的烯烃聚合物获得，其可通过使金属茂催化剂聚合相应的单体而获得。用于生产注射拉伸吹塑成型 描述了烯烃聚合物的容器，以及烯烃聚合物用于生产注射拉伸吹塑容器的用途。

公开(公告)号：US07001965B2

公开(公告)日：2006-02-21

申请号：US10971080

申请日：2004-10-25

申请人： David Appleyard ,  Franz Langhauser ,  Murray Horton ,  Roland Hingmann ,  Günther Schweier ,  Volker Rauschenberger ,  Ingolf Hennig ,  Dieter Lilge ,  Werner Schöne ,  Meinolf Kersting

发明人： David Appleyard ,  Franz Langhauser ,  Murray Horton ,  Roland Hingmann ,  Günther Schweier ,  Volker Rauschenberger ,  Ingolf Hennig ,  Dieter Lilge ,  Werner Schöne ,  Meinolf Kersting

IPC分类号： C08F210/06

CPC分类号： D01F6/30 ,  C08F210/06 ,  C08F210/16 ,  Y10T428/31938 ,  C08F4/6546 ,  C08F210/08 ,  C08F2500/12

摘要： Random copolymers of propylene with other 1-alkenes having up to carbon atoms, whose content of comonomers is in the range from 0.7 to 1.4% by weight if the only comonomer present in the propylene copolymers is ethylene, or whose content of comonomers is in the range from 0.7 to 3.0% by weight if at least one C4–C10-1-alkene is present as comonomer, and whose cold-xylene-soluble fraction is from 1.0 to 2.5% by weight if ethylene is present as a comonomer in the propylene copolymers, or whose cold-xylene-soluble fraction is from 0.75 to 2.0% by weight if the only comonomers present are C4–C10-1-alkenes, and a process for preparing the random copolymers of propylene is described, as is their use for producing films, fibers or moldings, and also the films, fibers and moldings themselves and biaxially stretched films made from random propylene copolymers of this type and processes for their production.

摘要翻译： 丙烯与其中具有至多碳的其它1-烯烃的无规共聚物

公开(公告)号：US07026421B2

公开(公告)日：2006-04-11

申请号：US10971079

申请日：2004-10-25

申请人： David Appleyard ,  Franz Langhauser ,  Murray Horton ,  Roland Hingmann ,  Günther Schweier ,  Volker Rauschenberger ,  Ingolf Hennig ,  Dieter Lilge ,  Werner Schöne ,  Meinolf Kersting

发明人： David Appleyard ,  Franz Langhauser ,  Murray Horton ,  Roland Hingmann ,  Günther Schweier ,  Volker Rauschenberger ,  Ingolf Hennig ,  Dieter Lilge ,  Werner Schöne ,  Meinolf Kersting

IPC分类号： C08F210/06 ,  C08F210/08

CPC分类号： D01F6/30 ,  C08F210/06 ,  C08F210/16 ,  Y10T428/31938 ,  C08F4/6546 ,  C08F210/08 ,  C08F2500/12

摘要： Random copolymers of propylene with other 1-alkenes having up to carbon atoms, whose content of comonomers is in the range from 0.7 to 1.4% by weight if the only comonomer present in the propylene copolymers is ethylene, or whose content of comonomers is in the range from 0.7 to 3.0% by weight if at least one C4–C10-1-alkene is present as comonomer, and whose cold-xylene-soluble fraction is from 1.0 to 2.5% by weight if ethylene is present as a comonomer in the propylene copolymers, or whose cold-xylene-soluble fraction is from 0.75 to 2.0% by weight if the only comonomers present are C4–C10-1-alkenes, and a process for preparing the random copolymers of propylene is described, as is their use for producing films, fibers or moldings, and also the films, fibers and moldings themselves and biaxially stretched films made from random propylene copolymers of this type and processes for their production.

摘要翻译： 丙烯与具有至多碳原子的其它1-烯烃的无规共聚物，如果丙烯共聚物中存在的共聚单体中唯一的共聚单体为共聚单体，其共聚单体的含量为0.7-1.4重量％，或其共聚单体的含量为 如果至少一个C 4 -C 10 - 1-烯烃作为共聚单体存在，其冷二甲苯可溶成分为 如果乙烯作为丙烯共聚物中的共聚单体存在，则其重量为1.0至2.5重量％，或者如果仅存在共聚单体为C 4 - 4，则冷二甲苯可溶成分为0.75-2.0重量％ 描述了用于制备膜，纤维或模制品的方法，以及薄膜，纤维和模制品本身以及双轴的方法制备丙烯的无规共聚物的方法。 由这种类型的无规丙烯共聚物制成的拉伸薄膜及其生产方法。